The Design of Organic and Metal-based Catalysts for the Oxidative Functionalization of Aliphatic Carbon-hydrogen Bonds

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ISBN 13 :
Total Pages : 652 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis The Design of Organic and Metal-based Catalysts for the Oxidative Functionalization of Aliphatic Carbon-hydrogen Bonds by : Benjamin Henry Brodsky

Download or read book The Design of Organic and Metal-based Catalysts for the Oxidative Functionalization of Aliphatic Carbon-hydrogen Bonds written by Benjamin Henry Brodsky and published by . This book was released on 2007 with total page 652 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Metal-Based Catalysts in Organic Synthesis

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Publisher : MDPI
ISBN 13 : 3036510621
Total Pages : 68 pages
Book Rating : 4.0/5 (365 download)

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Book Synopsis Metal-Based Catalysts in Organic Synthesis by : Manas Sutradhar

Download or read book Metal-Based Catalysts in Organic Synthesis written by Manas Sutradhar and published by MDPI. This book was released on 2021-08-30 with total page 68 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysts play a crucial role in the path towards the transformation of organic compounds. This book describes the recent development of metal-based catalysis in organic synthesis. Applications of various catalysts to interesting organic transformations are discussed. It covers important organic reactions such as cyclohexane oxidation under different energy stimuli, use of Pd-nanoparticles for carbonylation of aniline, ammoximation of methyl ethyl ketone by Ni-modified TS-1 and carbozincation of substituted 2-alkynylamines. This book will be a useful reference for researchers in the field of catalysis, organic chemistry and materials science. It is also intended to attract the attention of researchers with an industrial interest.

Carbon-Based Metal Free Catalysts

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Publisher : Elsevier
ISBN 13 : 0323885187
Total Pages : 290 pages
Book Rating : 4.3/5 (238 download)

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Book Synopsis Carbon-Based Metal Free Catalysts by : Abdullah Mohammed Ah Asiri

Download or read book Carbon-Based Metal Free Catalysts written by Abdullah Mohammed Ah Asiri and published by Elsevier. This book was released on 2022-05-11 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon-Based Metal Free Catalysts: Preparation, Structural and Morphological Property and Application covers the different aspects of carbon-based metal free catalysts, including the fabrication of catalysts from natural sources and carbon allotropes, their manufacturing and design, characterization techniques, and applications. Special features in the book include illustrations and tables which summarize up-to-date information on research carried out on manufacturing, design, characterization and applications of metal free catalysts. This book assembles the information and knowledge on metal free catalysts and emphasizes the concept of green technology in the field of manufacturing and design. It is an ideal reference source for lecturers, students, researchers and industrialists working in the field of new catalyst development, especially polymer composites and is a valuable reference book handbook for teaching, learning, and research. Describes the design on metal-free catalysts Includes manufacturing technique of carbon-based metal free catalysts Lists applications of carbon-based metal free catalysts Discusses the characterization of carbon-based metal free catalysts

C-H Activation for Asymmetric Synthesis

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Publisher : John Wiley & Sons
ISBN 13 : 3527343407
Total Pages : 294 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis C-H Activation for Asymmetric Synthesis by : Françoise Colobert

Download or read book C-H Activation for Asymmetric Synthesis written by Françoise Colobert and published by John Wiley & Sons. This book was released on 2019-11-11 with total page 294 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides, in one handbook, comprehensive coverage of one of the hottest topics in stereoselective chemistry Written by leading international authors in the field, this book introduces readers to C-H activation in asymmetric synthesis along with all of its facets. It presents stereoselective C-H functionalization with a broad coverage, from outer-sphere to inner-sphere C-H bond activation, and from the control of olefin geometry to the induction of point, planar and axial chirality. Moreover, methods wherein asymmetry is introduced either during the C-H activation or in a different elementary step are discussed. Presented in two parts?asymmetric activation of C(sp3)-H bonds and stereoselective synthesis implying activation of C(sp2)-H bonds?CH-Activation for Asymmetric Synthesis showcases the diversity of stereogenic elements, which can now be constructed by C-H activation methods. Chapters in Part 1 cover: C(sp3)-H bond insertion by metal carbenoids and nitrenoids; stereoselective C-C bond and C-N bond forming reactions through C(sp3)?H bond insertion of metal nitrenoids; enantioselective intra- and intermolecular couplings; and more. Part 2 looks at: C-H activation involved in stereodiscriminant step; planar chirality; diastereoselective formation of alkenes through C(sp2)?H bond activation; amongst other methods. -Covers one of the most rapidly developing fields in organic synthesis and catalysis -Clearly structured in two parts (activation of sp3- and activation of sp2-H bonds) -Edited by two leading experts in C-H activation in asymmetric synthesis CH-Activation for Asymmetric Synthesis will be of high interest to chemists in academia, as well as those in the pharmaceutical and agrochemical industry.

Activation and Functionalization of C-H Bonds

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Publisher : ACS Symposium
ISBN 13 : 9780841238497
Total Pages : 0 pages
Book Rating : 4.2/5 (384 download)

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Book Synopsis Activation and Functionalization of C-H Bonds by : Karen I. Goldberg

Download or read book Activation and Functionalization of C-H Bonds written by Karen I. Goldberg and published by ACS Symposium. This book was released on 2004 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Activation and Functionalization of C-H Bonds explores recent developments in the reaction chemistry of solution-phase transition-metal based systems with simple hydrocarbons and with more complex organic molecules. More than 20 internationally leading research groups contributed to this volume, and their chapters cover such topics as fundamental theoretical and mechanistic studies of C-H bond activation by metal complexes, catalytic systems for alkane functionalization, and new applications in synthetic organic chemistry. An introductory chapter offers an overview of stoichiometric and catalytic reactions of C-H bonds with transition metal complexes. The C-H bond is the most widespread linkage in organic chemistry, present in virtually every organic molecule. Unfortunately, C-H bonds are famously resistant to selective chemical transformations. The development of methods for their selective transformations has enormous potential value in fields ranging from the chemistry of fuels (for example, the conversion of methane to methanol) to the synthesis of the most complex organic molecules.

Hydroxylation of Unactivated Tertiary Carbon-hydrogen Bonds Using Organic and Metal-based Catalysts

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (91 download)

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Book Synopsis Hydroxylation of Unactivated Tertiary Carbon-hydrogen Bonds Using Organic and Metal-based Catalysts by : Ashley Margaret Adams

Download or read book Hydroxylation of Unactivated Tertiary Carbon-hydrogen Bonds Using Organic and Metal-based Catalysts written by Ashley Margaret Adams and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The selective hydroxylation of C--H bonds with complex substrates remains a grand challenge in modern synthetic chemistry. Selective methods for C--H oxidation have the potential to transform the field of natural product and complex molecule synthesis. While a variety of methods exist for the oxidation of C--H bonds, significant challenges in reaction efficiency, including catalyst turnover numbers and oxidant use, and positional selectivity still remain. One method that our laboratory has investigated for C--H hydroxylation uses 1,2,3-benzoxathiazine-2,2-dioxide-derived oxaziridines. By gaining an understanding of the off pathway processes that govern oxaziridine stability, significant improvements in reaction time, scope, and efficiency were obtained. Subsequent studies focused on elucidating the energetic requirements of the C--H bond oxidation event as well as probing the mechanism of the previously undescribed reduction of the oxaziridine intermediate in water and alcoholic solvents. The final chapter of this thesis details investigations into two metal-based approaches for catalyzing C--H hydroxylation, along with a comparative analysis of several methods for C--H hydroxylation that appear in the literature. These efforts serve to define the current scope and limitations of existing technologies for C--H hydroxylation and provide a reference for users of this technology.

Innovative Catalysis in Organic Synthesis

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Publisher : John Wiley & Sons
ISBN 13 : 3527646604
Total Pages : 375 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Innovative Catalysis in Organic Synthesis by : Pher G. Andersson

Download or read book Innovative Catalysis in Organic Synthesis written by Pher G. Andersson and published by John Wiley & Sons. This book was released on 2012-04-16 with total page 375 pages. Available in PDF, EPUB and Kindle. Book excerpt: C-H, C-O, C-C, and C-Heteroatom bond forming processes by using metal-ligand approaches for the synthesis of organic compounds of biological, pharmacological and organic nanotechnological utility are the key areas addressed in this book. Authored by a European team of leaders in the field, it brings together innovative approaches for a variety of catalysis reactions and processes frequently applied in organic synthesis into a handy reference work. It covers all major types of catalysis, including homogeneous, heterogeneous, and organocatalysis, as well as mechanistic and computational studies. Special attention is paid to the improvements in efficiency and sustainability of important catalytic processes, such as selective oxidations, hydrogenation, and cross-coupling reactions, and to their utilization in industry. The result is a valuable resource for advanced researchers in both academia and industry, as well as graduate students in organic chemistry aiming for chemo-, regio- or stereoselective synthesis of organic compounds by using novel catalytic systems.

Carbon-Based Metal-Free Catalysts

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Publisher : John Wiley & Sons
ISBN 13 : 3527811427
Total Pages : 746 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Carbon-Based Metal-Free Catalysts by : Liming Dai

Download or read book Carbon-Based Metal-Free Catalysts written by Liming Dai and published by John Wiley & Sons. This book was released on 2018-08-29 with total page 746 pages. Available in PDF, EPUB and Kindle. Book excerpt: Offering comprehensive coverage of this hot topic, this two-volume handbook and ready reference treats a wide range of important aspects, from synthesis and catalytic properties of carbon materials to their applications as metal-free catalysts in various important reactions and industrial processes. Following a look at recent advances in the development of carbon materials as carbon-based metal-free catalysts, subsequent sections deal with a mechanistic understanding for the molecular design of efficient carbon-based metal-free catalysts, with a special emphasis on heteroatom-doped carbon nanotubes, graphene, and graphite. Examples of important catalytic processes covered include clean energy conversion and storage, environmental protection, and synthetic chemistry. With contributions from world-leading scientists, this is an indispensable source of information for academic and industrial researchers in catalysis, green chemistry, electrochemistry, materials science, nanotechnology, energy technology, and chemical engineering, as well as graduates and scientists entering the field.

Organic Catalysis with Metal-Dinitrosyl Complexes and Synthetic Biomimetic Supramolecular Nanovessels

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ISBN 13 :
Total Pages : 201 pages
Book Rating : 4.:/5 (957 download)

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Book Synopsis Organic Catalysis with Metal-Dinitrosyl Complexes and Synthetic Biomimetic Supramolecular Nanovessels by : Chen Zhao

Download or read book Organic Catalysis with Metal-Dinitrosyl Complexes and Synthetic Biomimetic Supramolecular Nanovessels written by Chen Zhao and published by . This book was released on 2014 with total page 201 pages. Available in PDF, EPUB and Kindle. Book excerpt: The work described in this dissertation explores the field of organic catalysis with metal-dinitrosyl complexes and synthetic supramolecular nanovessels. Part I (Chapters 1-3) presents the development of both stoichiometric and catalytic vinylic C-H functionalization reactions of unactivated alkenes mediated by cobalt and ruthenium dinitrosyl complexes. Part II (Chapters 4-7) describes the design and synthesis of terephthalamide-based supramolecular M4L6 nanovessels and their application in organic catalysis. Part I - Metal-Dinitrosyl Mediated Vinylic C-H Functionalization Chapter 1 contains a brief literature review of C-H activation and functionalization reactions mediated by transition-metal complexes. Of the examples presented, the cobalt dinitrosyl mediated intermolecular vinylic C-H functionalization reaction offers an approach for the activation of simple alkenyl C-H bonds that takes advantage of the ligand-based reactivity of such cobalt complexes. The difficulties of isolating the reactive cobalt dinitrosyl species and achieving catalytic turnover for functionalization, as well as extension toward other metals, are also presented to provide a context in which Chapters 2 and 3 can be viewed. Chapter 2 describes the development of a one-pot cobalt-dinitrosyl mediated inter- and intramolecular vinylic C-H functionalization reaction of unactivated and alkyl-substituted alkenes. Enantioselective intramolecular cobalt-dinitrosyl mediated 5-exo-trig and 6-endo-trig cyclization reactions are also described. Although catalytic turnovers can be achieved with such complexes for vinylic C-H functionalization, generality of the methodology and broader substrate scope remain elusive. Chapter 3 presents the application of a ruthenium-dinitrosyl complex in the context of vinylic C-H functionalization reaction of simple alkenes. The recently discovered ruthenium-dinitrosyl complex proves to be stable for isolation and characterization, an improvement over the cobalt system, but also proves to be less reactive as a catalyst for vinylic C-H functionalization. The challenges associated with the development of metal-dinitrosyl catalyzed C-H functionalization and its outlook are also discussed. Part II - Synthesis of Terephthalamide-based Ga4L6 Supramolecular Nanovessels and their Application in Enantioselective and Stereospecific Organic Catalysis Chapter 4 introduces the field of supramolecular chemistry with a main focus on the synthesis and chemistry of enantiopure host complexes. Examples of asymmetric organic reactions catalyzed by chiral host assemblies are also presented to provide a platform from which Chapters 5-7 can be viewed. Chapter 5 describes the design, synthesis and characterization of enantiopure supramolecular Ga4L6 nanovessels that are based on terephthalamide (TAM)-derived ligands. The synthesis of achiral TAM-based ligands and their corresponding racemic host-guest complexes are also presented. Chapter 6 summarizes the development of an enantioselective ring-opening reaction of meso-episulfonium catalyzed by the enantiopure host assembly presented in Chapter 5. Additionally, the application of this new cluster as a chiral host catalyst for the Aza-Cope rearrangement and the Prins-like cyclization reactions are also discussed. Chapter 7 describes the development of a stereospecific reaction catalyzed by both racemic and enantiopure supramolecular Ga4L6 host assemblies. The host assemblies are capable of catalyzing the substitution reaction at a secondary benzylic carbon center to give products with overall stereochemical retention, while reaction of the same substrates in bulk solution gives products with inversion. Such ability of a biomimetic synthetic host assembly to reverse the stereochemical outcome of a nucleophilic substitution reaction is unprecedented in the field of supramolecular catalysis.

Visible Light Photocatalysis in Organic Chemistry

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Publisher : John Wiley & Sons
ISBN 13 : 3527335609
Total Pages : 454 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Visible Light Photocatalysis in Organic Chemistry by : Corey R.J. Stephenson

Download or read book Visible Light Photocatalysis in Organic Chemistry written by Corey R.J. Stephenson and published by John Wiley & Sons. This book was released on 2018-05-29 with total page 454 pages. Available in PDF, EPUB and Kindle. Book excerpt: Filling the need for a ready reference that reflects the vast developments in this field, this book presents everything from fundamentals, applications, various reaction types, and technical applications. Edited by rising stars in the scientific community, the text focuses solely on visible light photocatalysis in the context of organic chemistry. This primarily entails photoinduced electron transfer and energy transfer chemistry sensitized by polypyridyl complexes, yet also includes the use of organic dyes and heterogeneous catalysts. A valuable resource to the synthetic organic community, polymer and medicinal chemists, as well as industry professionals.

Carbon-Based Metal-Free Catalysts, 2 Volumes

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Publisher : Wiley-VCH
ISBN 13 : 9783527343416
Total Pages : 0 pages
Book Rating : 4.3/5 (434 download)

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Book Synopsis Carbon-Based Metal-Free Catalysts, 2 Volumes by : Liming Dai

Download or read book Carbon-Based Metal-Free Catalysts, 2 Volumes written by Liming Dai and published by Wiley-VCH. This book was released on 2019-01-04 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Offering comprehensive coverage of this hot topic, this two-volume handbook and ready reference treats a wide range of important aspects, from synthesis and catalytic properties of carbon materials to their applications as metal-free catalysts in various important reactions and industrial processes. Following a look at recent advances in the development of carbon materials as carbon-based metal-free catalysts, subsequent sections deal with a mechanistic understanding for the molecular design of efficient carbon-based metal-free catalysts, with a special emphasis on heteroatom-doped carbon nanotubes, graphene, and graphite. Examples of important catalytic processes covered include clean energy conversion and storage, environmental protection, and synthetic chemistry. With contributions from world-leading scientists, this is an indispensable source of information for academic and industrial researchers in catalysis, green chemistry, electrochemistry, materials science, nanotechnology, energy technology, and chemical engineering, as well as graduates and scientists entering the field.

C-H Bond Activation and Catalytic Functionalization I

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Publisher : Springer
ISBN 13 : 3319246305
Total Pages : 269 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis C-H Bond Activation and Catalytic Functionalization I by : Pierre H. Dixneuf

Download or read book C-H Bond Activation and Catalytic Functionalization I written by Pierre H. Dixneuf and published by Springer. This book was released on 2015-12-18 with total page 269 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal.

Catalyzed Carbon-Heteroatom Bond Formation

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Publisher : John Wiley & Sons
ISBN 13 : 3527633405
Total Pages : 541 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Catalyzed Carbon-Heteroatom Bond Formation by : Andrei K. Yudin

Download or read book Catalyzed Carbon-Heteroatom Bond Formation written by Andrei K. Yudin and published by John Wiley & Sons. This book was released on 2010-12-01 with total page 541 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by an experienced editor widely acclaimed within the scientific community, this book covers everything fromo9xygen to nitrogen functionalities. From the contents: Palladium-Catalyzed Syntheses of Five-Member Saturated Heterocyclic and of Aromatic Heterodynes Palladium-Catalysis for Oxidative 1, 2-Difunctionalization of Alkenes Rhodium-Catalyzed Amination of C-H-Bonds Carbon-Heteroatom Bond Formation by RH(I)-Catalyzed Ring-Opening Reactions Transition Metal-Catalyzed Synthesis of Lactones and of Monocyclic and Fused Five-Membered Aromatic heterocycles the Formation of Carbon-Sulfur and Carbon-Selenium bonds by Substitution and Addition reactions catalyzed by Transition Metal Complexes New Reactions of Copper Acetylides Gold Catalyzed Addition of Nitrogen, Sulfur and Oxygen Nucleophiles to C-C Multiple Bonds. The result is an indispensable source of information for the Strategic Planning of the Synthetic routes for organic, catalytic and medicinal chemists, as well as chemists in industry.

Novel Catalysts in Advanced Oxidation of Organic Pollutants

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Publisher : Springer
ISBN 13 : 3319289500
Total Pages : 69 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis Novel Catalysts in Advanced Oxidation of Organic Pollutants by : Süheyda Atalay

Download or read book Novel Catalysts in Advanced Oxidation of Organic Pollutants written by Süheyda Atalay and published by Springer. This book was released on 2016-01-27 with total page 69 pages. Available in PDF, EPUB and Kindle. Book excerpt: This brief summarizes the role of certain catalysts and associated processes that are involved in the reduction or elimination of hazardous substances from wastewater and the exploitation of renewable raw materials. The authors begin by providing a summary of the most recent developments in catalysts used in the advanced oxidation of organic pollutants in aqueous phase. Advanced Oxidation Processes (AOPS) are described in terms of homogeneous and heterogeneous catalysts. Some emphasis is placed on the role nanocatalysts, perovskite-type catalysts, and green catalysts play in several AOPs such as Fenton Chemistry, photocatalytic oxidation, and the hybrid technologies that combine different processes. Catalyst preparation, characterization, reaction chemistry, and process technology are described. Specific wastewater case studies which illustrate the role of these catalysts in AOPs completes the brief.

Metal-organic Framework Catalysts for Selective C-H Borylation

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Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (137 download)

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Book Synopsis Metal-organic Framework Catalysts for Selective C-H Borylation by : Jesse Brandon Duque

Download or read book Metal-organic Framework Catalysts for Selective C-H Borylation written by Jesse Brandon Duque and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Selective C-H functionalization of organic molecules is one of the most desired transformations in organic synthesis. In recent years, many groups have turned to using supramolecular chemistries to perturb native selectivity in reactions that are predominantly sterically controlled. In instances where there is little steric differentiation, people have turned to the development of supramolecular strategies that involve a level of directionality between substrate and catalyst assemblies primarily through non-covalent interactions. More proximal functionalizations to directing groups on substrates were the first to evolve, however branching out to more distal positions proved to be a formidable challenge. To address this discrepancy, significant research has been devoted to the use of porous materials as a potential support for use in transition metal catalysis to selectively functionalize a wide variety of compounds. One notable material type that has found itself in catalytic applications are metal-organic frameworks (MOFs). Because of their ability to be fitted with different types of metal and organic components, MOFs can contain a variety of functionalities for specific purposes integrated into them. The extended crystalline lattices and rigid framework of MOFs results in fixed spatial relationships between their structural features, and our main interest is exploiting these fixed relationships to selectively functionalize C-H bonds. In the short term, I sought to develop highly selective MOFs as effective C-H borylation catalysts. The long-term goal for my projects is to establish MOFs as tools for small molecule synthesis. The central hypothesis of this work is that the pore environment of MOFs can be modified to control selectivity in otherwise non or poorly selective transformations. To test this hypothesis, I investigated two different modes of perturbing selectivity in borylation reactions: selectivity through confinement and selectivity from substrate docking. In confinement-affected borylation, UiO-67-type MOFs were investigated for size confinement effects that assist in directing substrates into transition states where the ortho borylated regioisomer predominates. In the substrate docking approach, I investigated the use of MOF (Zn) PCN-222 as a metalloporphyrin-based director for substrate docking via Zn-substrate interactions. We were able to observe borylation activity using this MOF catalyst but did not observe significant regioselectivity in our experiments. In parallel with these studies, I developed a new approach toward high throughput experimentation in small molecule MOF catalysis, which allowed us to dispense submilligram quantities of MOF into multiple wells and lead to more efficient workflow using Chembeads technology developed by Abbvie and the team of Noah Tu.

Classics in Total Synthesis II

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Publisher : Wiley-VCH
ISBN 13 : 9783527306848
Total Pages : 639 pages
Book Rating : 4.3/5 (68 download)

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Book Synopsis Classics in Total Synthesis II by : K. C. Nicolaou

Download or read book Classics in Total Synthesis II written by K. C. Nicolaou and published by Wiley-VCH. This book was released on 2003-10-17 with total page 639 pages. Available in PDF, EPUB and Kindle. Book excerpt: Classics in Total Synthesis II is the long awaited sequel to Classics in Total Synthesis, a book that has made its mark as a superb tool for educating students and practitioners alike in the art of organic synthesis since its introduction in 1996. In this highly welcomed second volume, K.C. Nicolaou and Scott A. Snyder discuss in detail the most impressive accomplishments in natural product total synthesis during the 1990s and the first years of the 21st century. While all of the features that made the first volume of Classics so popular and unique as a teaching tool have been maintained, in this new treatise the authors seek to present the latest techniques and advance in organic synthesis as they beautifully describe the works of some of the most renowned synthetic organic chemists of our time. Key features include: Systematically develops domino reactions, cascade sequences, biomimetic strategies, and asymmetric catalysis through the chosen synthesis Discusses cutting edge synthetic technologies in terms of mechanism and scope Presents new reactions, such as olefin metathesis, in mini-review style Includes abundant references for further reading CD with useful teaching material for lecturers is included with hardback version (ISBN 3-527-30685-4) Graduate students, educators, and researchers in the fields of synthetic and medicinal chemistry will wish to have a copy of this book in their collection as an indispensable companion that both augments and supplements the original Classics in Total Synthesis. From the reviews: "... a volume, (...) which any chemist with an interest in synthetic organic chemistry will wish to acquire." –JACS (on the previous volume) "...this superb book (...) will be an essential purchase for many organic chemists." –Nature (on the previous volume) "...Classics II is undoubtedly an excellent bargain that is highly recommended to everybody interested in advanced organic chemistry. One of my co-workers confessed that Classics I was the book on his bedside table while he prepared his thesis defense. Isn't that the highest distinction for a monograph? I have every reason to believe that Classics II will equally stand the selection process by students (and probably their supervisors too)." –Angewandte Chemie, 2004 "Well, there is a new pleasant read for the advanced student and even the experienced. It is the second volume to the established Classics in Total Synthesis and it continues the series extremely well." –ChemBioChem, 2004 "...the real innovation of this volume is the inclusion of alternative pathways to the same target molecule by other researchers. This enables the reader to appreciate that there are also other solutions to certain structural problems than those of the original synthesis. ... Let us hope that K. C. Nicolaou and his associates will present us with these future achievements in the same clear, informative and innovative format they have with the previous two volumes." –Applied Organometallic Chemistry

Frontiers of Green Catalytic Selective Oxidations

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Publisher : Springer Nature
ISBN 13 : 9813297514
Total Pages : 295 pages
Book Rating : 4.8/5 (132 download)

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Book Synopsis Frontiers of Green Catalytic Selective Oxidations by : Konstantin P. Bryliakov

Download or read book Frontiers of Green Catalytic Selective Oxidations written by Konstantin P. Bryliakov and published by Springer Nature. This book was released on 2019-10-02 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: The demand for novel efficient and environmentally sustainable chemo, regio- and stereoselective catalyst systems for the oxidation of organic substrates is continuously growing in line with toughening economic and environmental constraints. This book addresses these issues; it consists of eleven chapters written by world-recognized experts in green and sustainable oxidation catalysis. The most urgent and challenging topics, in the judgment of the editor, such as green asymmetric epoxidations, sulfoxidatiuons, C–H oxidations; oxidation catalysis by polyoxometalates and oxidations in non-conventional solvents, etc. have been critically reviewed in this book. Both fundamental aspects, such as catalysts design, catalytic properties, nature of catalytically active sites and reaction mechanisms, and practical outlook of the oxidations have been addressed by the authors. The book appeals to a broad readership, particularly graduate students, employees of universities and research organizations, and industrial researchers, particularly those working in the areas of homogeneous oxidation catalysis, asymmetric synthesis, organocatalysis, sustainable catalytic processes and green chemistry, mechanisms of catalytic reactions, synthesis of bioactive compounds, biomimetic chemistry, etc. Konstantin Bryliakov is Leading Researcher at the Boreskov Institute of Catalysis. In 2016, he was elected Honorary Professor of the Russian Academy of Sciences.