Read Books Online and Download eBooks, EPub, PDF, Mobi, Kindle, Text Full Free.
An Exploration Of Mid To High Valent Transition Metal Complexes For Application To Catalysis
Download An Exploration Of Mid To High Valent Transition Metal Complexes For Application To Catalysis full books in PDF, epub, and Kindle. Read online An Exploration Of Mid To High Valent Transition Metal Complexes For Application To Catalysis ebook anywhere anytime directly on your device. Fast Download speed and no annoying ads. We cannot guarantee that every ebooks is available!
Book Synopsis An Exploration of Mid- to High-valent Transition Metal Complexes for Application to Catalysis by : Kelly E. Aldrich
Download or read book An Exploration of Mid- to High-valent Transition Metal Complexes for Application to Catalysis written by Kelly E. Aldrich and published by . This book was released on 2019 with total page 824 pages. Available in PDF, EPUB and Kindle. Book excerpt: The valency or oxidation state of a transition metal in a complex plays a large role in determining the reactivity of the complex. With transition metal chemistry, historically accessible chemistry has often focused on metals in a low oxidation state. However, transformations involving transition metals in high oxidation states are of equal importance in providing complex products for use in consumer products. Expanding the applications and understanding of transition metal complexes in high oxidation states is the focus of the research presented in this dissertation. Fundamental studies of how ligands interact with high valent metals is presented in chapters 2 and 3, where a chromium(VI) model complex has been used to study bonding interactions between this d0 transition metal and phosphine ligands. Practical application of high valent titanium(IV) catalysts to C--N bond forming reactions is presented in chapters 4--6. Finally, chapters 7 and 8 focus on the changes in the character of M--N double bonds, with M=Fe and Ru, as the metal is forced to higher oxidation states. Collectively, these studies demonstrate different approaches to the same general problems and questions of how chemists can better understand and utilize high valent transitions metals to do catalytically-target desired transformations.
Book Synopsis Transition Metal-Catalyzed Carbene Transformations by : Jianbo Wang
Download or read book Transition Metal-Catalyzed Carbene Transformations written by Jianbo Wang and published by John Wiley & Sons. This book was released on 2022-05-16 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents an up-to-date overview of the rapidly growing field of carbene transformations Carbene transformations have had an enormous impact on catalysis and organometallic chemistry. With the growth of transition metal-catalyzed carbene transformations in recent decades, carbene transformations are today an important compound class in organic synthesis as well as in the pharmaceutical and agrochemical industries. Edited by leading experts in the field, Transition Metal-Catalyzed Carbene Transformations is a thorough summary of the most recent advances in the rapidly expanding research area. This authoritative volume covers different reaction types such as ring forming reactions and rearrangement reactions, details their conditions and properties, and provides readers with accurate information on a wide range of carbene reactions. Twelve in-depth chapters address topics including carbene C-H bond insertion in alkane functionalization, the application of engineered enzymes in asymmetric carbene transfer, progress in transition-metal-catalyzed cross-coupling using carbene precursors, and more. Throughout the text, the authors highlight novel catalytic systems, transformations, and applications of transition-metal-catalyzed carbene transfer. Highlights the dynamic nature of the field of transition-metal-catalyzed carbene transformations Summarizes the catalytic radical approach for selective carbene cyclopropanation, high enantioselectivity in X-H insertions, and bio-inspired carbene transformations Introduces chiral N,N'-dioxide and chiral guanidine-based catalysts and different transformations with gold catalysis Discusses approaches in cycloaddition reactions with metal carbenes and polymerization with carbene transformations Outlines multicomponent reactions through gem-difunctionalization and transition-metal-catalyzed cross-coupling using carbene precursors Transition Metal-Catalyzed Carbene Transformations is essential reading for all chemists involved in organometallics, including organic and inorganic chemists, catalytic chemists, and chemists working in industry.
Book Synopsis Exploration of High-valent Transition Metal Arene Complexes by : Anthony James Lepine
Download or read book Exploration of High-valent Transition Metal Arene Complexes written by Anthony James Lepine and published by . This book was released on 2005 with total page 148 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis High Valent Early Transition Metal Complexes as Catalysts for Organic Transformations by : Mark W. Glenny
Download or read book High Valent Early Transition Metal Complexes as Catalysts for Organic Transformations written by Mark W. Glenny and published by . This book was released on 1999 with total page 516 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Transition Metals in Coordination Environments by : Ewa Broclawik
Download or read book Transition Metals in Coordination Environments written by Ewa Broclawik and published by Springer. This book was released on 2019-03-16 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on the electronic properties of transition metals in coordination environments. These properties are responsible for the unique and intricate activity of transition metal sites in bio- and inorganic catalysis, but also pose challenges for both theoretical and experimental studies. Written by an international group of recognized experts, the book reviews recent advances in computational modeling and discusses their interplay using experiments. It covers a broad range of topics, including advanced computational methods for transition metal systems; spectroscopic, electrochemical and catalytic properties of transition metals in coordination environments; metalloenzymes and biomimetic compounds; and spin-related phenomena. As such, the book offers an invaluable resource for all researchers and postgraduate students interested in both fundamental and application-oriented research in the field of transition metal systems.
Book Synopsis Homogeneous Transition-metal Catalysis by : Christopher Masters
Download or read book Homogeneous Transition-metal Catalysis written by Christopher Masters and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: Soluble catalysts are used extensively in many branches of chemistry and are indeed a vital constituent of many natural processes. They find wide application throughout the chemical industry where they assist in the production of several million tonnes of chemicals each year. Since homogeneous systems, especially those incorporating transition metals, often function effectively under milder conditions than their heterogeneous counterparts, they are becoming increasingly important at a time when the chemical industry in particular, and society in general, is seeking ways of conserving energy and of making the best possible use of available resources. My principal objective in- writing this book is to engender sufficient enthusiasm for, and knowledge of, the subject in the reader that he or she will be encouraged to begin, or continue, to make their own contribution to advancing our knowledge of homogeneous catalysis. After attempting to acquaint the reader with some of the ground rules I have tried to describe the present scope, and the future potential, of this fascinating field of chemistry by drawing both on academic and on industrial data sources. This approach stems from a personal conviction that future progress could be considerably hastened by a more meaningful dialogue between chemists working both in industrial and in academic research institutions. Wherever possible, examples of the commercial application of homogeneous catalyst systems have been included and no attempt has been made in any way to disguise the many unresolved questions and exciting challenges which still pervade this rapidly developing area.
Book Synopsis Transition Metal Carbyne Complexes by : F.R. Kreißl
Download or read book Transition Metal Carbyne Complexes written by F.R. Kreißl and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of transition metal carbyne complexes has become a highly attractive field during the past twenty years. In recent years its application to aspects of catalysis and metathesis has gained considerable interest from inorganic as well as organic chemists. In addition, organic synthesis by means of metal carbon multiple bond reagents offers the most sophisticated technology currently available. In consideration of these developments some of Professor E. O. Fischer's former coworkers and colleagues felt obliged to orga nize this NATO Advanced Research Workshop on Transition Metal Carbyne Complexes in the Bavarian Alps. They have been encouraged by the fact that most of the distinguished scientists in the field of metal-carbon multiple bond chemistry had finally agreed to participate and to present stimulating lectures. The organizers of the workshop are deeply grateful to the Scientific Affairs Division of the NATO for the generous financial support of the meeting in Wildbad Kreuth and for the preparation of this book. They also feel indebted to acknowledge the generous support from Wacker-Chemie, BASF, Peroxid-Chemie, Hoechst and Bayer. Finally they thank the staff of the Hanns-Seidel-Stiftung in Wildbad Kreuth for providing a pleasant and stimu lating atmosphere during the meeting.
Book Synopsis Application of Transition Metal Catalysts in Organic Synthesis by : L. Brandsma
Download or read book Application of Transition Metal Catalysts in Organic Synthesis written by L. Brandsma and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 349 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homogeneous catalysis is an important strategy for the synthesis of high-valued chemicals. L. Brandsma has carefully selected and checked the experimental procedures illustrating the catalytic use of copper, nickel, and palladium compounds in organic synthesis. All procedures are on a preparative scale, make economic use of solvents and catalysts, avoid toxic substances and have high yields.
Book Synopsis Transition Metal Sulphides by : Th. Weber
Download or read book Transition Metal Sulphides written by Th. Weber and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 357 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrotreating catalysis with transition metal sulphides is one of the most important areas of industrial heterogeneous catalysis. The present book deals with the chemical and catalytic aspects of transition metal sulphides, focusing on their use in hydrotreating catalysis. The book¿s 12 chapters present reviews of solid-state, coordination and organometallic chemistry, surface science and spectroscopic studies, quantum chemical calculations, catalytic studies with model and real catalysts, as well as refinery processes. A presentation of state-of-the-art background to pertinent work in the field. Can be used as an introduction to the chemical and catalytic properties of transition metal sulphides as well as an advanced level reference.
Book Synopsis Redox-based Catalytic Chemistry of Transition Metal Complexes by : Takahiko Kojima
Download or read book Redox-based Catalytic Chemistry of Transition Metal Complexes written by Takahiko Kojima and published by Royal Society of Chemistry. This book was released on 2024-12-20 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal complexes as catalysts play an indispensable role in transformation of chemical substances to value-added products using less energy-consuming processes and with high selectivity and efficiency. In collaboration with the Japan Society of Coordination Chemistry (JSCC), the work is a translation of the original Japanese book focusing on metal complex catalysts that are effective in redox reactions and covers important reactions involving metal complex catalysts. It describes not only what reactions proceed, but also the intermediates they pass through and how the reactions proceed, including computational chemistry approaches. It allows you to gain a deeper understanding of the reaction mechanisms of metal complex catalysts. The scope of this book includes oxidative reactions performed by high-valent metal-oxo species, reductive reactions, bond activation and bond formation, and photocatalytic reactions. Topics in this book will be interest to those studying catalytic chemistry and related fields including coordination chemistry, organometallic chemistry, organic chemistry, bioinorganic chemistry and industrial chemistry.
Book Synopsis Exploring Transition Metal Catalysis in Water for in Vivo Applications by : Eva J. Meeus
Download or read book Exploring Transition Metal Catalysis in Water for in Vivo Applications written by Eva J. Meeus and published by . This book was released on 2024 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Transition metal catalysis proves a powerful tool to achieve otherwise synthetically challenging, or even impossible, transformations with (high) selectivity and is therefore employed in various areas of chemistry. Recently, transition metal-catalysed reactions have been successfully performed in cells (in vitro) and living systems (in vivo). The achievements made thus far reveal the potential of transition metal catalysis and its applications in such biological settings. Interestingly, the scope is limited compared to the breadth of transition metal-catalysed reactions that have been unlocked for synthetic applications. Translating transition metal-catalysed reactions from flasks to cells is non-trivial as the conditions in cells are fairly different compared to the highly controlled and adaptable conditions achieved in a flask. The development of catalytic systems for future applications in vivo therefore proceeds through many steps, starting with evaluating their reactivity, selectivity, and stability in water and under biologically relevant and biomimetic conditions. By exploring transition metal-catalysed reactions in water for in vivo applications, this dissertation has contributed to the subfield of bioorthogonal chemistry devoted to complementing Nature’s repertoire of reactions. Our studies have revealed the challenges associated with the performance of transition metal catalysis in aqueous media and how a detailed understanding of a catalytic system can address them. Apart from these fundamental studies, we have performed explorative studies under biologically relevant and biomimetic conditions in the context of intracellular drug synthesis. Moreover, we have developed a new and compatible protocol that enables detailed kinetic studies in complex reaction media, comparable to the cellular environment, to facilitate the translation of transition metal catalysis from flasks to cells."--
Book Synopsis Early Main Group Metal Catalysis by : Sjoerd Harder
Download or read book Early Main Group Metal Catalysis written by Sjoerd Harder and published by John Wiley & Sons. This book was released on 2019-11-21 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain educational elements and deal with concepts illustrated by examples that cover the main developments. After a short introduction on polar organometallic chemistry and synthesis of early main group metal complexes, a variety of catalytic reactions are described, e.g. polymerization of alkenes, hydroamination and phosphination reactions, hydrosilylation, hydroboration and hydrogenation catalysis, as well as enantioselective and Lewis-acid catalysis. The book addresses organic chemists and researchers in industry interested in the state-of-the-art and new possibilities of early main group metal catalysis as well as newcomers to the field. Written by a team of leaders in the field, it is a very welcome addition to the area of main group metal chemistry, and to the field of catalysis.
Book Synopsis Catalysis by Precious Metals, Past and Future by : Marcela Martinez Tejada
Download or read book Catalysis by Precious Metals, Past and Future written by Marcela Martinez Tejada and published by MDPI. This book was released on 2020-04-15 with total page 204 pages. Available in PDF, EPUB and Kindle. Book excerpt: The future of the precious metals is shiny and resistant. Although expensive and potentially replaceable by transition metal catalysts, precious metal implementation in research and industry shows potential. These metals catalyze oxidation and hydrogenation due to their dissociative behavior toward hydrogen and oxygen, dehydrogenation, isomerization, and aromatization, etc. The precious metal catalysts, especially platinum-based catalysts, are involved in a variety of industrial processes. Examples include Pt–Rh gauze for nitric acid production, the Pt/Al2O3 catalyst for cyclohexane and propylene production, and Pd/Al2O3 catalysts for petrochemical hydropurification reactions, etc. A quick search of the number of published articles in the last five years containing a combination of corresponding “metals” (Pt, Pd, Ru, Rh and Au) and “catalysts” as keywords indicates the importance of the Pt catalysts, but also the continuous increase in the contribution of Pd and Au. This Special Issue reveals the importance of precious metals in catalysis and focuses on mono- and bi-metallic formulations of any supported precious metals and their promotional catalytic effect of other transition metals. The application of precious metals in diverse reactions, either homogeneous or heterogeneous, and studies of the preparation, characterization, and applications of the supported precious metal catalysts, are presented.
Book Synopsis Transition Metals in Homogeneous Catalysis by : Gerhard N. Schrauzer
Download or read book Transition Metals in Homogeneous Catalysis written by Gerhard N. Schrauzer and published by . This book was released on 1971 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Transition Metal Reagents and Catalysts by : Jiro Tsuji
Download or read book Transition Metal Reagents and Catalysts written by Jiro Tsuji and published by . This book was released on 2000-02-29 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition Metal Reagents and Catalysts Innovations in Organic Synthesis Jiro Tsuji Emeritus Professor, Tokyo Institute of Technology, Japan Numerous innovative and practical synthetic methods using transition metal complexes as either catalysts or reagents have been developed over the last 35 years. Transition Metal Reagents and Catalysts combines the varied applications of transition metal complexes in a unique and timely book in this rapidly advancing area of organic synthesis. This text is an easily understandable and enjoyable read for organic chemists who are not yet familiar with organo-transition metal chemistry. Transition Metal Reagents and Catalysts presents: * Complete coverage of nearly 35 years of transition metal complex chemistry * An in-depth treatment of many innovative synthetic methodologies * A rational classification of all reactions according to substrates and reaction mechanisms * Examples of important applications of transition metal catalysed reactions. A knowledge of organic synthesis using transition metal complexes is a must for all synthetic organic chemists. Written for chemists who wish to apply novel synthetic methods using transition metal complexes to solve problems in organic and pharmaceutical chemistry, such as synthesis of fine and bulk chemicals and natural products, Transition Metal Reagents and Catalysts is an essential reference source and an indispensible research companion.
Book Synopsis Transition Metals in the Synthesis of Complex Organic Molecules by : Louis S. Hegedus
Download or read book Transition Metals in the Synthesis of Complex Organic Molecules written by Louis S. Hegedus and published by University Science Books. This book was released on 1999 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.
Book Synopsis Heterocycles from Transition Metal Catalysis by : András Kotschy
Download or read book Heterocycles from Transition Metal Catalysis written by András Kotschy and published by Springer Science & Business Media. This book was released on 2005-12-28 with total page 209 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Heterocycles from Transition Metal Catalysis: Formation and Functionalization" provides a concise summary of the prominent role of late transition metal (palladium, nickel, copper) catalysed processes in the synthesis and functionalization of heterocyclic systems. It gives an introduction to catalytic transformations, an overview of the most important reaction types, and presents synthetically useful catalytic processes classified by the target system and the type of transformation. The book provides a representative selection of transition metal catalysed reactions transformations that are relevant in heterocyclic chemistry. In this way, the authors present a useful resource for members of the academic community looking for a textbook as well as industrial chemists in search of a reference book. This book will be an invaluable resource for synthetic chemists, medicinal chemists, and those more generally interested in applied catalysis.
