Tritium Isotope Separation from Light and Heavy Water by Bipolar Electrolysis

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ISBN 13 :
Total Pages : pages
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Download or read book Tritium Isotope Separation from Light and Heavy Water by Bipolar Electrolysis written by and published by . This book was released on 1980 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A process for separating tritium from light and heavy water is described. Hydrogen is transferred at and through bipolar electrodes at rates H> D> T. In a cell containing several bipolar electrodes placed in series between two terminal electrodes, a flow of hydrogen is established from the terminal anode compartment toward the terminal cathode. An electrolyte feed containing tritium is continuously added to the system and is subsequently transported countercurrent to the hydrogen mass transfer. A cascaded system is established, in which effluent streams enriched and depleted in tritium can be withdrawn. The voltage drop is smaller at any bipolar electrode as compared to the voltage for normal electrolysis. Cell design is compact because isotope separation occurs at bipolar electrodes without evolution of gas. Isotope separation was demonstrated in laboratory cells where a steady-state tritium concentration gradient was attained. This gradient was in agreement with concentrations calculated from a derived mathematical model.

Tritium Separation from Light and Heavy Water by Bipolar Electrolysis

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Download or read book Tritium Separation from Light and Heavy Water by Bipolar Electrolysis written by and published by . This book was released on 1979 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Use of bipolar electrolysis with countercurrent electrolyte flow to separate hydrogen isotopes was investigated for the removal of tritium from light water effluents or from heavy water moderator. Deuterium-tritium and protium-tritium separation factors occurring on a Pd-25% Ag bipolar electrode were measured to be 2.05 to 2.16 and 11.6 to 12.4 respectively, at current densities between 0.21 and 0.50 A cm−2, and at 35 to 90°C. Current densities up to 0.3 A cm−2 have been achieved in continuous operation, at 80 to 90°C, without significant gas formation on the bipolar electrodes. From the measured overvoltage at the bipolar electrodes and the electrolyte conductivity the power consumption per stage was calculated to be 3.0 kwh/kg H2O at 0.2 A cm−2 and 5.0 kwh/kg H2O at 0.5 A cm−2 current density, compared to 6.4 and 8.0 kwh/kg H2O for normal electrolysis. A mathematical model derived for hydrogen isotope separation by bipolar electrolysis, i.e., for a square cascade, accurately describes the results for protium-tritium separation in two laboratory scale, multistage experiments with countercurrent electrolyte flow; the measured tiritum concentration gradient through the cascade agreed with the calculated values.

Tritium separation from light and heavy water by bipolar electrolysis

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ISBN 13 :
Total Pages : 0 pages
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Book Synopsis Tritium separation from light and heavy water by bipolar electrolysis by : D. W. Ramey

Download or read book Tritium separation from light and heavy water by bipolar electrolysis written by D. W. Ramey and published by . This book was released on 1979 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Tritium Isotope Separation

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Publisher : CRC Press
ISBN 13 : 9780849343223
Total Pages : 330 pages
Book Rating : 4.3/5 (432 download)

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Book Synopsis Tritium Isotope Separation by : Gheorghe Vasaru

Download or read book Tritium Isotope Separation written by Gheorghe Vasaru and published by CRC Press. This book was released on 1993-03-25 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt: Tritium Isotope Separation is the first book to present a current overview of the separation processes for tritium isotopes. The book consists of two parts. Part I explores the sources of tritium and the evolution of the world's tritium inventory. Part II describes the processes and plants used for tritium isotope separation, enrichment methods for tritium for analytical purposes, methods for recovering and enriching tritium from nuclear and thermonuclear plants, and the laser method. The book in general emphasizes applications, performance, characterization, laboratory experiments, pilot plants and industrial production, reliability, and cost. An author index, subject index, list of acronyms and abbreviations, and glossary have been included to make the book an even more valuable reference. Tritium Isotope Separation will be an essential book for all nuclear energy engineers, nuclear physicists, and others working with various aspects of isotope separation science.

Energy Research Abstracts

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ISBN 13 :
Total Pages : 1696 pages
Book Rating : 4.U/5 (183 download)

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Download or read book Energy Research Abstracts written by and published by . This book was released on 1982 with total page 1696 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Fusion Energy Update

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ISBN 13 :
Total Pages : 116 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Fusion Energy Update by :

Download or read book Fusion Energy Update written by and published by . This book was released on 1980 with total page 116 pages. Available in PDF, EPUB and Kindle. Book excerpt:

INIS Atomindex

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ISBN 13 :
Total Pages : 998 pages
Book Rating : 4.:/5 (319 download)

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Download or read book INIS Atomindex written by and published by . This book was released on 1981 with total page 998 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Government Reports Announcements & Index

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ISBN 13 :
Total Pages : 1402 pages
Book Rating : 4.E/5 ( download)

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Download or read book Government Reports Announcements & Index written by and published by . This book was released on 1980 with total page 1402 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Energy Research Abstracts

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ISBN 13 :
Total Pages : 844 pages
Book Rating : 4.3/5 (129 download)

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Download or read book Energy Research Abstracts written by and published by . This book was released on 1982 with total page 844 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Government reports annual index

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ISBN 13 :
Total Pages : 980 pages
Book Rating : 4.3/5 (129 download)

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Download or read book Government reports annual index written by and published by . This book was released on 199? with total page 980 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Nuclear News

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ISBN 13 :
Total Pages : 402 pages
Book Rating : 4.3/5 (778 download)

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Download or read book Nuclear News written by and published by . This book was released on 1980 with total page 402 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Fossil Energy Update

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ISBN 13 :
Total Pages : 1126 pages
Book Rating : 4.:/5 (31 download)

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Book Synopsis Fossil Energy Update by :

Download or read book Fossil Energy Update written by and published by . This book was released on 1984 with total page 1126 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Platinum Metals Review

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ISBN 13 :
Total Pages : 742 pages
Book Rating : 4.:/5 (37 download)

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Download or read book Platinum Metals Review written by and published by . This book was released on 1978 with total page 742 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Metals Abstracts

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ISBN 13 :
Total Pages : 980 pages
Book Rating : 4.3/5 (91 download)

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Download or read book Metals Abstracts written by and published by . This book was released on 1982 with total page 980 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Tritium Removal from Contaminated Water Via Infrared Laser Multiple-photon Dissociation

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Tritium Removal from Contaminated Water Via Infrared Laser Multiple-photon Dissociation by :

Download or read book Tritium Removal from Contaminated Water Via Infrared Laser Multiple-photon Dissociation written by and published by . This book was released on 1983 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Isotope separation by means of infrared-laser multiple-photon dissociation offers an efficient way to recover tritium from contaminated light or heavy water found in fission and fusion reactors. For tritium recovery from heavy water, chemical exchange of tritium into deuterated chloroform is followed by selective laser dissociation of tritiated chloroform and removal of the tritiated photoproduct, TCl. The single-step separation factor is at least 2700 and is probably greater than 5000. Here we present a description of the tritium recovery process, along with recent accomplishments in photochemical studies and engineering analysis of a recovery system.

Laser-assisted Isotope Separation of Tritium

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (873 download)

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Book Synopsis Laser-assisted Isotope Separation of Tritium by :

Download or read book Laser-assisted Isotope Separation of Tritium written by and published by . This book was released on 1983 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Methods for laser-assisted isotope separation of tritium, using infrared multiple photon dissociation of tritium-bearing products in the gas phase. One such process involves the steps of (1) catalytic exchange of a deuterium-bearing molecule XYD with tritiated water DTO from sources such as a heavy water fission reactor, to produce the tritium-bearing working molecules XYT and (2) photoselective dissociation of XYT to form a tritium-rich product. By an analogous procedure, tritium is separated from tritium-bearing materials that contain predominately hydrogen such as a light water coolant from fission or fusion reactors.

Electroanalytical Abstracts

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ISBN 13 :
Total Pages : 1148 pages
Book Rating : 4.:/5 (6 download)

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Download or read book Electroanalytical Abstracts written by and published by . This book was released on 1982 with total page 1148 pages. Available in PDF, EPUB and Kindle. Book excerpt: International journal dealing with the documentation of all aspects of fundamental, physico-chemical and analytical electrochemistry.