The Development of Semiconducting Materials for Organic Photovoltaics

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Publisher :
ISBN 13 :
Total Pages : 188 pages
Book Rating : 4.:/5 (858 download)

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Book Synopsis The Development of Semiconducting Materials for Organic Photovoltaics by : Jessica D. Douglas

Download or read book The Development of Semiconducting Materials for Organic Photovoltaics written by Jessica D. Douglas and published by . This book was released on 2013 with total page 188 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemical structure of conjugated semiconducting materials strongly influences the performance of organic photovoltaic (OPV) devices. Thus a good understanding of the structure-function relationships that govern the optoelectronic and physical properties of OPV materials is necessary. In this dissertation, organic polymers and small molecules are evaluated in terms of OPV device output parameters, and molecular design rules are elucidated. The development of molecules with alternating electron-rich and electron-deficient backbone units provides materials with suitable optoelectronic properties for OPVs and favorable modularity for organic semiconductor design. The choice of specific aromatic units and side chains for conjugated materials are shown to modulate the energy levels and architecture of OPV devices, affecting each of the four mechanistic steps of OPV operation. In Chapter 2, the relationship between molecular packing parameters and the bulkiness of aliphatic solubilizing group extending away from a polymer backbone is elucidated, and high-performance OPV devices are achieved. In Chapter 3, the inclusion of a post-processing functionality on a polymer side chain is found to have a positive effect on the bulk morphology and overall performance of OPV devices. In Chapter 4, the influence of electron-withdrawing and quinoidal monomers on the optoelectronic properties of conjugated polymers is established, and energy level modulation is shown to affect the electron accepting and donating capabilities of OPV materials in a blended device. In Chapter 5, small molecules are designed with complementary light absorption properties in order to investigate a rarely observed charge generation mechanism.

Semiconductor Materials for Solar Photovoltaic Cells

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Publisher : Springer
ISBN 13 : 3319203312
Total Pages : 290 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis Semiconductor Materials for Solar Photovoltaic Cells by : M. Parans Paranthaman

Download or read book Semiconductor Materials for Solar Photovoltaic Cells written by M. Parans Paranthaman and published by Springer. This book was released on 2015-09-16 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book reviews the current status of semiconductor materials for conversion of sunlight to electricity, and highlights advances in both basic science and manufacturing. Photovoltaic (PV) solar electric technology will be a significant contributor to world energy supplies when reliable, efficient PV power products are manufactured in large volumes at low cost. Expert chapters cover the full range of semiconductor materials for solar-to-electricity conversion, from crystalline silicon and amorphous silicon to cadmium telluride, copper indium gallium sulfide selenides, dye sensitized solar cells, organic solar cells, and environmentally friendly copper zinc tin sulfide selenides. The latest methods for synthesis and characterization of solar cell materials are described, together with techniques for measuring solar cell efficiency. Semiconductor Materials for Solar Photovoltaic Cells presents the current state of the art as well as key details about future strategies to increase the efficiency and reduce costs, with particular focus on how to reduce the gap between laboratory scale efficiency and commercial module efficiency. This book will aid materials scientists and engineers in identifying research priorities to fulfill energy needs, and will also enable researchers to understand novel semiconductor materials that are emerging in the solar market. This integrated approach also gives science and engineering students a sense of the excitement and relevance of materials science in the development of novel semiconductor materials. · Provides a comprehensive introduction to solar PV cell materials · Reviews current and future status of solar cells with respect to cost and efficiency · Covers the full range of solar cell materials, from silicon and thin films to dye sensitized and organic solar cells · Offers an in-depth account of the semiconductor material strategies and directions for further research · Features detailed tables on the world leaders in efficiency demonstrations · Edited by scientists with experience in both research and industry

WOLEDs and Organic Photovoltaics

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Publisher : Springer Science & Business Media
ISBN 13 : 3642149359
Total Pages : 245 pages
Book Rating : 4.6/5 (421 download)

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Book Synopsis WOLEDs and Organic Photovoltaics by : Vivian W. W. Yam

Download or read book WOLEDs and Organic Photovoltaics written by Vivian W. W. Yam and published by Springer Science & Business Media. This book was released on 2010-11-19 with total page 245 pages. Available in PDF, EPUB and Kindle. Book excerpt: A major global issue that the world is facing today is the upcoming depletion of fossil fuels and the energy crisis. In 1998, the global annual energy consumption was 12. 7 TW; of which 80% was generated from fossil fuels. This also translates into huge annual emissions of CO that leads to massive environmental problems, 2 particularly the global warming, which could be disastrous. Future global annual energy needs are also estimated to rise dramatically. A major challenge confronting the world is to ?nd an additional 14–20 TW by 2050 when our energy reserves based on fossil fuels are vanishing. The massive demand for energy would require materials and/or processes that would help to provide new sources of clean ren- able energy or to develop processes that would harvest energy or to better utilize energy in an ef?cient manner. The present monograph, WOLEDs and Organic Photovoltaics – Recent Advances and Applications, focuses on a very important and timely subject of topical interest that deals with the more ef?cient use of energy through white organic light-emitting diodes (WOLEDs) for solid-state lighting and the development of clean sources of renewable energy through the harvesting of light energy for conversion into electrical energy in organic photovoltaics. While LED solid-state lighting and photovoltaics have been dominated by inorganic semiconductor materials and silicon-based solar cells, there have been growing interests in the development of WOLEDs and organic photovoltaics.

Design and Synthesis of New Organic Semiconductors for Organic Solar Cells

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Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (134 download)

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Book Synopsis Design and Synthesis of New Organic Semiconductors for Organic Solar Cells by : Xiaomei Ding

Download or read book Design and Synthesis of New Organic Semiconductors for Organic Solar Cells written by Xiaomei Ding and published by . This book was released on 2021 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molecular design and synthesis play critical roles in the development of organic semiconductors for organic photovoltaics (OPVs). This dissertation describes the design, synthesis, and characterization of three classes of organic semiconductors for OPVs: p-type semiconducting polymers, n-type semiconducting polymers, and non-fullerene small molecule acceptors. The relative merits of alternative building blocks and design strategies for organic semiconductors are investigated. Complex factors governing the underlying structure-property-processing-performance relationships are discussed in detail. The fundamentals of organic semiconductors and organic solar cells, state-of-the-art materials and devices, and challenges in the design and synthesis of materials are reviewed in Chapter 1. Chapter 2 discusses the strategy of selenophene substitution as a potential method to improve photovoltaic performance of the regular thiophene-based p-type semiconducting polymers. New selenophene-containing polymers were synthesized based on a widely used polymer, PBDB-T, where the original thiophene units at various side chain and backbone positions were substituted with selenophene. This study revealed the intramolecular and intermolecular interactions related with selenophene substitution, thus provided important guidelines in designing selenophene-containing polymers. Chapter 3 presents a comparative study of the alternating naphthalene diimide-thiophene copolymer, PNDIT-hd, and naphthalene diimide-selenophene copolymer, PNDIS-hd. The effects of selenophene substitution on the intrinsic and photovoltaic blend properties of n-type semiconducting naphthalene diimide-arylene copolymers with simple donor−acceptor architecture were investigated. This study demonstrated multiple advantages of selenophene substitution including enhancing light harvesting, formation of favorable morphology, and reducing charge recombination losses in all-polymer solar cell devices. Towards enhancing the intrinsic stability of small molecule acceptors, novel tridecacyclic ladder structure was designed and realized via Friedlander condensation reactions. The tridecacyclic ladder molecule acceptors (LMAs) described in Chapter 4 combined good solubility with enhanced stabilities and high photovoltaic performance. One of the new LMAs, LTX-4Cl, demonstrated a high PCE of 11.5% with high fill factor of 0.75. This study also unraveled the significant impact of side chains and halogenations on the molecular packing characteristics of the LMAs and the resulted photovoltaic performance. Finally, the results of the above studies are summarized in Chapter 5 and an outlook is given for future development of organic semiconductors and the organic photovoltaic technology.

Emerging Photovoltaic Materials

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Publisher : John Wiley & Sons
ISBN 13 : 1119407672
Total Pages : 827 pages
Book Rating : 4.1/5 (194 download)

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Book Synopsis Emerging Photovoltaic Materials by : Santosh K. Kurinec

Download or read book Emerging Photovoltaic Materials written by Santosh K. Kurinec and published by John Wiley & Sons. This book was released on 2018-11-30 with total page 827 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the recent advances in photovoltaics materials and their innovative applications. Many materials science problems are encountered in understanding existing solar cells and the development of more efficient, less costly, and more stable cells. This important and timely book provides a historical overview, but concentrates primarily on the exciting developments in the last decade. It includes organic and perovskite solar cells, photovoltaics in ferroelectric materials, organic-inorganic hybrid perovskite, materials with improved photovoltaic efficiencies as well as the full range of semiconductor materials for solar-to-electricity conversion, from crystalline silicon and amorphous silicon to cadmium telluride, copper indium gallium sulfide selenides, dye sensitized solar cells, organic solar cells, and environmentally-friendly copper zinc tin sulfide selenides.

New N-Type Polymers for Organic Photovoltaics

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Publisher :
ISBN 13 :
Total Pages : 4 pages
Book Rating : 4.:/5 (16 download)

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Book Synopsis New N-Type Polymers for Organic Photovoltaics by :

Download or read book New N-Type Polymers for Organic Photovoltaics written by and published by . This book was released on 2014 with total page 4 pages. Available in PDF, EPUB and Kindle. Book excerpt: This CRADA will develop improved thin film organic solar cells using a new n-type semiconducting polymer. High efficiency photovoltaics (PVs) based on inorganic semiconductors have good efficiencies (up to 30%) but are extremely expensive to manufacture. Organic PV technology has the potential to overcome this problem through the use of high-throughput production methods like reel-to-reel printing on flexible substrates. Unfortunately, today's best organic PVs have only a few percent efficiency, a number that is insufficient for virtually all commercial applications. The limited choice of stable n-type (acceptor) organic semiconductor materials is one of the key factors that prevent the further improvement of organic PVs. TDA Research, Inc. (TDA) previously developed a new class of electron-deficient (n-type) conjugated polymers for use in organic light emitting diodes (OLEDs). During this project TDA in collaboration with the National Renewable Energy Laboratory (NREL) will incorporate these electron-deficient polymers into organic photovoltaics and investigate their performance. TDA Research, Inc. (TDA) is developing new materials and polymers to improve the performance of organic solar cells. Materials being developed at TDA include spin coated transparent conductors, charge injection layers, fullerene derivatives, electron-deficient polymers, and three-phase (fullerene/polythiophene/dye) active layer inks.

WOLEDs and Organic Photovoltaics

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Publisher : Springer
ISBN 13 : 9783642149368
Total Pages : 240 pages
Book Rating : 4.1/5 (493 download)

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Book Synopsis WOLEDs and Organic Photovoltaics by : Vivian W. W. Yam

Download or read book WOLEDs and Organic Photovoltaics written by Vivian W. W. Yam and published by Springer. This book was released on 2011-07-23 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: A major global issue that the world is facing today is the upcoming depletion of fossil fuels and the energy crisis. In 1998, the global annual energy consumption was 12. 7 TW; of which 80% was generated from fossil fuels. This also translates into huge annual emissions of CO that leads to massive environmental problems, 2 particularly the global warming, which could be disastrous. Future global annual energy needs are also estimated to rise dramatically. A major challenge confronting the world is to ?nd an additional 14–20 TW by 2050 when our energy reserves based on fossil fuels are vanishing. The massive demand for energy would require materials and/or processes that would help to provide new sources of clean ren- able energy or to develop processes that would harvest energy or to better utilize energy in an ef?cient manner. The present monograph, WOLEDs and Organic Photovoltaics – Recent Advances and Applications, focuses on a very important and timely subject of topical interest that deals with the more ef?cient use of energy through white organic light-emitting diodes (WOLEDs) for solid-state lighting and the development of clean sources of renewable energy through the harvesting of light energy for conversion into electrical energy in organic photovoltaics. While LED solid-state lighting and photovoltaics have been dominated by inorganic semiconductor materials and silicon-based solar cells, there have been growing interests in the development of WOLEDs and organic photovoltaics.

Organic Solar Cells

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Publisher : Springer Science & Business Media
ISBN 13 : 1447148231
Total Pages : 268 pages
Book Rating : 4.4/5 (471 download)

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Book Synopsis Organic Solar Cells by : Wallace C.H. Choy

Download or read book Organic Solar Cells written by Wallace C.H. Choy and published by Springer Science & Business Media. This book was released on 2012-11-19 with total page 268 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic solar cells have emerged as new promising photovoltaic devices due to their potential applications in large area, printable and flexible solar panels. Organic Solar Cells: Materials and Device Physics offers an updated review on the topics covering the synthesis, properties and applications of new materials for various critical roles in devices from electrodes, interface and carrier transport materials, to the active layer composed of donors and acceptors. Addressing the important device physics issues of carrier and exciton dynamics and interface stability and novel light trapping structures, the potential for hybrid organic solar cells to provide high efficiency solar cells is examined and discussed in detail. Specific chapters covers key areas including: Latest research and designs for highly effective polymer donors/acceptors and interface materials Synthesis and application of highly transparent and conductive graphene Exciton and charge dynamics for in-depth understanding of the mechanism underlying organic solar cells. New potentials and emerging functionalities of plasmonic effects in OSCs Interface Degradation Mechanisms in organic photovoltaics improving the entire device lifetime Device architecture and operation mechanism of organic/ inorganic hybrid solar cells for next generation of high performance photovoltaics This reference can be practically and theoretically applied by senior undergraduates, postgraduates, engineers, scientists, researchers, and project managers with some fundamental knowledge in organic and inorganic semiconductor materials or devices.

Progress in High-Efficient Solution Process Organic Photovoltaic Devices

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Publisher : Springer
ISBN 13 : 3662455099
Total Pages : 421 pages
Book Rating : 4.6/5 (624 download)

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Book Synopsis Progress in High-Efficient Solution Process Organic Photovoltaic Devices by : Yang Yang

Download or read book Progress in High-Efficient Solution Process Organic Photovoltaic Devices written by Yang Yang and published by Springer. This book was released on 2015-02-17 with total page 421 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents an important technique to process organic photovoltaic devices. The basics, materials aspects and manufacturing of photovoltaic devices with solution processing are explained. Solution processable organic solar cells - polymer or solution processable small molecules - have the potential to significantly reduce the costs for solar electricity and energy payback time due to the low material costs for the cells, low cost and fast fabrication processes (ambient, roll-to-roll), high material utilization etc. In addition, organic photovoltaics (OPV) also provides attractive properties like flexibility, colorful displays and transparency which could open new market opportunities. The material and device innovations lead to improved efficiency by 8% for organic photovoltaic solar cells, compared to 4% in 2005. Both academic and industry research have significant interest in the development of this technology. This book gives an overview of the booming technology, focusing on the solution process for organic solar cells and provides a state-of-the-art report of the latest developments. World class experts cover fundamental, materials, devices and manufacturing technology of OPV technology.

Organic Photovoltaics

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Publisher : John Wiley & Sons
ISBN 13 : 3527656936
Total Pages : 766 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Organic Photovoltaics by : Christoph Brabec

Download or read book Organic Photovoltaics written by Christoph Brabec and published by John Wiley & Sons. This book was released on 2014-02-20 with total page 766 pages. Available in PDF, EPUB and Kindle. Book excerpt: The versatility of organic photovoltaics is already well known and this completely revised, updated, and enlarged edition of a classic provides an up-to-date overview of this hot topic. The proven structure of the successful first edition, divided into the three key aspects of successful device design: materials, device physics, and manufacturing technologies, has been retained. Important aspects such as printing technologies, substrates, and electrode systems are covered. The result is a balanced, comprehensive text on the fundamentals as well as the latest results in the area that will set R&D trends for years to come. With its combination of both academic and commercial technological views, this is an optimal source of information for scientists, engineers, and graduate students already actively working in this field, and looking for comprehensive summaries on specific topics.

Semiconductor Materials and Modelling for Solar Cells

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Publisher : Materials Research Forum LLC
ISBN 13 : 1644901439
Total Pages : 94 pages
Book Rating : 4.6/5 (449 download)

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Book Synopsis Semiconductor Materials and Modelling for Solar Cells by : Z. Pezeshki

Download or read book Semiconductor Materials and Modelling for Solar Cells written by Z. Pezeshki and published by Materials Research Forum LLC. This book was released on 2021-07-05 with total page 94 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book presents a comprehensive survey about advanced solar cell technologies. Focus is placed on semiconductor materials, solar cell efficiency, improvements in surface recombination velocity, charge density, high ultraviolet (UV) sensitivity, modeling of solar cells etc. The book references 281 original resources with their direct web links for in-depth reading. Keywords: Solar Cells, Thin Film Solar Cells, Solar Cell Efficiency, Semiconductor Materials, Surface Recombination Velocity, Charge Density, High UV Sensitivity, Heavily-doped Silicon Wafers, Amorphous Semiconductors, Nanocrystalline Semiconductors, Field Effect, Ferroelectric Semiconductors, Solar Cell Modelling.

Organic Photovoltaics

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Publisher : Springer Science & Business Media
ISBN 13 : 3662051877
Total Pages : 311 pages
Book Rating : 4.6/5 (62 download)

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Book Synopsis Organic Photovoltaics by : Christoph Joseph Brabec

Download or read book Organic Photovoltaics written by Christoph Joseph Brabec and published by Springer Science & Business Media. This book was released on 2013-11-21 with total page 311 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume describes and explains the fundamentals of organic/plastic solar cells in a manner accessible to both researchers and students. It provides an up-to-date and comprehensive account of these materials and corresponding devices, which will play a key role in future solar energy systems.

Flexible Solar Cells

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Publisher : John Wiley & Sons
ISBN 13 : 3527623795
Total Pages : 202 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Flexible Solar Cells by : Mario Pagliaro

Download or read book Flexible Solar Cells written by Mario Pagliaro and published by John Wiley & Sons. This book was released on 2008-11-21 with total page 202 pages. Available in PDF, EPUB and Kindle. Book excerpt: With the decline in the world's natural resources, the need for new and cheaper energy sources is evolving. One such source is the sun which generates heat and light which can be harnessed and used to our advantage. This reference book introduces the topic of photovoltaics in the form of flexible solar cells. There are explanations of the principles behind this technology, the engineering required to produce these products and the future possibilities offered by this technology. The chemistry and physics of the cells (both organic and inorganic) are clarified as well as production methods, with information how this can then be applied to the nanoscale as well. A complete guide to this new and exciting way of producing energy which will be invaluable to a variety of people from material scientists, chemists, electrical engineers, to management consultants and politicians.

Photovoltaics Beyond Silicon

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Publisher : Elsevier
ISBN 13 : 0323901891
Total Pages : 819 pages
Book Rating : 4.3/5 (239 download)

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Book Synopsis Photovoltaics Beyond Silicon by : Senthilarasu Sundaram

Download or read book Photovoltaics Beyond Silicon written by Senthilarasu Sundaram and published by Elsevier. This book was released on 2024-07-01 with total page 819 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photovoltaics Beyond Silicon: Innovative Materials, Sustainable Processing Technologies, and Novel Device Structures presents the latest innovations in materials, processing and devices to produce electricity via advanced, sustainable photovoltaics technologies. The book provides an overview of the novel materials and device architectures that have been developed to optimize energy conversion efficiencies and minimize environmental impacts. Advances in technologies for harnessing solar energy are extensively discussed, with topics including materials processing, device fabrication, sustainability of materials and manufacturing, and the current state-of-the-art. Contributions from leading international experts discuss the applications, challenges and future prospects of research in this increasingly vital field, providing a valuable resource for students and researchers working in this area. - Presents a comprehensive overview and detailed discussion of solar energy technology options for sustainable energy conversion - Provides an understanding of the environmental challenges to be overcome and discusses the importance of efficient materials utilization for clean energy - Looks at how to design materials processing and optimize device fabrication, including metrics such as power-to-weight ratio, effectiveness at EOL compared to BOL, life-cycle analysis

Molecular Semiconductors

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Publisher : Springer Science & Business Media
ISBN 13 : 3642700128
Total Pages : 302 pages
Book Rating : 4.6/5 (427 download)

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Book Synopsis Molecular Semiconductors by : J. Simon

Download or read book Molecular Semiconductors written by J. Simon and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 302 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the past thirty years considerable efforts have been made to design the synthesis and the study of molecular semiconductors. Molecular semiconductors - and more generally molecular materials - involve interactions between individual subunits which can be separately synthesized. Organic and metallo-organic derivatives are the basis of most of the molecular materials. A survey of the literature on molecular semiconductors leaves one rather confused. It does seem to be very difficult to correlate the molecular structure of these semiconductors with their experimental electrical properties. For inorganic materials a simple definition delimits a fairly homogeneous family. If an inorganic material has a conductivity intermediate between that of an 12 1 1 3 1 1 insulator « 10- n- cm- ) and that of a metal (> 10 n- cm- ), then it is a semiconductor and will exhibit the characteristic properties of this family, such as junction formation, photoconductivity, and the photovoltaic effect. For molecular compounds, such simplicity is certainly not the case. A huge number of molecular and macromolecular systems have been described which possess an intermediate conductivity. However, the various attempts which have been made to rationalize their properties have, more often than not, failed. Even very basic electrical properties such as the mechanism of the charge carrier formation or the nature and the density ofthe dopants are not known in detail. The study of molecular semiconductor junctions is very probably the most powerful approach to shed light on these problems.

Organic Photovoltaics

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Author :
Publisher : CRC Press
ISBN 13 : 1351837060
Total Pages : 916 pages
Book Rating : 4.3/5 (518 download)

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Book Synopsis Organic Photovoltaics by : Sam-Shajing Sun

Download or read book Organic Photovoltaics written by Sam-Shajing Sun and published by CRC Press. This book was released on 2017-12-19 with total page 916 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recently developed organic photovoltaics (OPVs) show distinct advantages over their inorganic counterparts due to their lighter weight, flexible shape, versatile materials synthesis and device fabrication schemes, and low cost in large-scale industrial production. Although many books currently exist on general concepts of PV and inorganic PV materials and devices, few are available that offer a comprehensive overview of recently fast developing organic and polymeric PV materials and devices. Organic Photovoltaics: Mechanisms, Materials, and Devices fills this gap. The book provides an international perspective on the latest research in this rapidly expanding field with contributions from top experts around the world. It presents a unified approach comprising three sections: General Overviews; Mechanisms and Modeling; and Materials and Devices. Discussions include sunlight capture, exciton diffusion and dissociation, interface properties, charge recombination and migration, and a variety of currently developing OPV materials/devices. The book also includes two forewords: one by Nobel Laureate Dr. Alan J. Heeger, and the other by Drs. Aloysius Hepp and Sheila Bailey of NASA Glenn Research Center. Organic Photovoltaics equips students, researchers, and engineers with knowledge of the mechanisms, materials, devices, and applications of OPVs necessary to develop cheaper, lighter, and cleaner renewable energy throughout the coming decades.

Photovoltaic Materials

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Author :
Publisher : World Scientific
ISBN 13 : 1911298747
Total Pages : 292 pages
Book Rating : 4.9/5 (112 download)

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Book Synopsis Photovoltaic Materials by : Bube Richard H

Download or read book Photovoltaic Materials written by Bube Richard H and published by World Scientific. This book was released on 1998-05-30 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: Research and development of photovoltaic solar cells is playing an ever larger practical role in energy supply and ecological conservation all over the world. Many materials science problems are encountered in understanding existing solar cells and the development of more efficient, less costly, and more stable cells. This important and timely book provides a historical overview, but concentrates primarily on exciting developments in the last decade. It describes the properties of the materials that play an important role in photovoltaic applications, the solar cell structures in which they are used, and the experimental and theoretical developments that have led to the most promising contenders./a