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Author : Harold Zeiss
Publisher :
ISBN 13 :
Total Pages : 122 pages
Book Rating : 4.:/5 (44 download)
Download or read book Benzenoid-metal Complexes written by Harold Zeiss and published by . This book was released on 1966 with total page 122 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Harold Zeiss
Publisher :
ISBN 13 :
Total Pages : 120 pages
Book Rating : 4.:/5 (43 download)
Download or read book Benzenoid-metal Complexes written by Harold Zeiss and published by . This book was released on 1966 with total page 120 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : B. L. Shaw
Publisher : Elsevier
ISBN 13 : 1483159698
Total Pages : 231 pages
Book Rating : 4.4/5 (831 download)
Download or read book Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis written by B. L. Shaw and published by Elsevier. This book was released on 2013-10-22 with total page 231 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis deals with the chemistry of organo-transition metal complexes and their uses as homogeneous catalysts and as intermediates in organic synthesis. The compounds are classified mainly from the number of carbon atoms that are actually bonded to the metal and to each other. This volume is comprised of eight chapters and begins with a discussion on alkyls, aryls, acetylides, fluorocarbon complexes, and carbides, along with olefin, allene, and acetylene complexes. The reader is then introduced to p-allylic and related complexes such as fluoroallyl complexes; complexes with conjugated diolefins including fluorodiolefins but excluding cyclobutadienes; cyclopentadienyl-metal, pentadienyl-metal, and related complexes; and arene complexes, related complexes with conjugated trienes, and thiophene complexes such as benzenoid-metal or arene-metal complexes, cyclopheptatriene complexes, and complexes with other six electron donors. Cycloheptatrienyl or tropylium complexes are also considered, along with cyclo-octatetraene, azulene complexes, and carborane complexes. This book will be a valuable source of information for inorganic chemists.
Author : William A. Nugent
Publisher : Wiley-Interscience
ISBN 13 :
Total Pages : 360 pages
Book Rating : 4.3/5 (91 download)
Download or read book Metal-Ligand Multiple Bonds written by William A. Nugent and published by Wiley-Interscience. This book was released on 1988-11-14 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: The only comprehensive one-volume text/reference on metal-ligand multiple bonds. Stresses the unified nature of the field and includes handy new tabulations of data. The flow within each subtopic is oxygen to nitrogen to carbon. Coverage is up-to-date--virtually every subtopic leads to interesting questions for future research. Presents information otherwise scattered through hundreds of publications.
Author : B. L. Shaw
Publisher : Elsevier
ISBN 13 : 1483181715
Total Pages : 231 pages
Book Rating : 4.4/5 (831 download)
Download or read book Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis written by B. L. Shaw and published by Elsevier. This book was released on 2016-06-06 with total page 231 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organo-Transition Metal Compounds and Related Aspects of Homogeneous Catalysis covers compounds that possess carbon atoms bonded to metal and to other carbon atoms. The order in which the substances appear in the book is based on the number of carbon atoms it have. The first section is about the alkyl, aryl, ethynyl, acyl, and carbene complexes. The second section deals with olefin and chelating diolefin complexes and complexes formed from acetylene. The following section covers the p-allylic complexes. The structures, stability, and bonding of alkyl and aryl complexes are fully covered. The magnetic moments and electronic spectra are discussed in detail.The fourth section discusses the conjugated diolefinic complexes that contain butadiene or cyclobutadiene. The rest of the book focuses on cyclopentadienyls, arene complexes, tropylium complexes, and complexes formed from cyclo-octatetraene or azulene. The book will be a useful tool for chemists, chemical engineers, and students and researchers in the field of chemistry.
Author : N. Farrell
Publisher : Springer Science & Business Media
ISBN 13 : 9401175683
Total Pages : 304 pages
Book Rating : 4.4/5 (11 download)
Download or read book Transition Metal Complexes as Drugs and Chemotherapeutic Agents written by N. Farrell and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: When this book was first conceived as a project the expanding interest in the clinical use of platinum and gold complexes made a survey of the relevant biological properties of metal complexes timely and appropriate. This timeliness has not diminished during the gestation and final publica tion of the manuscript. The introduction contains an explanation of the layout and approach to the book, which I wrote as an overall survey of the wide variety of biological properties of metal complexes. Hopefully, the reader will see the parallels in mechanisms and behavior, even in different organisms. The writing was considerably helped by the enthusiasm and confidence (totally unearned on my part) in the project of Professor Brian James and lowe him my special thanks. I also owe a great debt of gratitude to my colleagues, and especially to Eucler Paniago, of the Universidade Federal de Minas Gerais, for their comprehension and for the initial leave of absence which allowed me to begin the project. To those who read some or all of the manuscript and made suggestions, Bernhard Lippert, Kirsten Skov, and Tom Tritton, as well as the editor's reviewer I am also grateful. As usual, the final responsibility for errors or otherwise rests with the author.
Author : Muriel Tomlinson
Publisher : Elsevier
ISBN 13 : 1483280241
Total Pages : 218 pages
Book Rating : 4.4/5 (832 download)
Download or read book An Introduction to the Chemistry of Benzenoid Compounds written by Muriel Tomlinson and published by Elsevier. This book was released on 2016-07-29 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt: An Introduction to the Chemistry of Benzenoid Compounds is an introductory text to some chemical aspects of benzenoid compounds. This book is composed of 13 chapters that specifically cover the sources, properties, and reactions of these compounds. The opening chapters describe the structural aspects of benzenoid compounds, including their homologues, isomers, and aromaticity. The subsequent chapters deal with the disubstitution and addition reactions of the benzene nucleus. Considerable chapters are devoted to the synthesis of benzenoid derivatives, such as aromatic halides, nitro-compounds, carbonyl compounds, acids, and amines, phenols, alcohols, and naphthalene. The final chapter introduces the chemistry of anthracene, phenanthrene, and polycyclic aromatic hydrocarbons. This book is of value to organic chemistry students.
Author : D.M. Roundhill
Publisher : Springer Science & Business Media
ISBN 13 : 1489914951
Total Pages : 364 pages
Book Rating : 4.4/5 (899 download)
Download or read book Photochemistry and Photophysics of Metal Complexes written by D.M. Roundhill and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt: Focusing on practical applications, the author provides a balanced introduction to the many possible technological uses of metal complexes. Coverage includes the transition metals, lanthanide and actinide complexes, metal porphyrins, and many other complexes. This volume meets the needs of students and scientists in inorganic chemistry, chemical physics, and solid-state physics.
Author : M. Tsutsui
Publisher : Springer Science & Business Media
ISBN 13 : 1475755880
Total Pages : 220 pages
Book Rating : 4.4/5 (757 download)
Download or read book Introduction to Metal π-Complex Chemistry written by M. Tsutsui and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Plenum Press series, Monographs in Inorganic Chemistry, is intended to fill an obvious need for high-level surveys of recent research in that area, particularly in matters which go beyond the traditional or classical bound aries of the subject. The study of n-bonding of hydrocarbon groups (and their derivatives) to metals is exactly that kind of subject, for it provides a new way of understanding the behavior of metals (which constitute four-fifths of all the chemical elements). In addition, n-bonding has expanded the intriguing area of organometallic chemistry threefold, bringing in all the transition metals, the lanthanides, and the actinides. So much has been discovered and developed in the area of n-bonded "complexes" of the metals that important new industrial processes based on such substances have been developed. A truly comprehensive review of all n-bonded compounds of the metals would now result in an impossibly large and expensive volume, and would require monthly revision. Instead, the present authors have wisely decided to write a survey which outlines the general aspects of preparation, properties, structure, reactions, and uses of such compounds-a survey which can serve as a textbook, but which can also lead the more experienced practitioner to the most advanced literature on the subject. They have clarified and condensed the subject by means of good organization and a liberal use of diagrams-features which will please the general reader.
Author : P.L. Soni
Publisher : CRC Press
ISBN 13 : 1000404137
Total Pages : 403 pages
Book Rating : 4.0/5 (4 download)
Download or read book The Chemistry of Coordination Complexes and Transition Metals written by P.L. Soni and published by CRC Press. This book was released on 2021-05-13 with total page 403 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers all important nomenclature, theories of bonding and stereochemistry of coordination complexes. The authors have made an effort to inscribe the ideas knowledge, clearly and in an interesting way to benefit the readers. The complexities of Molecular Orbital theory have been explained in a very simple and easy manner. It also deals with transition and inner transition metals. Conceptually, all transition and inner transition elements form complexes which have definite geometry and show interesting properties. General and specific methods of preparation, physical and chemical properties of each element has been discussed at length. Group wise study of elements in d-block series have been explained. Important compounds, complexes and organometallic compounds of metals in different oxidation states have been given explicitly. Note: T&F does not sell or distribute the Hardback in India, Pakistan, Nepal, Bhutan, Bangladesh and Sri Lanka.
Author : Mandeep Dalal
Publisher : Dalal Institute
ISBN 13 : 8193872002
Total Pages : 480 pages
Book Rating : 4.1/5 (938 download)
Download or read book A Textbook of Inorganic Chemistry – Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Author : David Paul Kuhlman
Publisher :
ISBN 13 :
Total Pages : 224 pages
Book Rating : 4.:/5 (131 download)
Download or read book The Reaction of Benzyne with Transition Metal Complexes written by David Paul Kuhlman and published by . This book was released on 1970 with total page 224 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Pranjit Barman
Publisher : John Wiley & Sons
ISBN 13 : 3527839461
Total Pages : 229 pages
Book Rating : 4.5/5 (278 download)
Download or read book Schiff Base Metal Complexes written by Pranjit Barman and published by John Wiley & Sons. This book was released on 2023-05-11 with total page 229 pages. Available in PDF, EPUB and Kindle. Book excerpt: Schiff Base Metal Complexes Schiff bases are compounds created from a condensed amino compounds, which frequently form complexes with metal ions. They have diverse applications in biology, catalysis, material science and industry. Understanding these compounds, their properties, and the available methods for synthesizing them is a key to unlocking industrial innovation. Schiff Base Metal Complexes provides a comprehensive overview of these compounds. It introduces the compounds and their properties before discussing their various synthesizing methods. A survey of existing and potential applications gives a complete picture and makes this a crucial guide for researchers and industry professionals looking to work with Schiff base complexes. Schiff Base Metal Complexes readers will also find: A systematic and organized structure designed to make information instantly accessible Detailed coverage of thermal synthesis, photochemical synthesis, and more Challenges with different methods described in order to help readers make the correct choice for their own work Schiff Base Metal Complexes is a useful reference for organic chemists, materials scientists, and researchers or industry professionals working with organometallics.
Author : Houghton
Publisher : Cambridge University Press
ISBN 13 : 9780521219921
Total Pages : 324 pages
Book Rating : 4.2/5 (199 download)
Download or read book Metal Complexes-Organic Chemistry written by Houghton and published by Cambridge University Press. This book was released on 1979-07-12 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Hartmut Yersin
Publisher : Springer Science & Business Media
ISBN 13 : 9783540629221
Total Pages : 276 pages
Book Rating : 4.6/5 (292 download)
Download or read book Electronic and Vibronic Spectra of Transition Metal Complexes II written by Hartmut Yersin and published by Springer Science & Business Media. This book was released on 1997-07-16 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt: The unique properties and applications of transition metal compounds have long fascinated both physicists and chemists. This volume presents theoretical and experimental studies for a deeper understanding of the electronic and vibronic properties of these compounds. In particular, an introduction into properties of spin sublevels of dd*, dÂ*, and ÂÂ* states is given, and a modern ligand field theory based on the Angular Overlap Model is presented. In experimental case studies it is shown how to characterize different types of electronic transitions using modern methods of laser spectroscopy. Consequences of spin-orbit coupling, zero-field splittings, spin-lattice relaxations, chromophore-matrix interactions, Herzberg-Teller/Franck-Condon activities, and localization/delocalization properties are treated.
Author : D. Nicholls
Publisher : Elsevier
ISBN 13 : 148314643X
Total Pages : 201 pages
Book Rating : 4.4/5 (831 download)
Download or read book The Chemistry of Iron, Cobalt and Nickel written by D. Nicholls and published by Elsevier. This book was released on 2013-10-02 with total page 201 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Iron, Cobalt and Nickel deals with the chemistry of iron, cobalt, and nickel and covers topics ranging from the occurrence and distribution of all three elements to their properties, allotropy, and analytical chemistry. Compounds of iron, cobalt, and nickel in both low and high oxidation states are also discussed. This book is divided into three sections and begins with the history of iron, along with its occurrence and distribution, allotropy, and preparation and industrial production. The nuclear, physical, and chemical properties of iron, as well as the biological importance of iron compounds, are also considered. Compounds of iron are discussed, including carbonyls and nitric oxide complexes. The next two sections deal with the history, occurrence and distribution, allotropy, analytical chemistry, and preparation and industrial production of cobalt and nickel, along with their nuclear, physical, and chemical properties. Compounds of cobalt and nickel are examined, from carbonyls and nitrosyls to cyanides and organometallic compounds. This monograph will be a useful resource for inorganic chemists.
Author : Eva Neumann
Publisher : Cuvillier Verlag
ISBN 13 : 3736918011
Total Pages : 244 pages
Book Rating : 4.7/5 (369 download)
Download or read book Transition Metal Complexes with P,N-Ligands and Silylenes: Synthesis and Catalytic Studies written by Eva Neumann and published by Cuvillier Verlag. This book was released on 2006-02-15 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt: The term ligand [latin, ligare = bind] has its origin in coordination chemistry. It denotes a molecule that is able to bind to a metal center in most cases via one or several free electron pairs.[1] Ligands can be described by the number of electron-pair donor atoms as monodentate, bidentate, tridentate etc. ligands. The latter are also called chelating ligands [greek, chele = (crab’s) claw]. A typical classification of ligands is according to their electronic properties. They serve either as a σ-donating, σ-donating/π-accepting, or σ,π-donating/π-accepting ligands.[2] A more practical, often encountered approach is the classification of ligands according to their donor atoms, especially when larger molecules and molecules containing heteroatoms are regarded (compare 1.2). Coordination chemistry was already established in the 19th century. In 1893 Alfred Werner suggested an octahedral arrangement of ligands coordinated to a central metal ion for many compounds. This explained, for example, the appearance and reactivity of four different cobalt(III) complexes (Figure 1.1), when CoCl2 is dissolved in aqueous ammonia and then oxidized by air to the +3 oxidation state. The formulas of these complexes can be written as depicted in Figure 1.1. Werner’s work was rewarded with the Nobel prize in 1913.[3]
