Novel Strategies for the Synthesis of Tungsten(VI) and Molybdenum(VI) Imido/Oxo Alkylidene NHC Complexes and Their Application in Ring-Opening Metathesis Polymerization

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Publisher : Cuvillier Verlag
ISBN 13 : 3736966113
Total Pages : 186 pages
Book Rating : 4.7/5 (369 download)

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Book Synopsis Novel Strategies for the Synthesis of Tungsten(VI) and Molybdenum(VI) Imido/Oxo Alkylidene NHC Complexes and Their Application in Ring-Opening Metathesis Polymerization by : Janis Musso

Download or read book Novel Strategies for the Synthesis of Tungsten(VI) and Molybdenum(VI) Imido/Oxo Alkylidene NHC Complexes and Their Application in Ring-Opening Metathesis Polymerization written by Janis Musso and published by Cuvillier Verlag. This book was released on 2022-05-12 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recently, the synthesis of neutral and cationic group(VI) imido/oxo alkylidene N-heterocyclic carbene (NHC) complexes that tolerate protic functional groups and aldehydes was reported. Unprecedented turnover numbers of up to 1.2 million were found for their silica-supported representatives. Some group(VI) alkylidene NHC complexes even display stability towards moisture and air. Coordination of the NHC to tungsten imido bistriflate precursor complexes, however, can lead to undesired side reactions. This work consequently aimed at the development of novel, more efficient routes to neutral and cationic tungsten imido/oxo alkylidene NHC complexes. In addition, some molybdenum imido alkylidene NHC complexes were targeted. Thereby, the scope of synthetically accessible complexes was broadened and, subsequently, their reactivity in ring-opening metathesis polymerization (ROMP) was probed. Those complexes were used as thermally latent initiators for the ROMP of dicyclopentadiene. Precise determination of the onset temperature of polymerization was achieved via monitoring with differential scanning calorimetry. Furthermore, the selectivity of novel complexes was tested for the formation of stereoregular polymers through ROMP of enantiomerically pure norbornene derivatives, which allowed for the synthesis of up to 98% trans-isotactic or cis-syndiotactic polymers depending on the steric demand of the imido and the alkoxide ligand.

American Doctoral Dissertations

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Publisher :
ISBN 13 :
Total Pages : 724 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis American Doctoral Dissertations by :

Download or read book American Doctoral Dissertations written by and published by . This book was released on 1991 with total page 724 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis of Polymers

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Publisher : John Wiley & Sons
ISBN 13 : 3527644083
Total Pages : 1229 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Synthesis of Polymers by : Dieter A. Schlüter

Download or read book Synthesis of Polymers written by Dieter A. Schlüter and published by John Wiley & Sons. This book was released on 2012-05-23 with total page 1229 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymers are huge macromolecules composed of repeating structural units. While polymer in popular usage suggests plastic, the term actually refers to a large class of natural and synthetic materials. Due to the extraordinary range of properties accessible, polymers have come to play an essential and ubiquitous role in everyday life - from plastics and elastomers on the one hand to natural biopolymers such as DNA and proteins on the other hand. The study of polymer science begins with understanding the methods in which these materials are synthesized. Polymer synthesis is a complex procedure and can take place in a variety of ways. This book brings together the "Who is who" of polymer science to give the readers an overview of the large field of polymer synthesis. It is a one-stop reference and a must-have for all Chemists, Polymer Chemists, Chemists in Industry, and Materials Scientists.

Comprehensive Dissertation Index

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ISBN 13 :
Total Pages : 754 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Comprehensive Dissertation Index by :

Download or read book Comprehensive Dissertation Index written by and published by . This book was released on 1989 with total page 754 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Faculties, Publications, and Doctoral Theses in Chemistry and Chemical Engineering at United States Universities

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ISBN 13 :
Total Pages : 1646 pages
Book Rating : 4.0/5 ( download)

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Book Synopsis Faculties, Publications, and Doctoral Theses in Chemistry and Chemical Engineering at United States Universities by : American Chemical Society. Committee on Professional Training

Download or read book Faculties, Publications, and Doctoral Theses in Chemistry and Chemical Engineering at United States Universities written by American Chemical Society. Committee on Professional Training and published by . This book was released on 1991 with total page 1646 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Comprehensive Organometallic Chemistry II, Volume 14

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Publisher : Elsevier
ISBN 13 : 0080912745
Total Pages : 399 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Comprehensive Organometallic Chemistry II, Volume 14 by : Edward W. Abel

Download or read book Comprehensive Organometallic Chemistry II, Volume 14 written by Edward W. Abel and published by Elsevier. This book was released on 2002-09-10 with total page 399 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the publication Comprehensive Organometallic Chemistry in 1982, studies on the chemistry of molecules with carbon-metal bonds have continued to expand rapidly. This is due to many factors, ranging from the sheer intellectual challenge and excitement provided by the continuing production of novel results, which demand new ideas, through to the successful application of organometallic species in organic syntheses, the generation of living catalysts for polymerization, and the synthesis of precursors for materials employed in the electronic and ceramic industries. These factors led to the publication of the updated Comprehensive Organometallic Chemistry II. The original work serves as a basis for new volumes, focusing on organometallic chemistry reported since 1982, with reference back to the original work when necessary. For ease of use the new volumes maintain the same general structure as employed previously but reflect the changes in substance and direction the field has undergone in the last ten years. This book will serve as a pivotal reference point for new work and will function to generate new ideas and perceptions for the continued advance of what will surely continue as a vibrant area of chemistry.

Comprehensive Organometallic Chemistry III

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Publisher :
ISBN 13 :
Total Pages : 232 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Comprehensive Organometallic Chemistry III by : Robert H. Crabtree

Download or read book Comprehensive Organometallic Chemistry III written by Robert H. Crabtree and published by . This book was released on 2007 with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 1 reviews the preparations, properties, structure, bonding and applications of organometallic compounds of Alkali metal, Alkaline earth, Copper, Silver, Zinc, Mercury and Cadmium. It provides a clear and comprehensive overview of developments since 1993 and attempts to predict trends in the field over the next ten years. Like its predecessors, COMC (1982) and COMC-II (1995), this new work is the essential reference text for any chemist or technologist who needs to use or apply organometallic compounds. * valuable content available May 2009 as an individual volume * separate volumes will appeal to a wider chemistry and materials science audience * priced for individual researcher as well as library purchase

Advances in Organometallic Chemistry

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Publisher : Academic Press
ISBN 13 : 0080580416
Total Pages : 365 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Advances in Organometallic Chemistry by :

Download or read book Advances in Organometallic Chemistry written by and published by Academic Press. This book was released on 1996-12-06 with total page 365 pages. Available in PDF, EPUB and Kindle. Book excerpt: This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branches of chemistry and material science now interface with organometallic chemistry - the study of compounds containing carbon-metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancesments in organometallic chemistry. In basic research, Organometallics have contributed inter alia to metal cluster chemistry, surface chemistry, the stablilization of highly reactive species by metal coordination, chiral synthesis, the formulation of multiple bonds between carbon and the other elements and between the elements themselves. Advances in Organometallic Chemistry is an essential reference work for the academic and industrial chemist and will provide up-to-date material at the cutting edge of chemistry research. - Metal organic compounds of calcium, strontium, and barium in chemical vapour deposition - 17- and 19-electron organometallic complexes - Halocarbonyl complexes of molybdenum and tungsten - Substituent effects in metallacene chemistry

Comprehensive Coordination Chemistry

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Publisher : Pergamon
ISBN 13 : 9780080359502
Total Pages : 674 pages
Book Rating : 4.3/5 (595 download)

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Book Synopsis Comprehensive Coordination Chemistry by : Geoffrey Wilkinson

Download or read book Comprehensive Coordination Chemistry written by Geoffrey Wilkinson and published by Pergamon. This book was released on 1987 with total page 674 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Comprehensive Organometallic Chemistry III, Volume 5

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Publisher :
ISBN 13 :
Total Pages : 1008 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Comprehensive Organometallic Chemistry III, Volume 5 by : D. M. P. Mingos

Download or read book Comprehensive Organometallic Chemistry III, Volume 5 written by D. M. P. Mingos and published by . This book was released on 2007 with total page 1008 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides essential information for any chemist or technologist who needs to use or apply organometallic compounds. Provides a comprehensive overview of recent developments in the field and attempts to predict trends in the field over the next ten years.

Organic Reactions, Volume 102

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Publisher : John Wiley & Sons
ISBN 13 : 1119651220
Total Pages : 990 pages
Book Rating : 4.1/5 (196 download)

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Book Synopsis Organic Reactions, Volume 102 by :

Download or read book Organic Reactions, Volume 102 written by and published by John Wiley & Sons. This book was released on 2020-07-08 with total page 990 pages. Available in PDF, EPUB and Kindle. Book excerpt: Band 102 dieser Reihe für Organische Chemiker in Wissenschaft und Industrie präsentiert eine kritische Auseinandersetzung mit weit verbreiteten organischen Reaktionen oder bestimmten Phasen einer Reaktion. Betrachtet werden die notwendigen Vorbereitungen. Der Schwerpunkt liegt dabei auf Einschränkungen, Störeinflüssen, Struktureffekten und der Auswahl experimenteller Verfahren. Das Fachbuch beinhaltet Tabellen, die alle möglichen Beispiele für die jeweilige Reaktion beschreiben. Detaillierte Prozeduren zeigen wichtige Modifikationen jeder Methode.

Dissertation Abstracts International

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ISBN 13 :
Total Pages : 810 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Dissertation Abstracts International by :

Download or read book Dissertation Abstracts International written by and published by . This book was released on 2009 with total page 810 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis of Organometallic Compounds

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Publisher : John Wiley & Sons
ISBN 13 : 0471971952
Total Pages : 450 pages
Book Rating : 4.4/5 (719 download)

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Book Synopsis Synthesis of Organometallic Compounds by : Sanshiro Komiya

Download or read book Synthesis of Organometallic Compounds written by Sanshiro Komiya and published by John Wiley & Sons. This book was released on 1997-05-28 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt: Inorganic Chemistry: Inorganic Chemistry: A Textbook Series This series reflects the breadth of modern research in inorganic chemistry and fulfils the need for advanced texts. The series covers the whole range of inorganic and physical chemistry, solid state chemistry, coordination chemistry, main group chemistry and bioinorganic chemistry. Synthesis of Organometallic Compounds A Practical Guide Edited by Sanshiro Komiya Tokyo University of Agriculture and Technology, Japan. This book describes the concepts of organometallic chemistry and provides an overview of the chemistry of each metal including the synthesis and handling of its important organometallic compounds. Synthesis of Organometallic Compounds: A Practical Guide provides: an excellent introduction to organometallic synthesis detailed synthetic protocols for the most important organometallic syntheses an overview of the reactivity, applications and versatility of organometallic compounds a survey of metals and their organometallic derivatives The purpose of this book is to serve as a practical guide to understanding the general concepts of organometallics for graduate students and scientists who are not necessarily specialists in organometallic chemistry.

Comprehensive Organometallic Chemistry III

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Publisher : Elsevier Science
ISBN 13 : 9780080445908
Total Pages : 778 pages
Book Rating : 4.4/5 (459 download)

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Book Synopsis Comprehensive Organometallic Chemistry III by :

Download or read book Comprehensive Organometallic Chemistry III written by and published by Elsevier Science. This book was released on 2006-12-26 with total page 778 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive Organometallic Chemistry, (COMC-III), Third Edition, 13 Volume Set is aimed at the specialist and non-specialist alike. It covers the major developments in the field in a carefully presented way with extensive cross-references. COMC-III provides a clear and comprehensive overview of developments since 1993 and attempts to predict trends in the field over the next ten years. Applications of organometallic chemistry continue to expand and this has been reflected by the significant increase in the number of volumes devoted to applications in COMC-III. Organic chemists have edited the volumes on organometallic chemistry towards organic synthesis - this is now organized by reaction type so as to be readily accessible to the organic community. Like its predecessors, COMC (1982) and COMC-II (1995), this new work is the essential reference text for any chemist or technologist who needs to use or apply organometallic compounds. Also available online via ScienceDirect (2006) - featuring extensive browsing, searching, and internal cross-referencing between articles in the work, plus dynamic linking to journal articles and abstract databases, making navigation flexible and easy. For more information, pricing options and availability visit www.info.sciencedirect.com. Presents a comprehensive overview of the major developments in the field since 1993 providing general and significant insights Highlights the expansion of applications in organometallic chemistry with a strong organic synthesis focus Provides a structured first point of entry to the key literature and background material for those planning research, teaching and writing about the area

Organometallic Compounds

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Publisher : John Wiley & Sons
ISBN 13 : 3527351787
Total Pages : 453 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Organometallic Compounds by : Dakeshwar Kumar Verma

Download or read book Organometallic Compounds written by Dakeshwar Kumar Verma and published by John Wiley & Sons. This book was released on 2023-03-08 with total page 453 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic Compounds An up-to-date overview of the fundamentals, synthesis, and applications of organometallic compounds Organometallic Compounds: Synthesis, Reactions, and Applications delivers an accessible and robust introduction to the fundamentals of organometallic compounds, including their reactions, catalytic mechanisms, and modern applications, including carbon-dioxide fixation, reduction, gas adsorption and purification, drug delivery, renewable energy, and wastewater treatment. The book also covers toxicological and computational studies. The authors address the current challenges confronting researchers seeking to sustainably synthesize and process organometallic compounds and offer complete coverage on the most recent advancements in applications relating to the fields of environmental science, electronics, fossil fuels, and more. Readers will also find: Introduces to fundamentals, nomenclature, properties, and classification of organometallic compounds Discusses methods of synthesis of organometallic compounds Practical discussions of organometallic complexes of the lanthanoids and actinoids, as well as bio-organometallic chemistry Includes characterization techniques of organometallic compounds Perfect for organic, environmental, inorganic, water, and catalytic chemists, Organometallic Compounds: Synthesis, Reactions, and Applications will also benefit chemical engineers and industrial chemists.

Research in Materials

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Publisher :
ISBN 13 :
Total Pages : 612 pages
Book Rating : 4.:/5 (43 download)

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Book Synopsis Research in Materials by :

Download or read book Research in Materials written by and published by . This book was released on 1993 with total page 612 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Advances in Organometallic Chemistry

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Publisher : Academic Press
ISBN 13 : 0123972779
Total Pages : 193 pages
Book Rating : 4.1/5 (239 download)

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Book Synopsis Advances in Organometallic Chemistry by : Anthony F. Hill

Download or read book Advances in Organometallic Chemistry written by Anthony F. Hill and published by Academic Press. This book was released on 2012-12-31 with total page 193 pages. Available in PDF, EPUB and Kindle. Book excerpt: Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field that has expanded enormously since the publication of Volume 1 in 1964. - Contributions from leading authorities - Informs and updates on all the latest developments in the field