Applications of Polyhedral Oligomeric Silsesquioxanes

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Publisher : Springer Science & Business Media
ISBN 13 : 904813787X
Total Pages : 440 pages
Book Rating : 4.0/5 (481 download)

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Book Synopsis Applications of Polyhedral Oligomeric Silsesquioxanes by : Claire Hartmann-Thompson

Download or read book Applications of Polyhedral Oligomeric Silsesquioxanes written by Claire Hartmann-Thompson and published by Springer Science & Business Media. This book was released on 2011-01-03 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: The commercial availability and decreasing cost of polyhedral oligomeric silsesquioxanes in recent years has opened up the field to everybody who wishes to apply these unique properties in their own technologies. This is the first book to provide a comprehensive overview of these applications, and covers the synthesis, characterization and history of polyhedral oligomeric silsesquioxanes, their use as metallasilsesquioxane catalysts, their effect upon polymer properties and plastics performance, and their use in superhydrophobic nanocomposites, and electronics, energy, space and biomedical applications. "Applications of Polyhedral Oligomeric Silsesquioxanes" is a valuable reference for those working across a range of disciplines, including chemists, materials scientists, polymer physicists, plastics engineers, surface scientists, and anybody with a commercial or academic interest in plastics, composite materials, space materials, dental materials, tissue engineering, drug delivery, lithography, fuel cells, batteries, lubricants, or liquid crystal, LED, sensor, photovoltaic or biomedical devices.

Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites

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Publisher : Elsevier
ISBN 13 : 0128213582
Total Pages : 578 pages
Book Rating : 4.1/5 (282 download)

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Book Synopsis Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites by : Sabu Thomas

Download or read book Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites written by Sabu Thomas and published by Elsevier. This book was released on 2021-03-25 with total page 578 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyhedral Oligomeric Silsesquioxane (POSS) Polymer Nanocomposites: From Synthesis to Applications offers extensive coverage of polyhedral oligomeric silsesquioxanes and their nanocomposites, including their synthesis, characterization, interfacial interactions and advanced applications. Sections introduce essentials, information on their preparation and discussions on polymeric materials, including elastomers, thermoplastics, thermosetting polymers, polymer blends and IPNs. Further sections cover the latest analysis techniques, examine the properties of POSS-polymer nanocomposites, and discuss key application areas, such as biological, energy, defense, and space. Finally, issues surrounding industry implementation and lifecycle are explored. This is a valuable reference for researchers, scientists and advanced students in the areas of polymer composites and nanocomposites, polymer chemistry, polymer physics, polymer science, and materials science and engineering. In an industrial setting, this book will be of great interest to scientists, R&D professionals, and engineers across industries and disciplines. - Covers all aspects of polyhedral oligomeric silsesquioxanes (POSS) and their nanocomposites, including synthesis and characterization techniques, properties, analysis, applications and trends - Targets POSS nanocomposites, describing synthesis, characterization and the selection of POSS filler types according to polymeric material - Explains the preparation and utilization of POSS polymer nanocomposites for cutting-edge applications, including biological, energy, and defense field applications

Silicon Containing Hybrid Copolymers

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Publisher : John Wiley & Sons
ISBN 13 : 3527823484
Total Pages : 302 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Silicon Containing Hybrid Copolymers by : Chaobin He

Download or read book Silicon Containing Hybrid Copolymers written by Chaobin He and published by John Wiley & Sons. This book was released on 2020-01-31 with total page 302 pages. Available in PDF, EPUB and Kindle. Book excerpt: Combines chemistry and material science in order to provide a complete overview of the design, synthesis, and applications of organo-silica This book offers comprehensive and systematic coverage of the latest developments in functional hybrid silicon copolymers, their applications, and how they were developed in relation to previous works in the preparation of various functional groups terminated silicone materials. Silicon Containing Hybrid Copolymers begins with a chapter that introduces readers to organo-silicon materials. It then presents a chapter on reactive functionally terminated polyorganosiloxanes, and contains a section on the methods and advances of functionalized polyhedral oligomeric silsesquioxanes (POSS) and copolymers. Nanostructured self-assemblies from silicon containing hybrid copolymers are discussed?as are superhydrophobic materials derived from hybrid silicon. Other chapters examine silicone copolymers for healthcare and personal care applications; construction of organic optoelectronic materials by using polyhedral oligomeric silsesquioxanes (POSS); and 3D printing silicone materials and devices. The book also includes an overview of material toughening and fire retardancy in regards to hybrid POSS nanocomposites. This title: -Focuses on design and synthesis strategies, providing a valuable resource for researchers in academia and industry -Presents recent applications, with emphasis on the underlying strategies and the influence from previous designs, in fields such as healthcare and consumer care -Combines synthetic pathways with design specific considerations to provide the reader with greater control over the design process Silicon Containing Hybrid Copolymers is an ideal book for materials scientists, polymer chemists, and bioinorganic chemists.

POSS-Based Polymers

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Publisher : MDPI
ISBN 13 : 3039219944
Total Pages : 310 pages
Book Rating : 4.0/5 (392 download)

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Book Synopsis POSS-Based Polymers by : Ignazio Blanco

Download or read book POSS-Based Polymers written by Ignazio Blanco and published by MDPI. This book was released on 2019-12-19 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: The combination of functional polymers with inorganic nanostructured compounds has become a major area of research and technological development owing to the remarkable properties and multifunctionalities deriving from their nano and hybrid structures. In this context, polyhedral oligomeric silsesquioxanes (POSSs) have increasing importance and a dominant position with respect to the reinforcement of polymeric materials. Although POSSs were first described in 1946 by Scott, these materials, however, have not immediately been successful if we consider that, starting from 1946 and up to 1995, we find in the literature 85 manuscripts regarding POSSs; which means that less than two papers per year were published over 50 years. Since 1995, we observe an exponential growth of scientific manuscripts concerning POSSs. It is changing from an annual average of 20 manuscripts for the period 1995–2000 to an annual average of about 400 manuscripts, with an increase of 2800%. The introduction of POSSs inorganic nanostructures into polymers gives rise to polymer nanostructured materials (PNMs) with interesting mechanical and physical properties, thus representing a radical alternative to the traditional filled polymers or polymer compositions.

Polymer/POSS Nanocomposites and Hybrid Materials

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Publisher : Springer
ISBN 13 : 3030023273
Total Pages : 470 pages
Book Rating : 4.0/5 (3 download)

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Book Synopsis Polymer/POSS Nanocomposites and Hybrid Materials by : Susheel Kalia

Download or read book Polymer/POSS Nanocomposites and Hybrid Materials written by Susheel Kalia and published by Springer. This book was released on 2018-11-27 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides an overview of polymer nanocomposites and hybrid materials with polyhedral oligomeric silsesquioxanes (POSS). Among inorganic nanoparticles, functionalized POSS are unique nano-building blocks that can be used to create a wide variety of hybrid and composite materials, where precise control of nanostructures and properties is required. This book describes the influence of incorporation of POSS moieties into (organic) polymer matrices on the mechanical, thermal and flammability behavior of composites and hybrid organic-inorganic materials. Importantly, POSS-containing materials can be bio-functionalized by linking e.g. peptides and growth factors through appropriate surface modification in order to enhance the haemo-compatibility of cardiovascular devices made of these materials. This volume includes descriptions of synthesis routes of POSS and POSS-containing polymeric materials (e.g. based on polyolefines, epoxy resins and polyurethanes), presentation of POSS’ role as flame retardants and as biocompatible linker, as well as the depiction of decomposition and ageing processes.

Chemistry of Bioconjugates

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Publisher : John Wiley & Sons
ISBN 13 : 1118776372
Total Pages : 934 pages
Book Rating : 4.1/5 (187 download)

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Book Synopsis Chemistry of Bioconjugates by : Ravin Narain

Download or read book Chemistry of Bioconjugates written by Ravin Narain and published by John Wiley & Sons. This book was released on 2013-12-02 with total page 934 pages. Available in PDF, EPUB and Kindle. Book excerpt: Explores bioconjugate properties and applications of polymers, dendrimers, lipids, nanoparticles, and nanotubes Bioconjugation has enabled breakthroughs across many areas of industry and biomedicine. With its emphasis on synthesis, properties and applications, this book enables readers to understand the connection between chemistry and the biological application of bioconjugated materials. Its detailed descriptions of methods make it possible for researchers to fabricate and take full advantage of bioconjugates for a broad range of applications. Moreover, the book sets the foundation for the development of new applications, including assays, imaging, biosensors, drug delivery, and diagnostics. Chemistry of Bioconjugates features contributions from an international team of leading experts and pioneers in the field. These contributions reflect the authors’ firsthand laboratory experience as well as a thorough review of the current literature. The book’s six sections examine: General methods of bioconjugation Polymer bioconjugates Organic nanoparticle-based bioconjugates Inorganic nanomaterial bioconjugates, including metals and metal oxides Cell-based, hydrogel/microgel, and glyco-bioconjugates Characterization, physico-(bio)chemical properties, and applications of bioconjugates This comprehensive exploration of bioconjugates includes discussions of polymers, dendrimers, lipids, nanoparticles, and nanotubes. References at the end of each chapter serve as a gateway to the most important original research findings and reviews in the field. By drawing together and analyzing all the latest chemical methods and research findings on the physico-chemical and biochemical properties of bioconjugates, Chemistry of Bioconjugates sheds new light on the significance and potential of bioconjugation. The book is recommended for organic and polymer chemists, biochemists, biomaterial scientists, carbohydrate chemists, biophysicists, bioengineers, and drug and gene delivery scientists.

Silicon Polymers

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Publisher : Springer Science & Business Media
ISBN 13 : 3642160476
Total Pages : 242 pages
Book Rating : 4.6/5 (421 download)

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Book Synopsis Silicon Polymers by : Aziz M. Muzafarov

Download or read book Silicon Polymers written by Aziz M. Muzafarov and published by Springer Science & Business Media. This book was released on 2010-09-22 with total page 242 pages. Available in PDF, EPUB and Kindle. Book excerpt: Modern Synthetic and Application Aspects of Polysilanes: An Underestimated Class of Materials?, by A. Feigl, A. Bockholt, J. Weis, and B. Rieger; * Conjugated Organosilicon Materials for Organic Electronics and Photonics, by Sergei A. Ponomarenko and Stephan Kirchmeyer; * Polycarbosilanes Based on Silicon-Carbon Cyclic Monomers, by E.Sh. Finkelshtein, N.V. Ushakov, and M.L. Gringolts; * New Synthetic Strategies for Structured Silicones Using B(C6F5)3, by Michael A. Brook, John B. Grande, and François Ganachaud; * Polyhedral Oligomeric Silsesquioxanes with Controlled Structure: Formation and Application in New Si-Based Polymer Systems, by Yusuke Kawakami, Yuriko Kakihana, Akio Miyazato, Seiji Tateyama, and Md. Asadul Hoque;

Polymers for Light-emitting Devices and Displays

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Publisher : John Wiley & Sons
ISBN 13 : 1119654602
Total Pages : 288 pages
Book Rating : 4.1/5 (196 download)

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Book Synopsis Polymers for Light-emitting Devices and Displays by : Inamuddin

Download or read book Polymers for Light-emitting Devices and Displays written by Inamuddin and published by John Wiley & Sons. This book was released on 2020-05-27 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymers for Light-Emitting Devices and Displays provides an in-depth overview of fabrication methods and unique properties of polymeric semiconductors, and their potential applications for LEDs including organic electronics, displays, and optoelectronics. Some of the chapter subjects include: • The newest polymeric materials and processes beyond the classical structure of PLED • Conjugated polymers and their application in the light-emitting diodes (OLEDs & PLEDs) as optoelectronic devices. • The novel work carried out on electrospun nanofibers used for LEDs. • The roles of diversified architectures, layers, components, and their structural modifications in determining efficiencies and parameters of PLEDs as high-performance devices. • Polymer liquid crystal devices (PLCs), their synthesis, and applications in various liquid crystal devices (LCs) and displays. • Reviews the state-of-art of materials and technologies to manufacture hybrid white light-emitting diodes based on inorganic light sources and organic wavelength converters.

Molecular Spectroscopy—Experiment and Theory

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Publisher : Springer
ISBN 13 : 3030013553
Total Pages : 529 pages
Book Rating : 4.0/5 (3 download)

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Book Synopsis Molecular Spectroscopy—Experiment and Theory by : Andrzej Koleżyński

Download or read book Molecular Spectroscopy—Experiment and Theory written by Andrzej Koleżyński and published by Springer. This book was released on 2018-10-10 with total page 529 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book reviews various aspects of molecular spectroscopy and its application in materials science, chemistry, physics, medicine, the arts and the earth sciences. Written by an international group of recognized experts, it examines how complementary applications of diverse spectroscopic methods can be used to study the structure and properties of different materials. The chapters cover the whole spectrum of topics related to theoretical and computational methods, as well as the practical application of spectroscopic techniques to study the structure and dynamics of molecular systems, solid-state crystalline and amorphous materials, surfaces and interfaces, and biological systems. As such, the book offers an invaluable resource for all researchers and postgraduate students interested in the latest developments in the theory, experimentation, measurement and application of various advanced spectroscopic methods for the study of materials.

An Introduction to Ionic Liquids

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Publisher : Royal Society of Chemistry
ISBN 13 : 1849737053
Total Pages : 297 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis An Introduction to Ionic Liquids by : Michael Freemantle

Download or read book An Introduction to Ionic Liquids written by Michael Freemantle and published by Royal Society of Chemistry. This book was released on 2019-03-22 with total page 297 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the late 1990s, there was an explosion of research on ionic liquids and they are now a major topic of academic and industrial interest with numerous existing and potential applications. Since then, the number of scientific papers focusing on ionic liquids has risen exponentially, including a few edited multi-author books covering the latest advances in ionic liquids chemistry and several volumes of symposium proceedings. Much of the content in these books and volumes is written using technical jargon that only scientists at the cutting edge of ionic liquids research will understand and ionic liquids are hardly covered in most modern chemistry textbooks. This is the first single-author book on ionic liquids and the first introductory book on the topic. It is written in a clear, concise and consistent way. The book provides a useful introduction to ionic liquids for those readers who are not familiar with the topic. It is also wide ranging, embracing every aspect of the chemistry and applications of ionic liquids. The book draws extensively on the primary scientific literature to provide numerous examples of research on ionic liquids. These examples will enable the reader to become familiar with the key developments in ionic liquids chemistry over recent years. The book provides an introduction to: ionic liquids; their nomenclature; history; physical, chemical and biological properties; and their wide ranging uses and potential applications in catalysis, electrochemistry, inorganic chemistry, organic chemistry, analysis, biotechnology, green chemistry and clean technology. Notable and important chapters include "The Green Credentials of Ionic Liquids" and "Biotechnology." The chapter on "Applications" includes sections with brief descriptions of recent research on the development of ionic liquids: - for the construction of a liquid mirror for a moon telescope - for use as rocket propellants - for use as antimicrobial agents that combat MRSA - as active pharmaceutical ingredients and antiviral drugs - for embalming and tissue preservation Science students, researchers, teachers in academic institutions and chemists and other scientists in industry and government laboratories will find the book an invaluable introduction to one of the most rapidly advancing and exciting fields of science and technology today.

Shape Memory Polymers

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Publisher : Smithers Rapra
ISBN 13 : 1909030333
Total Pages : 326 pages
Book Rating : 4.9/5 (9 download)

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Book Synopsis Shape Memory Polymers by : Jinlian Hu

Download or read book Shape Memory Polymers written by Jinlian Hu and published by Smithers Rapra. This book was released on 2014-05-27 with total page 326 pages. Available in PDF, EPUB and Kindle. Book excerpt: Shape-memory polymers (SMP) are a unique branch of the smart materials family which are capable of changing shape on-demand upon exposure to external stimulus. The discovery of SMP made a significant breakthrough in the developments of novel smart materials for a variety of engineering applications, superseded the traditional materials, and also influenced the current methods of product designing. This book provides the latest advanced information of on-going research domains of SMP. This will certainly enlighten the reader to the achievements and tremendous potentials of SMP. The basic fundamentals of SMP, including shape-memory mechanisms and mechanics are described. This will aid reader to become more familiar with SMP and the basic concepts, thus guiding them in undergoing independent research in the SMP field. The book also provides the reader with associated challenges and existing application problems of SMP. This could assist the reader to focus more on these issues and further exploit their knowledge to look for innovative solutions. Future outlooks of SMP research are discussed as well. This book should prove to be extremely useful for academics, R&D managers, researcher scientists, engineers, and all others related to the SMP research.

Fire Retardancy of Polymers

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Publisher : Royal Society of Chemistry
ISBN 13 : 1847552390
Total Pages : 434 pages
Book Rating : 4.8/5 (475 download)

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Book Synopsis Fire Retardancy of Polymers by : Michel Le Bras

Download or read book Fire Retardancy of Polymers written by Michel Le Bras and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 434 pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of polymers is restricted by their flammability - they may indeed initiate or propagate fire. Fire Retardancy of Polymers focuses on mineral additives from either micro- or nano-composites for application in fire retardants. With the use of fire retardant additives containing halogen or phosphorus compounds in decline, the need for other systems is evident. The major materials that are used are alumina trihydrate or magnesium hydroxide which account for more than 50% by weight of the world-wide sales of fire retardants. Recent works have shown that such halogen-free compounds may give enhanced fire retardancy to polymeric materials when used in low levels, alone, or in synergistic mixtures. The corresponding fire performance depends on the dispersion of the mineral filler, with micrometer-scale dispersion leading to the best performances. Specialists discuss these new applications of mineral fillers with particular emphasis on action mechanisms, new materials including textiles, toxicology and hazards. With extensive references, this book provides a comprehensive and up-to-date view of these applications. This book will appeal to professionals, materials scientists and engineers looking for novel ways to eliminate fire hazards and improve flame retardancy of materials, with a special interest in sustainable development.

Siloxane-Based Polymers

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Publisher : MDPI
ISBN 13 : 3038971251
Total Pages : 188 pages
Book Rating : 4.0/5 (389 download)

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Book Synopsis Siloxane-Based Polymers by : Ignazio Blanco

Download or read book Siloxane-Based Polymers written by Ignazio Blanco and published by MDPI. This book was released on 2019-07-11 with total page 188 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book, a collection of 12 original contributions and 4 reviews, provides a selection of the most recent advances in the preparation, characterization, and applications of polymeric nanocomposites comprising nanoparticles. The concept of nanoparticle-reinforced polymers came about three decades ago, following the outstanding discovery of fullerenes and carbon nanotubes. One of the main ideas behind this approach is to improve the matrix mechanical performance. The nanoparticles exhibit higher specific surface area, surface energy, and density compared to microparticles and, hence, lower nanofiller concentrations are needed to attain properties comparable to, or even better than, those obtained by conventional microfiller loadings, which facilitates processing and minimizes the increase in composite weight. The addition of nanoparticles into different polymer matrices opens up an important research area in the field of composite materials. Moreover, many different types of inorganic nanoparticles, such as quantum dots, metal oxides, and ceramic and metallic nanoparticles, have been incorporated into polymers for their application in a wide range of fields, ranging from medicine to photovoltaics, packaging, and structural applications.

Functional Fillers for Plastics

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Publisher : John Wiley & Sons
ISBN 13 : 9783527629855
Total Pages : 531 pages
Book Rating : 4.6/5 (298 download)

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Book Synopsis Functional Fillers for Plastics by : Marino Xanthos

Download or read book Functional Fillers for Plastics written by Marino Xanthos and published by John Wiley & Sons. This book was released on 2010-01-07 with total page 531 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive and up-to-date overview of the major mineral and organic fillers for plastics, their production, structure and properties, as well as their applications in terms of primary and secondary functions. Edited and co-authored by Professor Marino Xanthos with contributions by international experts from industry and academia, this book presents methods of mixing/incorporation technologies, surface treatments and modifications for enhanced functionality, an analysis of parameters affecting filler performance and a presentation of current and emerging applications. Additionally, the novel classification according to modification of specific polymer properties rather than filler chemical composition provides a better understanding of the relationships between processing, structure and properties of products containing functional fillers and the identification of new markets and applications. For engineers, scientists and technologists involved in the important sector of polymer composites.

Microwaves in Nanoparticle Synthesis

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Publisher : John Wiley & Sons
ISBN 13 : 3527648143
Total Pages : 324 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Microwaves in Nanoparticle Synthesis by : Satoshi Horikoshi

Download or read book Microwaves in Nanoparticle Synthesis written by Satoshi Horikoshi and published by John Wiley & Sons. This book was released on 2013-05-03 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: For the first time, this comprehensive handbook presents the emerging field of microwave technology for the synthesis of nanoparticles. Divided into three parts--fundamentals, methods, and applications--it covers topics including microwave theory, scale-up, microwave plasma synthesis, characterization, and more. This offers both an important volume for academic researchers, and a resource for those in industry exploring the applications of nanoparticles in semiconductors, electronics, catalysis, sensors, and more.

New Polymeric Materials Based on Element-Blocks

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Publisher : Springer
ISBN 13 : 9789811328886
Total Pages : 0 pages
Book Rating : 4.3/5 (288 download)

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Book Synopsis New Polymeric Materials Based on Element-Blocks by : Yoshiki Chujo

Download or read book New Polymeric Materials Based on Element-Blocks written by Yoshiki Chujo and published by Springer. This book was released on 2019-01-12 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book introduces the recent progress that has resulted from utilizing the idea of "element-block polymers". A structural unit consisting of various groups of elements is called an "element-block." The design and synthesis of new element-blocks, polymerization of these blocks, and development of methods of forming higher-order structures and achieving hierarchical interface control in order to yield the desired functions are expected to result in manifold advantages. These benefits will encourage the creation of new polymeric materials that share, at a high level, electronic, optical, and magnetic properties not achievable with conventional organic polymeric materials as well as forming properties of molding processability and flexible designability that inorganic materials lack. By pioneering innovative synthetic processes that exploit the reactivity of elements and the preparation techniques employed for inorganic element-blocks, the aim is (1) to create a new series of innovative polymers based on the novel concept of element-block polymers, in which the characteristics of elements are extensively combined and utilized, and (2) to formulate theories related to these polymers. This book demonstrates especially the design strategies and the resulting successful examples offering highly functional materials that utilize element-block polymers as a key unit.

Reactive and Functional Polymers Volume One

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Publisher : Springer Nature
ISBN 13 : 3030434036
Total Pages : 434 pages
Book Rating : 4.0/5 (34 download)

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Book Synopsis Reactive and Functional Polymers Volume One by : Tomy J. Gutiérrez

Download or read book Reactive and Functional Polymers Volume One written by Tomy J. Gutiérrez and published by Springer Nature. This book was released on 2020-08-25 with total page 434 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reactive and functional polymers are manufactured with the aim of improving the performance of unmodified polymers or providing functionality for different applications. These polymers are created mainly through chemical reactions, but there are other important modifications that can be carried out by physical alterations in order to obtain reactive and functional polymers. This volume presents a comprehensive analysis of these reactive and functional polymers. Reactive and Functional Polymers Volume One provides the principles and foundations for the design, development, manufacture and processing of reactive and functional polymers based primarily on biopolymers, polyesters and polyurenthanes. The text provides an in-depth review of updated sources on reactive resins and silicones. In this book, world-renowned researchers have participated, including Dr. Runcang Sun (Associate editor for the journal ‘Carbohydrate Polymers’). With its comprehensive scope and up-to-date coverage of issues and trends in Reactive and Functional Polymers, this is an outstanding book for students, professors, researchers and industrialists working in the field of polymers and plastic materials.