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Synthesis Characterisation And Reactions Of Neutral And Cationic Complexes Of Molybdenum Ii And Tungsten Ii
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Book Synopsis Novel Strategies for the Synthesis of Tungsten(VI) and Molybdenum(VI) Imido/Oxo Alkylidene NHC Complexes and Their Application in Ring-Opening Metathesis Polymerization by : Janis Musso
Download or read book Novel Strategies for the Synthesis of Tungsten(VI) and Molybdenum(VI) Imido/Oxo Alkylidene NHC Complexes and Their Application in Ring-Opening Metathesis Polymerization written by Janis Musso and published by Cuvillier Verlag. This book was released on 2022-05-12 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recently, the synthesis of neutral and cationic group(VI) imido/oxo alkylidene N-heterocyclic carbene (NHC) complexes that tolerate protic functional groups and aldehydes was reported. Unprecedented turnover numbers of up to 1.2 million were found for their silica-supported representatives. Some group(VI) alkylidene NHC complexes even display stability towards moisture and air. Coordination of the NHC to tungsten imido bistriflate precursor complexes, however, can lead to undesired side reactions. This work consequently aimed at the development of novel, more efficient routes to neutral and cationic tungsten imido/oxo alkylidene NHC complexes. In addition, some molybdenum imido alkylidene NHC complexes were targeted. Thereby, the scope of synthetically accessible complexes was broadened and, subsequently, their reactivity in ring-opening metathesis polymerization (ROMP) was probed. Those complexes were used as thermally latent initiators for the ROMP of dicyclopentadiene. Precise determination of the onset temperature of polymerization was achieved via monitoring with differential scanning calorimetry. Furthermore, the selectivity of novel complexes was tested for the formation of stereoregular polymers through ROMP of enantiomerically pure norbornene derivatives, which allowed for the synthesis of up to 98% trans-isotactic or cis-syndiotactic polymers depending on the steric demand of the imido and the alkoxide ligand.
Book Synopsis British National Bibliography for Report Literature by :
Download or read book British National Bibliography for Report Literature written by and published by . This book was released on 2000 with total page 714 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Journal of Chemical Sciences written by and published by . This book was released on 2000 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Comprehensive Organometallic Chemistry II by : Edward W. Abel
Download or read book Comprehensive Organometallic Chemistry II written by Edward W. Abel and published by Elsevier. This book was released on 1995 with total page 650 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Dissertation Abstracts International by :
Download or read book Dissertation Abstracts International written by and published by . This book was released on 2008 with total page 906 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Comprehensive Dissertation Index by :
Download or read book Comprehensive Dissertation Index written by and published by . This book was released on 1989 with total page 712 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Comprehensive Organometallic Chemistry III, Volume 5 by : D. M. P. Mingos
Download or read book Comprehensive Organometallic Chemistry III, Volume 5 written by D. M. P. Mingos and published by . This book was released on 2007 with total page 1008 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides essential information for any chemist or technologist who needs to use or apply organometallic compounds. Provides a comprehensive overview of recent developments in the field and attempts to predict trends in the field over the next ten years.
Book Synopsis American Doctoral Dissertations by :
Download or read book American Doctoral Dissertations written by and published by . This book was released on 2002 with total page 776 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Mass Spectrometry Bulletin written by and published by . This book was released on 1992 with total page 924 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chemical Abstracts written by and published by . This book was released on 1991 with total page 2470 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Journal of the Chemical Society by :
Download or read book Journal of the Chemical Society written by and published by . This book was released on 1989 with total page 692 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis CSIR Publications by : South African Council for Scientific and Industrial Research
Download or read book CSIR Publications written by South African Council for Scientific and Industrial Research and published by . This book was released on 1979 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 42 by : Francois Mathey
Download or read book Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 42 written by Francois Mathey and published by Thieme. This book was released on 2014-05-14 with total page 2006 pages. Available in PDF, EPUB and Kindle. Book excerpt: Science of Synthesis: Houben-Weyl Methods of Molecular Transformations is the entirely new edition of the acclaimed reference series, Houben-Weyl, the standard synthetic chemistry resource since 1909. This new edition is published in English and will comprise 48 volumes published between the years 2000 and 2008. Science of Synthesis is a quality reference work developed by a highly esteemed editorial board to provide a comprehensive and critical selection of reliable organic and organometallic synthetic methods. This unique resource is designed to be the first point of reference when searching for a synthesis strategy. Contains the expertise of presently 400 leading chemists worldwide Critically evaluates the preparative applicability and significance of the synthetic methods Discusses relevant background information and provides detailed experimental procedures For full information on the Science of Synthesis series, visit the Science of Synthesis Homepage.
Book Synopsis Bulletin of the Chemical Society of Japan by : Nihon Kagakkai
Download or read book Bulletin of the Chemical Society of Japan written by Nihon Kagakkai and published by . This book was released on 1997 with total page 1322 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Canadian Journal of Chemistry written by and published by . This book was released on 2005 with total page 1220 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Comprehensive Organometallic Chemistry by : Geoffrey Wilkinson
Download or read book Comprehensive Organometallic Chemistry written by Geoffrey Wilkinson and published by . This book was released on 1982 with total page 1408 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Summaries of FY ... Research in the Chemical Sciences by :
Download or read book Summaries of FY ... Research in the Chemical Sciences written by and published by . This book was released on 1992 with total page 518 pages. Available in PDF, EPUB and Kindle. Book excerpt:
