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Atmospheric Degradation Of Organic Substances
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Book Synopsis Atmospheric Degradation of Organic Substances by : Walter Klöpffer
Download or read book Atmospheric Degradation of Organic Substances written by Walter Klöpffer and published by John Wiley & Sons. This book was released on 2008-01-08 with total page 258 pages. Available in PDF, EPUB and Kindle. Book excerpt: This compilation on the degradation of 1,100 commercially important chemical products is the first publication to make this knowledge publicly accessible in one book. The data and annotations have been painstakingly assembled over a 10-year period in a collaboration between academia and regulatory authorities. The work explains in detail the methods, including computational ones, for the environmental assessment of volatile and semi-volatile substances, and is rounded off with data tables of degradation rates. A key resource for manufacturers and regulators of such substances.
Download or read book Atmospheric Degradation written by and published by . This book was released on 2018-05 with total page 314 pages. Available in PDF, EPUB and Kindle. Book excerpt: Earth's atmosphere holds a mass of organic compounds, which differ by orders of magnitude regarding fundamental properties such as volatility, reactivity, and propensity to form cloud droplets, affecting their impact on global climate and human health. Volatile organic compounds (VOCs) play a vital role in the chemistry of the atmosphere by impelling ozone and hydroxyl radical (OH) concentrations and the renovation rates of nitrogen oxides (NOx). Elevated levels of VOCs and NOx have led to an approximate doubling of ozone in the lower troposphere over the past couple of centuries, making tropospheric ozone the third most important anthropogenic greenhouse gas after carbon dioxide (CO2) and methane. Monitoring of volatile organic compounds (VOCs) is a key piece in understanding photochemical air quality in urban atmosphere. Anthropogenic sources such as incomplete combustion of organic substances, the use of petrochemical solvents, and vaporizations of petroleum products are sources of VOCs. Every day, large quantities of volatile organic compounds (VOCs) are emitted into the atmosphere from both anthropogenic and natural sources. Therefore, their sources, sinks and dwelling times are the subject of current research. Atmospheric Degradation of Organic Substances describes the current state of knowledge of the chemistry of VOCs as well as the methods and techniques to analyze gaseous and particulate organic compounds in the atmosphere. The book also includes evaluation of the relative ozone-forming potentials of the captured VOC species in the atmosphere of urban settlement. The analytical toolbox available for chemists to study atmospheric organic compounds has expanded considerably during the past decade, opening new windows into speciation, time resolution and detection of reactive and semi-volatile compounds at low concentrations. This has provided unprecedented opportunities, but also revealed new scientific challenges.This book is of interest to students, practitioners, as well as guiding tool for researchers in the field of atmospheric research.
Book Synopsis Volatile Organic Compounds in the Atmosphere by : R M Harrison
Download or read book Volatile Organic Compounds in the Atmosphere written by R M Harrison and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 156 pages. Available in PDF, EPUB and Kindle. Book excerpt: Interest in volatile organic compounds (VOCs) as air pollutants has increased dramatically in recent years. This book covers a number of very topical issues concerning VOCs, including stratospheric ozone depletion due to CFCs, and the properties of alternative substances; the role of VOCs in the photochemical formation of lower atmosphere (tropospheric) ozone; and the problem of the direct toxicity of VOCs such as benzene and formaldehyde. This Issue reviews our current knowledge of VOCs, drawing upon the expertise of renowned experts and major national and international research programmes. It examines man-made and natural sources, as well as pathways and chemical reactions in the atmosphere. It also looks closely at the sources and concentrations of VOCs indoors, where humans are most likely to be exposed to them. Volatile Organic Compounds in the Atmosphere describes techniques used for the calculation of emissions inventories and strategies for control, and explores the many Government policy matters relating to VOCs. It provides readers with in-depth, clearly explained coverage of the many complex scientific and policy issues surrounding VOCs in the atmosphere.
Book Synopsis Volatile Organic Compounds in the Atmosphere by : Ralf Koppmann
Download or read book Volatile Organic Compounds in the Atmosphere written by Ralf Koppmann and published by John Wiley & Sons. This book was released on 2008-04-15 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt: Every day, large quantities of volatile organic compounds (VOCs) are emitted into the atmosphere from both anthropogenic and natural sources. The formation of gaseous and particulate secondary products caused by oxidation of VOCs is one of the largest unknowns in the quantitative prediction of the earth’s climate on a regional and global scale, and on the understanding of local air quality. To be able to model and control their impact, it is essential to understand the sources of VOCs, their distribution in the atmosphere and the chemical transformations which remove these compounds from the atmosphere. In recent years techniques for the analysis of organic compounds in the atmosphere have been developed to increase the spectrum of detectable compounds and their detection limits. New methods have been introduced to increase the time resolution of those measurements and to resolve more complex mixtures of organic compounds. Volatile Organic Compounds in the Atmosphere describes the current state of knowledge of the chemistry of VOCs as well as the methods and techniques to analyse gaseous and particulate organic compounds in the atmosphere. The aim is to provide an authoritative review to address the needs of both graduate students and active researchers in the field of atmospheric chemistry research.
Book Synopsis Atmospheric Measurements and Degradation Mechanisms of a Number of Volatile Organic Compounds by : Yujie Zhang
Download or read book Atmospheric Measurements and Degradation Mechanisms of a Number of Volatile Organic Compounds written by Yujie Zhang and published by . This book was released on 2012 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbonyls and BTEX (Benzene, Toluene, Ethylbenzene, and Xylenes) represent an important class of VOCs (volatile organic compounds) in the atmosphere. They are emitted into the atmosphere through anthropogenic and biogenic sources. Their atmospheric degradation leads to the formation of ozone, photooxidants and organic aerosols affecting the air quality at the local and regional scales and human health. It is, hence, of importance to measure their atmospheric concentrations and investigate their fate. In the present thesis, we have conducted a systematic measurement study of carbonyls and BTEX in Beijing during the period of Jul 2008-Aug 2010 in order to evaluate their ambient levels, possible sources and the influence of characteristic weather conditions. In a separate work, we performed a series of experimental studies on the OH-initiated oxidation of isopropyl formate, isobutyl formate, and n-propyl isobutyrate using the ICARE-CNRS (Orleans) simulation chamber from which we derived the product yields. The data obtained are presented and discussed.
Book Synopsis Environmental Inorganic Chemistry for Engineers by : James G. Speight
Download or read book Environmental Inorganic Chemistry for Engineers written by James G. Speight and published by Butterworth-Heinemann. This book was released on 2017-05-10 with total page 594 pages. Available in PDF, EPUB and Kindle. Book excerpt: Environmental Inorganic Chemistry for Engineers explains the principles of inorganic contaminant behavior, also applying these principles to explore available remediation technologies, and providing the design, operation, and advantages or disadvantages of the various remediation technologies. Written for environmental engineers and researchers, this reference provides the tools and methods that are imperative to protect and improve the environment. The book's three-part treatment starts with a clear and rigorous exposition of metals, including topics such as preparations, structures and bonding, reactions and properties, and complex formation and sequestering. This coverage is followed by a self-contained section concerning complex formation, sequestering, and organometallics, including hydrides and carbonyls. Part Two, Non-Metals, provides an overview of chemical periodicity and the fundamentals of their structure and properties. - Clearly explains the principles of inorganic contaminant behavior in order to explore available remediation technologies - Provides the design, operation, and advantages or disadvantages of the various remediation technologies - Presents a clear exposition of metals, including topics such as preparations, structures, and bonding, reaction and properties, and complex formation and sequestering
Book Synopsis Disposal of Dangerous Chemicals in Urban Areas and Mega Cities by : Ian Barnes
Download or read book Disposal of Dangerous Chemicals in Urban Areas and Mega Cities written by Ian Barnes and published by Springer. This book was released on 2012-10-16 with total page 355 pages. Available in PDF, EPUB and Kindle. Book excerpt: Oxides and acids of nitrogen play an important role in regulating atmospheric radical levels, in particular, that of the OH radical the main initiator of the degradation of chemicals in the atmosphere. A comprehensive overview on the methods used to measure nitrogen oxides and acids in the troposphere is given and difficulties and artefacts associated with the use of the techniques for measurements in urban and mega city environments is illustrated. State-of-the-art methods for the measurement of OH and HO2 radicals are reviewed and recently recognised difficulties, in particular with the measurement of HO2 radicals, are highlighted. Other contributions to the book cover our present understanding of the gas, aqueous and particulate/aerosol phase atmospheric degradation chemistry of volatile organic compounds (VOCs) under NOx conditions typical of rural, urban and mega city environments. Examples of measurements of NOx and VOCs in the atmospheres of these environments are given, in particular for the megacities Cairo and Beijing, in conjunction with modelling studies which attempt to simulate the field observations using state-of-the art knowledge on the chemistry of the VOCs and radical levels.
Book Synopsis Atmospheric Degradation Mechanism of Organic Sulfur Compounds by : Thorsten Benter
Download or read book Atmospheric Degradation Mechanism of Organic Sulfur Compounds written by Thorsten Benter and published by . This book was released on 2002 with total page 123 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Atmospheric Transformation of Volatile Organic Compounds by :
Download or read book Atmospheric Transformation of Volatile Organic Compounds written by and published by . This book was released on 2008 with total page 9 pages. Available in PDF, EPUB and Kindle. Book excerpt: To be able to understand and predict the concentration of a target compound in the atmosphere one must understand the atmospheric chemistry involved. The transformation of volatile organic compounds (VOCs) in the troposphere is predominantly driven by the interaction with the hydroxyl and nitrate radicals. The hydroxyl radical exists in daylight conditions and its reaction rate constant with an organic compound is typically very fast. The nitrate radical drives the nighttime chemistry. These radicals can scavenge hydrogen from an organic molecule generating secondary products that are often overlooked in detection schemes. Secondary products can be more stable and serve as a better target compound in detection schemes. The gas-phase reaction of the hydroxyl radical (OH) with cyclohexanol (COL) has been studied. The rate coefficient was determined to be (19.0+4.8) x 10-12cm3 molecule-1 s-1 (at 297+3 oK and 1 atmosphere total pressure) using the relative rate technique with pentanal, decane, and tridecane as the reference compounds. Assuming an average OH concentration of 1 x 106 molecules cm-3, an atmospheric lifetime of 15 h is calculated for cyclohexanol. Products of the OH + COL reaction were determined to more clearly define cyclohexanol's atmospheric degradation mechanism. The observed products were: cyclohexanone, hexanedial, 3-hydroxycyclohexanone, and 4-hydroxycyclohexanone. Consideration of the potential reaction pathways suggests that each of these products is formed via hydrogen abstraction at a different site on the cyclohexanol ring.
Book Synopsis Atmospheric Degradation Mechanisms of Organic Sulphur Compounds by : Cecilia Arsene
Download or read book Atmospheric Degradation Mechanisms of Organic Sulphur Compounds written by Cecilia Arsene and published by . This book was released on 2001 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Experimental Study of the Chemical Degradation of Biogenic Volatile Organic Compounds by Atmospheric OH Radicals by : Michael Rolletter
Download or read book Experimental Study of the Chemical Degradation of Biogenic Volatile Organic Compounds by Atmospheric OH Radicals written by Michael Rolletter and published by . This book was released on 2021 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Environmental Organic Chemistry for Engineers by : James G. Speight
Download or read book Environmental Organic Chemistry for Engineers written by James G. Speight and published by Butterworth-Heinemann. This book was released on 2016-11-02 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt: Environmental Organic Chemistry for Engineers clearly defines the principles of environmental organic chemistry and the role they play in forming remediation strategies. In this reference, the author explores parameter estimation methods, the thermodynamics, and kinetics needed to predict the fate, transports, and reactivity of organic compounds in air, water, and soils. The book's four part treatment starts with the classification of organic molecules and physical properties of natural organic matter, halocarbons, phenols, polyaromatic hydrocarbons, organophosphates, and surfactants. An overview of remediation technologies and a discussion of the interactions that lead to physical properties that affect chemical distribution in the environment is also detailed, as are the important reaction classes of organic molecules, including substituent effects and structure and activity relationships found in Part Two and Three. Part four is devoted to the strengths and weaknesses of different remediation technologies and when they should be employed. - Clearly defines the principles of environmental organic chemistry and the role they play in forming remediation strategies - Includes the tools and methods for classifying environmental contaminants found in air, water, and soil - Presents a wide-range of remediation technologies and when they should be deployed for maximum effect
Book Synopsis Global Sources of Local Pollution by : National Research Council
Download or read book Global Sources of Local Pollution written by National Research Council and published by National Academies Press. This book was released on 2010-02-15 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recent advances in air pollution monitoring and modeling capabilities have made it possible to show that air pollution can be transported long distances and that adverse impacts of emitted pollutants cannot be confined to one country or even one continent. Pollutants from traffic, cooking stoves, and factories emitted half a world away can make the air we inhale today more hazardous for our health. The relative importance of this "imported" pollution is likely to increase, as emissions in developing countries grow, and air quality standards in industrial countries are tightened. Global Sources of Local Pollution examines the impact of the long-range transport of four key air pollutants (ozone, particulate matter, mercury, and persistent organic pollutants) on air quality and pollutant deposition in the United States. It also explores the environmental impacts of U.S. emissions on other parts of the world. The book recommends that the United States work with the international community to develop an integrated system for determining pollution sources and impacts and to design effective response strategies. This book will be useful to international, federal, state, and local policy makers responsible for understanding and managing air pollution and its impacts on human health and well-being.
Book Synopsis OECD Guidelines for the Testing of Chemicals, Section 3 Test No. 311: Anaerobic Biodegradability of Organic Compounds in Digested Sludge: by Measurement of Gas Production by : OECD
Download or read book OECD Guidelines for the Testing of Chemicals, Section 3 Test No. 311: Anaerobic Biodegradability of Organic Compounds in Digested Sludge: by Measurement of Gas Production written by OECD and published by OECD Publishing. This book was released on 2006-07-11 with total page 20 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Test Guideline describes a screening method for the evaluation of potential anaerobic biodegradability of organic chemicals under specific conditions. Washed digested sludge, containing low (
Book Synopsis Volatile Organic Compounds in the Atmosphere by : ed Hester
Download or read book Volatile Organic Compounds in the Atmosphere written by ed Hester and published by . This book was released on 1995 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Handbook on Biodegradation and Biological Treatment of Hazardous Organic Compounds by : M.H. van Agteren
Download or read book Handbook on Biodegradation and Biological Treatment of Hazardous Organic Compounds written by M.H. van Agteren and published by Springer Science & Business Media. This book was released on 1998-05-31 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt: The introduction of synthetic organic chemicals into the environment during the last few decades has given rise to major concern about the ecotoxicological effects and ultimate fate of these compounds. The pollutants that are considered to be most hazardous because of their intrinsic toxicity, high exposure level, or recalcitrant behavior in the environment have been placed on blacklists and other policy priority lists. The fate of synthetic compounds that enter the environment is mainly determined by their rate of biodegradation, which therefore also has a major effect on the degree of bioaccumulation and the risk of ecotoxicological effects. The degree and rate of biodegradation is also of critical importance for the feasibility of biological techniques to clean up contaminated sites and waste streams. The biodegradation of xenobiotics has thus been the subject of numerous studies, which resulted in thousands of publications in scientific journals, books, and conference proceedings. These studies led to a deeper understanding of the diversity of biodegradation processes. As a result, it has become possible to enhance the rate of degradation of recalcitrant pollutants during biological treatment and to design completely new treatment processes. At present, much work is being done to expand the range of pollutants to which biodegradation can be applied, and to make treatment techniques less expensive and better applicable for waste streams which are difficult to handle.
Book Synopsis Chemistry of Marine Water and Sediments by : Antonio Gianguzza
Download or read book Chemistry of Marine Water and Sediments written by Antonio Gianguzza and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 513 pages. Available in PDF, EPUB and Kindle. Book excerpt: The most important processes on the Earth`s surface occur in the Ocean where materials and energy are primarily exchanged. In the case of marine chemistry different fields of chemistry from organic to inorganic as well as thermodynamics and biochemistry are involved. Analytical Chemistry is a very important tool for the quantification of biogeochemical processes by providing correct and even more sophisticated methodologies. These are often directly applied 'in situ', in order to detect trace and ultra-trace natural and anthropogenic substances. Kinetic and thermodynamic studies allow us to establish whether the process occurs. Once discovered it is then possible to build up general models for environmental systems. This book gathers many aspects with the aim of creating a general picture of the chemical processes occurring in the marine environment
