Read Books Online and Download eBooks, EPub, PDF, Mobi, Kindle, Text Full Free.
The Electrochemistry Of Uranium And The Single Potentials Of Some Oxides Of Uranium
Download The Electrochemistry Of Uranium And The Single Potentials Of Some Oxides Of Uranium full books in PDF, epub, and Kindle. Read online The Electrochemistry Of Uranium And The Single Potentials Of Some Oxides Of Uranium ebook anywhere anytime directly on your device. Fast Download speed and no annoying ads. We cannot guarantee that every ebooks is available!
Book Synopsis The Electrochemistry of Uranium and the Single Potentials of Some Oxides of Uranium by : Chester A. Pierle
Download or read book The Electrochemistry of Uranium and the Single Potentials of Some Oxides of Uranium written by Chester A. Pierle and published by . This book was released on 1919 with total page 68 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Electrochemistry Of Uranium And The Single Potentials Of Some Oxides Of Uranium by : Chester A. Pierle
Download or read book The Electrochemistry Of Uranium And The Single Potentials Of Some Oxides Of Uranium written by Chester A. Pierle and published by Legare Street Press. This book was released on 2023-07-18 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book delves into the electrochemistry of uranium and its oxides. The author explores the various potentials of uranium and its oxides, providing insights into the properties and reactions of these important materials. This work has been selected by scholars as being culturally important, and is part of the knowledge base of civilization as we know it. This work is in the "public domain in the United States of America, and possibly other nations. Within the United States, you may freely copy and distribute this work, as no entity (individual or corporate) has a copyright on the body of the work. Scholars believe, and we concur, that this work is important enough to be preserved, reproduced, and made generally available to the public. We appreciate your support of the preservation process, and thank you for being an important part of keeping this knowledge alive and relevant.
Book Synopsis The Journal of Physical Chemistry by :
Download or read book The Journal of Physical Chemistry written by and published by . This book was released on 1919 with total page 676 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Journal of Physical Chemistry by : Wilder Dwight Bancroft
Download or read book The Journal of Physical Chemistry written by Wilder Dwight Bancroft and published by . This book was released on 1919 with total page 680 pages. Available in PDF, EPUB and Kindle. Book excerpt: Includes section "New Books"
Book Synopsis Journal of the Chemical Society by : Chemical Society (Great Britain)
Download or read book Journal of the Chemical Society written by Chemical Society (Great Britain) and published by . This book was released on 1920 with total page 2022 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Science Abstracts written by and published by . This book was released on 1920 with total page 776 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Science Abstracts written by and published by . This book was released on 1960 with total page 966 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Journal of the Chemical Society by : Chemical Society (Great Britain)
Download or read book Journal of the Chemical Society written by Chemical Society (Great Britain) and published by . This book was released on 1920 with total page 1240 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chemical Abstracts written by and published by . This book was released on 1920 with total page 1348 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Uranium and Its Compounds by : Frederick Emory Croxton
Download or read book Uranium and Its Compounds written by Frederick Emory Croxton and published by . This book was released on 1955 with total page 712 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Journal of Industrial and Engineering Chemistry by :
Download or read book The Journal of Industrial and Engineering Chemistry written by and published by . This book was released on 1920 with total page 1258 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Chemical News and Journal of Physical Science by : William Crookes
Download or read book Chemical News and Journal of Physical Science written by William Crookes and published by . This book was released on 1920 with total page 688 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chemical Abstracts written by and published by . This book was released on 1994-03-07 with total page 1668 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Journal of Industrial and Engineering Chemistry by :
Download or read book Journal of Industrial and Engineering Chemistry written by and published by . This book was released on 1920 with total page 1260 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Uranium and Its Compounds by : Fred E. Corxton
Download or read book Uranium and Its Compounds written by Fred E. Corxton and published by . This book was released on 1951 with total page 722 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Electrochemical and Surface Compositional Studies on Uranium Dioxide by : Mayuri Razdan
Download or read book Electrochemical and Surface Compositional Studies on Uranium Dioxide written by Mayuri Razdan and published by . This book was released on 2013 with total page 574 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis describes electrochemical and surface compositional studies performed on a number of simulated nuclear fuel (SIMFUEL) materials under conditions relevant to permanent disposal of spent nuclear fuel in a geologic repository. This is important since a number of critical issues have been identified in the event of waste container failure. The research performed was mainly focused in three areas: (i) the influence of low pH on the surface chemistry of UO2, since acidity could develop within corrosion product deposits and flaws in the fuel; (ii) the combined influence of dissolved H2 and H2O2 (H2 and H2O2 are key reducing and oxidizing agents) in the presence of HCO32-/ CO32- (the key ground water species) on the fuel corrosion process (iii) the influence of rare earth (REIII) fission product doping on the fuel corrosion process (since matrix doping process with REIII influences the fuel bulk properties, it is expected to influence both anodic and cathodic kinetics under natural corrosion conditions). The influence of H2O2 on 1.5 at% SIMFUEL in acidic (pH 1-4) conditions was studied voltammetrically using a rotating disk electrode (RDE), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) to determine the composition and morphology of the oxidized UO2 surface. The H2O2 reduction mechanism is shown to occur on either a UV-containing surface layer of composition UIV1−2xUV2xO2+x or on an adsorbed UV surface intermediate, depending on the surface composition which is determined by solution pH and H2O2 concentration. The UIV1−2xUV2xO2+x catalytic surface lattice layer, if formed is more stable and supports H2O2 reduction up to the diffusion-controlled limit. By contrast, the UV adsorbed surface intermediate is unstable which prevents significant H2O2 reduction. The simultaneous occurrence of both reduction mechanisms demonstrates the influence of locally established surface compositions and the switch from one to the other appears to be controlled by the diffusive transport conditions at the electrode surface. In addition to H2O2, the influence of the dominant reducing species, H2, anticipated inside a failed waste container was investigated at different [H2O2] in the presence of the key ground water species (HCO3-/CO32-). Their combined influence on the redox behavior of UO2 was followed using open circuit corrosion potential measurements (ECORR), cathodic stripping voltammetry (CSV) and XPS. The presence of HCO3-/CO32- in solution inhibits UO2 oxidation at lower [H2O2]. The influence of dissolved H2 in suppressing surface oxidation under ambient conditions depends primarily on chemically added [H2O2] and was evident in the presence of carbonate for H2O2 concentrations ≤ 10-5 mol L-1. A second goal of the thesis was to study the effect of fission products (metallic particles and rare earth (RE3+)) on UO2 oxidation. These studies were conducted on 0.3 wt% Yttrium-doped UO2 (Y-UO2), 6 wt% Gadolinium doped UO2 (Gd-UO2), 12.9 wt% Dysprosium doped UO2 (Dy-UO2) and 1 wt% Palladium-doped UO2 (Pd-UO2) electrodes. The electrodes were characterized using Raman Spectroscopy and SEM/EDX and their anodic oxidation studied electrochemically and by XPS. Voltammetric experiments on Y-doped UO2 electrodes containing noble metal particles showed the presence of a current at sub-thermodynamic potentials consistent with a lattice containing a mixture of stoichiometric and non-stoichiometric domains. Their presence was verified by Raman and XPS analyses. Electrochemical investigations on homogeneously REIII doped electrodes demonstrated a clear doping influence on both stages of the anodic oxidation process; i.e., on the initial matrix oxidization step (UO2 → UO2+x) and on its further oxidation to soluble UVI (as UO22+). Doping appears to influence the kinetics of the second step more than that of first step. Raman spectroscopy shows that an increase in doping level leads to the formation of REIII-Oxygen vacancy (OV) clusters which decreases the number of the OV sites required for oxidation. The influence of carbonate/bicarbonate (the key groundwater constituents likely to influence fuel dissolution) on the electrochemical oxidation process of RE-doped UO2 (Gd-UO2) was examined using CV, potentiostatic polarization and XPS. While CV scans show that carbonate has a significant catalytic effect on the oxidative dissolution of UO2, a stable surface layer (UO2+x) is present irrespective of carbonate concentration. Potentiostatic experiments in the potential range -0.5 to 0.5V also show that the oxidation/dissolution currents are increased in the presence of carbonate. XPS analyses showed the electrode to be free of UVI species. This indicates that the slow step in the overall anodic dissolution process is the electrochemical formation of UVI not its chemical dissolution.
Book Synopsis The Chemical News and Journal of Physical Science by :
Download or read book The Chemical News and Journal of Physical Science written by and published by . This book was released on 1920 with total page 332 pages. Available in PDF, EPUB and Kindle. Book excerpt: