D-Orbitals in the Chemistry of Silicon, Phosphorus and Sulfur

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Publisher : Springer
ISBN 13 :
Total Pages : 240 pages
Book Rating : 4.:/5 (44 download)

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Book Synopsis D-Orbitals in the Chemistry of Silicon, Phosphorus and Sulfur by : H. Kwart

Download or read book D-Orbitals in the Chemistry of Silicon, Phosphorus and Sulfur written by H. Kwart and published by Springer. This book was released on 1977-12 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book was undertaken for the purpose of bringing together the widely diverse lines of experimental work and thinking which has been expressed but has often been unheard on the title question. It will be clear to the reader that a critical viewpoint has been maintained in assembling the material of this rapidly expanding area of concern to organic chemists. It should be clear, too, that the authors are not purvey ing a singular viewpoint and do not regard the discussions presented as the ultimate word on the subject. In fact, it should be anticipated that many ofthe viewpoints pre sented may have to be altered in the light of new developments. In recognition of this and to show the wayan appendix of recent results and interpretation has been included where an alteration in viewpoint on some of the material treated in the text has been necessitated by developments in the most recent literature. This ap pendix should be regarded as the reader's opportunity to maintain currency in all aspects of this subject ifit is kept abreast of the literature. The bibliography, from which most of the material of discussion has been drawn, is organized in a somewhat unusual manner which deserves some explana tion here. A reference citation can consist of (as much as) a six space combination of letters and numerals.

Organic Sulfur Compounds

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Publisher : Elsevier
ISBN 13 : 1483224856
Total Pages : 637 pages
Book Rating : 4.4/5 (832 download)

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Book Synopsis Organic Sulfur Compounds by : N. Kharasch

Download or read book Organic Sulfur Compounds written by N. Kharasch and published by Elsevier. This book was released on 2013-10-22 with total page 637 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Sulfur Compounds, Volume I deals with the chemistry of organic sulfur compounds such as disulfides, polysulfides, olefins, acetylenes, and chloroethylenes. Topics covered range from the inorganic acids of sulfur and the thermodynamics of organic sulfur compounds to some applications of isotopic sulfur and the stereochemistry of disulfides and polysulfides. The mechanism of oxidation of thiols to disulfides is also discussed. Comprised of 40 chapters, this volume first considers the precise structures of elemental sulfur in relation to the reactions of sulfur compounds, followed by an analysis of the inorganic acids of sulfur. The reader is then introduced to the thermodynamics of organic sulfur compounds and the bonding characteristics of the sulfur atom, as well as the infrared spectra of organosulfur compounds. Subsequent chapters focus on the ionic scission of the sulfur-sulfur bond; nucleophilic reactions of thiols with acetylene and chloroethylene; reactions of sulfur with olefins; and the chemistry of isothiocyanates. This book should prove useful to advanced students, practitioners, and research workers in the field of organic chemistry.

The Chemistry of Organic Sulfur Compounds

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Publisher : Elsevier
ISBN 13 : 1483156117
Total Pages : 475 pages
Book Rating : 4.4/5 (831 download)

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Book Synopsis The Chemistry of Organic Sulfur Compounds by : Norman Kharasch

Download or read book The Chemistry of Organic Sulfur Compounds written by Norman Kharasch and published by Elsevier. This book was released on 2013-10-22 with total page 475 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Organic Sulfur Compounds deals with the chemistry of organic sulfur compounds such as thiocyanates, 1-alkynyl thioethers, thiols, and olefins. Topics covered range from the mechanisms of Raney nickel desulfuration to olefin sulfide chemistry, desulfonylation reactions, and alkaline decomposition of aliphatic disulfides. The reaction of cyanide with cystine and cystine peptides is also discussed. This volume is comprised of 15 chapters and begins with an introduction to electron correlation and bond properties in some selected sulfur compounds including thionyl and sulfuryl fluoride. The following chapters explore the mechanisms of Raney nickel desulfuration; isomerization of organic thiocyanates; polyfluoroalkyl derivatives of sulfur; anionic oxidation of thiols and co-oxidation of thiols with olefins; and the chemistry of the 1,2-sithiole ring. Thiohydantoins, thiophosgene, and the alkaline decomposition of aliphatic disulfides are also considered. The final chapter is devoted to oxidation of disulfides, with special reference to cystine. This book will be a useful resource for organic chemists.

Chemical Processes in Soils

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Publisher :
ISBN 13 :
Total Pages : 752 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Chemical Processes in Soils by : M. A. Tabatabai

Download or read book Chemical Processes in Soils written by M. A. Tabatabai and published by . This book was released on 2005 with total page 752 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Organic Chemistry of Sulfur

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Publisher : Springer Science & Business Media
ISBN 13 : 1468420496
Total Pages : 714 pages
Book Rating : 4.4/5 (684 download)

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Book Synopsis Organic Chemistry of Sulfur by : S. Oae

Download or read book Organic Chemistry of Sulfur written by S. Oae and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 714 pages. Available in PDF, EPUB and Kindle. Book excerpt: In recent years organic sulfur chemistry has been growing at an even faster pace than the very rapid development in other fields of chemistry. This phenomenal growth is undoubtedly a reflection of industrial and public demands: not only was sulfur recently in overall surplus for the first time in the history of the chemical industry but it has now become a prin cipal environmental hazard in the form of sulfur dioxide, sulfuric acid and hydrogen sulfide. Another reason, discernible in the last fifteen years, has been the desire, on the part of individual chemists and all types of research managers, to move away from the established chemistry of carbon into the less well understood and sometimes virgin chemistries of the other elements which form covalent bonds. As a result of this movement the last decade has seen the development of sulfur chemistry into a well-organized and now much better understood branch of organic chemistry. Enough of the detail has become clear to see mechanistic interrelationships between previously unconnected reactions and with this clarification the whole subject has in tum become systema tized and subdivided. The divalent sulfur chemistry of thiols, monosulfides, disulfides and polysulfides is a large area in itself, much of it devoted to oxidation-reduction and the breakage and formation of sulfur-sulfur bonds, although interesting discoveries are now being made about the reac tivity of certain sulfur-carbon bonds. Of course, this area has its own mas sive biochemical branch involving enzymes and proteins.

Phosphorus Compounds

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Publisher : Springer Science & Business Media
ISBN 13 : 9048138175
Total Pages : 477 pages
Book Rating : 4.0/5 (481 download)

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Book Synopsis Phosphorus Compounds by : Maurizio Peruzzini

Download or read book Phosphorus Compounds written by Maurizio Peruzzini and published by Springer Science & Business Media. This book was released on 2011-06-10 with total page 477 pages. Available in PDF, EPUB and Kindle. Book excerpt: Each chapter of Phosphorus Compounds: Advanced Tools in Catalysis and Material Sciences have been carefully selected by the editors in order to represent a state-of-the-art overview of how phosphorus chemistry can provide solutions in various fields of applications. The editors have assembled an international array of world-renowned scientists and each chapter is written by experts in the fields of synthetic chemistry, homogeneous catalysis, dendrimers, theoretical calculations, materials science, and medicinal chemistry with a special focus on the chemistry of phosphorus compounds. Phosphorus Compounds: Advanced Tools in Catalysis and Material Sciences is of interest to a general readership ranging from advanced university course students to experts in academia and industry.

Elaboration And Applications Of Metal-organic Frameworks

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Publisher : World Scientific
ISBN 13 : 9813226749
Total Pages : 730 pages
Book Rating : 4.8/5 (132 download)

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Book Synopsis Elaboration And Applications Of Metal-organic Frameworks by : Shengqian Ma

Download or read book Elaboration And Applications Of Metal-organic Frameworks written by Shengqian Ma and published by World Scientific. This book was released on 2018-01-31 with total page 730 pages. Available in PDF, EPUB and Kindle. Book excerpt: This title takes researchers in as well as out of the field of metal-organic framework (MOF) and then guides them on a journey to rediscover and rethink how these designer coordination polymers will influence the realm of materials science. This book opens with a look at a deeply controversial issue, MOF stability, which has plagued many systems, but ultimately has led to better materials that proved to be more robust allowing them to be investigated for multiple applications. This book successfully highlights many of these useful applications that MOFs are well adapted for. Because MOF components, inorganic and organic, can combine the best of both chemical domains, MOFs will improve our environment by removing harmful contaminants from the air and water, reduce the energy required to perform chemical reactions, partition hard to separate molecular mixtures, and form the next-generation of magnetic and electronic materials. MOFs will eventually be used for everyday activities — for monitoring or reacting to changing conditions. Readers of this book can then take note and implement MOFs in their line of research.

An Introduction to Organosulfur Chemistry

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Publisher : John Wiley & Sons
ISBN 13 :
Total Pages : 272 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis An Introduction to Organosulfur Chemistry by : R. J. Cremlyn

Download or read book An Introduction to Organosulfur Chemistry written by R. J. Cremlyn and published by John Wiley & Sons. This book was released on 1996-12-23 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sulfur chemistry is becoming increasingly important as the role of this element is explored in both biological and environmental fields. After the initial chapters have discussed the synthesis, reactivity, and properties of the compounds in general, each of the next nine chapters takes a specific sulfur containing functional group and expands the discussion on synthetic procedures. The final chapter looks at the major uses of organo-sulfur compounds and their impact on biological and environmental areas.

Veterans at Risk

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Publisher : National Academies Press
ISBN 13 : 030904832X
Total Pages : 448 pages
Book Rating : 4.3/5 (9 download)

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Book Synopsis Veterans at Risk by : Institute of Medicine

Download or read book Veterans at Risk written by Institute of Medicine and published by National Academies Press. This book was released on 1993-02-01 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recently, World War II veterans have come forward to claim compensation for health effects they say were caused by their participation in chemical warfare experiments. In response, the Veterans Administration asked the Institute of Medicine to study the issue. Based on a literature review and personal testimony from more than 250 affected veterans, this new volume discusses in detail the development and chemistry of mustard agents and Lewisite followed by interesting and informative discussions about these substances and their possible connection to a range of health problems, from cancer to reproductive disorders. The volume also offers an often chilling historical examination of the use of volunteers in chemical warfare experiments by the U.S. militaryâ€"what the then-young soldiers were told prior to the experiments, how they were "encouraged" to remain in the program, and how they were treated afterward. This comprehensive and controversial book will be of importance to policymakers and legislators, military and civilian planners, officials at the Department of Veterans Affairs, military historians, and researchers.

Sulfur

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Publisher : ASA-CSSA-SSSA
ISBN 13 : 9780891181682
Total Pages : 362 pages
Book Rating : 4.1/5 (816 download)

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Book Synopsis Sulfur by : Joseph Jez

Download or read book Sulfur written by Joseph Jez and published by ASA-CSSA-SSSA. This book was released on 2008 with total page 362 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sulfur forms and cycling processes in soil and their relationship to sulfur fertility / Jeff J. Schoenau and Sukhdev S. Malhi -- Sulfur nutrition of crops in the Indo-Gangetic plains of South Asia / M.P.S. Khurana, U.S. Sandana and Bijay-Singh -- Soil sulfur cycling temperate agricultural systems / Jørgen Eriksen -- History of sulfur deficiency in crops / Silvia Haneklaus, Elke Bloem and Ewald Schnug -- Availability of sulfur to crops from soil and other sources / Warren A. Dick, David Kost and Liming Chen -- Sulfur and cysteine metabolism / Rainer Hoefgen and Holger Hesse -- Sulfur response based on crop, source, and landscape position / Dave Franzen and Cynthia A. Grant -- Sulfur management for soybean production / Kiyoko Hitsuda [and others] -- Sulfur in a fertilizer program for corn / George W. Rehm and John G. Clapp -- Sulfur nutrition and wheat quality / Hamid A. Naeem -- Sulfur and marketable yield of potato / Alexander D. Pavlista -- Sulfur, its role in onion production and related alliums / George E. Boyhan -- Sulfur and the production of rice in wetland and dryland ecosystems / Richard W. Bell -- Evaluation of the relative significance of sulfur and other essential mineral elements in oilseed rape, cereals, and sugar beet production / Ewald Schnug and Silvia Haneklaus -- Improving the sulfur-containing amino acids of soybean to enhance its nutritional value in animal feed / Hari B. Krishnan -- Methionine metabolism in plants / Rachel Amir and Yael Hacham -- Plant sulfur compounds and human health / Joseph M. Jez and Naomi K. Fukagawa -- A future crop biotechnology view of sulfur and selenium / Muhammad Sayyar Khan and Rüdiger Hell.

Humus Chemistry

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Publisher : John Wiley & Sons
ISBN 13 : 9780471594741
Total Pages : 516 pages
Book Rating : 4.5/5 (947 download)

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Book Synopsis Humus Chemistry by : F. J. Stevenson

Download or read book Humus Chemistry written by F. J. Stevenson and published by John Wiley & Sons. This book was released on 1994-08-16 with total page 516 pages. Available in PDF, EPUB and Kindle. Book excerpt: A reference text focusing on basic organic chemistry and reactions of naturally occurring organic substances in soils. Covers pools of organic matter in soils, transformations, methods of extraction and fractionation. Section two deals primarily with the chemistry of known classes of organic compounds in soils including saccharides, lipids and constituents containing nitrogen, phosphorus and sulfur. Section three is concerned with basic organic chemistry of humic substances, followed by the importance of organic matter associations and interactions. Contains new chapters on NMR spectroscopy, analytical pyrolysis and on chemical structures.

Tables of Spectral Data for Structure Determination of Organic Compounds

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Publisher : Springer Science & Business Media
ISBN 13 : 3662224550
Total Pages : 325 pages
Book Rating : 4.6/5 (622 download)

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Book Synopsis Tables of Spectral Data for Structure Determination of Organic Compounds by : Ernö Pretsch

Download or read book Tables of Spectral Data for Structure Determination of Organic Compounds written by Ernö Pretsch and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 325 pages. Available in PDF, EPUB and Kindle. Book excerpt: Although numerical data are, in principle, universal, the compilations presented in this book are extensively annotated and interleaved with text. This translation of the second German edition has been prepared to facilitate the use of this work, with all its valuable detail, by the large community of English-speaking scientists. Translation has also provided an opportunity to correct and revise the text, and to update the nomenclature. Fortunately, spectroscopic data and their relationship with structure do not change much with time so one can predict that this book will, for a long period of time, continue to be very useful to organic chemists involved in the identification of organic compounds or the elucidation of their structure. Klaus Biemann Cambridge, MA, April 1983 Preface to the First German Edition Making use of the information provided by various spectroscopic tech niques has become a matter of routine for the analytically oriented organic chemist. Those who have graduated recently received extensive training in these techniques as part of the curriculum while their older colleagues learned to use these methods by necessity. One can, therefore, assume that chemists are well versed in the proper choice of the methods suitable for the solution of a particular problem and to translate the experimental data into structural information.

Manual of Classification

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Publisher :
ISBN 13 :
Total Pages : 998 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Manual of Classification by : United States. Patent and Trademark Office

Download or read book Manual of Classification written by United States. Patent and Trademark Office and published by . This book was released on 1986 with total page 998 pages. Available in PDF, EPUB and Kindle. Book excerpt: Includes list of replacement pages.

Environmental Degradation and Transformation of Organic Chemicals

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Publisher : CRC Press
ISBN 13 : 1420006770
Total Pages : 738 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Environmental Degradation and Transformation of Organic Chemicals by : Alasdair H. Neilson

Download or read book Environmental Degradation and Transformation of Organic Chemicals written by Alasdair H. Neilson and published by CRC Press. This book was released on 2007-08-09 with total page 738 pages. Available in PDF, EPUB and Kindle. Book excerpt: Addressing the persistent environmental threat of organic chemicals with a fresh approach to degradation and transformation processes, Environmental Degradation and Transformation of Organic Chemicals examines a wide range of compounds as well as abiotic and microbiological reactions mediated by microorganisms. The book emphasizes the pathways used

A Laboratory Manual of Organic Chemistry

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Publisher :
ISBN 13 :
Total Pages : 176 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis A Laboratory Manual of Organic Chemistry by : Roger John Williams

Download or read book A Laboratory Manual of Organic Chemistry written by Roger John Williams and published by . This book was released on 1928 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Phosphorus-31 NMR Spectroscopy

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Publisher : Springer Science & Business Media
ISBN 13 : 3540791183
Total Pages : 138 pages
Book Rating : 4.5/5 (47 download)

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Book Synopsis Phosphorus-31 NMR Spectroscopy by : Olaf Kühl

Download or read book Phosphorus-31 NMR Spectroscopy written by Olaf Kühl and published by Springer Science & Business Media. This book was released on 2008-08-22 with total page 138 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nuclear Magnetic Resonance is a powerful tool, especially for the identification of 1 13 hitherto unknown organic compounds. H- and C-NMR spectroscopy is known and applied by virtually every synthetically working Organic Chemist. Con- quently, the factors governing the differences in chemical shift values, based on chemical environment, bonding, temperature, solvent, pH, etc. , are well understood, and specialty methods developed for almost every conceivable structural challenge. Proton and carbon NMR spectroscopy is part of most bachelors degree courses, with advanced methods integrated into masters degree and other graduate courses. In view of this universal knowledge about proton and carbon NMR spectr- copy within the chemical community, it is remarkable that heteronuclear NMR is still looked upon as something of a curiosity. Admittedly, most organic compounds contain only nitrogen, oxygen, and sulfur atoms, as well as the obligatory hydrogen and carbon atoms, elements that have an unfavourable isotope distribution when it comes to NMR spectroscopy. Each of these three elements has a dominant isotope: 14 16 32 16 32 N (99. 63% natural abundance), O (99. 76%), and S (95. 02%), with O, S, and 34 14 S (4. 21%) NMR silent. N has a nuclear moment I = 1 and a sizeable quadrupolar moment that makes the NMR signals usually very broad and dif cult to analyse.

The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules

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Publisher : Elsevier
ISBN 13 : 0080571166
Total Pages : 522 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules by : Daimay Lin-Vien

Download or read book The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules written by Daimay Lin-Vien and published by Elsevier. This book was released on 1991-12-02 with total page 522 pages. Available in PDF, EPUB and Kindle. Book excerpt: This necessary desk reference for every practicing spectroscopist represents the first definitive book written specifically to integrate knowledge about group frequencies in infrared as well as Raman spectra. In the spirit of previous classics developed by Bellamy and others, this volume has expanded its scope and updated its coverage. In addition to detailing characteristic group frequencies of compounds from a comprehensive assortment of categories, the book includes a collection of spectra and a literature search conducted to verify existing correlations and to determine ways to enhance correlations between vibrational frequencies and molecular structure. Particular attention has been given to the correlation between Raman characteristic frequencies and molecular structure. - Constitutes a necessary reference for every practicing vibrational spectroscopist - Provides the new definitive text on characteristic frequencies of organic molecules - Incorporates group frequencies for both infrared and Raman spectra - Details the characteristic IR and Raman frequencies of compounds in more than twenty major categories - Includes an extensive collection of spectra - Compiled by internationally recognized experts