Synthesis, Characterization, and Electrochemical Performance of Oxide Cathode Materials for Use in Lithium Ion Batteries

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ISBN 13 :
Total Pages : 236 pages
Book Rating : 4.:/5 (63 download)

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Book Synopsis Synthesis, Characterization, and Electrochemical Performance of Oxide Cathode Materials for Use in Lithium Ion Batteries by : Brandon Joseph Kelly

Download or read book Synthesis, Characterization, and Electrochemical Performance of Oxide Cathode Materials for Use in Lithium Ion Batteries written by Brandon Joseph Kelly and published by . This book was released on 2009 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis, Characterization, and Electrochemical Investigation of Layered Oxide Materials for Lithium Ion Batteries

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ISBN 13 :
Total Pages : 316 pages
Book Rating : 4.:/5 (639 download)

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Book Synopsis Synthesis, Characterization, and Electrochemical Investigation of Layered Oxide Materials for Lithium Ion Batteries by : Donglin Han

Download or read book Synthesis, Characterization, and Electrochemical Investigation of Layered Oxide Materials for Lithium Ion Batteries written by Donglin Han and published by . This book was released on 2005 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis and Characterization of Lini0. 6mn0. 35co0. 05o2 and Li2fesio4/C As Electrodes for Rechargeable Lithium Ion Battery

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ISBN 13 : 9781361298015
Total Pages : pages
Book Rating : 4.2/5 (98 download)

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Book Synopsis Synthesis and Characterization of Lini0. 6mn0. 35co0. 05o2 and Li2fesio4/C As Electrodes for Rechargeable Lithium Ion Battery by : Pengda Hong

Download or read book Synthesis and Characterization of Lini0. 6mn0. 35co0. 05o2 and Li2fesio4/C As Electrodes for Rechargeable Lithium Ion Battery written by Pengda Hong and published by . This book was released on 2017-01-26 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Synthesis and characterization of LiNi0.6Mn0.35Co0.05O2 and Li2FeSiO4/C as electrodes for rechargeable lithium ion battery" by Pengda, Hong, 洪鹏达, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: The rechargeable lithium ion batteries (LIB) are playing increasingly important roles in powering portal commercial electronic devices. They are also the potential power sources of electric mobile vehicles. The first kind of the cathode materials, LiXCoO2, was commercialized by Sony Company in 1980s, and it is still widely used today in LIB. However, the high cost of cobalt source, its environmental unfriendliness and the safety issue of LiXCoO2 have hindered its widespread usage today. Searching for alternative cathode materials with low cost of the precursors, being environmentally benign and more stable in usage has become a hot topic in LIB research and development. In the first part of this study, lithium nickel manganese cobalt oxide (LiNi0.6Mn0.35Co0.05O2) is studied as the electrode. The materials are synthesized at high temperatures by solid state reaction method. The effect of synthesis temperature on the electrochemical performance is investigated, where characterizations by, for example, X-ray diffraction (XRD) and scanning electron microscopy (SEM), for particle size distribution, specific surface area, and charge-discharge property, are done over samples prepared at different conditions for comparison. The electrochemical tests of the rechargeable Li ion batteries using LiNi0.6Mn0.35Co0.05 cathode prepared at optimum conditions are carried out in various voltage ranges, at different discharge rates and at high temperature. In another set of experiments, the material is adopted as anode with lithium foil as the cathode, and its capacitance is tested. In the second part of this study, the iron based cathode material is investigated. Lithium iron orthosilicate with carbon coating is synthesized at 700℃ by solid state reaction, which is assisted by high energy ball milling. Characterizations are done for discharge capacities of the samples with different carbon weight ratio coatings. DOI: 10.5353/th_b4715029 Subjects: Lithium ion batteries Cathodes Lithium compounds - Synthesis Cobalt compounds - Synthesis Manganese compounds - Synthesis Silicon compounds - Synthesis Iron compounds - Synthesis

Materials for Lithium-Ion Batteries

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Publisher : Springer Science & Business Media
ISBN 13 : 9780792366508
Total Pages : 658 pages
Book Rating : 4.3/5 (665 download)

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Book Synopsis Materials for Lithium-Ion Batteries by : Christian Julien

Download or read book Materials for Lithium-Ion Batteries written by Christian Julien and published by Springer Science & Business Media. This book was released on 2000-10-31 with total page 658 pages. Available in PDF, EPUB and Kindle. Book excerpt: A lithium-ion battery comprises essentially three components: two intercalation compounds as positive and negative electrodes, separated by an ionic-electronic electrolyte. Each component is discussed in sufficient detail to give the practising engineer an understanding of the subject, providing guidance on the selection of suitable materials in actual applications. Each topic covered is written by an expert, reflecting many years of experience in research and applications. Each topic is provided with an extensive list of references, allowing easy access to further information. Readership: Research students and engineers seeking an expert review. Graduate courses in electrical drives can also be designed around the book by selecting sections for discussion. The coverage and treatment make the book indispensable for the lithium battery community.

Handbook of Sodium-Ion Batteries

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Publisher : CRC Press
ISBN 13 : 1000625931
Total Pages : 765 pages
Book Rating : 4.0/5 (6 download)

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Book Synopsis Handbook of Sodium-Ion Batteries by : George Zhao

Download or read book Handbook of Sodium-Ion Batteries written by George Zhao and published by CRC Press. This book was released on 2023-01-31 with total page 765 pages. Available in PDF, EPUB and Kindle. Book excerpt: The need for batteries has grown exponentially in response to the increase in global energy demand and to the ambitious goals that governments have set up for sustainable energy development worldwide, especially in developed countries. While lithium-ion batteries currently dominate the energy storage market, the limited and unevenly distributed lithium resources have caused huge concerns over the sustainability of the lithium-ion battery technology. Sodium-ion batteries have significant benefits over lithium-ion batteries, including sodium’s abundance in the Earth’s crust. These batteries have therefore gained research interest, and efforts are being made to use them in place of lithium-ion batteries. While the past decade has witnessed significant research advances and breakthroughs in developing the sodium-ion battery technology, there still remain fundamental challenges that must be overcome to push the technology forward. This book comprises 13 chapters that discuss the fundamental challenges, electrode materials, electrolytes, separators, advanced instrumental analysis techniques, and computational methods for sodium-ion batteries from renowned scientists. The book is a unique combination of all aspects associated with sodium-ion batteries and can therefore be used as a handbook.

Electrochemical Energy

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Publisher : CRC Press
ISBN 13 : 1351231200
Total Pages : 1051 pages
Book Rating : 4.3/5 (512 download)

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Book Synopsis Electrochemical Energy by : Pei Kang Shen

Download or read book Electrochemical Energy written by Pei Kang Shen and published by CRC Press. This book was released on 2018-10-08 with total page 1051 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrochemical Energy: Advanced Materials and Technologies covers the development of advanced materials and technologies for electrochemical energy conversion and storage. The book was created by participants of the International Conference on Electrochemical Materials and Technologies for Clean Sustainable Energy (ICES-2013) held in Guangzhou, China, and incorporates select papers presented at the conference. More than 300 attendees from across the globe participated in ICES-2013 and gave presentations in six major themes: Fuel cells and hydrogen energy Lithium batteries and advanced secondary batteries Green energy for a clean environment Photo-Electrocatalysis Supercapacitors Electrochemical clean energy applications and markets Comprised of eight sections, this book includes 25 chapters featuring highlights from the conference and covering every facet of synthesis, characterization, and performance evaluation of the advanced materials for electrochemical energy. It thoroughly describes electrochemical energy conversion and storage technologies such as batteries, fuel cells, supercapacitors, hydrogen generation, and their associated materials. The book contains a number of topics that include electrochemical processes, materials, components, assembly and manufacturing, and degradation mechanisms. It also addresses challenges related to cost and performance, provides varying perspectives, and emphasizes existing and emerging solutions. The result of a conference encouraging enhanced research collaboration among members of the electrochemical energy community, Electrochemical Energy: Advanced Materials and Technologies is dedicated to the development of advanced materials and technologies for electrochemical energy conversion and storage and details the technologies, current achievements, and future directions in the field.

Impedance Spectroscopy

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Publisher : John Wiley & Sons
ISBN 13 : 1119333180
Total Pages : 1088 pages
Book Rating : 4.1/5 (193 download)

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Book Synopsis Impedance Spectroscopy by : Evgenij Barsoukov

Download or read book Impedance Spectroscopy written by Evgenij Barsoukov and published by John Wiley & Sons. This book was released on 2018-03-22 with total page 1088 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Essential Reference for the Field, Featuring Protocols, Analysis, Fundamentals, and the Latest Advances Impedance Spectroscopy: Theory, Experiment, and Applications provides a comprehensive reference for graduate students, researchers, and engineers working in electrochemistry, physical chemistry, and physics. Covering both fundamentals concepts and practical applications, this unique reference provides a level of understanding that allows immediate use of impedance spectroscopy methods. Step-by-step experiment protocols with analysis guidance lend immediate relevance to general principles, while extensive figures and equations aid in the understanding of complex concepts. Detailed discussion includes the best measurement methods and identifying sources of error, and theoretical considerations for modeling, equivalent circuits, and equations in the complex domain are provided for most subjects under investigation. Written by a team of expert contributors, this book provides a clear understanding of impedance spectroscopy in general as well as the essential skills needed to use it in specific applications. Extensively updated to reflect the field’s latest advances, this new Third Edition: Incorporates the latest research, and provides coverage of new areas in which impedance spectroscopy is gaining importance Discusses the application of impedance spectroscopy to viscoelastic rubbery materials and biological systems Explores impedance spectroscopy applications in electrochemistry, semiconductors, solid electrolytes, corrosion, solid state devices, and electrochemical power sources Examines both the theoretical and practical aspects, and discusses when impedance spectroscopy is and is not the appropriate solution to an analysis problem Researchers and engineers will find value in the immediate practicality, while students will appreciate the hands-on approach to impedance spectroscopy methods. Retaining the reputation it has gained over years as a primary reference, Impedance Spectroscopy: Theory, Experiment, and Applications once again present a comprehensive reference reflecting the current state of the field.

Synthesis and Characterization of Carbon Nanotube Modified Electrode Materials for Li-ion Batteries

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ISBN 13 :
Total Pages : 418 pages
Book Rating : 4.:/5 (922 download)

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Book Synopsis Synthesis and Characterization of Carbon Nanotube Modified Electrode Materials for Li-ion Batteries by :

Download or read book Synthesis and Characterization of Carbon Nanotube Modified Electrode Materials for Li-ion Batteries written by and published by . This book was released on 2009 with total page 418 pages. Available in PDF, EPUB and Kindle. Book excerpt: Today, the Lithium ion (Li-ion) is the fastest growing and most promising rechargeable battery chemistry. For high current demands, there is an emphasis on the importance of very low cell resistance to allow unrestricted flow of current. The electrochemical performance of Li-ion batteries relies significantly on the properties of the cathode materials, the anode materials and the electrolytes. In this study, novel anode and cathode materials were synthesized and systematically studied for Li-ion battery application. Novel anode synthesis involved the substitution of the flat foil current collectors normally used by nano- or micro-wire arrays, as the higher surface area makes it possible to pack much more active material into an electrode. Ni or Cu wire arrays with wire thicknesses of 200 nm, 400 nm or 1 \03BCm were synthesised. Carbon nanotubes (CNTs) were chosen as the Li-insertion compound due to its high theoretical reversible lithium storage capacity. Synthesis of the Cu or Ni/CNT consolidated composite anodes were done using novel synthetic techniques, combining template synthesis via electrochemical deposition and chemical vapour deposition (CVD) techniques. XRD analysis of both the Ni and Cu wire arrays after carbon nanotube deposition, confirmed that the crystallinity of the wire arrays were not altered by the CVD of carbon nanotubes. The optimal results were obtained for the 200 nm Cu/CNT consolidated composite anode. The current density obtained for the Li de-intercalation (\03AFp) was 0.463 A/g. A reversible discharge capacity of 358 mAh/g was obtained in the subsequent charge/discharge cycling. The composite anode materials showed good charge/discharge cycling performances and a high capacity integrity was maintained in the cycling behaviour analyses.

Synthesis, Characterization, and Electrochemical Investigation of Novel Electrode Materials for Lithium Ion Batteries [microform]

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Publisher : National Library of Canada = Bibliothèque nationale du Canada
ISBN 13 : 9780612772366
Total Pages : 516 pages
Book Rating : 4.7/5 (723 download)

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Book Synopsis Synthesis, Characterization, and Electrochemical Investigation of Novel Electrode Materials for Lithium Ion Batteries [microform] by : Tracy Alexandra Kerr

Download or read book Synthesis, Characterization, and Electrochemical Investigation of Novel Electrode Materials for Lithium Ion Batteries [microform] written by Tracy Alexandra Kerr and published by National Library of Canada = Bibliothèque nationale du Canada. This book was released on 2002 with total page 516 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Transition Metal Oxides for Electrochemical Energy Storage

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Publisher : John Wiley & Sons
ISBN 13 : 3527344934
Total Pages : 436 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Transition Metal Oxides for Electrochemical Energy Storage by : Jagjit Nanda

Download or read book Transition Metal Oxides for Electrochemical Energy Storage written by Jagjit Nanda and published by John Wiley & Sons. This book was released on 2022-03-28 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition Metal Oxides for Electrochemical Energy Storage Explore this authoritative handbook on transition metal oxides for energy storage Metal oxides have become one of the most important classes of materials in energy storage and conversion. They continue to have tremendous potential for research into new materials and devices in a wide variety of fields. Transition Metal Oxides for Electrochemical Energy Storage delivers an insightful, concise, and focused exploration of the science and applications of metal oxides in intercalation-based batteries, solid electrolytes for ionic conduction, pseudocapacitive charge storage, transport and 3D architectures and interfacial phenomena and defects. The book serves as a one-stop reference for materials researchers seeking foundational and applied knowledge of the titled material classes. Transition Metal Oxides offers readers in-depth information covering electrochemistry, morphology, and both in situ and in operando characterization. It also provides novel approaches to transition metal oxide-enabled energy storage, like interface engineering and three-dimensional nanoarchitectures. Readers will also benefit from the inclusion of: A thorough introduction to the landscape and solid-state chemistry of transition metal oxides for energy storage An exploration of electrochemical energy storage mechanisms in transition metal oxides, including intercalation, pseudocapacitance, and conversion Practical discussions of the electrochemistry of transition metal oxides, including oxide/electrolyte interfaces and energy storage in aqueous electrolytes An examination of the characterization of transition metal oxides for energy storage Perfect for materials scientists, electrochemists, inorganic chemists, and applied physicists, Transition Metal Oxides for Electrochemical Energy Storage will also earn a place in the libraries of engineers in power technology and professions working in the electrotechnical industry seeking a one-stop reference on transition metal oxides for energy storage.

Solid State Batteries

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Publisher : Springer Nature
ISBN 13 : 3031124707
Total Pages : 298 pages
Book Rating : 4.0/5 (311 download)

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Book Synopsis Solid State Batteries by : Nithyadharseni Palaniyandy

Download or read book Solid State Batteries written by Nithyadharseni Palaniyandy and published by Springer Nature. This book was released on 2022-11-01 with total page 298 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers a comprehensive analysis of novel design strategies in higher energy solid-state lithium batteries. It describes synthesis and experimental techniques to characterize the physical, chemical and electrochemical properties of the electrode and electrolytes. The book reports on electrochemical measurements of conductivity and related parameters in solid electrolytes and its interfaces. It also presents various technologies that have been used for the fabrication of all-solid-state lithium-ion batteries such as thin-film, 3D printing (additive manufacturing) and atomic layer deposition. A large part of the text focus on the description on the complete functioning and challenges with the electrochemistry of the electrodes and solid electrolyte interfaces. The book also supplies valuable insight into potential growth opportunities in this exciting market and cost-effective design tactics in solid-state assemblies.

Investigations of Cathode Materials for Lithium-ion Batteries

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ISBN 13 :
Total Pages : 282 pages
Book Rating : 4.:/5 (426 download)

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Book Synopsis Investigations of Cathode Materials for Lithium-ion Batteries by : Dong Zhang

Download or read book Investigations of Cathode Materials for Lithium-ion Batteries written by Dong Zhang and published by . This book was released on 1999 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Structural and Electrochemical Characterization of High-energy Oxide Cathodes for Lithium Ion Batteries

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Publisher :
ISBN 13 :
Total Pages : 376 pages
Book Rating : 4.:/5 (828 download)

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Book Synopsis Structural and Electrochemical Characterization of High-energy Oxide Cathodes for Lithium Ion Batteries by : Eun Sung Lee

Download or read book Structural and Electrochemical Characterization of High-energy Oxide Cathodes for Lithium Ion Batteries written by Eun Sung Lee and published by . This book was released on 2012 with total page 376 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lithium-ion batteries are the most promising rechargeable battery system for both vehicle applications and stationary storage of electricity produced from renewable sources such as solar and wind energies. However, the current lithium ion technology does not fully meet the requirements of these applications in terms of energy and power density. One approach to realizing a combination of high energy and power density is to use a composite cathode that consists of the high-capacity lithium-rich layered oxide Li[Li, Mn, Ni, Co]O2 and the high-voltage spinel oxide LiMn[subscript 1.5]Ni[subscript 0.5]O4. This dissertation explores the unique structural characteristics and their effect on the electrochemical performance of the layered-spinel composite oxide cathodes along with individual layered and spinel oxides over a wide voltage range (5.0 -- 2.0 V). Initially, the effect of cation ordering on the electrochemical and structural characteristics of LiMn[subscript 1.5]Ni[subscript 0.5]O4 during cycling between 5.0 and 2.0 V were investigated by an analysis of the X-ray diffraction (XRD) and electrochemical data. Structural studies revealed that the cation ordering affects the size of the empty-octahedral sites in the spinel lattice. The differences in the size of the empty-octahedral sites affect the discharge profile below 3 V due to the variation in lattice distortion during lithium ion insertion into 16c octahedral sites. With the doped LiMn1.5Ni0.5-xMxO4 (M = Cr, Fe, Co, and Ga) spinels, different dopant ions have different effects on the degree of cation ordering due to the differences in ionic radii and surface-segregation characteristics. The compositional and wt.% variations of the layered and spinel phases from the nominal values in the layered-spinel composites were obtained by employing a joint XRD and neutron diffraction (ND) Rietveld refinement method. With the obtained composition and ex-situ XRD data, the mechanism for the increase in capacity and the facile phase transformation of the layered phase in the composite cathodes to a 3 V spinel-like phase during cycling was proposed. Investigations focused on synthesis temperature revealed that the electrochemical characteristics of the composites are highly affected by the synthesis temperature due to the change in the surface area of the sample and cation ordering of the spinel phase. In addition, the electrochemical performance of the lithium-rich layered oxide Li[Li, Mn, Ni, Co]O2 could be improved by blending it with a lithium-free insertion host VO2(B) and by controlling the amount of lithium ions extracted from the layered lattice during the first charge process.

Nanostructured Materials Engineering and Characterization for Battery Applications

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Publisher : Elsevier
ISBN 13 : 0323914217
Total Pages : 715 pages
Book Rating : 4.3/5 (239 download)

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Book Synopsis Nanostructured Materials Engineering and Characterization for Battery Applications by : Amadou Belal Gueye

Download or read book Nanostructured Materials Engineering and Characterization for Battery Applications written by Amadou Belal Gueye and published by Elsevier. This book was released on 2024-06-28 with total page 715 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanostructured Materials Engineering and Characterization for Battery Applications is designed to help solve fundamental and applied problems in the field of energy storage. Broken up into four separate sections, the book begins with a discussion of the fundamental electrochemical concepts in the field of energy storage. Other sections look at battery materials engineering such as cathodes, electrolytes, separators and anodes and review various battery characterization methods and their applications. The book concludes with a review of the practical considerations and applications of batteries.This will be a valuable reference source for university professors, researchers, undergraduate and postgraduate students, as well as scientists working primarily in the field of materials science, applied chemistry, applied physics and nanotechnology. Presents practical consideration for battery usage such as LCA, recycling and green batteries Covers battery characterization techniques including electrochemical methods, microscopy, spectroscopy and X-ray methods Explores battery models and computational materials design theories

Synthesis, Characterization, and Applications of Chromium Manganese Oxides as Cathode Materials in Lithium-ion Batteries

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Publisher :
ISBN 13 :
Total Pages : 108 pages
Book Rating : 4.:/5 (481 download)

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Book Synopsis Synthesis, Characterization, and Applications of Chromium Manganese Oxides as Cathode Materials in Lithium-ion Batteries by : Kinson Chihang Kam

Download or read book Synthesis, Characterization, and Applications of Chromium Manganese Oxides as Cathode Materials in Lithium-ion Batteries written by Kinson Chihang Kam and published by . This book was released on 2001 with total page 108 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Rechargeable Organic Batteries

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Publisher : John Wiley & Sons
ISBN 13 : 3527839127
Total Pages : 309 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Rechargeable Organic Batteries by : Yongzhu Fu

Download or read book Rechargeable Organic Batteries written by Yongzhu Fu and published by John Wiley & Sons. This book was released on 2024-03-14 with total page 309 pages. Available in PDF, EPUB and Kindle. Book excerpt: A must-have reference on sustainable organic energy storage systems Organic electrode materials have the potential to overcome the intrinsic limitations of transition metal oxides as cathodes in rechargeable batteries. As promising alternatives to metal-based batteries, organic batteries are renewable, low-cost, and would enable a greener rechargeable world. Rechargeable Organic Batteries is an up-to-date reference and guide to the next generation of sustainable organic electrodes. Focused exclusively on organic electrode materials for rechargeable batteries, this unique volume provides comprehensive coverage of the structures, advantages, properties, reaction mechanisms, and performance of various types of organic cathodes. In-depth chapters examine carbonyl-, organosulfur-, radical-, and organometallic complexes, as well as polymer-based active materials for electrochemical energy storage (EES) technologies. Throughout the book, possible application cases and potential challenges are discussed in detail. Presents advanced characterization methods for verifying redox mechanisms of organic materials Examines recent advances in carbonyl-based small-molecule cathode materials in battery systems including lithium-ion, sodium-ion, and aqueous zinc-ion batteries Introduces organosulfide-inorganic composite cathodes with high electrical conductivity and fast reaction kinetics Outlines research progress on radical electrode materials, polymer-based organic cathode materials, and the development of all-organic batteries Summarizes the synthesis processes, redox mechanisms, and electrochemical performance of different kinds of organic anode materials for metal-ion batteries Featuring a general introduction to organic batteries, including a discussion of their necessity and advantages, Rechargeable Organic Batteries is essential reading for electrochemists, materials scientists, organic chemists, physical chemists, and solid-state chemists working in the field.

Synthesis and Electrochemical Characterization of Novel Electroactive Materials for Lithium-ion Batteries

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Publisher :
ISBN 13 :
Total Pages : 254 pages
Book Rating : 4.:/5 (112 download)

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Book Synopsis Synthesis and Electrochemical Characterization of Novel Electroactive Materials for Lithium-ion Batteries by : Karl Joseph Kreder (III)

Download or read book Synthesis and Electrochemical Characterization of Novel Electroactive Materials for Lithium-ion Batteries written by Karl Joseph Kreder (III) and published by . This book was released on 2017 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lithium-ion batteries (LIBs) have become ubiquitous as energy storage devices for mobile electronics, electric vehicles, and are beginning to be used for electric grid-scale energy storage. Lithium-ion batteries offer higher efficiencies, energy density, and longer life compared to incumbent technologies such as lead-acid and nickel metal hydride. Applications in which LIBs are used are continuing to demand better performing batteries at lower cost, which requires improvement in electroactive materials. This dissertation investigates the low temperature synthesis and modification of LiCoPO4 as a potential high-voltage and therefore higher energy density polyanion cathode material for LIBs, as well as a new class of interdigitated metal foil anodes which promises to be an inexpensive, higher energy density, alternative to graphite. Chapter 1 is a brief introduction to lithium-ion batteries and the principle of operation of intercalation type electrochemical energy storage devices. The components of lithium ion batteries are introduced, specifically the anode, cathode, separator, and electrolyte. Some of the shortfalls of the current technologies are discussed and areas of research interest are highlighted. Chapter 2 is a brief overview of the various experimental methods that are generally applicable to more than one of the subsequent chapters. Methods which are specific to a given study are discussed in their respective chapters. Chapter 3 presents work on the low temperature microwave-assisted solovthermal synthesis (MW-ST) of three unique polymorphs of LiCoPO4, specifically the polymorphs belonging to the Pnma, Cmcm, and Pn21a space groups. Prior to this work, only the Pnma polymorph had been reported via MW-ST method, and electrochemistry had not yet been reported for either the Pn21a or Cmcm polymorph. The dependence of the polymorphs on both the water content, and ammonium hydroxide content of the solvent was shown. Although, the electrochemistry of both the Pn21a and Cmcm polymorphs was found to be inferior to the Pnma polymorph, the ability to synthesize phase pure materials was crucial to conducting the work presented in chapters 4 and 5. Chapter 4 presents the aliovalent substitution of V3+ for Co2+ in LiCoPO4 via a low-temperature MW-ST process. Substitution of up to 7% vanadium for cobalt was demonstrated and verified by changes in the lattice parameters with vanadium content. Both the ionic and electronic conductivity of LiCoPO4 was enhanced with increasing vanadium substitution, which was attributed to the introduction of both charge carriers as well as inter-tunnel cobalt vacancies. Finally, the first cycle capacity was enhanced (from 69 mAh/g to 115 mAh/g) as well as the capacity retention over cycling. Chapter 5 demonstrates a novel technique of MW-ST assisted coating of a thin (2-5nm) conformal coating of LiFePO4 on vanadium substituted LiCoPO4. Although the vanadium substitution was able to independently increase the performance of LiCoPO4, the materials still suffers from severe side reactions with the electrolyte. The coating of LiFePO4 effectively raises the Fermi energy of the cathode material above the high occupied molecular orbital (HOMO) of the electrolyte preventing side reactions and increase the coulombic efficiency to nearly 100%. Chapter 6 introduces a novel method of producing high surface area, electrically conductive, metal nanofoams via a MW-ST process. Nickel, copper, and silver metal nanofoams are made via an inexpensive yet scalable process whereby metal acetates are reduced by polyglycol under microwave irradiation. The nanofoams were characterized via BET, SEM, XRD, EDS, and TEM. The nanofoams have potential uses in many clean energy applications, particularly lithium-ion batteries. Chapter 7 introduces a new framework for making a new class of high capacity, low-cost alloying anodes for lithium ion batteries. A novel interdigitated metal foil anode (IMFA) in which a nanosized active material, such as tin, is interdigitated with an electrically conductive matrix, such as aluminum, is presented. The foils are formed by the rolling of a eutectic Al-Sn alloy into a foil, which is an extremely cheap and scalable process. The anodes demonstrate an approximately 70% increase in capacity compared to graphite over 100 cycles, at reasonably fast rates (C/5), and high coulombic efficiency (>99%). Finally, Chapter 8 gives a brief overview of the results of the prior work and proposes areas for future research