Beta Diketiminate Ligands As Supports For Alkaline Earth And Aluminum Complexes Synthesis Characterization And Reactivity Studies

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The Group 13 Metals Aluminium, Gallium, Indium and Thallium

Author : Simon Aldridge
Publisher : John Wiley & Sons
ISBN 13 : 0470976683
Total Pages : 990 pages
Book Rating : 4.4/5 (79 download)

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Book Synopsis The Group 13 Metals Aluminium, Gallium, Indium and Thallium by : Simon Aldridge

Download or read book The Group 13 Metals Aluminium, Gallium, Indium and Thallium written by Simon Aldridge and published by John Wiley & Sons. This book was released on 2011-02-10 with total page 990 pages. Available in PDF, EPUB and Kindle. Book excerpt: The last two decades have seen a renaissance in interest in the chemistry of the main group elements. In particular research on the metals of group 13 (aluminium, gallium, indium and thallium) has led to the synthesis and isolation of some very novel and unusual molecules, with implications for organometallic synthesis, new materials development, and with biological, medical and, environmental relevance. The Group 13 Metals Aluminium, Gallium, Indium and Thallium aims to cover new facts, developments and applications in the context of more general patterns of physical and chemical behaviour. Particular attention is paid to the main growth areas, including the chemistry of lower formal oxidation states, cluster chemistry, the investigation of solid oxides and hydroxides, advances in the formation of III-V and related compounds, the biological significance of Group 13 metal complexes, and the growing importance of the metals and their compounds in the mediation of organic reactions. Chapters cover: general features of the group 13 elements group 13 metals in the +3 oxidation state: simple inorganic compounds formal oxidation state +3: organometallic chemistry formal oxidation state +2: metal-metal bonded vs. mononuclear derivatives group 13 metals in the +1 oxidation state mixed or intermediate valence group 13 metal compounds aluminium and gallium clusters: metalloid clusters and their relation to the bulk phases, to naked clusters, and to nanoscaled materials simple and mixed metal oxides and hydroxides: solids with extended structures of different dimensionalities and porosities coordination and solution chemistry of the metals: biological, medical and, environmental relevance III-V and related semiconductor materials group 13 metal-mediated organic reactions The Group 13 Metals Aluminium, Gallium, Indium and Thallium provides a detailed, wide-ranging, and up-to-date review of the chemistry of this important group of metals. It will find a place on the bookshelves of practitioners, researchers and students working in inorganic, organometallic, and materials chemistry.

Molecular Clusters of the Main Group Elements

Author : Matthias Driess
Publisher : John Wiley & Sons
ISBN 13 : 3527614370
Total Pages : 460 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Molecular Clusters of the Main Group Elements by : Matthias Driess

Download or read book Molecular Clusters of the Main Group Elements written by Matthias Driess and published by John Wiley & Sons. This book was released on 2008-11-21 with total page 460 pages. Available in PDF, EPUB and Kindle. Book excerpt: With more than 20 contributions from leading research groups, this book provides essential information for chemists and materials scientists working with molecular clusters. It treats both homonuclear and heteronuclear clusters, including: the theory and concepts in main-group cluster chemistry, * novel boranes and heteroboranes, * silicon/germanium/tin clusters, * alkali metal suboxides, * clusters in alloys with mercury, * chalkogen clusters * and numerous other compound classes. The whole is illustrated by examples of the great potential for technical applications such as electron storage, cancer therapy and in optoelectronic devices. Its systematic coverage of all relevant main group elements makes this the prime reference source in the field.

Alkaline-Earth Metal Compounds

Author : Sjoerd Harder
Publisher : Springer
ISBN 13 : 3642362702
Total Pages : 282 pages
Book Rating : 4.6/5 (423 download)

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Book Synopsis Alkaline-Earth Metal Compounds by : Sjoerd Harder

Download or read book Alkaline-Earth Metal Compounds written by Sjoerd Harder and published by Springer. This book was released on 2013-07-20 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Activation of Small Molecules

Author : William B. Tolman
Publisher : John Wiley & Sons
ISBN 13 : 3527609377
Total Pages : 382 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Activation of Small Molecules by : William B. Tolman

Download or read book Activation of Small Molecules written by William B. Tolman and published by John Wiley & Sons. This book was released on 2006-12-13 with total page 382 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first to combine both the bioinorganic and the organometallic view, this handbook provides all the necessary knowledge in one convenient volume. Alongside a look at CO2 and N2 reduction, the authors discuss O2, NO and N2O binding and reduction, activation of H2 and the oxidation catalysis of O2. Edited by the highly renowned William Tolman, who has won several awards for his research in the field.

Comprehensive Coordination Chemistry II

Author : J. A. McCleverty
Publisher : Newnes
ISBN 13 : 0080913164
Total Pages : 11845 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Comprehensive Coordination Chemistry II by : J. A. McCleverty

Download or read book Comprehensive Coordination Chemistry II written by J. A. McCleverty and published by Newnes. This book was released on 2003-12-03 with total page 11845 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Coordination Chemistry II (CCC II) is the sequel to what has become a classic in the field, Comprehensive Coordination Chemistry, published in 1987. CCC II builds on the first and surveys new developments authoritatively in over 200 newly comissioned chapters, with an emphasis on current trends in biology, materials science and other areas of contemporary scientific interest.

Inorganic Syntheses, Volume 35

Author :
Publisher : John Wiley & Sons
ISBN 13 : 0470651547
Total Pages : 221 pages
Book Rating : 4.4/5 (76 download)

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Book Synopsis Inorganic Syntheses, Volume 35 by :

Download or read book Inorganic Syntheses, Volume 35 written by and published by John Wiley & Sons. This book was released on 2010-08-13 with total page 221 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Inorganic Syntheses series provides all users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely compounds. Includes complete, up-to-date procedures involving important inorganic substances Contains subject, contributor, and formula indexes

Early Main Group Metal Catalysis

Author : Sjoerd Harder
Publisher : John Wiley & Sons
ISBN 13 : 3527344489
Total Pages : 400 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Early Main Group Metal Catalysis by : Sjoerd Harder

Download or read book Early Main Group Metal Catalysis written by Sjoerd Harder and published by John Wiley & Sons. This book was released on 2020-04-06 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain educational elements and deal with concepts illustrated by examples that cover the main developments. After a short introduction on polar organometallic chemistry and synthesis of early main group metal complexes, a variety of catalytic reactions are described, e.g. polymerization of alkenes, hydroamination and phosphination reactions, hydrosilylation, hydroboration and hydrogenation catalysis, as well as enantioselective and Lewis-acid catalysis. The book addresses organic chemists and researchers in industry interested in the state-of-the-art and new possibilities of early main group metal catalysis as well as newcomers to the field. Written by a team of leaders in the field, it is a very welcome addition to the area of main group metal chemistry, and to the field of catalysis.

Iron-Catalysed Hydrofunctionalisation of Alkenes and Alkynes

Author : Mark Greenhalgh
Publisher : Springer
ISBN 13 : 9783319815688
Total Pages : 306 pages
Book Rating : 4.8/5 (156 download)

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Book Synopsis Iron-Catalysed Hydrofunctionalisation of Alkenes and Alkynes by : Mark Greenhalgh

Download or read book Iron-Catalysed Hydrofunctionalisation of Alkenes and Alkynes written by Mark Greenhalgh and published by Springer. This book was released on 2018-05-27 with total page 306 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis gives a thorough account of the development of iron-catalysed hydrosilylation, hydroboration and hydromagnesiation reactions. With extraordinary referencing and scientific argument, Mark Greenhalgh describes the development of methodologies which require only commercially available materials and non-specialised techniques. The intention of this approach is to ensure the science can be adopted widely by the chemical community. In addition to an insight into the processes involved in methodology development, Greenhalgh discusses and determines the relevant reaction mechanisms. This thesis provides not only the most thorough review of the area, but offers a level of insight well beyond that expected from a Ph.D. student. The work in this thesis has been published at the highest level, and the results and ideas have led to 3 industry-funded Ph.D. studentships and grant income in excess of £1 million.

Selective Catalysis for Renewable Feedstocks and Chemicals

Author : Kenneth M. Nicholas
Publisher : Springer
ISBN 13 : 3319086545
Total Pages : 265 pages
Book Rating : 4.3/5 (19 download)

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Book Synopsis Selective Catalysis for Renewable Feedstocks and Chemicals by : Kenneth M. Nicholas

Download or read book Selective Catalysis for Renewable Feedstocks and Chemicals written by Kenneth M. Nicholas and published by Springer. This book was released on 2014-09-13 with total page 265 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb

Author : Vladimir Ya. Lee
Publisher : John Wiley & Sons
ISBN 13 : 1119956269
Total Pages : 390 pages
Book Rating : 4.1/5 (199 download)

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Book Synopsis Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb by : Vladimir Ya. Lee

Download or read book Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb written by Vladimir Ya. Lee and published by John Wiley & Sons. This book was released on 2011-07-22 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt: Until recently the low-coordinate compounds of the heavier elements of group 14 were known only as transient, unstable species which were difficult to isolate. However recent developments have led to the stabilisation of these compounds and today heavier group 14 element cations, radicals, anions, carbene analogues, alkene and alkyne analogues and aromatics have all been prepared as highly reactive, stable, fully characterizable and readily available organometallic reagents. Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb describes the chemistry of this exciting new class of organometallics, with an emphasis on their major similarities and differences with the analogous species in organic chemistry. Topics covered include include the synthesis, structure, reactions and synthetic applications of : Si-, Ge-, Sn and Pb-centered cations, radicals and anions heavy analogues of carbenes: silylenes, germylenes, stannylenes and plumbylenes heavy analogues of alkenes: disilenes, digermenes, distannenes, diplumbenes heavy analogues of alkynes: disilynes, digermynes, distannynes, diplumbynes, and their valence isomers heteronuclear derivatives: silenes, germenes, stannenes, silagermenes, silastannenes, germastannenes heavy analogues of alkenes of the type: >E14=E13-, >E14=E15-, >E14=E16 [where E13, E14, E15 and E16 are elements of the groups 13, 14, 15 and 16] cyclic compounds (three-, four-, five-, and six-membered rings) heavy analogues of 1,3-dienes, allenes and other cumulenes heavy analogues of aromatic compounds; including a comparison between organometallic and organic aromaticity Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb is an essential guide to this emerging class of organometallic reagents for researchers and students in main group, organometallic, synthetic and silicon chemistry

Metal Amide Chemistry

Author : Michael Lappert
Publisher : John Wiley & Sons
ISBN 13 : 9780470740378
Total Pages : 370 pages
Book Rating : 4.7/5 (43 download)

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Book Synopsis Metal Amide Chemistry by : Michael Lappert

Download or read book Metal Amide Chemistry written by Michael Lappert and published by John Wiley & Sons. This book was released on 2008-12-23 with total page 370 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by internationally recognised leaders in the field, Metal Amide Chemistry is the authoritative survey of this important class of compounds, the first since Lappert and Power’s 1980 book “Metal and Metalloid Amides.” An introduction to the topic is followed by in-depth discussions of the amide compounds of: alkali metals alkaline earth metals zinc, cadmium and mercury the transition metals group 3 and lanthanide metals group 13 metals silicon and the group 14 metals group 15 metals the actinide metals Accompanied by a substantial bibliography, this is an essential guide for researchers and advanced students in academia and research working in synthetic organometallic, organic and inorganic chemistry, materials chemistry and catalysis.

Inorganic Syntheses

Author : Philip P. Power
Publisher : John Wiley & Sons
ISBN 13 : 1119477840
Total Pages : 288 pages
Book Rating : 4.1/5 (194 download)

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Book Synopsis Inorganic Syntheses by : Philip P. Power

Download or read book Inorganic Syntheses written by Philip P. Power and published by John Wiley & Sons. This book was released on 2018-07-04 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: The newest volume in the authoritative Inorganic Syntheses book series provides users of inorganic substances with detailed and foolproof procedures for the preparation of important and timely inorganic and organometallic compounds that can be used in reactions to develop new materials, drug targets, and bio-inspired chemical entities.

Zinc Catalysis

Author : Stephan Enthaler
Publisher : John Wiley & Sons
ISBN 13 : 3527335986
Total Pages : 326 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Zinc Catalysis by : Stephan Enthaler

Download or read book Zinc Catalysis written by Stephan Enthaler and published by John Wiley & Sons. This book was released on 2015-04-27 with total page 326 pages. Available in PDF, EPUB and Kindle. Book excerpt: Filling the gap in the market for comprehensive coverage of this hot topic, this timely book covers a wide range of organic transformations, e. g. reductions of unsaturated compounds, oxidation reactions, Friedel-Crafts reactions, hydroamination reactions, depolymerizations, transformations of carbon dioxide, oxidative coupling reactions, as well as C-C, C-N, and C-O bond formation reactions. A chapter on the application of zinc catalysts in total synthesis is also included. With its aim of stimulating further research and discussion in the field, this is a valuable reference for professionals in academia and industry wishing to learn about the latest developments.

Molecular Metal-Metal Bonds

Author : Stephen T. Liddle
Publisher : John Wiley & Sons
ISBN 13 : 3527335412
Total Pages : 590 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Molecular Metal-Metal Bonds by : Stephen T. Liddle

Download or read book Molecular Metal-Metal Bonds written by Stephen T. Liddle and published by John Wiley & Sons. This book was released on 2015-06-22 with total page 590 pages. Available in PDF, EPUB and Kindle. Book excerpt: Systematically covering all the latest developments in the field, this is a comprehensive and handy introduction to metal-metal bonding. The chapters follow a uniform, coherent structure for a clear overview, allowing readers easy access to the information. The text covers such topics as synthesis, properties, structures, notable features, reactivity and examples of applications of the most important compounds in each group with metal-metal bonding throughout the periodic table. With its general remarks at the beginning of each chapter, this is a must-have reference for all molecular inorganic chemists, including PhD students and postdocs, as well as more experienced researchers.

Organophosphorus Chemistry

Author : David W. Allen
Publisher : Royal Society of Chemistry
ISBN 13 : 1849733775
Total Pages : 427 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Organophosphorus Chemistry by : David W. Allen

Download or read book Organophosphorus Chemistry written by David W. Allen and published by Royal Society of Chemistry. This book was released on 2012 with total page 427 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organophosphorus Chemistry provides a comprehensive and critical review of the recent literature. Coverage includes phosphines and their chalcogenides, phosphonium salts, low coordination number phosphorus compounds, penta- and hexa-coordinated compounds, quiquevalent phosphorus acids, nucleotides and nucleic aicds, ylides and related compounds, phosphazenes and the application of physical methods in the study of organophosphorus compounds.

N-Heterocyclic Carbenes

Author : Silvia Diez-Gonzalez
Publisher : Royal Society of Chemistry
ISBN 13 : 1782626816
Total Pages : 637 pages
Book Rating : 4.7/5 (826 download)

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Book Synopsis N-Heterocyclic Carbenes by : Silvia Diez-Gonzalez

Download or read book N-Heterocyclic Carbenes written by Silvia Diez-Gonzalez and published by Royal Society of Chemistry. This book was released on 2016-11-04 with total page 637 pages. Available in PDF, EPUB and Kindle. Book excerpt: In less than 20 years N-heterocyclic carbenes (NHCs) have become well-established ancillary ligands for the preparation of transition metal-based catalysts. This is mainly due to the fact that NHCs tend to bind strongly to metal centres, avoiding the need of excess ligand in catalytic reactions. Also, NHC‒metal complexes are often insensitive to air and moisture, and have proven remarkably resistant to oxidation. This book showcases the wide variety of applications of NHCs in different chemistry fields beyond being simple phosphine mimics. This second edition has been updated throughout, and now includes a new chapter on NHC‒main group element complexes. It covers the synthesis of NHC ligands and their corresponding metal complexes, as well as their bonding and stereoelectronic properties and applications in catalysis. This is complemented by related topics such as organocatalysis and biologically active complexes. Written for organic and inorganic chemists, this book is ideal for postgraduates, researchers and industrialists.

Organometallics in Process Chemistry

Author : Thomas J. Colacot
Publisher : Springer Nature
ISBN 13 : 3030279618
Total Pages : 334 pages
Book Rating : 4.0/5 (32 download)

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Book Synopsis Organometallics in Process Chemistry by : Thomas J. Colacot

Download or read book Organometallics in Process Chemistry written by Thomas J. Colacot and published by Springer Nature. This book was released on 2020-04-01 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume gives an overview of the applications of organometallic chemistry in process chemistry relevant to the current topics in synthetic chemistry. This volume starts with an introduction on the historical development of organometallics in process chemistry and is followed by chapters dealing with the last five years’ development in various organometallic reaction types such as the challenging cross coupling process, construction of 3.1.0 bicycles, pressure and transfer hydrogenations of historically challenging compounds such as esters, utilization of carbon dioxide for making organic compounds by flow process, drug synthesis and metal detection and scavenging in the finished APIs. A chapter by Colacot et.al., is also devoted to the process development and structural understanding of organometallic catalysts with particular emphasis to LnPd(0) catalysts. An academia – industry collaborated chapter on the use of water as a solvent for organometallic processes is included in this book.