Olefin Metathesis and Polymerization Catalysts

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Publisher : Springer Science & Business Media
ISBN 13 : 940113328X
Total Pages : 567 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Olefin Metathesis and Polymerization Catalysts by : Yavuz Imamogammalu

Download or read book Olefin Metathesis and Polymerization Catalysts written by Yavuz Imamogammalu and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 567 pages. Available in PDF, EPUB and Kindle. Book excerpt: Olefin metathesis reaction can be considered as one of the most successful organic reactions with many applications in the low molecular weight range and also in the polymer field. The use of catalysts with their selective and effective transformation properties in olefin metathesis I polymerization systems is a growing interest. There has been great effort and competition in developing active and commercially useful catalysts. The main aim of this ASI was to gather several research groups and also the people from industry. to present existing knowledge and latest results in the field. A wide range of topics through homogeneous and heterogeneous aspects have been considered. Attention has been drawn to the metal-carbene and metallacyclobutane complexes as active species, the initiation mechanisms, the stereochemistry and thermodynamics of these reactions. New catalytic systems for the metathesis of alkenes and alkynes and fot' ring opening polymeriZation I block copolymerization reactions have been introduced. Spectroscopic studies for the characteriZation of catalysts, simulation studies explaining the function of chain carrier species and polymer degradation have also been covered. A detailed industrial report concerning the patents and applications in olefin metathesis I cyc1001efin polymerization area, fabrication and derivation has been presented. This volume contains the main lectures and seminars given at the NATO Advanced Study Institute on " Olefin Metathesis and Polymerization Catalysts: Synthesis, Mechanism and Utilization", held at Akcay. Babkesir. Turkey between 10th and 22nd September 1989.

Metathesis Chemistry

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Publisher : Springer Science & Business Media
ISBN 13 : 1402060904
Total Pages : 506 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Metathesis Chemistry by : Yavuz Imamoglu

Download or read book Metathesis Chemistry written by Yavuz Imamoglu and published by Springer Science & Business Media. This book was released on 2007-07-04 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt: Discover why olefin metathesis has asserted itself as a powerful strategy for obtaining fine chemicals, biologically active compounds, architecturally complex assemblies, new materials, and functionalized polymers. This volume compiles all the latest trends in olefin metathesis. In particular, you’ll learn how olefin metathesis has growing potential for the development of sustainable technologies with many possible industrial applications.

Rhenium, Molybdenum and Tungsten Organometallic Homogeneous Catalysts. Synthesis, Characterisation and Application in Olefin Epoxidation

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (696 download)

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Book Synopsis Rhenium, Molybdenum and Tungsten Organometallic Homogeneous Catalysts. Synthesis, Characterisation and Application in Olefin Epoxidation by :

Download or read book Rhenium, Molybdenum and Tungsten Organometallic Homogeneous Catalysts. Synthesis, Characterisation and Application in Olefin Epoxidation written by and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The present manuscript deals with the synthesis and catalytic applications of organometallic transition metal compounds. First, the manuscript describes the synthesis and characterization of Schiff base adducts of methyltrioxorhenium (VII) and its application in olefin epoxidation catalysis with H2O2 as the oxidant. Second, the mechanistic features of the epoxidation reaction with cyclopentadienyl molybdenum alkyl complexes are described. Finally, a new family of highly stable cyclopentadienyl molybdenum and tungsten ansa complexes with cycloalkyl units as bridging moieties is reported. The remarkable epoxidation capabilities at moderate temperatures of these novel complexes are studied as well as being compared with those of previously synthesised related compounds.