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Accelerated Oxidation Of Metals At High Temperatures
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Book Synopsis High Temperature Oxidation and Corrosion of Metals by : David John Young
Download or read book High Temperature Oxidation and Corrosion of Metals written by David John Young and published by Elsevier. This book was released on 2008-10-03 with total page 593 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book is concerned with understanding the fundamental mechanisms of high temperature alloy oxidation. It uses this understanding to develop methods of predicting oxidation rates and the way they change with temperature, gas chemistry and alloy composition. The focus is on designing (or selecting) alloy compositions which provide optimal resistance to attack by corrosive gases. . Emphasises quantitative calculations for predicting reaction rates and the effects of temperature, oxidant activities and alloy compositions. . Uses phase diagrams and diffusion paths to analyse and interpret scale structures and internal precipitation distributions . Provides a detailed examination of corrosion in industrial gases (water vapour effects, carburisation and metal dusting, sulphidation) . Text is well supported by numerous micrographs, phase diagrams and tabulations of relevant thermodynamic and kinetic data . Combines physical chemistry and materials science methodologies.
Book Synopsis Introduction to the High Temperature Oxidation of Metals by : Neil Birks
Download or read book Introduction to the High Temperature Oxidation of Metals written by Neil Birks and published by Cambridge University Press. This book was released on 2009-07-16 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: A straightforward treatment describing the oxidation processes of metals and alloys at elevated temperatures. This 2006 second edition retains the fundamental theory but incorporates advances made in understanding degradation phenomena. The first half provides an authoritative introduction to the basic principles, covering thermodynamics and mechanisms of high temperature corrosion of metals and alloys. The latter half extends the discussion to oxidation processes in complex systems, from reactions in mixed environments to protective techniques, including coatings and atmosphere control. The authors provide a logical and expert treatment of the subject, producing a revised edition that will be a comprehensive guide to material scientists and engineers requiring an understanding of this elementary process.
Book Synopsis Introduction to the High Temperature Oxidation of Metals by : Neil Birks
Download or read book Introduction to the High Temperature Oxidation of Metals written by Neil Birks and published by Cambridge University Press. This book was released on 2006-03-30 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: A straightforward treatment describing the oxidation processes of metals and alloys at elevated temperatures. This 2006 second edition retains the fundamental theory but incorporates advances made in understanding degradation phenomena. The first half provides an authoritative introduction to the basic principles, covering thermodynamics and mechanisms of high temperature corrosion of metals and alloys. The latter half extends the discussion to oxidation processes in complex systems, from reactions in mixed environments to protective techniques, including coatings and atmosphere control. The authors provide a logical and expert treatment of the subject, producing a revised edition that will be a comprehensive guide to material scientists and engineers requiring an understanding of this elementary process.
Book Synopsis High Temperature Coatings by : Sudhangshu Bose
Download or read book High Temperature Coatings written by Sudhangshu Bose and published by Butterworth-Heinemann. This book was released on 2017-11-27 with total page 418 pages. Available in PDF, EPUB and Kindle. Book excerpt: High Temperature Coatings, Second Edition, demonstrates how to counteract the thermal effects of rapid corrosion and degradation of exposed materials and equipment that can occur under high operating temperatures. This is the first true practical guide on the use of thermally protective coatings for high-temperature applications, including the latest developments in materials used for protective coatings. It covers the make-up and behavior of such materials under thermal stress and the methods used for applying them to specific types of substrates, as well as invaluable advice on inspection and repair of existing thermal coatings. With his long experience in the aerospace gas turbine industry, the author has compiled the very latest in coating materials and coating technologies, as well as hard-to-find guidance on maintaining and repairing thermal coatings, including appropriate inspection protocols. The book is supplemented with the latest reference information and additional support to help readers find more application- and industry-type coatings specifications and uses. - Offers an overview of the underlying fundamental concepts of thermally-protective coatings, including thermodynamics, energy kinetics, crystallography and equilibrium phases - Covers essential chemistry and physics of underlying substrates, including steels, nickel-iron alloys, nickel-cobalt alloys and titanium alloys - Provides detailed guidance on a wide variety of coating types, including those used against high temperature corrosion and oxidative degradation and thermal barrier coatings
Book Synopsis Developments in High Temperature Corrosion and Protection of Materials by : W Gao
Download or read book Developments in High Temperature Corrosion and Protection of Materials written by W Gao and published by Elsevier. This book was released on 2008-04-09 with total page 677 pages. Available in PDF, EPUB and Kindle. Book excerpt: High temperature corrosion is a phenomenon that occurs in components that operate at very high temperatures, such as gas turbines, jet engines and industrial plants. Engineers are constantly striving to understand and prevent this type of corrosion. This book examines the latest developments in the understanding of high temperature corrosion processes and protective oxide scales and coatings.Part one looks at high temperature corrosion. Chapters cover diffusion and solid state reactions, external and internal oxidation of alloys, metal dusting corrosion, tribological degradation, hot corrosion, and oxide scales on hot-rolled steel strips. Modern techniques for analysing high temperature oxidation and corrosion are also discussed. Part two discusses methods of protection using ceramics, composites, protective oxide scales and coatings. Chapters focus on layered ternary ceramics, alumina scales, Ti-Al intermetallic compounds, metal matrix composites, chemical vapour deposited silicon carbide, nanocrystalline coatings and thermal barrier coatings. Part three provides case studies illustrating some of the challenges of high temperature corrosion to industry and how they can be overcome. Case studies include the petrochemical industry, modern incinerators and oxidation processing of electronic materials.This book is a valuable reference tool for engineers who develop heat resistant materials, mechanical engineers who design and maintain high temperature equipment and plant, and research scientists and students who study high temperature corrosion and protection of materials. - Describes the latest developments in understanding high temperature corrosion - Presents the latest research by the leading innovators from around the globe - Case studies are provided to illustrate key points
Book Synopsis High-temperature Oxidation of Metals by : Per Kofstad
Download or read book High-temperature Oxidation of Metals written by Per Kofstad and published by . This book was released on 1966 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Corrosion Tests and Standards by : Robert Baboian
Download or read book Corrosion Tests and Standards written by Robert Baboian and published by ASTM International. This book was released on 2005 with total page 887 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Coatings for High-Temperature Structural Materials by : National Research Council
Download or read book Coatings for High-Temperature Structural Materials written by National Research Council and published by National Academies Press. This book was released on 1996-05-13 with total page 102 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book assesses the state of the art of coatings materials and processes for gas-turbine blades and vanes, determines potential applications of coatings in high-temperature environments, identifies needs for improved coatings in terms of performance enhancements, design considerations, and fabrication processes, assesses durability of advanced coating systems in expected service environments, and discusses the required inspection, repair, and maintenance methods. The promising areas for research and development of materials and processes for improved coating systems and the approaches to increased coating standardization are identified, with an emphasis on materials and processes with the potential for improved performance, quality, reproducibility, or manufacturing cost reduction.
Download or read book Shreir's Corrosion written by and published by Elsevier. This book was released on 2009-02-27 with total page 3652 pages. Available in PDF, EPUB and Kindle. Book excerpt: This four-volume reference work builds upon the success of past editions of Elsevier’s Corrosion title (by Shreir, Jarman, and Burstein), covering the range of innovations and applications that have emerged in the years since its publication. Developed in partnership with experts from the Corrosion and Protection Centre at the University of Manchester, Shreir’s Corrosion meets the research and productivity needs of engineers, consultants, and researchers alike. Incorporates coverage of all aspects of the corrosion phenomenon, from the science behind corrosion of metallic and non-metallic materials in liquids and gases to the management of corrosion in specific industries and applications Features cutting-edge topics such as medical applications, metal matrix composites, and corrosion modeling Covers the benefits and limitations of techniques from scanning probes to electrochemical noise and impedance spectroscopy
Book Synopsis Accelerated Aging by : Robert L. Feller
Download or read book Accelerated Aging written by Robert L. Feller and published by Getty Publications. This book was released on 1995-03-02 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: Accelerated Aging: Photochemical and Thermal Aspects represents the culmination of more than 40 years of research by noted scientist Robert L. Feller. The book focuses on the long-term performance of materials such as wool, dyes, and organic compounds; their resistance to change when exposed to environmental factors such as oxygen, ozone, moisture, heat, and light; and their physical durability with handling and use over time. Processes of deterioration are discussed based on speeded-up laboratory studies designed to clarify the chemical reactions involved and their physical consequences.
Book Synopsis Introduction to High Temperature Oxidation and Corrosion by : A. S. Khanna
Download or read book Introduction to High Temperature Oxidation and Corrosion written by A. S. Khanna and published by ASM International. This book was released on 2002-01-01 with total page 337 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text for graduate and post graduate students covers fundamentals of high temperature corrosion and related topics. Early chapters cover the thermodynamics and kinetics of oxidation and defect structure of oxides and diffusion in oxides, and later chapters cover thin and thick layer oxidation, o
Book Synopsis High Temperature Materials and Mechanisms by : Yoseph Bar-Cohen
Download or read book High Temperature Materials and Mechanisms written by Yoseph Bar-Cohen and published by CRC Press. This book was released on 2014-03-03 with total page 586 pages. Available in PDF, EPUB and Kindle. Book excerpt: The use of high-temperature materials in current and future applications, including silicone materials for handling hot foods and metal alloys for developing high-speed aircraft and spacecraft systems, has generated a growing interest in high-temperature technologies. High Temperature Materials and Mechanisms explores a broad range of issues related to high-temperature materials and mechanisms that operate in harsh conditions. While some applications involve the use of materials at high temperatures, others require materials processed at high temperatures for use at room temperature. High-temperature materials must also be resistant to related causes of damage, such as oxidation and corrosion, which are accelerated with increased temperatures. This book examines high-temperature materials and mechanisms from many angles. It covers the topics of processes, materials characterization methods, and the nondestructive evaluation and health monitoring of high-temperature materials and structures. It describes the application of high temperature materials to actuators and sensors, sensor design challenges, as well as various high temperature materials and mechanisms applications and challenges. Utilizing the knowledge of experts in the field, the book considers the multidisciplinary nature of high temperature materials and mechanisms, and covers technology related to several areas including energy, space, aerospace, electronics, and metallurgy. Supplies extensive references at the end of each chapter to enhance further study Addresses related science and engineering disciplines Includes information on drills, actuators, sensors and more A comprehensive resource of information consolidated in one book, this text greatly benefits students in materials science, aerospace and mechanical engineering, and physics. It is also an ideal resource for professionals in the industry.
Book Synopsis The Oxidation of Metals and Alloys by : Erich Scheil
Download or read book The Oxidation of Metals and Alloys written by Erich Scheil and published by . This book was released on 1952 with total page 22 pages. Available in PDF, EPUB and Kindle. Book excerpt: This paper reviews the various types of oxidation processes occurring with pure metals and gives explanations for the varying time-temperature-oxidation rate relations that exist for copper, tungsten, zinc, cadmium, and tantalum. The effect of shape and crystal structure on oxidation is discussed. Principles derived are applied to the oxidation of alloys.
Book Synopsis Reaction of C0-Ni-V Alloys with O2 at 1,3510 to 1,4290K by : Robert M. Doerr
Download or read book Reaction of C0-Ni-V Alloys with O2 at 1,3510 to 1,4290K written by Robert M. Doerr and published by . This book was released on 1970 with total page 26 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Report of Investigations written by and published by . This book was released on with total page 564 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Performance of MCrAlX coatings by : Pimin Zhang
Download or read book Performance of MCrAlX coatings written by Pimin Zhang and published by Linköping University Electronic Press. This book was released on 2019-11-04 with total page 80 pages. Available in PDF, EPUB and Kindle. Book excerpt: MCrAlY coatings (M=Ni and/or Co) are widely used for the protection of superalloy components against oxidation and hot corrosion in the hot sections of gas turbines. The drive for coating systems to bestow adequate oxidation and corrosion resistance upon the components becomes urgent as an inevitable result of the necessary improvement in engine combustion efficiency and service lifetime. Through the careful design of the composition, MCrAlY coating performance can be optimized to meet the needs under different service conditions and component materials, therefore, “MCrAlX”, with “X” stands for the minor alloying elements, is used to highlight the effect. In the present thesis, the performance of new MCrAlX coatings is investigated with respect to oxidation, hot corrosion and interactions between coating-superalloy substrates. Oxidation of MCrAlX coatings can be generally categorized into initial, steady and close-to-end stages. Coating performance can be affected by various factors at different stages, therefore, experiments were designed by targeting the oxidation stages. Investigation on the initial stage oxidation behavior of MCrAlY coatings with post-deposition surface treatments reveals the different growth mechanisms of alumina scales. Surface treatments significantly reduce the alumina growth rate by suppressing transient alumina development and aiding the early formation of ?-Al2O3, which improves the long-term oxidation performance of the coating. Similarly, the modification of minor alloy elements in MCrAlX coatings also serves the purpose. The oxidation behavior of new MCrAlX coatings was investigated at the steady oxidation stage, followed by the microstructure observation, thermodynamic and kinetic simulations. As an alternative reactive element addition of Y, Ce shows a negative effect on the formation of columnar alumina scales of high strain tolerance. In comparison, Fe or Ru addition shows no influence on alumina growth, rather than strengthening the phase stability in the coating and reducing the interdiffusion between coating-substrate through different mechanisms. As the oxidation proceeds to the close-to-end stage, a reliable criterion to estimate the capability of coating to form ?-Al2O3 is of great importance to accurately evaluate coating lifetime. A temperature-dependent critical Al-activity criterion was proposed to better predict the formation of a continuous ?-Al2O3 scale based on correction of elemental activity using thermodynamic database to replace the empirical Al-concentration based criterion. Severe interdiffusion occurs between coating-substrate during high temperature oxidation, accelerating the degradation of the system. Interdiffusion behavior of diffusion couples of superalloys-MCrAlX coatings were examined. It is highlighted that the recrystallization of superficial layer of the substrate contributes to the secondary reaction zone formation and element interdiffusion controls subsequent zone thickening. Study on Type I hot corrosion behavior of new MCrAlX coatings shows that the addition of Fe has no influence on basic fluxing reactions before severe Al depletion from the coating occurs. Instead, it boosts the “effective” Al supply of coating by shifting the equilibrium concentration of Al in the ? phase to a low Al level. Besides, the pre-mature coating degradation at the coating-substrate interface was due to the fast growth of corrosion products from substrate induced large local volume expansions, resulting in early coating spallation. MCrAlY ytbeläggningar (M=Ni och/eller Co) används ofta för att skydda komponenter tillverkade av superlegeringar mot oxidation samt högtemperaturskorrosion i de heta gasturbindelarna. Förbättrad förbränningseffektivitet och livslängd hos gasturbiner, gör att ytbeläggningssystemen måste besitta adekvata oxidations- och korrosionsmotstånd. Genom att omsorgsfullt utforma den kemiska sammansättningen hos MCrAlY ytbeläggningar kan deras prestanda optimeras för att möta kraven från olika driftförhållanden samt olika substratmaterial, därför används beteckningen "MCrAlX" för att belysa förändringar av den kemiska kompositionen, där "X" står för reaktiva legeringsämnen som tillsätts i mindre mängder. I denna avhandling undersöks prestandan hos en ny MCrAlX ytbeläggning med hänsyn till oxidation, högtemperaturskorrosion och interaktionen mellan ytbeläggningen och superlegeringssubstratet. Oxidation av MCrAlX ytbeläggningar kan generellt kategoriseras i tre faser; initiala, stabila och nära-slutet fasen. Ytbeläggningens prestanda kan påverkas av olika faktorer vid de olika faserna, därför utformades olika experiment för att undersöka de olika oxidationsfaserna. Undersökningen av den initiala fasen av oxidationsbeteendet hos MCrAlX ytbeläggningar som genomgått ytbehandlingar efter ytbeläggningsdeponeringen avslöjade olika tillväxtmekanismer hos aluminiumoxidskikten. Aluminiumoxidens tillväxthastighet reducerades signifikant av ytbehandlingarna, detta genom att undertrycka utvecklingen av övergående aluminiumoxid och bistå den tidiga tillväxten av ?-Al2O3, vilket förbättrar ytbeläggningens oxidationsprestanda långsiktigt. De reaktiva legeringsämnena som tillsätts i mindre mänger påverkar ytbeläggningens oxidationsprestanda på liknande sätt. Oxidationsbeteendet hos de nya MCrAlX ytbeläggningarna i den stabila fasen följdes av mikrostrukturundersökning, termodynamiska och kinetiska simuleringar. Det framkom att Ce visar en negativ effekt på bildandet av kolumnära aluminiumoxidskikt med hög töjningstolerans som alternativt reaktivt legeringsämne till Y. Jämförelsevis ger Fe- eller Ru-tillsatser ingen påverkan på aluminiumoxidtillväxten, förutom att det förstärker fasstabiliteten i ytbeläggningen samt genom olika mekanismer reducerar interdiffusionen mellan ytbeläggningen och substratet. När oxidationsprocessen kommit till nära-slutet fasen, är det viktigt att uppskatta kapaciteten hos en ytbeläggning att bilda ?-Al2O3, detta då det är ett tillförlitligt kriterium för att noggrant kunna utvärdera ytbeläggningens livslängd. Därför föreslogs ett temperaturberoende kriterium för kritisk Al-aktivitet för att bättre kunna förutsäga bildandet av ett kontinuerligt ?-Al2O3-skikt. Kriteriet baserades på korrigering av legeringsämnens aktivitet genom att använda en termodynamisk databas, detta för att ersätta det empiriska Al-koncentrations baserade kriteriet. Vid högtemperatursoxidation sker en omfattande interdiffusion mellan ytbeläggningen och substratet, vilket accelererar degraderingen av ytbeläggningssystemet. Därför har interdiffusionsbeteendet mellan superlegeringssubstratet och MCrAlX ytbeläggningen undersökts i denna avhandling. Det framkom att rekristallisationen av ytliga skikt av substratet bidrar till formationen av den sekundära reaktionszonen och att interdiffusion kontrollerar zonens efterföljande tjocklektillväxt. Undersökningen av Typ I högtemperaturskorrosionsbeteendet hos en ny MCrAlX ytbeläggning visar att legeringstillägg av Fe inte påverkar de grundläggande flödesreaktionerna innan en kritisk Al utarmning sker i ytbeläggningen. Istället stimulerar det tillförseln av Al genom att skifta jämviktskoncentrationen av Al i ? fasen till en låg nivå av Al. Det framkom också att den tidiga degraderingen av ytbeläggningen vid gränsskiktet mellan ytbeläggningen och substratet kommer av att den snabba tillväxten av korrosionsprodukter från substratet inducerade en stor lokal volymsutvidgning, vilket ledde till tidig ytbeläggningsspallation.
Book Synopsis Oxidation of Metals by : Karl Hauffe
Download or read book Oxidation of Metals written by Karl Hauffe and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 460 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the translation, the author had the opportunity to re view several chapters, taking into consideration the more recent literature. As far as possible all new theoretical concepts and experi mental data published before 1963 have been quoted and discussed under the theoretical viewpoint of this book. A new chapter "Passivity and Inhibition During High-Tempera ture Oxidation" was introduced. Section 4.8 was enlarged by a dis cussion of the transition from internal to external oxidation. The author very much appreciates the cooperation of the trans lator and of Plenum Press. Gottingen, April 1.965 Karl Hauffe v Preface The number of publications concerned with oxidation and cor rosion processes has become so copious that many engineers and scientists find it practically impossible to obtain an overall view of the growing body of knowledge and to bring order to the confusing multiplicity of experimental data. As a result the need for a compre hensive survey of the present state of research in this field has be come more and more urgent.
