Integrated Forest Biorefineries

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Publisher : Royal Society of Chemistry
ISBN 13 : 1849735069
Total Pages : 323 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Integrated Forest Biorefineries by : Lew Christopher

Download or read book Integrated Forest Biorefineries written by Lew Christopher and published by Royal Society of Chemistry. This book was released on 2012-09-30 with total page 323 pages. Available in PDF, EPUB and Kindle. Book excerpt: This reference book describes how bioprocessing and biotechnology could enhance the value extracted from wood-based lignocellulosic fiber by employing both biochemical and thermochemical conversion processes. It documents recent accomplishments and suggests future prospects for research and development of integrated forest biorefineries (IFBR) as the path forward for the pulp, paper and other fiber-processing industries. This is the only book to cover this area of high economic, social, and environmental importance. It is aimed at industrialists and academics from diverse science and engineering backgrounds including chemical and biotechnology companies, governmental and professional bodies, and scholarly societies. The Editor and contributors are internationally recognized scientists and many are leaders in their respective fields. The book starts with an introductory overview of the current state of biorefining and a justification for future developments. The next four chapters deal with social, economic and environmental issues related to regulations, biomass production and supply, process modelling, and life cycle analysis. Subsequent chapters focus on the extraction of biochemicals from biomass and their potential utilization to add value to the IFBR prior to pulping. The book then presents, compares and evaluates two types of forest biorefineries based on kraft and organosolv pulping. Finally, the book assess the potential of waste biomass and streams, such paper mill sludge and black liquor, to serve as feedstock for biofuel production and value-added biomaterials through both the biochemical and thermochemical routes of biomass bioprocessing. The economics of the described IFBR processes and products, and their environmental impact, is a major focus in most of the chapters. Practical examples are presented where relevant and applicable.

The London Underground and the public-private partnership agreements

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Author :
Publisher : The Stationery Office
ISBN 13 : 9780215038319
Total Pages : 134 pages
Book Rating : 4.0/5 (383 download)

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Book Synopsis The London Underground and the public-private partnership agreements by : Great Britain: Parliament: House of Commons: Transport Committee

Download or read book The London Underground and the public-private partnership agreements written by Great Britain: Parliament: House of Commons: Transport Committee and published by The Stationery Office. This book was released on 2008-01-25 with total page 134 pages. Available in PDF, EPUB and Kindle. Book excerpt: This report from the Transport Committee, examines London Underground and the Public-Private Partnership Agreements. The Government originally announced proposals for modernising the London Underground network system via Public-Private Partnership (PPP) agreements in 1998. Three contracts were drawn up with: (i) Tube Lines for the maintenance and renewal of the Jubilee, Piccadilly and Northern Lines; (ii) with Metronet Rail BVC for the maintenance and renewal of the Bakerloo, Central, Victoria & Waterloo & City Lines; (iii) with Metronet Rail SSL, responsible for the maintenance and renewal of the "sub-surface lines": the Circle, District, Hammersmith & City, Metropolitan & East London Lines. These PPP Agreements, 30 years in duration, were arrangements to maintain, renew and upgrade parts of London Underground by private sector infrastructure companies (Infracos), whilst London Underground is responsible for services to customers. The PPP Agreements also set out a performance-related incentive and penalty scheme to remunerate the Infracos for the improvements they make to the network. In May 2007, Metronet admitted an overspend of £1 billion and was refused access to loan facilities by the banks. It then made a reference to the PPP Arbiter, which in turn triggered an Extraordinary Review (which occurs when extra costs are incurred above the level allowed for the bid). Metronet put in a bid for £551m but the PPP Arbiter provisionally concluded that a sum of £121m was appropriate. Metronet subsequently went into administration on 18 July 2007. The report sets out a number of conclusions and recommendations, including: contracts that were supposed to deliver 35 station upgrades, in fact delivered only 14, 40% of the requirement; stations that were supposed to cost Metronet SSL £2m, cost £7.5m, with only 65% of schedule track renewal accomplished; the Committee criticises the consequences of the imposition of PPP on Transport for London, as a "lamentable state of affairs", with the future of most of London Underground's upgrade and maintenance work in doubt; the Committee states, that the Government should remember the failure of Metronet before it considers entering similar arrangements; that the Government should publish a candid analysis of the events preceding Metronet's collapse and its consequences; the Committee believe that the PPP model was flawed and probably inferior to traditional public-sector management; that the Government needs to prioritise transparency and clarity to taxpayers and ensure that any future contracts result in clear accountability.

Scientific Canadian Mechanics' Magazine and Patent Office Record

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Author :
Publisher :
ISBN 13 :
Total Pages : 1070 pages
Book Rating : 4.E/5 ( download)

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Book Synopsis Scientific Canadian Mechanics' Magazine and Patent Office Record by : Canada. Patent Office

Download or read book Scientific Canadian Mechanics' Magazine and Patent Office Record written by Canada. Patent Office and published by . This book was released on 1966-03 with total page 1070 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Metal-Support and Metal-Additive Effects in Catalysis

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Publisher : Elsevier
ISBN 13 : 0080954367
Total Pages : 397 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Metal-Support and Metal-Additive Effects in Catalysis by : B. Imelik

Download or read book Metal-Support and Metal-Additive Effects in Catalysis written by B. Imelik and published by Elsevier. This book was released on 2000-04-01 with total page 397 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Support and Metal-Additive Effects in Catalysis, Volume 11, documents the proceedings of an international symposium organized by the Institut de Recherches sur la Catalyse - CNRS – Villeurbanne and sponsored by the Centre National de la Recherche Scientifique, Ecully (Lyon), September 14-16, 1982. This volume contains 40 manuscripts that cover a wide range of topics. Among these are studies of metal-support interactions involving Pt/Al2O3, Pt/TiO2,Fe/TiO2, Pt/MgO, Rh /Al2O3, and Pt/CeO2 catalysts. There are also separate chapters dealing with ethane, n-butane, and cyclohexane hydrogenolysis; skeletal isomerization of methylpentanes; the catalytic activity and selectivity of noble metals; CO hydrogenation over supported on SiO2, Al2O3, Ti O2,and Zr O2 nickel catalysts; and the role of promoters in Pd catalysts for methanol synthesis. Subsequent chapters cover the poisoning of platinum and nickel by sulfur; C6H6 and CO chemisorption on Pt78Ni22 (111) single crystal alloy; the surface composition of industrial ammonia synthesis catalysts; and the role of alkalis and electronegative promoters on Fe and Ni catalysts.

Methanol Synthesis Technology

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Author :
Publisher : CRC Press
ISBN 13 : 9780849346101
Total Pages : 254 pages
Book Rating : 4.3/5 (461 download)

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Book Synopsis Methanol Synthesis Technology by : Sunggyu Lee

Download or read book Methanol Synthesis Technology written by Sunggyu Lee and published by CRC Press. This book was released on 1989-12-04 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt: This easy-to-read work is a comprehensive review which focuses primarily on catalytic methanol synthesis. It includes a historic summary of the development of methanol synthesis technology, as well as extensive discussions on statistical experimental design, fabrication and operation of laboratory scale systems. This unique volume also discusses various new catalysts and processes, with special attention to the thermodynamics of methanol synthesis-especially in relation to the new liquid phase process. The comprehensive and practical approach to chemical and synfuel process development makes it an excellent reference in methanol synthesis, reactor design, and scale-up. Written as a practical guide to researchers who are involved in hands-on process research, this book is also a valuable asset to practicing chemical engineers and graduate students interested in reaction engineering, thermodynamics, catalyst development and process design.

Transformation of Carbon Dioxide to Formic Acid and Methanol

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Author :
Publisher : Springer
ISBN 13 : 9811032505
Total Pages : 128 pages
Book Rating : 4.8/5 (11 download)

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Book Synopsis Transformation of Carbon Dioxide to Formic Acid and Methanol by : Wan-Hui Wang

Download or read book Transformation of Carbon Dioxide to Formic Acid and Methanol written by Wan-Hui Wang and published by Springer. This book was released on 2017-10-26 with total page 128 pages. Available in PDF, EPUB and Kindle. Book excerpt: This brief explains the principles and fundamentals of carbon dioxide utilization and highlights the transformation to fuels and value-added chemicals such as formic acid and methanol. It is divided into six chapters, including an introduction to the basics of CO2 utilization and transformation of CO2 to formic acid and methanol with homogeneous and heterogeneous catalysts, respectively. The brief will appeal to a wide readership of academic and industrial researchers focusing on homogeneous and heterogeneous catalysis, organometallic chemistry, green chemistry, energy conversion and storage.

The Chemistry of the Catalyzed Hydrogenation of Carbon Monoxide

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Author :
Publisher : Springer Science & Business Media
ISBN 13 : 3642696627
Total Pages : 239 pages
Book Rating : 4.6/5 (426 download)

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Book Synopsis The Chemistry of the Catalyzed Hydrogenation of Carbon Monoxide by : G. Henrici-Olive

Download or read book The Chemistry of the Catalyzed Hydrogenation of Carbon Monoxide written by G. Henrici-Olive and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 239 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the oil embargo, in the winter 1973174, parts of Western Europe present ed an almost war-like aspect on Saturdays and Sundays: no traffic on the high ways, no crowds at ski resorts and other weekend entertainment places, no gaso line at the pumps. Living and teaching then in that part of the world, and discussing the situa tion with our students, we came to the conclusion that it would be timely to col lect the fine chemistry already known at the time in the field of conversion of coal to gasoline and other chemicals, and by this way help to draw the attention to this important alternative to crude oil. The idea of this book was born. The energy shock of the early seventies has been healthy and of great conse quences in chemistry. Large amounts of research money have been put to work since, and our knowledge of the possibilities and limitations of coal-based chemistry has increased enormously. During several years it appeared inap propriate to write a monograph about a topic which was in the midst of such an impetuous development. Nevertheless, we collected, and critically selected, the upcoming work as it appeared in the literature, and also tried to provide some modest input ourselves. Now, ten years later, the situation seems to be settled to a certain degree.

Methanol and Carbonylation

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Author :
Publisher : Technip Editions
ISBN 13 : 9782710805298
Total Pages : 272 pages
Book Rating : 4.8/5 (52 download)

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Book Synopsis Methanol and Carbonylation by : Jean Gauthier-Lafaye

Download or read book Methanol and Carbonylation written by Jean Gauthier-Lafaye and published by Technip Editions. This book was released on 1987 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Chemicals from Synthesis Gas

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Publisher : Springer Science & Business Media
ISBN 13 : 9401710198
Total Pages : 234 pages
Book Rating : 4.4/5 (17 download)

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Book Synopsis Chemicals from Synthesis Gas by : R.A. Sheldon

Download or read book Chemicals from Synthesis Gas written by R.A. Sheldon and published by Springer Science & Business Media. This book was released on 2013-04-18 with total page 234 pages. Available in PDF, EPUB and Kindle. Book excerpt: The origins of the petrochemical industry can be traced back to the 1920s when simple organic chemicals such as ethanol and isopropanol were first prepared on an industrial scale from by-products (ethylene and propylene) of oil refining. This oil-based petrochemical industry, with lower olefms and aromatics as the key building blocks, rapidly developed into the enormous industry it is today. A multitude of products that are indispensible to modern day society, from plastics to pharmaceuticals, are derived from oil and natural gas-based hydro carbons. The industry had its heyday in the '50s and '60s when predictions of future growth rates tended to be exponential curves. However, two developments that took place in the early '70s disturbed this simplistic and optimistic view of the future. Firstly, the publication of the report for the Cub of Rome on the 'Limits to Growth' emphasized the finite nature of non-renewable fossil fuel resources. Secondly, the Oil Crisis of 1973 emphasized the vulnerability of an energy and chemicals industry that is based largely on a single raw material.

Direct Methane to Methanol

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Author :
Publisher : Elsevier
ISBN 13 : 0444632514
Total Pages : 321 pages
Book Rating : 4.4/5 (446 download)

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Book Synopsis Direct Methane to Methanol by : Vladimir Arutyunov

Download or read book Direct Methane to Methanol written by Vladimir Arutyunov and published by Elsevier. This book was released on 2014-01-30 with total page 321 pages. Available in PDF, EPUB and Kindle. Book excerpt: Direct Methane to Methanol: Foundations and Prospects of the Process offers a state-of-the-art account of one of the most interesting and potentially commercial technologies for direct conversion of natural gas into valuable chemicals. The book thoroughly explains the complex and unusual chemistry of the process, as well as possible applications for direct methane to methanol (DMTM). It covers topics involving thermokinetics, pressure, direct oxidation of heavier alkanes, and more, and provides detailed appendices with experimental data and product yields. This book provides all those who work in the field of gas processing and gas chemistry with the theory and experimental data to develop and apply new processes based on direct oxidation of natural gas. All those who deal with oil and natural gas production and processing will learn about this promising technology for the conversion of gas into more valuable chemicals. - Reviews more than 350 publications on high-pressure, low-temperature oxidation of methane and other gas phase hydrocarbons - Contains rare material available for the first time in English - Explains the reasons of previous failure and outlines the way forward for commercial development of the conversion technology - Presents a deep theoretical knowledge of this complex conversion process

Development of Catalysts to Produce Methanol from Coal Via Synthesis Gas

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Author :
Publisher :
ISBN 13 : 9780642867667
Total Pages : 169 pages
Book Rating : 4.8/5 (676 download)

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Book Synopsis Development of Catalysts to Produce Methanol from Coal Via Synthesis Gas by : M. S. Wainwright

Download or read book Development of Catalysts to Produce Methanol from Coal Via Synthesis Gas written by M. S. Wainwright and published by . This book was released on 1984 with total page 169 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Catalytic Synthesis of Alkene-Carbon Monoxide Copolymers and Cooligomers

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Publisher : Springer Science & Business Media
ISBN 13 : 1441992669
Total Pages : 330 pages
Book Rating : 4.4/5 (419 download)

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Book Synopsis Catalytic Synthesis of Alkene-Carbon Monoxide Copolymers and Cooligomers by : Ayusman Sen

Download or read book Catalytic Synthesis of Alkene-Carbon Monoxide Copolymers and Cooligomers written by Ayusman Sen and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt: 217 2. COPOLYMERIZATION OF PROPENE OR HIGHER I-ALKENES WITH 218 CARBON MONOXIDE 2. 1. Ligands and polymerization conditions 218 2. 2. Spiroketal formation 221 2. 3. Enantioselectivity 222 2. 4. Higher I-Alkenes 226 3. COPOLYMERIZATION OF STYRENE OR ITS DERIVATIVES WITH 226 CARBON MONOXIDE 4. COPOLYMERIZATION OF OTHER OLEANS WITH CARBON MONOXIDE 230 5. ASYMMETRIC TERPOLYMERIZATION OF MORE THAN Two KINDS OF 232 OLEFINS WITH CARBON MONOXIDE 6. POLYKETONE CONFORMATION 233 7. CONCLUSION 234 Chapter 8. Chain Propagation Mechanisms 237 Ayusman Sen 1. INTRODUCTION 237 2. PALLADIUM (II) BASED SYSTEMS 238 3. NICKEL (II) BASED SYSTEMS 256 4. RHODIUM (I) BASED SYSTEMS 257 5. CONCLUSION 261 Chapter 9. Theoretical Studies on Copolymerization of Polar Monomers 265 Peter Margl, Artur Michalak, and Tom Ziegler 1. INTRODUCTION 265 2. COPOLYMERIZATION OF CARBON MONOXIDE WITH ETHYLENE 267 2. 1. Experimental and calculated rates for the insertion processes for 267 copolymerization catalysed by Pd(II) systems. 2. 2. A more detailed look at the productive and unproductive cycles 270 in copolymerization catalysed by Pd(II) complexes. 2. 2. 1. The productive cycle 270 2. 2. 2. C2H4 misinsertion into an ethylene terminated polyketone 275 chain 2. 3. Experimental and calculated rates for the insertion processes for 277 alternating copolymerization catalyzed by Ni(II) systems 3. COPOLYMERIZATION OF OLEFINS WITH POLAR MONOMERS OTHER 280 THAN CO 3. 1. Preferred binding mode of oxygen containing monomers 282 3. 2. Preferred binding mode of nitrogen containing monomers 285 3. 3.

Industrial Applications of Homogeneous Catalysis

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Publisher : Springer Science & Business Media
ISBN 13 : 9400938977
Total Pages : 371 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Industrial Applications of Homogeneous Catalysis by : A. Mortreux

Download or read book Industrial Applications of Homogeneous Catalysis written by A. Mortreux and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 371 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysts are now widely used in both laboratory and industrial-scale chemistry. Indeed, it is hard to find any complex synthesis or industrial process that does not, at some stage, utilize a catalytic reaction. The development of homogeneous transition metal catalysts on the laboratory scale has demonstrated that these systems can be far superior to the equivalent heterogeneous systems, at least in terms of selectivity. is an increasing interest in this field of research from both an Thus, there academic and industrial point of view. In connection with the rapid developments in this area, four universities from the E.E.C (Aachen, FRG; Liege, Belgium; Milan, Italy; and Lille, France) have collaborated to organise a series of seminars for high-level students and researchers. These meetings have been sponsored by the Commission of the E.E.C and state organizations. The most recent of these meetings was held in Lille in September 1985 and this book contains updated and expanded presentations of most of the lectures given there. These lectures are concerned with the field of homogeneous transition metal catalysis and its application to the synthesis of organic intermediates and fine chemicals from an academic and industrial viewpoint. The continuing petroleum crisis which began in the early 1970s has given rise to the need to develop new feedstocks for the chemical industry.

Development of Catalysts to Produce Methanol from Coal Via Synthesis Gas

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Publisher :
ISBN 13 : 9780642082992
Total Pages : 52 pages
Book Rating : 4.0/5 (829 download)

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Book Synopsis Development of Catalysts to Produce Methanol from Coal Via Synthesis Gas by : M. S. Wainwright

Download or read book Development of Catalysts to Produce Methanol from Coal Via Synthesis Gas written by M. S. Wainwright and published by . This book was released on 1986 with total page 52 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Carbonylation

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Publisher : Springer Science & Business Media
ISBN 13 : 1475795769
Total Pages : 295 pages
Book Rating : 4.4/5 (757 download)

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Book Synopsis Carbonylation by : H.M. Colquhoun

Download or read book Carbonylation written by H.M. Colquhoun and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the publication of our earlier book on transition metal mediated organic synthesis, * there has been a widespread increase of interest in this topic, and transition metal based methodology has become firmly established in many areas of organic chemistry. The direct, catalytic formation of organic carbonyl compounds using carbon monoxide as the source of the carbonyl group has seen exceptional progress, and this carbonylation chemistry is being used increasingly in research and on a larger scale for fine chemicals production. In view of these developments, there is a need for a modem, practi cally oriented book dealing with transition metal based carbonylation chemistry. The present monograph should help fulfill this need, since it is intended specifically to foster the adoption of catalytic carbonylation as a general tool in synthetic organic chemistry. It deals exclusively with reactions involving the interconversion of carbon monoxide and organic carbonyl compounds, and although the majority of the reactions discussed involve catalytic formation of carbonyl compounds, potentially valuable syntheses requiring stoichiometric quantities of transition metal are also included. In addition, a chapter is devoted to the remarkably useful reverse transformation (decarbonylation), in which an organic carbonyl group is eliminated in the form of carbon monoxide.

Catalysis in the Refining of Fischer-Tropsch Syncrude

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Author :
Publisher : Royal Society of Chemistry
ISBN 13 : 1849732019
Total Pages : 295 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Catalysis in the Refining of Fischer-Tropsch Syncrude by : Arno de Klerk

Download or read book Catalysis in the Refining of Fischer-Tropsch Syncrude written by Arno de Klerk and published by Royal Society of Chemistry. This book was released on 2010-12-15 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fischer-Tropsch Synthesis (FTS) has been used on a commercial scale for more than eighty years. It was initially developed for strategic reasons because it offered a source of transportation fuels that was independent from crude oil. Unlike crude, Fischer-Tropsch synthetic crude is rich in olefins and oxygenates, while being sulphur and nitrogen free. Consequently, the catalysis involved in refining it is significantly different and only a few catalysts have been developed for the purpose. Until now, an account of this topic has been missing from the literature, despite mounting interest in the technology. This is the first book to provide a review and analysis of the literature (journal and patent) on the catalysis needed to refine syncrude to transportation fuels. It specifically highlights the impact of oxygenates and how oxygenates affect selectivity and deactivation. This aspect is also related to the refining of biomass derived liquids. Topics covered include: dimerisation / oligomerisation, isomerisation / hydroisomerisation, catalytic cracking / hydrocracking and hydrogenation, catalytic reforming, aromatic alkylation, etherification, dehydration, and some oxygenate and wax specific conversions.

Methane Conversion by Oxidative Processes

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Publisher : Springer Science & Business Media
ISBN 13 : 9401574499
Total Pages : 556 pages
Book Rating : 4.4/5 (15 download)

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Book Synopsis Methane Conversion by Oxidative Processes by : Wolf

Download or read book Methane Conversion by Oxidative Processes written by Wolf and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: A reasonable case could be made that the scientific interest in catalytic oxidation was the basis for the recognition of the phenomenon of catalysis. Davy, in his attempt in 1817 to understand the science associated with the safety lamp he had invented a few years earlier, undertook a series of studies that led him to make the observation that a jet of gas, primarily methane, would cause a platinum wire to continue to glow even though the flame was extinguished and there was no visible flame. Dobereiner reported in 1823 the results of a similar investigation and observed that spongy platina would cause the ignition of a stream of hydrogen in air. Based on this observation Dobereiner invented the first lighter. His lighter employed hydrogen (generated from zinc and sulfuric acid) which passed over finely divided platinum and which ignited the gas. Thousands of these lighters were used over a number of years. Dobereiner refused to file a patent for his lighter, commenting that "I love science more than money." Davy thought the action of platinum was the result of heat while Dobereiner believed the ~ffect ~as a manifestation of electricity. Faraday became interested in the subject and published a paper on it in 1834; he concluded that the cause for this reaction was similar to other reactions.