Asymmetric Domino Reactions

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Asymmetric Domino Reactions

Author : Helene Pellissier
Publisher : Royal Society of Chemistry
ISBN 13 : 184973710X
Total Pages : 519 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Asymmetric Domino Reactions by : Helene Pellissier

Download or read book Asymmetric Domino Reactions written by Helene Pellissier and published by Royal Society of Chemistry. This book was released on 2013-03-13 with total page 519 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the latest developments in asymmetric domino reactions, focussing on those published in the last 6 years. These fascinating reactions have rapidly become one of the most current fields in organic chemistry, since they allow reaching easily high molecular complexity in an economically favourable way with advantages of savings in solvent, time, energy, and costs. Unsurprisingly, the high levels of efficiency and enantioselectivity generally reached in these reactions have been exploited for the production of a wide number of complex chiral molecules with dense stereochemistry and functionality, which are motifs present in biologically active compounds and natural products. The book is divided into three principal sections, dealing successively with asymmetric domino reactions based on the use of chiral auxiliaries, asymmetric domino reactions based on the use of chiral metal catalysts, and asymmetric domino reactions based on the use of chiral organocatalysts, covering the literature since the beginning of 2006.

Asymmetric Metal Catalysis in Enantioselective Domino Reactions

Author : Helene Pellissier
Publisher : John Wiley & Sons
ISBN 13 : 3527346198
Total Pages : 402 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Asymmetric Metal Catalysis in Enantioselective Domino Reactions by : Helene Pellissier

Download or read book Asymmetric Metal Catalysis in Enantioselective Domino Reactions written by Helene Pellissier and published by John Wiley & Sons. This book was released on 2019-11-11 with total page 402 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduces an innovative and outstanding tool for the easy synthesis of complex chiral structures in a single step Covering all of the literature since the beginning of 2006, this must-have book for chemists collects the major progress in the field of enantioselective one-, two-, and multicomponent domino reactions promoted by chiral metal catalysts. It clearly illustrates how enantioselective metal-catalyzed processes constitute outstanding tools for the development of a wide variety of fascinating one-pot asymmetric domino reactions, thereby allowing many complex products to be easily generated from simple materials in one step. The book also strictly follows the definition of domino reactions by Tietze as single-, two-, as well as multicomponent transformations. Asymmetric Metal Catalysis in Enantioselective Domino Reactions is divided into twelve chapters, dealing with enantioselective copper-, palladium-, rhodium-, scandium-, silver-, nickel-, gold-, magnesium-, cobalt-, zinc-, yttrium and ytterbium-, and other metal-catalyzed domino reactions. Most of the chapters are divided into two parts dealing successively with one- and two-component domino reactions, and three-component processes. Each part is subdivided according to the nature of domino reactions. Each chapter of the book includes selected applications of synthetic methodologies to prepare natural and biologically active products. -Presents the novel combination of asymmetric metal catalysis with the concept of fascinating domino reactions, which allows high molecular complexity with a remarkable level of enantioselectivity -Showcases an incredible tool synthesizing complex and diverse chiral structures in a single reaction step -Includes applications in total synthesis of natural products and biologically active compounds -Written by a renowned international specialist in the field -Stimulates the design of novel asymmetric domino reactions and their use in the synthesis of natural products, pharmaceuticals, agrochemicals, and materials Asymmetric Metal Catalysis in Enantioselective Domino Reactions will be of high interest to synthetic, organic, medicinal, and catalytic chemists in academia and R&D departments.

Asymmetric Domino Reactions

Author : Hélène Pellissier
Publisher : Royal Society of Chemistry
ISBN 13 : 1849736510
Total Pages : 519 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Asymmetric Domino Reactions by : Hélène Pellissier

Download or read book Asymmetric Domino Reactions written by Hélène Pellissier and published by Royal Society of Chemistry. This book was released on 2013 with total page 519 pages. Available in PDF, EPUB and Kindle. Book excerpt: Accessible references for researchers and industrialists in this exciting field, covering both developments and applications of catalysis.

Domino Reactions in Organic Synthesis

Author : Lutz F. Tietze
Publisher : John Wiley & Sons
ISBN 13 : 3527608680
Total Pages : 631 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Domino Reactions in Organic Synthesis by : Lutz F. Tietze

Download or read book Domino Reactions in Organic Synthesis written by Lutz F. Tietze and published by John Wiley & Sons. This book was released on 2006-12-13 with total page 631 pages. Available in PDF, EPUB and Kindle. Book excerpt: Domino reactions enable you to build complex structures in one-pot reactions without the need to isolate intermediates- a dream comes true. In this book, the well-respected expert, Professor Lutz Tietze, summarizes the possibilities of this reaction type - an approach for an efficiant, economically benificial and ecological benign synthesis. A definite must for every organic chemist.

Organocatalytic Asymmetric Domino Reactions Via N-heterocyclic Carbene and Bifunctional Hydrogen-bonding Donor Catalysts

Author : Long Zhao
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (17 download)

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Book Synopsis Organocatalytic Asymmetric Domino Reactions Via N-heterocyclic Carbene and Bifunctional Hydrogen-bonding Donor Catalysts by : Long Zhao

Download or read book Organocatalytic Asymmetric Domino Reactions Via N-heterocyclic Carbene and Bifunctional Hydrogen-bonding Donor Catalysts written by Long Zhao and published by . This book was released on 2018* with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Asymmetric Metal Catalysis in Enantioselective Domino Reactions

Author : Helene Pellissier
Publisher : John Wiley & Sons
ISBN 13 : 3527822526
Total Pages : 342 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Asymmetric Metal Catalysis in Enantioselective Domino Reactions by : Helene Pellissier

Download or read book Asymmetric Metal Catalysis in Enantioselective Domino Reactions written by Helene Pellissier and published by John Wiley & Sons. This book was released on 2019-07-12 with total page 342 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduces an innovative and outstanding tool for the easy synthesis of complex chiral structures in a single step Covering all of the literature since the beginning of 2006, this must-have book for chemists collects the major progress in the field of enantioselective one-, two-, and multicomponent domino reactions promoted by chiral metal catalysts. It clearly illustrates how enantioselective metal-catalyzed processes constitute outstanding tools for the development of a wide variety of fascinating one-pot asymmetric domino reactions, thereby allowing many complex products to be easily generated from simple materials in one step. The book also strictly follows the definition of domino reactions by Tietze as single-, two-, as well as multicomponent transformations. Asymmetric Metal Catalysis in Enantioselective Domino Reactions is divided into twelve chapters, dealing with enantioselective copper-, palladium-, rhodium-, scandium-, silver-, nickel-, gold-, magnesium-, cobalt-, zinc-, yttrium and ytterbium-, and other metal-catalyzed domino reactions. Most of the chapters are divided into two parts dealing successively with one- and two-component domino reactions, and three-component processes. Each part is subdivided according to the nature of domino reactions. Each chapter of the book includes selected applications of synthetic methodologies to prepare natural and biologically active products. -Presents the novel combination of asymmetric metal catalysis with the concept of fascinating domino reactions, which allows high molecular complexity with a remarkable level of enantioselectivity -Showcases an incredible tool synthesizing complex and diverse chiral structures in a single reaction step -Includes applications in total synthesis of natural products and biologically active compounds -Written by a renowned international specialist in the field -Stimulates the design of novel asymmetric domino reactions and their use in the synthesis of natural products, pharmaceuticals, agrochemicals, and materials Asymmetric Metal Catalysis in Enantioselective Domino Reactions will be of high interest to synthetic, organic, medicinal, and catalytic chemists in academia and R&D departments.

Development of New Asymmetric Organocatalytic Domino Reactions for the Synthesis of (benzo-fused) Five- and Benzo-fused Six-membered Cyclic Compounds

Download Development of New Asymmetric Organocatalytic Domino Reactions for the Synthesis of (benzo-fused) Five- and Benzo-fused Six-membered Cyclic Compounds PDF Online Free

Author : Stanimira Hristeva
Publisher :
ISBN 13 : 9783843925358
Total Pages : pages
Book Rating : 4.9/5 (253 download)

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Book Synopsis Development of New Asymmetric Organocatalytic Domino Reactions for the Synthesis of (benzo-fused) Five- and Benzo-fused Six-membered Cyclic Compounds by : Stanimira Hristeva

Download or read book Development of New Asymmetric Organocatalytic Domino Reactions for the Synthesis of (benzo-fused) Five- and Benzo-fused Six-membered Cyclic Compounds written by Stanimira Hristeva and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Domino and Intramolecular Rearrangement Reactions as Advanced Synthetic Methods in Glycoscience

Author : Zbigniew J. Witczak
Publisher : John Wiley & Sons
ISBN 13 : 1119044200
Total Pages : 372 pages
Book Rating : 4.1/5 (19 download)

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Book Synopsis Domino and Intramolecular Rearrangement Reactions as Advanced Synthetic Methods in Glycoscience by : Zbigniew J. Witczak

Download or read book Domino and Intramolecular Rearrangement Reactions as Advanced Synthetic Methods in Glycoscience written by Zbigniew J. Witczak and published by John Wiley & Sons. This book was released on 2016-02-23 with total page 372 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book consists of a brief introduction, a foreward provided by professor Danishefsky of Columbia University, and about 14 - 16 chapters, each written by one or two eminent scholars/authors describing their recent research in the area of either domino reactions or intramolecular rearrangements in carbohydrate chemistry. Three or four chapters will be reviews. The domino (cascade, tandem) reactions are always intramolecular. They are usually very fast, clean and offer highly complex structures in a one pot process. Intramolecular rearrangements offer very similar advantages and often lead to highly complex products as well. Although many recently isolated carbohydrates fulfill various sophisticated functions, their structures are often very complex. The editors cover the broadest scope of novel methodologies possible. All the synthetic and application aspects of domino/cascade reactions are explored in this book. A second theme that will be covered is intramolecular rearrangement, which is also fast, stereoselective, and often constitutes one or more steps of domino / cascade process. Selected examples of intramolecular rearrangements are presented. Together, both processes offer an elegant and convenient approach to the synthesis of many complex molecules, which are normally difficult to synthesize via alternative routes. It appears that domino and intramolecular rearrangements are ideally suited to synthesize certain specific modified monosaccharides. What is particularly important is that both processes are intermolecular and almost always yield products with very well-defined stereochemistry. This high definition is absolutely crucial when synthesizing advanced, modified mono and oligosaccharides. The choice of contributors reflects an emphasis on both therapeutic and pharmacological aspects of carbohydrate chemistry.

N-heterocyclic Carbene - and Copper-catalyzed Asymmetric Domino Reactions

Author : Tao Shu
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (18 download)

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Book Synopsis N-heterocyclic Carbene - and Copper-catalyzed Asymmetric Domino Reactions by : Tao Shu

Download or read book N-heterocyclic Carbene - and Copper-catalyzed Asymmetric Domino Reactions written by Tao Shu and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Asymmetric Organic Reactions

Author : James D. Morrison
Publisher :
ISBN 13 :
Total Pages : 492 pages
Book Rating : 4.:/5 (45 download)

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Book Synopsis Asymmetric Organic Reactions by : James D. Morrison

Download or read book Asymmetric Organic Reactions written by James D. Morrison and published by . This book was released on 1980 with total page 492 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Catalytic Asymmetric Conjugate Reactions

Author : Armando Cordova
Publisher : John Wiley & Sons
ISBN 13 : 3527632093
Total Pages : 489 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Catalytic Asymmetric Conjugate Reactions by : Armando Cordova

Download or read book Catalytic Asymmetric Conjugate Reactions written by Armando Cordova and published by John Wiley & Sons. This book was released on 2010-12-01 with total page 489 pages. Available in PDF, EPUB and Kindle. Book excerpt: This unique and long-awaited handbook on this important topic in the hot field of stereoselective organic synthesis covers several types of nucleophiles. Top international authors deal with modern forms of achieving stereoselective conjugate additions based on the use of chiral auxiliaries or asymmetric catalysis, such as P-N ligands, organocatalysis, domino reactions, Lewis acid and base catalysis. There is also a discussion of the employment of enantioselective conjugate addition transformations in total synthesis of important molecules. With its reliable and previously unpublished experimental procedures, this is a true source of high quality information.

Domino Reactions. Asymmetric Palladium(II)-catalyzed Cyclizations-carbonylations in the Synthesis of Natural Compounds

Author : Jana Dohanosova
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (8 download)

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Book Synopsis Domino Reactions. Asymmetric Palladium(II)-catalyzed Cyclizations-carbonylations in the Synthesis of Natural Compounds by : Jana Dohanosova

Download or read book Domino Reactions. Asymmetric Palladium(II)-catalyzed Cyclizations-carbonylations in the Synthesis of Natural Compounds written by Jana Dohanosova and published by . This book was released on 2012 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Intramolecular Wacker-type cyclization of unsaturated polyols and aminopolyols represents a powerful method in the synthesis of oxygen- or nitrogen-containing heterocycles. The thesis offers an insight into the systematic study of domino intramolecular palladium(II)-catalyzed cyclization and coupling reaction allowing the implementation of side chains into heterocyclic skeletons along with the formation of two stereocenters in a single step. Different types of coupling partners and reaction conditions were examined, the influence of substrate substituents on diastereoselectivity is discussed. The applications in the synthesis of naturally occuring compounds or their analogs are outlined (anisomycin, varitriol). Palladium(II)-catalyzed oxycarbonylation represents an interesting transformation of unsaturated polyols into bicyclic lactones with tetrahydrofuran structural motif with excellent cis-stereoselectivity. The first example of the use of ionic liquids as reaction media in the asymmetric Pd(II)-catalyzed oxycarbonylation is described. Based on a ligand screening, the chiral bis(oxazoline)-type ligands were successfully used in the Pd(II)-promoted bicyclisationof racemic pent-4-ene-1,3-diol (±)-69a. The kinetic resolution of (±)-69a in the presenceof chiral catalyst and p-benzoquinone under carbon monoxide atmosphere using acetic acid and/or ionic liquid as solvent afforded enantioenriched 2,6-dioxabicyclo[3.3.0]octane-3-ones(R,R)-70a (57% ee) and (S,S)-70a (80% ee), respectively.

Principles and Applications of Asymmetric Synthesis

Author : Guo-Qiang Lin
Publisher : John Wiley & Sons
ISBN 13 : 0471465240
Total Pages : 536 pages
Book Rating : 4.4/5 (714 download)

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Book Synopsis Principles and Applications of Asymmetric Synthesis by : Guo-Qiang Lin

Download or read book Principles and Applications of Asymmetric Synthesis written by Guo-Qiang Lin and published by John Wiley & Sons. This book was released on 2003-05-29 with total page 536 pages. Available in PDF, EPUB and Kindle. Book excerpt: Asymmetric synthesis remains a challenge to practicing scientistsas the need for enantiomerically pure or enriched compoundscontinues to increase. Over the last decade, a large amount ofliterature has been published in this field. Principles andApplications of Asymmetric Synthesis consolidates and evaluates themost useful methodologies into a one-volume resource for theconvenience of practicing scientists and students. Authored by internationally renowned scientists in the field, thisreliable reference covers more than 450 reactions and includesimportant stoichiometric as well as catalytic asymmetric reactions.The first chapter reviews the basic principles, commonnomenclature, and analytical methods, and the remainder of the bookis organized according to reaction type. The text examines suchtopics as: Carbon-carbon bond formations involving carbonyls, enamines,imines, and enolates Asymmetric C-O bond formations including epoxidation,dihydroxylation, and aminohydroxylation Asymmetric synthesis using the Diels-Alder reaction and othercyclizations Applications to the total synthesis of natural products Use of enzymes in asymmetric synthesis Practicing chemists in the pharmaceutical, fine chemical, andagricultural professions as well as graduate students will findthat Principles and Applications of Asymmetric Synthesis affordscomprehensive and current coverage.

Principles of Asymmetric Synthesis

Author : Robert E. Gawley
Publisher : Elsevier
ISBN 13 : 0080914136
Total Pages : 569 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Principles of Asymmetric Synthesis by : Robert E. Gawley

Download or read book Principles of Asymmetric Synthesis written by Robert E. Gawley and published by Elsevier. This book was released on 2012-05-29 with total page 569 pages. Available in PDF, EPUB and Kindle. Book excerpt: The world is chiral. Most of the molecules in it are chiral, and asymmetric synthesis is an important means by which enantiopure chiral molecules may be obtained for study and sale. Using examples from the literature of asymmetric synthesis, this book presents a detailed analysis of the factors that govern stereoselectivity in organic reactions. After an explanation of the basic physical-organic principles governing stereoselective reactions, the authors provide a detailed, annotated glossary of stereochemical terms. A chapter on "Practical Aspects of Asymmetric Synthesis" provides a critical overview of the most common methods for the preparation of enantiomerically pure compounds, techniques for analysis of stereoisomers using chromatographic, spectroscopic, and chiroptical methods. The authors then present an overview of the most important methods in contemporary asymmetric synthesis organized by reaction type. Thus, there are four chapters on carbon-carbon bond forming reactions, one chapter on reductions, and one on oxidations (carbon-oxygen and carbon-nitrogen bond forming reactions). This organization allows the reader to compare the leading methods for asymmetric synthesis in an appropriate context. A highlight of the book is the presentation and discussion of transition states at the current level of understanding, for important reaction types. In addition, extensive tables of examples are used to give the reader an appreciation for the scope of each reaction. Finally, leading references are provided to natural product synthesis that has been accomplished using a given reaction as a key step. Authoritative glossary to aid understanding of stereochemical terminology Explanations of the key factors influencing stereoselectivity with numerous examples, organized by reaction type A handy reference guide to the literature of asymmetric synthesis for practitioners in the field

Asymmetric Dearomatization Reactions

Author : Shu-Li You
Publisher : John Wiley & Sons
ISBN 13 : 3527338519
Total Pages : 422 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Asymmetric Dearomatization Reactions by : Shu-Li You

Download or read book Asymmetric Dearomatization Reactions written by Shu-Li You and published by John Wiley & Sons. This book was released on 2016-09-13 with total page 422 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first comprehensive account of the rapidly growing field of asymmetric dearomatization reactions with a focus on catalytic methods. It introduces the concept of dearomatization and describes recent progress in asymmetric reaction procedures with different catalyst systems, such as organocatalysts, transition metal catalysts, and enzymes. Chapters on dearomatizations of electron-deficient aromatic rings, dearomatization reactions via transition metal-catalyzed cross-couplings as well as dearomatization strategies in the synthesis of complex natural products are also included. Written by pioneers in the field, this is a highly valuable source of information not only for professional synthetic chemists in academia and industry but also for all those are interested in asymmetric methodologies and organic synthesis in general.

Reactions and Syntheses

Author : Lutz F. Tietze
Publisher : John Wiley & Sons
ISBN 13 : 3527338144
Total Pages : 667 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Reactions and Syntheses by : Lutz F. Tietze

Download or read book Reactions and Syntheses written by Lutz F. Tietze and published by John Wiley & Sons. This book was released on 2015-06-22 with total page 667 pages. Available in PDF, EPUB and Kindle. Book excerpt: The second edition of this classic text book has been completely revised, updated, and extended to include chapters on biomimetic amination reactions, Wacker oxidation, and useful domino reactions. The first-class author team with long-standing experience in practical courses on organic chemistry covers a multitude of preparative procedures of reaction types and compound classes indispensable in modern organic synthesis. Throughout, the experiments are accompanied by the theoretical and mechanistic fundamentals, while the clearly structured sub-chapters provide concise background information, retrosynthetic analysis, information on isolation and purification, analytical data as well as current literature citations. Finally, in each case the synthesis is labeled with one of three levels of difficulty. An indispensable manual for students and lecturers in chemistry, organic chemists, as well as lab technicians and chemists in the pharmaceutical and agrochemical industries.

Dienamine Catalysis for Organic Synthesis

Author : Kengadarane Anebouselvy
Publisher : Royal Society of Chemistry
ISBN 13 : 1782620907
Total Pages : 220 pages
Book Rating : 4.7/5 (826 download)

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Book Synopsis Dienamine Catalysis for Organic Synthesis by : Kengadarane Anebouselvy

Download or read book Dienamine Catalysis for Organic Synthesis written by Kengadarane Anebouselvy and published by Royal Society of Chemistry. This book was released on 2018-03-02 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the last decade a new era in asymmetric catalysis has been realised by the discovery of L-proline induced chiral enamines from carbonyls. Inspired by this, researchers have developed many other primary catalytic species in situ, more recently secondary catalytic species such as aminals have been identified for use in asymmetric synthesis. High-yielding asymmetric synthesis of bioactive and natural products through mild catalysis is an efficient approach in reaction engineering. In the early days, synthetic chemists mainly focused on the synthesis of complex molecules, with less attention on the reaction efficiency and eco-friendly conditions. Recent investigations have been directed towards the development of atom economy, eco-friendly and enantioselective synthesis for more targeted and efficient synthesis. Building on the momentum of this rapidly expanding research area, Dienamine catalysis for organic synthesis will provide a comprehensive introduction, from the preformed species, in situ generation and onto their applications in the synthesis of bioactive molecules and natural products.