BENCH-SCALE STEAM REFORMING OF ACTUAL TANK 48H WASTE.

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Book Synopsis BENCH-SCALE STEAM REFORMING OF ACTUAL TANK 48H WASTE. by :

Download or read book BENCH-SCALE STEAM REFORMING OF ACTUAL TANK 48H WASTE. written by and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Fluidized Bed Steam Reforming (FBSR) has been demonstrated to be a viable technology to remove>99% of the organics from Tank 48H simulant, to remove>99% of the nitrate/nitrite from Tank 48H simulant, and to form a solid product that is primarily carbonate based. The technology was demonstrated in October of 2006 in the Engineering Scale Test Demonstration Fluidized Bed Steam Reformer1 (ESTD FBSR) at the Hazen Research Inc. (HRI) facility in Golden, CO. The purpose of the Bench-scale Steam Reformer (BSR) testing was to demonstrate that the same reactions occur and the same product is formed when steam reforming actual radioactive Tank 48H waste. The approach used in the current study was to test the BSR with the same Tank 48H simulant and same Erwin coal as was used at the ESTD FBSR under the same operating conditions. This comparison would allow verification that the same chemical reactions occur in both the BSR and ESTD FBSR. Then, actual radioactive Tank 48H material would be steam reformed in the BSR to verify that the actual tank 48H sample reacts the same way chemically as the simulant Tank 48H material. The conclusions from the BSR study and comparison to the ESTD FBSR are the following: (1) A Bench-scale Steam Reforming (BSR) unit was successfully designed and built that: (a) Emulated the chemistry of the ESTD FBSR Denitration Mineralization Reformer (DMR) and Carbon Reduction Reformer (CRR) known collectively as the dual reformer flowsheet. (b) Measured and controlled the off-gas stream. (c) Processed real (radioactive) Tank 48H waste. (d) Met the standards and specifications for radiological testing in the Savannah River National Laboratory (SRNL) Shielded Cells Facility (SCF). (2) Three runs with radioactive Tank 48H material were performed. (3) The Tetraphenylborate (TPB) was destroyed to> 99% for all radioactive Bench-scale tests. (4) The feed nitrate/nitrite was destroyed to>99% for all radioactive BSR tests the same as the ESTD FBSR. (5) The radioactive Tank 48H DMR product was primarily made up of soluble carbonates. The three most abundant species were thermonatrite, [Na2CO3 · H2O], sodium carbonate, [Na2CO3], and trona, [Na3H(CO3)2 · 2H2O] the same as the ESTD FBSR. (6) Insoluble solids analyzed by X-Ray Diffraction (XRD) did not detect insoluble carbonate species. However, they still may be present at levels below 2 wt%, the sensitivity of the XRD methodology. Insoluble solids XRD characterization indicated that various Fe/Ni/Cr/Mn phases are present. These crystalline phases are associated with the insoluble sludge components of Tank 48H slurry and impurities in the Erwin coal ash. The percent insoluble solids, which mainly consist of un-burnt coal and coal ash, in the products were 4 to 11 wt% for the radioactive runs. (7) The Fe{sup +2}/Fe{sub total} REDOX measurements ranged from 0.58 to 1 for the three radioactive Bench-scale tests. REDOX measurements> 0.5 showed a reducing atmosphere was maintained in the DMR indicating that pyrolysis was occurring. (8) Greater than 90% of the radioactivity was captured in the product for all three runs. (9) The collective results from the FBSR simulant tests and the BSR simulant tests indicate that the same chemistry occurs in the two reactors. (10) The collective results from the BSR simulant runs and the BSR radioactive waste runs indicates that the same chemistry occurs in the simulant as in the real waste. The FBSR technology has been proven to destroy the organics and nitrates in the Tank 48H waste and form the anticipated solid carbonate phases as expected.

STEAM REFORMING TECHNOLOGY DEMONSTRATION FOR THE DESTRUCTION OF ORGANICS ON ACTUAL DOE SAVANNAH RIVER SITE TANK 48H WASTE 9138

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Book Synopsis STEAM REFORMING TECHNOLOGY DEMONSTRATION FOR THE DESTRUCTION OF ORGANICS ON ACTUAL DOE SAVANNAH RIVER SITE TANK 48H WASTE 9138 by :

Download or read book STEAM REFORMING TECHNOLOGY DEMONSTRATION FOR THE DESTRUCTION OF ORGANICS ON ACTUAL DOE SAVANNAH RIVER SITE TANK 48H WASTE 9138 written by and published by . This book was released on 2009 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This paper describes the design of the Bench-scale Steam Reformer (BSR); a processing unit for demonstrating steam reforming technology on actual radioactive waste [1]. It describes the operating conditions of the unit used for processing a sample of Savannah River Site (SRS) Tank 48H waste. Finally, it compares the results from processing the actual waste in the BSR to processing simulant waste in the BSR to processing simulant waste in a large pilot scale unit, the Fluidized Bed Steam Reformer (FBSR), operated at Hazen Research Inc. in Golden, CO. The purpose of this work was to prove that the actual waste reacted in the same manner as the simulant waste in order to validate the work performed in the pilot scale unit which could only use simulant waste.

2009 PILOT SCALE FLUIDIZED BED STEAM REFORMING TESTING USING THE THOR (THERMAL ORGANIC REDUCTION) PROCESS

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ISBN 13 :
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Book Synopsis 2009 PILOT SCALE FLUIDIZED BED STEAM REFORMING TESTING USING THE THOR (THERMAL ORGANIC REDUCTION) PROCESS by :

Download or read book 2009 PILOT SCALE FLUIDIZED BED STEAM REFORMING TESTING USING THE THOR (THERMAL ORGANIC REDUCTION) PROCESS written by and published by . This book was released on 2009 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The Savannah River Site (SRS) must empty the contents of Tank 48H, a 1.3 million gallon Type IIIA HLW storage tank, to return this tank to service. The tank contains organic compounds, mainly potassium tetraphenylborate that cannot be processed downstream until the organic components are destroyed. The THOR{reg_sign} Treatment Technologies (TTT) Fluidized Bed Steam Reforming (FBSR) technology, herein after referred to as steam reforming, has been demonstrated to be a viable process to remove greater than 99.9% of the organics from Tank 48H during various bench scale and pilot scale tests. These demonstrations were supported by Savannah River Remediation (SRR) and the Department of Energy (DOE) has concurred with the SRR recommendation to proceed with the deployment of the FBSR technology to treat the contents of Tank 48H. The Savannah River National Laboratory (SRNL) developed and proved the concept with non-radioactive simulants for SRR beginning in 2003. By 2008, several pilot scale campaigns had been completed and extensive crucible testing and bench scale testing were performed in the SRNL Shielded Cells using Tank 48H radioactive sample. SRNL developed a Tank 48H non-radioactive simulant complete with organic compounds, salt, and metals characteristic of those measured in a sample of the radioactive contents of Tank 48H. FBSR Pilot Scaled Testing with the Tank 48H simulant has demonstrated the ability to remove greater than 98% of the nitrites and greater than 99.5% of the nitrates from the Tank 48H simulant, and to form a solid product that is primarily alkali carbonate. The alkali carbonate is soluble and, thus, amenable to pumping as a liquid to downstream facilities for processing. The FBSR technology was demonstrated in October of 2006 in the Engineering Scale Test Demonstration (ESTD) pilot scale steam reformer at the Hazen Research Inc. (HRI) facility in Golden, CO. Additional ESTD tests were completed in 2008 and in 2009 that further demonstrated the TTT steam reforming process ability to destroy organics in the Tank 48 simulant and produce a soluble carbonate waste form. The ESTD was operated at varying feed rates and Denitration and Mineralization Reformer (DMR) temperatures, and at a constant Carbon Reduction Reformer (CRR) temperature of 950 C. The process produced a dissolvable carbonate product suitable for processing downstream. ESTD testing was performed in 2009 at the Hazen facility to demonstrate the long term operability of an integrated FBSR processing system with carbonate product and carbonate slurry handling capability. The final testing demonstrated the integrated TTT FBSR capability to process the Tank 48 simulant from a slurry feed into a greater than 99.9% organic free and primarily dissolved carbonate FBSR product slurry. This paper will discuss the SRNL analytical results of samples analyzed from the 2008 and 2009 THOR{reg_sign} steam reforming ESTD performed with Tank 48H simulant at HRI in Golden, Colorado. The final analytical results will be compared to prior analytical results from samples in terms of organic, nitrite, and nitrate destruction.

TWR Bench-Scale Steam Reforming Demonstration

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ISBN 13 :
Total Pages : pages
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Book Synopsis TWR Bench-Scale Steam Reforming Demonstration by : D. W. Marshall

Download or read book TWR Bench-Scale Steam Reforming Demonstration written by D. W. Marshall and published by . This book was released on 2003 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by ThermoChem Waste Remediation, LLC, (TWR) for treatment of SBW into a ''road ready'' waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). TWR is the licensee of Manufacturing Technology Conservation International (MTCI) steam-reforming technology in the field of radioactive waste treatment. A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrate residues were about 400 ppm in the product and NOx destruction exceeded 86%. The demonstration was successful.

THOR Bench-Scale Steam Reforming Demonstration

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ISBN 13 :
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Book Synopsis THOR Bench-Scale Steam Reforming Demonstration by : D. W. Marshall

Download or read book THOR Bench-Scale Steam Reforming Demonstration written by D. W. Marshall and published by . This book was released on 2003 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The Idaho Nuclear Technology and Engineering Center (INTEC) was home to nuclear fuel reprocessing activities for decades at the Idaho National Engineering and Environmental Laboratory. As a result of the reprocessing activities, INTEC has accumulated approximately one million gallons of acidic, radioactive, sodium-bearing waste (SBW). The purpose of this demonstration was to investigate a reforming technology, offered by THORsm Treatment Technologies, LLC, for treatment of SBW into a ''road ready'' waste form that would meet the waste acceptance criteria for the Waste Isolation Pilot Plant (WIPP). A non-radioactive simulated SBW was used based on the known composition of waste tank WM-180 at INTEC. Rhenium was included as a non-radioactive surrogate for technetium. Data was collected to determine the nature and characteristics of the product, the operability of the technology, the composition of the off-gases, and the fate of key radionuclides (cesium and technetium) and volatile mercury compounds. The product contained a low fraction of elemental carbon residues in the cyclone and filter vessel catches. Mercury was quantitatively stripped from the product but cesium, rhenium (Tc surrogate), and the heavy metals were retained. Nitrates were not detected in the product and NOx destruction exceeded 98%. The demonstration was successful.

CRUCIBLE TESTING OF TANK 48H RADIOACTIVEWASTE SAMPLE USING FLUIDIZED BED STEAMREFORMING TECHNOLOGY FOR ORGANICDESTRUCTION.

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ISBN 13 :
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Book Synopsis CRUCIBLE TESTING OF TANK 48H RADIOACTIVEWASTE SAMPLE USING FLUIDIZED BED STEAMREFORMING TECHNOLOGY FOR ORGANICDESTRUCTION. by :

Download or read book CRUCIBLE TESTING OF TANK 48H RADIOACTIVEWASTE SAMPLE USING FLUIDIZED BED STEAMREFORMING TECHNOLOGY FOR ORGANICDESTRUCTION. written by and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of crucible scale testing with actual radioactive Tank 48H material was to duplicate the test results that had been previously performed on simulant Tank 48H material. The earlier crucible scale testing using simulants was successful in demonstrating that bench scale crucible tests produce results that are indicative of actual Fluidized Bed Steam Reforming (FBSR) pilot scale tests. Thus, comparison of the results using radioactive Tank 48H feed to those reported earlier with simulants would then provide proof that the radioactive tank waste behaves in a similar manner to the simulant. Demonstration of similar behavior for the actual radioactive Tank 48H slurry to the simulant is important as a preliminary or preparation step for the more complex bench-scale steam reformer unit that is planned for radioactive application in the Savannah River National Laboratory (SRNL) Shielded Cells Facility (SCF) later in 2008. The goals of this crucible-scale testing were to show 99% destruction of tetraphenylborate and to demonstrate that the final solid product produced is sodium carbonate. Testing protocol was repeated using the specifications of earlier simulant crucible scale testing, that is sealed high purity alumina crucibles containing a pre-carbonated and evaporated Tank 48H material. Sealing of the crucibles was accomplished by using an inorganic 'nepheline' sealant. The sealed crucibles were heat-treated at 650 C under constant argon flow to inert the system. Final product REDOX measurements were performed to establish the REDuction/OXidation (REDOX) state of known amounts of added iron species in the final product. These REDOX measurements confirm the processing conditions (pyrolysis occurring at low oxygen fugacity) of the sealed crucible environment which is the environment actually achieved in the fluidized bed steam reformer process. Solid product dissolution in water was used to measure soluble cations and anions, and to investigate insoluble fractions of the product solids. Radioanalytical measurements were performed on the Tank 48H feed material and on the dissolved products in order to estimate retention of Cs-137 in the process. All aspects of prior crucible scale testing with simulant Tank 48H slurry were demonstrated to be repeatable with the actual radioactive feed. Tetraphenylborate destruction was shown to be>99% and the final solid product is sodium carbonate crystalline material. Less than 10 wt% of the final solid products are insoluble components comprised of Fe/Ni/Cr/Mn containing sludge components and Ti from monosodium titanate present in Tank 48H. REDOX measurements on the radioactive solid products indicate a reducing atmosphere with extremely low oxygen fugacity--evidence that the sealed crucible tests performed in the presence of a reductant (sugar) under constant argon purge were successful in duplicating the pyrolysis reactions occurring with the Tank 48H feed. Soluble anion measurements confirm that using sugar as reductant at 1X stoichiometry was successful in destroying nitrate/nitrite in the Tank 48H feed. Radioanalytical measurements indicate that (almost equal to)75% of the starting Cs-137 is retained in the solid product. No attempts were made to analyze/measure other potential Cs-137 in the process, i.e., as possible volatile components on the inner surface of the alumina crucible/lid or as offgas escaping the sealed crucible. The collective results from these crucible scale tests on radioactive material are in good agreement with simulant testing. Crucible scale processing has been shown to duplicate the complex reactions of an actual fluidized bed steam reformer. Thus this current testing should provide a high degree of confidence that upcoming bench-scale steam reforming with radioactive Tank 48H slurry will be successful in tetraphenylborate destruction and production of sodium carbonate product.

Environmental Issues and Waste Management Technologies in the Ceramic and Nuclear Industries X

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Publisher : John Wiley & Sons
ISBN 13 : 1118408446
Total Pages : 271 pages
Book Rating : 4.1/5 (184 download)

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Book Synopsis Environmental Issues and Waste Management Technologies in the Ceramic and Nuclear Industries X by : John D. Vienna

Download or read book Environmental Issues and Waste Management Technologies in the Ceramic and Nuclear Industries X written by John D. Vienna and published by John Wiley & Sons. This book was released on 2012-04-11 with total page 271 pages. Available in PDF, EPUB and Kindle. Book excerpt: These proceedings capture advances in the state of knowledge in nuclear and waste materials science and technology. In addition, the proceedings addresses the environmental issues associated with ceramic processing. Included are the status of environmental issues and their solutions, both current and proposed.

CRUCIBLE TESTING OF TANK 48 RADIOACTIVE WASTE SAMPLE USING FBSR TECHNOLOGY FOR ORGANIC DESTRUCTION.

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Book Synopsis CRUCIBLE TESTING OF TANK 48 RADIOACTIVE WASTE SAMPLE USING FBSR TECHNOLOGY FOR ORGANIC DESTRUCTION. by :

Download or read book CRUCIBLE TESTING OF TANK 48 RADIOACTIVE WASTE SAMPLE USING FBSR TECHNOLOGY FOR ORGANIC DESTRUCTION. written by and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of crucible scale testing with actual radioactive Tank 48H material was to duplicate the test results that had been previously performed on simulant Tank 48H material. The earlier crucible scale testing using simulants was successful in demonstrating that bench scale crucible tests produce results that are indicative of actual Fluidized Bed Steam Reforming (FBSR) pilot scale tests. Thus, comparison of the results using radioactive Tank 48H feed to those reported earlier with simulants would then provide proof that the radioactive tank waste behaves in a similar manner to the simulant. Demonstration of similar behavior for the actual radioactive Tank 48H slurry to the simulant is important as a preliminary or preparation step for the more complex bench-scale steam reformer unit that is planned for radioactive application in the Savannah River National Laboratory (SRNL) Shielded Cells Facility (SCF) later in 2008. The goals of this crucible-scale testing were to show 99% destruction of tetraphenylborate and to demonstrate that the final solid product produced is sodium carbonate. Testing protocol was repeated using the specifications of earlier simulant crucible scale testing, that is sealed high purity alumina crucibles containing a pre-carbonated and evaporated Tank 48H material. Sealing of the crucibles was accomplished by using an inorganic 'nepheline' sealant. The sealed crucibles were heat-treated at 650 C under constant argon flow to inert the system. Final product REDOX measurements were performed to establish the REDuction/OXidation (REDOX) state of known amounts of added iron species in the final product. These REDOX measurements confirm the processing conditions (pyrolysis occurring at low oxygen fugacity) of the sealed crucible environment which is the environment actually achieved in the fluidized bed steam reformer process. Solid product dissolution in water was used to measure soluble cations and anions, and to investigate insoluble fractions of the product solids. Radioanalytical measurements were performed on the Tank 48H feed material and on the dissolved products in order to estimate retention of Cs-137 in the process. All aspects of prior crucible scale testing with simulant Tank 48H slurry were demonstrated to be repeatable with the actual radioactive feed. Tetraphenylborate destruction was shown to be>99% and the final solid product is sodium carbonate crystalline material. Less than 10 wt% of the final solid products are insoluble components comprised of Fe/Ni/Cr/Mn containing sludge components and Ti from monosodium titanate present in Tank 48H. REDOX measurements on the radioactive solid products indicate a reducing atmosphere with extremely low oxygen fugacity--evidence that the sealed crucible tests performed in the presence of a reductant (sugar) under constant argon purge were successful in duplicating the pyrolysis reactions occurring with the Tank 48H feed. Soluble anion measurements confirm that using sugar as reductant at 1X stoichiometry was successful in destroying nitrate/nitrite in the Tank 48H feed. Radioanalytical measurements indicate that (almost equal to)75% of the starting Cs-137 is retained in the solid product. No attempts were made to analyze/measure other potential Cs-137 in the process, i.e., as possible volatile components on the inner surface of the alumina crucible/lid or as offgas escaping the sealed crucible. The collective results from these crucible scale tests on radioactive material are in good agreement with simulant testing. Crucible scale processing has been shown to duplicate the complex reactions of an actual fluidized bed steam reformer. Thus this current testing should provide a high degree of confidence that upcoming bench-scale steam reforming with radioactive Tank 48H slurry will be successful in tetraphenylborate destruction and production of sodium carbonate product.

ספר משפט כתוב על הקרי והכתיב

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ISBN 13 :
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Book Synopsis ספר משפט כתוב על הקרי והכתיב by :

Download or read book ספר משפט כתוב על הקרי והכתיב written by and published by . This book was released on 1978 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

FLUIDIZED BED STEAM REFORMING ENABLING ORGANIC HIGH LEVEL WASTE DISPOSAL.

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ISBN 13 :
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Book Synopsis FLUIDIZED BED STEAM REFORMING ENABLING ORGANIC HIGH LEVEL WASTE DISPOSAL. by :

Download or read book FLUIDIZED BED STEAM REFORMING ENABLING ORGANIC HIGH LEVEL WASTE DISPOSAL. written by and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Waste streams planned for generation by the Global Nuclear Energy Partnership (GNEP) and existing radioactive High Level Waste (HLW) streams containing organic compounds such as the Tank 48H waste stream at Savannah River Site have completed simulant and radioactive testing, respectfully, by Savannah River National Laboratory (SRNL). GNEP waste streams will include up to 53 wt% organic compounds and nitrates up to 56 wt%. Decomposition of high nitrate streams requires reducing conditions, e.g. provided by organic additives such as sugar or coal, to reduce NOX in the off-gas to N2 to meet Clean Air Act (CAA) standards during processing. Thus, organics will be present during the waste form stabilization process regardless of the GNEP processes utilized and exists in some of the high level radioactive waste tanks at Savannah River Site and Hanford Tank Farms, e.g. organics in the feed or organics used for nitrate destruction. Waste streams containing high organic concentrations cannot be stabilized with the existing HLW Best Developed Available Technology (BDAT) which is HLW vitrification (HLVIT) unless the organics are removed by pretreatment. The alternative waste stabilization pretreatment process of Fluidized Bed Steam Reforming (FBSR) operates at moderate temperatures (650-750 C) compared to vitrification (1150-1300 C). The FBSR process has been demonstrated on GNEP simulated waste and radioactive waste containing high organics from Tank 48H to convert organics to CAA compliant gases, create no secondary liquid waste streams and create a stable mineral waste form.

Steam Reforming Technology for Denitration and Immobilization of DOE Tank Wastes

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ISBN 13 :
Total Pages : 13 pages
Book Rating : 4.:/5 (316 download)

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Book Synopsis Steam Reforming Technology for Denitration and Immobilization of DOE Tank Wastes by : J. B. Mason

Download or read book Steam Reforming Technology for Denitration and Immobilization of DOE Tank Wastes written by J. B. Mason and published by . This book was released on 2003 with total page 13 pages. Available in PDF, EPUB and Kindle. Book excerpt: THOR Treatment Technologies, LLC (THOR) is a joint venture formed in June 2002 by Studsvik, Inc. (Studsvik) and Westinghouse Government Environmental Services Company LLC to further develop, market, and deploy Studsvik's patented THORSM non-incineration, steam reforming waste treatment technology. This paper provides an overview of the THORSM steam reforming process as applied to the denitration and conversion of Department of Energy (DOE) tank wastes to an immobilized mineral form. Using the THORSM steam reforming technology to treat nitrate containing tank wastes could significantly benefit the DOE by reducing capital and life-cycle costs, reducing processing and programmatic risks, and positioning the DOE to meet or exceed its stakeholder commitments for tank closure. Specifically, use of the THORSM technology can facilitate processing of up to 75% of tank wastes without the use of vitrification, yielding substantial life-cycle cost savings.

Environmental Issues and Waste Management Technologies in the Ceramic and Nuclear Industries

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Publisher :
ISBN 13 :
Total Pages : 292 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Environmental Issues and Waste Management Technologies in the Ceramic and Nuclear Industries by :

Download or read book Environmental Issues and Waste Management Technologies in the Ceramic and Nuclear Industries written by and published by . This book was released on 2005 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: Consists of proceedings of various symposia held during the Annual Meeting of the American Ceramic Society.

Steady-State Simulation of Steam Reforming of INEEL Tank Farm Waste

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (684 download)

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Book Synopsis Steady-State Simulation of Steam Reforming of INEEL Tank Farm Waste by :

Download or read book Steady-State Simulation of Steam Reforming of INEEL Tank Farm Waste written by and published by . This book was released on 2002 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A steady-state model of the Sodium-Bearing Waste steam reforming process at the Idaho National Engineering and Environmental Laboratory has been performed using the commercial ASPEN Plus process simulator. The preliminary process configuration and its representation in ASPEN are described. As assessment of the capability of the model to mechanistically predict product stream compositions was made, and fidelity gaps and opportunities for model enhancement were identified, resulting in the following conclusions: 1) Appreciable benefit is derived from using an activity coefficient model for electrolyte solution thermodynamics rather than assuming ideality (unity assumed for all activity coefficients). The concentrations of fifteen percent of the species present in the primary output stream were changed by more than 50%, relative to Electrolyte NRTL, when ideality was assumed; 2) The current baseline model provides a good start for estimating mass balances and performing integrated process optimization because it contains several key species, uses a mechanistic electrolyte thermodynamic model, and is based on a reasonable process configuration; and 3) Appreciable improvement to model fidelity can be realized by expanding the species list and the list of chemical and phase transformations. A path forward is proposed focusing on the use of an improved electrolyte thermodynamic property method, addition of chemical and phase transformations for key species currently absent from the model, and the combination of RGibbs and Flash blocks to simulate simultaneous phase and chemical equilibria in the off-gas treatment train.

Waste Forms Technology and Performance

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Publisher : National Academies Press
ISBN 13 : 0309187338
Total Pages : 308 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Waste Forms Technology and Performance by : National Research Council

Download or read book Waste Forms Technology and Performance written by National Research Council and published by National Academies Press. This book was released on 2011-09-05 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Department of Energy's Office of Environmental Management (DOE-EM) is responsible for cleaning up radioactive waste and environmental contamination resulting from five decades of nuclear weapons production and testing. A major focus of this program involves the retrieval, processing, and immobilization of waste into stable, solid waste forms for disposal. Waste Forms Technology and Performance, a report requested by DOE-EM, examines requirements for waste form technology and performance in the cleanup program. The report provides information to DOE-EM to support improvements in methods for processing waste and selecting and fabricating waste forms. Waste Forms Technology and Performance places particular emphasis on processing technologies for high-level radioactive waste, DOE's most expensive and arguably most difficult cleanup challenge. The report's key messages are presented in ten findings and one recommendation.

Progress in Thermochemical Biomass Conversion

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Publisher : John Wiley & Sons
ISBN 13 : 047069484X
Total Pages : 1744 pages
Book Rating : 4.4/5 (76 download)

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Book Synopsis Progress in Thermochemical Biomass Conversion by : A. V. Bridgwater

Download or read book Progress in Thermochemical Biomass Conversion written by A. V. Bridgwater and published by John Wiley & Sons. This book was released on 2008-04-30 with total page 1744 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is for chemical engineers, fuel technologists, agricultural engineers and chemists in the world-wide energy industry and in academic, research and government institutions. It provides a thorough review of, and entry to, the primary and review literature surrounding the subject. The authors are internationally recognised experts in their field and combine to provide both commercial relevance and academic rigour. Contributions are based on papers delivered to the Fifth International Conference sponsored by the IEA Bioenergy Agreement.

Municipal Solid Waste to Energy Conversion Processes

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Publisher : John Wiley & Sons
ISBN 13 : 1118029275
Total Pages : 402 pages
Book Rating : 4.1/5 (18 download)

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Book Synopsis Municipal Solid Waste to Energy Conversion Processes by : Gary C. Young

Download or read book Municipal Solid Waste to Energy Conversion Processes written by Gary C. Young and published by John Wiley & Sons. This book was released on 2010-11-29 with total page 402 pages. Available in PDF, EPUB and Kindle. Book excerpt: MUNICIPAL SOLID WASTE TO ENERGY CONVERSION PROCESSES A TECHNICAL AND ECONOMIC REVIEW OF EMERGING WASTE DISPOSAL TECHNOLOGIES Intended for a wide audience ranging from engineers and academics to decision-makers in both the public and private sectors, Municipal Solid Waste to Energy Conversion Processes: Economic, Technical, and Renewable Comparisons reviews the current state of the solid waste disposal industry. It details how the proven plasma gasification technology can be used to manage Municipal Solid Waste (MSW) and to generate energy and revenues for local communities in an environmentally safe manner with essentially no wastes. Beginning with an introduction to pyrolysis/gasification and combustion technologies, the book provides many case studies on various waste-to-energy (WTE) technologies and creates an economic and technical baseline from which all current and emerging WTE technologies could be compared and evaluated. Topics include: Pyrolysis/gasification technology, the most suitable and economically viable approach for the management of wastes Combustion technology Other renewable energy resources including wind and hydroelectric energy Plasma economics Cash flows as a revenue source for waste solids-to-energy management Plant operations, with an independent case study of Eco-Valley plant in Utashinai, Japan Extensive case studies of garbage to liquid fuels, wastes to electricity, and wastes to power ethanol plants illustrate how currently generated MSW and past wastes in landfills can be processed with proven plasma gasification technology to eliminate air and water pollution from landfills.

Hydrogen Production Technologies

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 1119283655
Total Pages : 653 pages
Book Rating : 4.1/5 (192 download)

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Book Synopsis Hydrogen Production Technologies by : Mehmet Sankir

Download or read book Hydrogen Production Technologies written by Mehmet Sankir and published by John Wiley & Sons. This book was released on 2017-03-20 with total page 653 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides a comprehensive practical review of the new technologies used to obtain hydrogen more efficiently via catalytic, electrochemical, bio- and photohydrogen production. Hydrogen has been gaining more attention in both transportation and stationary power applications. Fuel cell-powered cars are on the roads and the automotive industry is demanding feasible and efficient technologies to produce hydrogen. The principles and methods described herein lead to reasonable mitigation of the great majority of problems associated with hydrogen production technologies. The chapters in this book are written by distinguished authors who have extensive experience in their fields, and readers will have a chance to compare the fundamental production techniques and learn about the pros and cons of these technologies. The book is organized into three parts. Part I shows the catalytic and electrochemical principles involved in hydrogen production technologies. Part II addresses hydrogen production from electrochemically active bacteria (EAB) by decomposing organic compound into hydrogen in microbial electrolysis cells (MECs). The final part of the book is concerned with photohydrogen generation. Recent developments in the area of semiconductor-based nanomaterials, specifically semiconductor oxides, nitrides and metal free semiconductor-based nanomaterials for photocatalytic hydrogen production are extensively discussed.