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Absolute Rate Constants For Hydrocarbon Autoxidation Vii Reactivities Of Peroxy Radicals Toward Hydrocarbons And Hydroperoxides
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Book Synopsis Absolute Rate Constants for Hydrocarbon Autoxidation. Vii. Reactivities of Peroxy Radicals Toward Hydrocarbons and Hydroperoxides by : J. A. Howard
Download or read book Absolute Rate Constants for Hydrocarbon Autoxidation. Vii. Reactivities of Peroxy Radicals Toward Hydrocarbons and Hydroperoxides written by J. A. Howard and published by . This book was released on 1967 with total page 18 pages. Available in PDF, EPUB and Kindle. Book excerpt: The four propagation and three termination rate constants for the co-oxidation of cumene and Tetralin were determined at 30C and 56C. The secondary tetralylperoxy radical is about four times as reactive in hydrogen atom abstraction as the tertiary cumylperoxy radical. The rate constant for termination by reaction of a tetralylperoxy and a cumylperoxy radical has about one quarter of the value for termination by two tetralylperoxy radicals. Rate constants for the transfer of hydroperoxidic hydrogen to peroxy radicals were measured. This reaction exhibits an exceptionally large deuterium isotope effect. A possible explanation for the high value is suggested. The absolute rate constants at 30C. for hydrogen atom abstraction from toluene, ethylbenzene, cumene, and Tetralin by cumylperoxy, tetralylperoxy, and 9,10-dihydroanthracyl-9-peroxy radicals were measured. (Author).
Book Synopsis Absolute Rate Constants for Hydrocarbon Autoxidation. Xvi. Reactions of Peroxy Radicals at Low Temperatures by : K. Adamic
Download or read book Absolute Rate Constants for Hydrocarbon Autoxidation. Xvi. Reactions of Peroxy Radicals at Low Temperatures written by K. Adamic and published by . This book was released on 1969 with total page 7 pages. Available in PDF, EPUB and Kindle. Book excerpt: The equilibrium constants for the formation of some t-alkyl tetroxides and the rate constants for irreversible decay of the tetroxides have been measured by electron spin resonance spectroscopy at low temperatures. The equilibrium constant appears to be virtually independent of the nature of the alkyl groups. It is concluded that differences in the rate of constants for chain termination by t-peroxy radicals at ambient temperatures are due chiefly to the differences in rate constants for irreversible tetroxide decomposition. The activation parameters for this reaction indicate that it occurs by one bond rather than two bond scission. (Author).
Book Synopsis Absolute Rate Constants for Hydrocarbon Oxidation. Xii. Rate Constants for Secondary Peroxy Radicals by : J. A. Howard
Download or read book Absolute Rate Constants for Hydrocarbon Oxidation. Xii. Rate Constants for Secondary Peroxy Radicals written by J. A. Howard and published by . This book was released on 1968 with total page 7 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rate constants were measured for hydrogen abstraction from four aralkanes and addition to two aralkenes by five secondary and one primary peroxy radical. These rate constants appear to show a slight dependence on the structure of the attacking peroxy radicals which may be due to the inductive effects of the substituents on the radical. The secondary and primary peroxy radicals are generally about 2-4 times more reactive than tertiary peroxy radicals in abstraction and 4-8 times more reactive in addition. The lower reactivity of tertiary peroxy radicals is probably due to steric factors. (Author).
Book Synopsis ABSOLUTE RATE CONSTANTS FOR HYDROCARBON AUTOXIDATION. XV. THE INDUCED DECOMPOSITION OF SOME T-HYDROPEROXIDES. by : J. A. Howard
Download or read book ABSOLUTE RATE CONSTANTS FOR HYDROCARBON AUTOXIDATION. XV. THE INDUCED DECOMPOSITION OF SOME T-HYDROPEROXIDES. written by J. A. Howard and published by . This book was released on 1969 with total page 6 pages. Available in PDF, EPUB and Kindle. Book excerpt: The radical induced decomposition of several t-hydroperoxides at 30C has been studied. In the self reaction of t-alkylperoxy radicals the ratio of the rates of alkoxy radical diffusion from the cage to combination in the cage is essentially independent of the size of the t-alkyl group. The 1,1-diphenylethoxy radical undergoes a 1,2-phenyl shift to yield the 1-phenyl-1-phenoxyethyl radical more rapidly that it undergoes beta-scission. (Author).
Book Synopsis Application of Thermodynamics to Biological and Materials Science by : Mizutani Tadashi
Download or read book Application of Thermodynamics to Biological and Materials Science written by Mizutani Tadashi and published by BoD – Books on Demand. This book was released on 2011-01-14 with total page 644 pages. Available in PDF, EPUB and Kindle. Book excerpt: Progress of thermodynamics has been stimulated by the findings of a variety of fields of science and technology. The principles of thermodynamics are so general that the application is widespread to such fields as solid state physics, chemistry, biology, astronomical science, materials science, and chemical engineering. The contents of this book should be of help to many scientists and engineers.
Book Synopsis Bioscience Methodologies in Physical Chemistry by : Alberto D'Amore
Download or read book Bioscience Methodologies in Physical Chemistry written by Alberto D'Amore and published by CRC Press. This book was released on 2013-07-29 with total page 516 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of bioscience methodologies in physical chemistry stands at the intersection of the power and generality of classical and quantum physics with the minute molecular complexity of chemistry and biology. This book provides an application of physical principles in explaining and rationalizing chemical and biological phenomena. It does not stick to the classical topics that are conventionally considered as part of physical chemistry; instead it presents principles deciphered from a modern point of view, which is the strength of this book.
Book Synopsis U.S. Government Research and Development Reports Index by :
Download or read book U.S. Government Research and Development Reports Index written by and published by . This book was released on 1968 with total page 826 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Nutraceutical and Specialty Lipids and their Co-Products by : Fereidoon Shahidi
Download or read book Nutraceutical and Specialty Lipids and their Co-Products written by Fereidoon Shahidi and published by CRC Press. This book was released on 2006-03-14 with total page 579 pages. Available in PDF, EPUB and Kindle. Book excerpt: While certain saturated and trans fats continue to face scrutiny as health hazards, new evidence indicates that, in addition to supplying foods with flavor and texture, fats also provide us with dietary components that are absolutely critical to our well-being. The importance of essential fatty acids and fat-soluble vitamins and other minor
Book Synopsis U.S. Government Research & Development Reports by :
Download or read book U.S. Government Research & Development Reports written by and published by . This book was released on 1970 with total page 710 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Oxidation of Organic Compounds written by and published by . This book was released on 1968 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Oxidation of Organic Compounds: Liquid-phase, base-catalyzed and heteroatom oxidations, radical initiation and interactions, inhibition by :
Download or read book Oxidation of Organic Compounds: Liquid-phase, base-catalyzed and heteroatom oxidations, radical initiation and interactions, inhibition written by and published by . This book was released on 1968 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Advances in Chemistry Series written by and published by . This book was released on 1968 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The National Research Council Review by : National Research Council of Canada
Download or read book The National Research Council Review written by National Research Council of Canada and published by . This book was released on 1968 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Absolute Rate Constants for Hydrocarbon Autoxidation by : J. A. Howard
Download or read book Absolute Rate Constants for Hydrocarbon Autoxidation written by J. A. Howard and published by . This book was released on 1965 with total page 8 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Soviet Progress in Chemistry written by and published by . This book was released on 1991 with total page 502 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Government Reports Annual Index by :
Download or read book Government Reports Annual Index written by and published by . This book was released on 1968 with total page 660 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Bibliography of Scientific and Industrial Reports by :
Download or read book Bibliography of Scientific and Industrial Reports written by and published by . This book was released on 1970-07 with total page 940 pages. Available in PDF, EPUB and Kindle. Book excerpt:
