Transition Metals Second Edition

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Organic Synthesis Using Transition Metals

Author : Roderick Bates
Publisher : John Wiley & Sons
ISBN 13 : 1119978939
Total Pages : 5 pages
Book Rating : 4.1/5 (199 download)

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Book Synopsis Organic Synthesis Using Transition Metals by : Roderick Bates

Download or read book Organic Synthesis Using Transition Metals written by Roderick Bates and published by John Wiley & Sons. This book was released on 2012-04-30 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metals open up new opportunities for synthesis, because their means of bonding and their reaction mechanisms differ from those of the elements of the s and p blocks. In the last two decades the subject has mushroomed - established reactions are seeing both technical improvements and increasing numbers of applications, and new reactions are being developed. The practicality of the subject is demonstrated by the large number of publications coming from the process development laboratories of pharmaceutical companies, and its importance is underlined by the fact that three Nobel prizes have been awarded for discoveries in this field in the 21st Century already. Organic Synthesis Using Transition Metals, 2nd Edition considers the ways in which transition metals, as catalysts and reagents, can be used in organic synthesis, both for pharmaceutical compounds and for natural products. It concentrates on the bond-forming reactions that set transition metal chemistry apart from "classical" organic chemistry. Each chapter is extensively referenced and provides a convenient point of entry to the research literature. Topics covered include: introduction to transition metals in organic synthesis coupling reactions C-H activation carbonylative coupling reactions alkene and alkyne insertion reactions electrophilic alkene and alkyne complexes reactions of alkyne complexes carbene complexes h3- or p-allyl -allyl complexes diene, dienyl and arene complexes cycloaddition and cycloisomerisation reactions For this second edition the text has been extensively revised and expanded to reflect the significant improvements and advances in the field since the first edition, as well as the large number of new transition metal-catalysed processes that have come to prominence in the last 10 years – for example the extraordinary progress in coupling reactions using “designer” ligands, catalysis using gold complexes, new opportunities arising from metathesis chemistry, and C-H activation – without neglecting the well established chemistry of metals such as palladium. Organic Synthesis Using Transition Metals, 2nd Edition will find a place on the bookshelves of advanced undergraduates and postgraduates working in organic synthesis, catalysis, medicinal chemistry and drug discovery. It is also useful for practising researchers who want to refresh and enhance their knowledge of the field.

Transition Metals in the Synthesis of Complex Organic Molecules

Author : Louis S. Hegedus
Publisher : University Science Books
ISBN 13 : 9781891389047
Total Pages : 358 pages
Book Rating : 4.3/5 (89 download)

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Book Synopsis Transition Metals in the Synthesis of Complex Organic Molecules by : Louis S. Hegedus

Download or read book Transition Metals in the Synthesis of Complex Organic Molecules written by Louis S. Hegedus and published by University Science Books. This book was released on 1999 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.

Electronic Structure and Properties of Transition Metal Compounds

Author : Isaac B. Bersuker
Publisher : John Wiley & Sons
ISBN 13 : 0470920858
Total Pages : 658 pages
Book Rating : 4.4/5 (79 download)

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Book Synopsis Electronic Structure and Properties of Transition Metal Compounds by : Isaac B. Bersuker

Download or read book Electronic Structure and Properties of Transition Metal Compounds written by Isaac B. Bersuker and published by John Wiley & Sons. This book was released on 2010-12-01 with total page 658 pages. Available in PDF, EPUB and Kindle. Book excerpt: With more than 40% new and revised materials, this second edition offers researchers and students in the field a comprehensive understanding of fundamental molecular properties amidst cutting-edge applications. Including ~70 Example-Boxes and summary notes, questions, exercises, problem sets, and illustrations in each chapter, this publication is also suitable for use as a textbook for advanced undergraduate and graduate students. Novel material is introduced in description of multi-orbital chemical bonding, spectroscopic and magnetic properties, methods of electronic structure calculation, and quantum-classical modeling for organometallic and metallobiochemical systems. This is an excellent reference for chemists, researchers and teachers, and advanced undergraduate and graduate students in inorganic, coordination, and organometallic chemistry.

The Organometallic Chemistry of the Transition Metals

Author : Robert H. Crabtree
Publisher : John Wiley & Sons
ISBN 13 : 0471718750
Total Pages : 600 pages
Book Rating : 4.4/5 (717 download)

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Book Synopsis The Organometallic Chemistry of the Transition Metals by : Robert H. Crabtree

Download or read book The Organometallic Chemistry of the Transition Metals written by Robert H. Crabtree and published by John Wiley & Sons. This book was released on 2005-06-14 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fully updated and expanded to reflect recent advances, this Fourth Edition of the classic text provides students and professional chemists with an excellent introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications.

Handbook of Transition Metal Polymerization Catalysts

Author : Ray Hoff
Publisher : John Wiley & Sons
ISBN 13 : 1119242134
Total Pages : 696 pages
Book Rating : 4.1/5 (192 download)

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Book Synopsis Handbook of Transition Metal Polymerization Catalysts by : Ray Hoff

Download or read book Handbook of Transition Metal Polymerization Catalysts written by Ray Hoff and published by John Wiley & Sons. This book was released on 2018-05-08 with total page 696 pages. Available in PDF, EPUB and Kindle. Book excerpt: Including recent advances and historically important catalysts, this book overviews methods for developing and applying polymerization catalysts – dealing with polymerization catalysts that afford commercially acceptable high yields of polymer with respect to catalyst mass or productivity. • Contains the valuable data needed to reproduce syntheses or use the catalyst for new applications • Offers a guide to the design and synthesis of catalysts, and their applications in synthesis of polymers • Includes the information essential for choosing the appropriate reactions to maximize yield of polymer synthesized • Presents new chapters on vanadium catalysts, Ziegler catalysts, laboratory homopolymerization, and copolymerization

Kinetics and Mechanism of Reactions of Transition Metal Complexes

Author : Ralph G. Wilkins
Publisher : Wiley-VCH
ISBN 13 : 9783527282531
Total Pages : 480 pages
Book Rating : 4.2/5 (825 download)

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Book Synopsis Kinetics and Mechanism of Reactions of Transition Metal Complexes by : Ralph G. Wilkins

Download or read book Kinetics and Mechanism of Reactions of Transition Metal Complexes written by Ralph G. Wilkins and published by Wiley-VCH. This book was released on 1991-08-28 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thoroughly revised and updated edition of one of the classics of kinetics text books continues the successful concept of the 1974 edition: In its first part, a simplified approach to the determination of rate laws and mechnisms is given steadily working up to complex situations. In the following chapters the principles developed there are extensively used in a comprehensive account of reactions of transition metal complexes, including reactions of biological signifacance. The text is illustrated by numerous figures and tables. Points of further interest are highlighted in special insets. 140 problems, taken from the original literature, enable the student to apply and deepen his newly acquired knowledge and make the book highly useful for courses in inorganic and organometallic reaction mechanisms. Furthermore, a wealth of over 1700 references renders it an indispensable work for the active researcher.

Transition Metals, Second Edition

Author : Monica Halka
Publisher : Infobase Holdings, Inc
ISBN 13 : 1438182139
Total Pages : 158 pages
Book Rating : 4.4/5 (381 download)

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Book Synopsis Transition Metals, Second Edition by : Monica Halka

Download or read book Transition Metals, Second Edition written by Monica Halka and published by Infobase Holdings, Inc. This book was released on 2019-12-01 with total page 158 pages. Available in PDF, EPUB and Kindle. Book excerpt: More so than any of the other major groups of elements in the periodic table, the transition metals have shaped human history and have been the workhorses of industry. The discovery of metallic copper ended the Stone Age and ushered in the Bronze Age. Alloys of iron (especially steel) later took over, and the Iron Age replaced the Bronze Age. Copper, silver, and gold—and, more recently, platinum—have been the precious metals from which coins and jewelry have been made from ancient times to the present. Each chapter in the newly updated, full-color Transition Metals, Second Edition discusses a group of elements, including their similarities and differences and current research and applications. Ideal for high school or college students interested in chemistry and physics, this straightforward resource is devoted to the chemical and physical properties of transition metals and how they are useful in everyday life. Some of the transition metals covered include scandium, titanium, manganese, cobalt, and zinc.

Homogeneous Catalysis

Author : George William Parshall
Publisher : John Wiley & Sons
ISBN 13 :
Total Pages : 262 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Homogeneous Catalysis by : George William Parshall

Download or read book Homogeneous Catalysis written by George William Parshall and published by John Wiley & Sons. This book was released on 1980 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contains a balanced discussion of homogeneous catalytic reactions that are used in industry, featuring every documented example employed in a current commercial process, or that have a broad application in the organic synthesis laboratory. Incorporates synthesis with chiral catalysts in chapters on hydrogenation, CO chemistry and olefin oxidation. New additions include Tennessee Eastman's coal-based acetic anhydride plant and IFP's Dimersol process for dimerizing propylene as well as major changes in the areas on pharmaceuticals, flavors, fragrances, agricultural and electronic chemicals.

Transition Metal Carbonyl Cluster Chemistry

Author : Paul J. Dyson
Publisher : CRC Press
ISBN 13 : 1482283077
Total Pages : 180 pages
Book Rating : 4.4/5 (822 download)

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Book Synopsis Transition Metal Carbonyl Cluster Chemistry by : Paul J. Dyson

Download or read book Transition Metal Carbonyl Cluster Chemistry written by Paul J. Dyson and published by CRC Press. This book was released on 2018-10-03 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.

Transition Metal Oxides

Author : Chintamani Nagesa Ramachandra Rao
Publisher : VCH Publishers
ISBN 13 :
Total Pages : 360 pages
Book Rating : 4.:/5 (318 download)

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Book Synopsis Transition Metal Oxides by : Chintamani Nagesa Ramachandra Rao

Download or read book Transition Metal Oxides written by Chintamani Nagesa Ramachandra Rao and published by VCH Publishers. This book was released on 1995 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Organic Light Emitting Diodes

Author : Luiz F. R. Pereira
Publisher : CRC Press
ISBN 13 : 9814267295
Total Pages : 366 pages
Book Rating : 4.8/5 (142 download)

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Book Synopsis Organic Light Emitting Diodes by : Luiz F. R. Pereira

Download or read book Organic Light Emitting Diodes written by Luiz F. R. Pereira and published by CRC Press. This book was released on 2012-05-29 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book addresses the development of OLEDs based on rare-earth and transition metal complexes, especially focusing on europium, terbium, ruthenium, and rhenium. The idea is to explain how these organic materials can be used to build OLEDs. Taking into account the actual state of the art and the expected pathways, the book proposes further developments in the field. It presents intensive experimental results for a better explanation. This book is meant for scientists and engineers who work in this new OLED framework. It also has didactic utility for graduation students and teachers working on optoelectronics.

Transition Metal Compounds

Author : Daniel Khomskii
Publisher : Cambridge University Press
ISBN 13 : 1107020174
Total Pages : 501 pages
Book Rating : 4.1/5 (7 download)

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Book Synopsis Transition Metal Compounds by : Daniel Khomskii

Download or read book Transition Metal Compounds written by Daniel Khomskii and published by Cambridge University Press. This book was released on 2014-10-23 with total page 501 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes all aspects of the physics of transition metal compounds, providing a comprehensive overview of this diverse class of solids. Set within a modern conceptual framework, this is an invaluable, up-to-date resource for graduate students, researchers and industrial practitioners in solid-state physics and chemistry, materials science, and inorganic chemistry.

Transition Metals

Author : Ajay Kumar Mishra
Publisher :
ISBN 13 : 9781613245590
Total Pages : 0 pages
Book Rating : 4.2/5 (455 download)

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Book Synopsis Transition Metals by : Ajay Kumar Mishra

Download or read book Transition Metals written by Ajay Kumar Mishra and published by . This book was released on 2011-10 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book, the authors present topical research in the study of the characteristics, properties and uses of transition metals. Topics discussed include the non-linear optical properties of transition metal nanoparticles synthesised by ion implantation; the structural and magnetic characterisation of Cu-Picolinate and Cu-Quinaldinate molecular systems; application of transition metals as active compounds in separation techniques; the reactivity of unstable chemicals in the presence of transition metals and the bioinorganic and redox reactions in biological systems of transition metals.

Organic Synthesis Using Transition Metals

Author : Roderick Bates
Publisher : John Wiley & Sons
ISBN 13 : 1118313666
Total Pages : 5 pages
Book Rating : 4.1/5 (183 download)

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Book Synopsis Organic Synthesis Using Transition Metals by : Roderick Bates

Download or read book Organic Synthesis Using Transition Metals written by Roderick Bates and published by John Wiley & Sons. This book was released on 2012-04-12 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metals open up new opportunities for synthesis, because their means of bonding and their reaction mechanisms differ from those of the elements of the s and p blocks. In the last two decades the subject has mushroomed - established reactions are seeing both technical improvements and increasing numbers of applications, and new reactions are being developed. The practicality of the subject is demonstrated by the large number of publications coming from the process development laboratories of pharmaceutical companies, and its importance is underlined by the fact that three Nobel prizes have been awarded for discoveries in this field in the 21st Century already. Organic Synthesis Using Transition Metals, 2nd Edition considers the ways in which transition metals, as catalysts and reagents, can be used in organic synthesis, both for pharmaceutical compounds and for natural products. It concentrates on the bond-forming reactions that set transition metal chemistry apart from "classical" organic chemistry. Each chapter is extensively referenced and provides a convenient point of entry to the research literature. Topics covered include: introduction to transition metals in organic synthesis coupling reactions C-H activation carbonylative coupling reactions alkene and alkyne insertion reactions electrophilic alkene and alkyne complexes reactions of alkyne complexes carbene complexes h3- or p-allyl -allyl complexes diene, dienyl and arene complexes cycloaddition and cycloisomerisation reactions For this second edition the text has been extensively revised and expanded to reflect the significant improvements and advances in the field since the first edition, as well as the large number of new transition metal-catalysed processes that have come to prominence in the last 10 years – for example the extraordinary progress in coupling reactions using “designer” ligands, catalysis using gold complexes, new opportunities arising from metathesis chemistry, and C-H activation – without neglecting the well established chemistry of metals such as palladium. Organic Synthesis Using Transition Metals, 2nd Edition will find a place on the bookshelves of advanced undergraduates and postgraduates working in organic synthesis, catalysis, medicinal chemistry and drug discovery. It is also useful for practising researchers who want to refresh and enhance their knowledge of the field.

Mössbauer Spectroscopy and Transition Metal Chemistry

Author : P. Gütlich
Publisher : Springer Science & Business Media
ISBN 13 : 3662125455
Total Pages : 292 pages
Book Rating : 4.6/5 (621 download)

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Book Synopsis Mössbauer Spectroscopy and Transition Metal Chemistry by : P. Gütlich

Download or read book Mössbauer Spectroscopy and Transition Metal Chemistry written by P. Gütlich and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: Two decades have passed since the original discovery of recoilless nuclear gamma resonance by Rudolf Mossbauer; the spectroscopic method based on this resonance effect - referred to as Mossbauer spectroscopy - has developed into a powerful tool in solid-state research. The users are chemists, physicists, biologists, geologists, and scientists from other disciplines, and the spectrum of problems amenable to this method has become extraordinarily broad. In the present volume we have confined ourselves to applications of Mossbauer spectroscopy to the area of transition elements. We hope that the book will be useful not only to non-Mossbauer special ists with problem-Oriented activities in the chemistry and physics of transition elements, but also to those actively working in the field of Mossbauer spectroscopy on systems (compounds as well as alloys) of transition elements. The first five chapters are directed to introducing the reader who is not familiar with the technique to the principles of the recoilless nuclear resonance effect, the hyperfme interactions between nuclei and electronic properties such as electric and magnetic fields, some essential aspects about measurements, and the evaluation of Moss bauer spectra. Chapter 6 deals with the interpretation of Mossbauer parameters of iron compounds. Here we have placed emphasis on the information about the electronic structure, in correlation with quantum chemical methods, because of its importance for chemical bonding and magnetic properties.

Comprehensive Inorganic Chemistry II

Author :
Publisher : Newnes
ISBN 13 : 0080965296
Total Pages : 7694 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Comprehensive Inorganic Chemistry II by :

Download or read book Comprehensive Inorganic Chemistry II written by and published by Newnes. This book was released on 2013-07-23 with total page 7694 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Inorganic Chemistry II, Nine Volume Set reviews and examines topics of relevance to today’s inorganic chemists. Covering more interdisciplinary and high impact areas, Comprehensive Inorganic Chemistry II includes biological inorganic chemistry, solid state chemistry, materials chemistry, and nanoscience. The work is designed to follow on, with a different viewpoint and format, from our 1973 work, Comprehensive Inorganic Chemistry, edited by Bailar, Emeléus, Nyholm, and Trotman-Dickenson, which has received over 2,000 citations. The new work will also complement other recent Elsevier works in this area, Comprehensive Coordination Chemistry and Comprehensive Organometallic Chemistry, to form a trio of works covering the whole of modern inorganic chemistry. Chapters are designed to provide a valuable, long-standing scientific resource for both advanced students new to an area and researchers who need further background or answers to a particular problem on the elements, their compounds, or applications. Chapters are written by teams of leading experts, under the guidance of the Volume Editors and the Editors-in-Chief. The articles are written at a level that allows undergraduate students to understand the material, while providing active researchers with a ready reference resource for information in the field. The chapters will not provide basic data on the elements, which is available from many sources (and the original work), but instead concentrate on applications of the elements and their compounds. Provides a comprehensive review which serves to put many advances in perspective and allows the reader to make connections to related fields, such as: biological inorganic chemistry, materials chemistry, solid state chemistry and nanoscience Inorganic chemistry is rapidly developing, which brings about the need for a reference resource such as this that summarise recent developments and simultaneously provide background information Forms the new definitive source for researchers interested in elements and their applications; completely replacing the highly cited first edition, which published in 1973

Molecular Orbitals of Transition Metal Complexes

Author : Yves Jean
Publisher : Oxford University Press on Demand
ISBN 13 : 0198530935
Total Pages : 288 pages
Book Rating : 4.1/5 (985 download)

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Book Synopsis Molecular Orbitals of Transition Metal Complexes by : Yves Jean

Download or read book Molecular Orbitals of Transition Metal Complexes written by Yves Jean and published by Oxford University Press on Demand. This book was released on 2005-03-24 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book starts with the most elementary ideas of molecular orbital theory and leads the reader progressively to an understanding of the electronic structure, geometry and, in some cases, reactivity of transition metal complexes. The qualitative orbital approach, based on simple notions such as symmetry, overlap and electronegativity, is the focus of the presentation and a substantial part of the book is associated with the mechanics of the assembly of molecular orbital diagrams. The first chapter recalls the basis for electron counting in transition metal complexes. The main ligand fields (octahedral, square planar, tetrahedral, etc.) are studied in the second chapter and the structure of the "d block" is used to trace the relationships between the electronic structure and the geometry of the complexes. The third chapter studies the change in analysis when the ligands have pi-type interactions with the metal. All these ideas are then used in the fourth chapter to study a series of selected applications of varying complexity (e.g. structure and reactivity). The fifth chapter deals with the "isolobal analogy" which points out the resemblance between the molecular orbitals of inorganic and organic species and provides a bridge between these two subfields of chemistry. The last chapter is devoted to a presentation of basic Group Theory with applications to some of the complexes studied in the earlier chapters.