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Transition Metal Imido Complexes
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Book Synopsis Metal-Ligand Multiple Bonds by : William A. Nugent
Download or read book Metal-Ligand Multiple Bonds written by William A. Nugent and published by Wiley-Interscience. This book was released on 1988-11-14 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: The only comprehensive one-volume text/reference on metal-ligand multiple bonds. Stresses the unified nature of the field and includes handy new tabulations of data. The flow within each subtopic is oxygen to nitrogen to carbon. Coverage is up-to-date--virtually every subtopic leads to interesting questions for future research. Presents information otherwise scattered through hundreds of publications.
Book Synopsis Early Transition Metal Imido Complexes Supported by Heterocyclic Ligands by : Paul John Wilson
Download or read book Early Transition Metal Imido Complexes Supported by Heterocyclic Ligands written by Paul John Wilson and published by . This book was released on 1999 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Transition Metal Imido Complexes by : Martyn Paul Coles
Download or read book Transition Metal Imido Complexes written by Martyn Paul Coles and published by . This book was released on 1995 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis of Group IV Imido Complexes Supported by -diketiminate Ligands by : Jie Fang
Download or read book Synthesis of Group IV Imido Complexes Supported by -diketiminate Ligands written by Jie Fang and published by . This book was released on 2001 with total page 146 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Late Transition Metal. Mu.-oxo And. Mu.-imido Complexes by :
Download or read book Late Transition Metal. Mu.-oxo And. Mu.-imido Complexes written by and published by . This book was released on 1990 with total page 8 pages. Available in PDF, EPUB and Kindle. Book excerpt: The synthesis and reactions of late-transition-metal oxo and imido complexes was explored. The deprotonation of platinum(II) hydroxo complexes yielded new oxo complexes. Attempted deprotonation of Cp*Rh(III) hydroxo complexes did not give oxo complexes but complex mixtures probably resulting from reduction of the Rh(III) center. The reaction of Na/Hg with (Cp*RhCl2)2 gave the very reactive Rh(II) dimer, (Cp*RhCl)2. Rhodium(I) imido complexes with the bis(dimethylphosphino)methane ligand were prepared and found to be similar to the previously prepared bis(diphenylphosphino)methane complexes. Attempts to prepare bis(diphenylphosphino)methylamine, bis(diphenylphosphino)phenylamine, PMe{sub e} and NO analogues were not successful. Attempts to prepare Cp*Rh(III) imido complexes resulted in amido complexes and reduction. Rhodium (III) tris(3.5-dimethylpyrazoyl)borate analogues are reduction resistant but have not yet yielded imido complexes. The first imido complexes of Au were prepared by treating a Au oxo complex with amines or isocyanates. Dimeric Cp*Rh dioxygen and nitrosobenzene complexes were prepared by insertion into the Rh-Rh bond of (Cp*RhCl)2. The dioxygen complex activates a C-H bond of the Cp* ligand on treatment with PMe3. Imido and oxo complexes nitrene and oxygen atom transfer product in reactions with CO. A novel electrophilic ring addition was observed with sterically protected aryl imido complexes. 15 refs.
Book Synopsis Late Transition Metal Oxo and Imido Complexes by :
Download or read book Late Transition Metal Oxo and Imido Complexes written by and published by . This book was released on 1992 with total page 4 pages. Available in PDF, EPUB and Kindle. Book excerpt: A range of new phosphine Au(I) oxo complexes, [(LAu)[sub 3]([mu]-O)][sup +], were prepared, testing the limits of the phosphine steric and electronic properties. Their reaction with reducing agents (hydrazines, CO and RNC) give a variety of new and known gold clusters in unprecedented high yields and establish the steric and electronic relationships between the phosphine and the nuclearity of the product Au cluster. The [L[sub 2]Pt([mu]-O)][sub 2] class of dioxo complexes has been expanded to include the first anionic oxo complex, ([(dppm-H)Pt([mu]-O)][sub 2])Li[sub 2] and the first Pt imido complexes, [(L[sub 2]Pt)[sub 2]([mu]-O)([mu]-NR)] and [L[sub 2]Pt([mu]-NR)][sub 2]. The previously observed Rh imido/amido A-frame chemistry has been extended to Ir. The p-MePh-imido complex has been characterized by X-ray diffraction and clearly shows the resonance delocalization of the nitrogen lone pair into the aryl ring which is responsible for the previously observed electrophilic ring addition and oxidative ring coupling reactions.
Book Synopsis Transition Metal Imido Schiff Base Complexes by : Ramkrishna Ramnauth
Download or read book Transition Metal Imido Schiff Base Complexes written by Ramkrishna Ramnauth and published by . This book was released on 2003 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Late Transition Metal Oxo and Imido Complexes. Progress Report, May 15 1992--May 14, 1992 by :
Download or read book Late Transition Metal Oxo and Imido Complexes. Progress Report, May 15 1992--May 14, 1992 written by and published by . This book was released on 1992 with total page 4 pages. Available in PDF, EPUB and Kindle. Book excerpt: A range of new phosphine Au(I) oxo complexes, [(LAu)3([mu]-O)], were prepared, testing the limits of the phosphine steric and electronic properties. Their reaction with reducing agents (hydrazines, CO and RNC) give a variety of new and known gold clusters in unprecedented high yields and establish the steric and electronic relationships between the phosphine and the nuclearity of the product Au cluster. The [L2Pt([mu]-O)]2 class of dioxo complexes has been expanded to include the first anionic oxo complex, ([(dppm-H)Pt([mu]-O)]2)Li2 and the first Pt imido complexes, [(L2Pt)2([mu]-O)([mu]-NR)] and [L2Pt([mu]-NR)]2. The previously observed Rh imido/amido A-frame chemistry has been extended to Ir. The p-MePh-imido complex has been characterized by X-ray diffraction and clearly shows the resonance delocalization of the nitrogen lone pair into the aryl ring which is responsible for the previously observed electrophilic ring addition and oxidative ring coupling reactions.
Book Synopsis Transition Metal Carbyne Complexes by : F.R. Kreißl
Download or read book Transition Metal Carbyne Complexes written by F.R. Kreißl and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of transition metal carbyne complexes has become a highly attractive field during the past twenty years. In recent years its application to aspects of catalysis and metathesis has gained considerable interest from inorganic as well as organic chemists. In addition, organic synthesis by means of metal carbon multiple bond reagents offers the most sophisticated technology currently available. In consideration of these developments some of Professor E. O. Fischer's former coworkers and colleagues felt obliged to orga nize this NATO Advanced Research Workshop on Transition Metal Carbyne Complexes in the Bavarian Alps. They have been encouraged by the fact that most of the distinguished scientists in the field of metal-carbon multiple bond chemistry had finally agreed to participate and to present stimulating lectures. The organizers of the workshop are deeply grateful to the Scientific Affairs Division of the NATO for the generous financial support of the meeting in Wildbad Kreuth and for the preparation of this book. They also feel indebted to acknowledge the generous support from Wacker-Chemie, BASF, Peroxid-Chemie, Hoechst and Bayer. Finally they thank the staff of the Hanns-Seidel-Stiftung in Wildbad Kreuth for providing a pleasant and stimu lating atmosphere during the meeting.
Book Synopsis The Synthesis, Characterization and Reactivity of Novel Late-transition Metal Bridging Amido and Imido Complexes by : Manoj K. Kolel-Veetil
Download or read book The Synthesis, Characterization and Reactivity of Novel Late-transition Metal Bridging Amido and Imido Complexes written by Manoj K. Kolel-Veetil and published by . This book was released on 1995 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Transition Metal Complexes Containing Organoimido Ligands with Remote Functionality by : Kirk Cryer
Download or read book Transition Metal Complexes Containing Organoimido Ligands with Remote Functionality written by Kirk Cryer and published by . This book was released on 1997 with total page 294 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Organometallic Chemistry of the Transition Metals by : Robert H. Crabtree
Download or read book The Organometallic Chemistry of the Transition Metals written by Robert H. Crabtree and published by John Wiley & Sons. This book was released on 2005-06-14 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fully updated and expanded to reflect recent advances, this Fourth Edition of the classic text provides students and professional chemists with an excellent introduction to the principles and general properties of organometallic compounds, as well as including practical information on reaction mechanisms and detailed descriptions of contemporary applications.
Book Synopsis Transition Metals in the Synthesis of Complex Organic Molecules by : Louis S. Hegedus
Download or read book Transition Metals in the Synthesis of Complex Organic Molecules written by Louis S. Hegedus and published by University Science Books. This book was released on 1999 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: This second edition offers easy access to the field of organotransition metal chemistry. The book covers the basics of transition metal chemistry, giving a practical introduction to organotransition reaction mechanisms.
Book Synopsis Transition Metal-Dinitrogen Complexes by : Yoshiaki Nishibayashi
Download or read book Transition Metal-Dinitrogen Complexes written by Yoshiaki Nishibayashi and published by John Wiley & Sons. This book was released on 2019-05-06 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive book that explores nitrogen fixation by using transition metal-dinitrogen complexes Nitrogen fixation is one of the most prominent fields of research in chemistry. This book puts the focus on the development of catalytic ammonia formation from nitrogen gas under ambient reaction conditions that has been recently repowered by some research groups. With contributions from noted experts in the field, Transition Metal-Dinitrogen Complexes offers an important guide and comprehensive resource to the most recent research and developments on the topic of nitrogen fixation by using transition metal-dinitrogen. The book is filled with the information needed to understand the synthesis of transition metal-dinitrogen complexes and their reactivity. This important book: -Offers a resource for understanding nitrogen fixation chemistry that is essential for explosives, pharmaceuticals, dyes, and all forms of life -Includes the information needed for anyone interested in the field of nitrogen fixation by using transition metal-dinitrogen complexes -Contains state-of-the-art research on synthesis of transition metal-dinitrogen complexes and their reactivity in nitrogen fixation -Incorporates contributions from well-known specialists and experts with an editor who is an innovator in the field of dinitrogen chemistry Written for chemists and scientists with an interest in nitrogen fixation, Transition Metal-Dinitrogen Complexes is a must-have resource to the burgeoning field of nitrogen fixation by using transition metal-dinitrogen complexes.
Book Synopsis Silylamido Complexes of Early Transition Metals by : Tomislav Ilkov Gountchev
Download or read book Silylamido Complexes of Early Transition Metals written by Tomislav Ilkov Gountchev and published by . This book was released on 1999 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Reactivity of Imido and Oxo Complexes of Transition Metals by :
Download or read book Synthesis and Reactivity of Imido and Oxo Complexes of Transition Metals written by and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Refer to the Full-Text, p.16-18.
Book Synopsis Fundamental Transition Metal Organometallic Chemistry by : Charles M. Lukehart
Download or read book Fundamental Transition Metal Organometallic Chemistry written by Charles M. Lukehart and published by Thomson Brooks/Cole. This book was released on 1985 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt:
