Syngas Generation from Hydrocarbons and Oxygenates with Structured Catalysts

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Publisher : Nova Science Publishers
ISBN 13 : 9781608763238
Total Pages : 0 pages
Book Rating : 4.7/5 (632 download)

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Book Synopsis Syngas Generation from Hydrocarbons and Oxygenates with Structured Catalysts by : Vladislav Sadykov

Download or read book Syngas Generation from Hydrocarbons and Oxygenates with Structured Catalysts written by Vladislav Sadykov and published by Nova Science Publishers. This book was released on 2012 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Syngas generation by oxidative or steam reforming of hydrocarbons and oxygenates now attracts a lot of attention of researchers in the fields of heterogeneous catalysis and chemical engineering due to its tremendous importance for energy generation and synfuels production. This book reviews results of the long-term research of the international team of scientists aimed at development of efficient processes of syngas generation in structured catalytic reactors. Multiscale integrated optimisation approach is applied throughout of this work including design of nanocomposite active components stable to coking and sintering; developing heat-conducting monolithic substrates comprised of refractory alloys and cermets (honeycomb and microchannel structures, gauzes etc) and procedures of their loading with active components; design and manufacturing of several types of pilot-scale reactors (with the radial or the axial flow direction) equipped with unique liquid fuel evaporation and mixing units and internal heat exchangers. Extended tests of these reactors fed by fuels from C1 to gasoline, mineral and sunflower oil have been carried out with a broad variation of experimental parameters including stability tests up to 1000 h. Performance analysis has been made with a due regard for equilibrium restrictions on the operational parameters. Transient behaviour of the monolith reactor during start-up (ignition) of the methane partial oxidation to synthesis gas was studied and analysed via mathematical modelling based upon detailed elementary step mechanism. This provides required bases for theoretical optimisation of the catalyst bed configuration and process parameters.

Natural Gas Conversion V

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Publisher : Elsevier
ISBN 13 : 0080537308
Total Pages : 1005 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Natural Gas Conversion V by : A. Parmaliana

Download or read book Natural Gas Conversion V written by A. Parmaliana and published by Elsevier. This book was released on 1998-09-17 with total page 1005 pages. Available in PDF, EPUB and Kindle. Book excerpt: On January 1988, the ascertained and economically accessible reserves of Natural Gas (NG) amounted to over 144,000 billion cubic meters worldwide, corresponding to 124 billion tons of oil equivalents (comparable with the liquid oil reserves, which are estimated to be 138 billion TOE). It is hypothesized that the volume of NG reserve will continue to grow at the same rate of the last decade. Forecasts on production indicate a potential increase from about 2,000 billion cubic meters in 1990 to not more than 3,300 billion cubic meters in 2010, even in a high economic development scenario. NG consumption represents only one half of oil: 1.9 billion TOE/y as compared to 3.5 of oil. Consequently, in the future gas will exceed oil as a carbon atom source. In the future the potential for getting energetic vectors or petrochemicals from NG will continue to grow.The topics covered in Natural Gas Conversion V reflect the large global R&D effort to look for new and economic ways of NG exploitation. These range from the direct conversion of methane and light paraffins to the indirect conversion through synthesis gas to fuels and chemicals. Particularly underlined and visible are the technologies already commercially viable.These proceedings prove that mature and technologically feasible processes for natural gas conversion are already available and that new and improved catalytic approaches are currently developing, the validity and feasibility of which will soon be documented. This is an exciting area of modern catalysis, which will certainly open novel and rewarding perspectives for the chemical, energy and petrochemical industries.

Catalysts for Syngas Production

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Publisher : MDPI
ISBN 13 : 3039365959
Total Pages : 184 pages
Book Rating : 4.0/5 (393 download)

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Book Synopsis Catalysts for Syngas Production by : Javier Ereña Loizaga

Download or read book Catalysts for Syngas Production written by Javier Ereña Loizaga and published by MDPI. This book was released on 2020-12-10 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Special Issue on “Catalysts for Syngas Production”, included in the Catalysts open access journal, shows new research about the development of catalysts and catalytic routes for syngas production, and the optimization of the reaction conditions for the process. This issue includes ten articles about the different innovative processes for syngas production. Synthesis gas (or syngas) is a mixture of hydrogen and carbon monoxide, with different chemical composition and H2/CO molar ratios, depending on the feedstock and production technology used. Syngas may be obtained from alternative sources to oil, such as natural gas, coal, biomass, organic wastes, etc. Syngas is a very good intermediate for the production of high value compounds at the industrial scale, such as hydrogen, methanol, liquid fuels, and a wide range of chemicals. Accordingly, efforts should be made on the co-feeding of CO2 with syngas, as an alternative for reducing greenhouse gas emissions. In addition, more syngas will be required in the near future, in order to satisfy the demand for synfuels and high value chemicals.

Rh-Based Catalysts for Syngas Conversion to Oxygenates

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Publisher : LAP Lambert Academic Publishing
ISBN 13 : 9783843358378
Total Pages : 132 pages
Book Rating : 4.3/5 (583 download)

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Book Synopsis Rh-Based Catalysts for Syngas Conversion to Oxygenates by : Manuel Ojeda

Download or read book Rh-Based Catalysts for Syngas Conversion to Oxygenates written by Manuel Ojeda and published by LAP Lambert Academic Publishing. This book was released on 2010-10 with total page 132 pages. Available in PDF, EPUB and Kindle. Book excerpt: The production of hydrocarbons by Fischer-Tropsch synthesis is an attractive option for obtaining liquid fuels from synthesis gas (H2 + CO). This process often employs Fe and/or Co catalysts. The use of rhodium catalysts is an attractive alternative because it allows obtaining higher oxygenates with 2 or more carbon atoms. These compounds posses a high added value, and among others, their use as additives in gasoline is of special interest. The main drawback of rhodium catalysts is the high price, and consequently, it is required to optimize the composition and pretreatment of the catalyst to obtain maximum yields to the desired products. In recent years, numerous studies have attempted to correlate the physicochemical properties of the catalyst (promoters, pretreatment, support, etc.) with its catalytic performance, although there are still certain aspects that remain controversial and need to be clarified. This publication focuses on Rh/Al2O3 catalysts for the production of higher oxygenates via CO hydrogenation. In particular, the effects of promoter addition of promoters, rhodium particle size, and pretreatment step, are discussed.

Concepts In Syngas Manufacture

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Publisher : World Scientific
ISBN 13 : 1908978007
Total Pages : 390 pages
Book Rating : 4.9/5 (89 download)

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Book Synopsis Concepts In Syngas Manufacture by : Jens Rostrup-nielsen

Download or read book Concepts In Syngas Manufacture written by Jens Rostrup-nielsen and published by World Scientific. This book was released on 2011-07-21 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a general overview of syngas technologies as well as an in-depth analysis of the steam reforming process. Syngas is a mixture of hydrogen and carbon oxides which can be made from hydrocarbons, coal and biomass. It is an important intermediate in the chemical industry for manufacture of ammonia, methanol and other petrochemicals as well as hydrogen for refineries and fuel cells. Syngas is playing a growing role in the energy sector, because it can be converted into a number of important energy carriers and fuels. Syngas catalysis creates new options and flexibility in the complex energy network. The steam reforming process is the main technology today for manufacture of syngas. It is a complex intern-mingling of catalysis and heat transfer with restrictions caused by secondary phenomena such as carbon formation. Many of the principles are applicable for other gasification technologies of growing importance. Concepts of Syngas Preparation aims to provide a comprehensive introduction to this complex field of growing importance and gives a detailed analysis of the catalyst and process problems. This book also serves as an important link between science and industry by illustrating how the basic principles can be applied to solve design issues and operational problems./a

Hydrogen and Syngas Production and Purification Technologies

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Publisher : John Wiley & Sons
ISBN 13 : 0471719757
Total Pages : 572 pages
Book Rating : 4.4/5 (717 download)

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Book Synopsis Hydrogen and Syngas Production and Purification Technologies by : Ke Liu

Download or read book Hydrogen and Syngas Production and Purification Technologies written by Ke Liu and published by John Wiley & Sons. This book was released on 2010-01-07 with total page 572 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covers the timely topic of fuel cells and hydrogen-based energy from its fundamentals to practical applications Serves as a resource for practicing researchers and as a text in graduate-level programs Tackles crucial aspects in light of the new directions in the energy industry, in particular how to integrate fuel processing into contemporary systems like nuclear and gas power plants Includes homework-style problems

Basic Principles in Applied Catalysis

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Publisher : Springer Science & Business Media
ISBN 13 : 3662059819
Total Pages : 540 pages
Book Rating : 4.6/5 (62 download)

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Book Synopsis Basic Principles in Applied Catalysis by : Manfred Baerns

Download or read book Basic Principles in Applied Catalysis written by Manfred Baerns and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by a team of internationally recognized experts, this book addresses the most important types of catalytic reactions and catalysts as used in industrial practice. Both applied aspects and the essential scientific principles are described. The main topics can be summarized as follows: heterogeneous, homogeneous and biocatalysis, catalyst preparation and characterization, catalytic reaction engineering and kinetics, catalyst deactivation and industrial perspective.

Advances in Synthesis Gas: Methods, Technologies and Applications

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Publisher : Elsevier
ISBN 13 : 0323985009
Total Pages : 598 pages
Book Rating : 4.3/5 (239 download)

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Book Synopsis Advances in Synthesis Gas: Methods, Technologies and Applications by : Mohammad Reza Rahimpour

Download or read book Advances in Synthesis Gas: Methods, Technologies and Applications written by Mohammad Reza Rahimpour and published by Elsevier. This book was released on 2022-10-18 with total page 598 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Synthesis Gas: Methods, Technologies and Applications: Syngas Production and Preparation is a collection of various chapters concerning many aspects of syngas production technologies, including common methods like gasification, steam/dry/autothermal reforming, membrane technology, etc., along with novel methods like plasma technology, micro-reactors, electrolysis processes as well as photocatalytic systems. In addition, different sources for producing syngas, including oil, crude oil, heavy oil, microalgae, black liquor, tar and bitumen, as well as municipal, agricultural, food, plastic, wood and cardboard wastes are described in detail. - Introduces syngas characteristics and its properties - Describes various methods and technologies for producing syngas - Discusses syngas production from different roots and feedstocks

Small-Scale Gas to Liquid Fuel Synthesis

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Publisher : CRC Press
ISBN 13 : 1466599391
Total Pages : 580 pages
Book Rating : 4.4/5 (665 download)

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Book Synopsis Small-Scale Gas to Liquid Fuel Synthesis by : Nick Kanellopoulos

Download or read book Small-Scale Gas to Liquid Fuel Synthesis written by Nick Kanellopoulos and published by CRC Press. This book was released on 2015-02-23 with total page 580 pages. Available in PDF, EPUB and Kindle. Book excerpt: It is estimated that a large fraction of natural gas reserves are found in locations from where transport is not economical. If these isolated natural gas reserves could be converted to synthetic fuels, they would generate around 250 billion barrels of synthetic oil-a quantity equal to one-third of the Middle East's proven oil reserves. Small-Scale

Oxyfuel Combustion for Clean Energy Applications

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Publisher : Springer
ISBN 13 : 3030105881
Total Pages : 378 pages
Book Rating : 4.0/5 (31 download)

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Book Synopsis Oxyfuel Combustion for Clean Energy Applications by : Medhat A. Nemitallah

Download or read book Oxyfuel Combustion for Clean Energy Applications written by Medhat A. Nemitallah and published by Springer. This book was released on 2019-02-11 with total page 378 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book aims to be the reference book in the area of oxyfuel combustion, covering the fundamentals, design considerations and current challenges in the field. Its first part provides an overview of the greenhouse gas emission problem and the current carbon capture and sequestration technologies. The second part introduces oxy-fuel combustion technologies with emphasis on system efficiency, combustion and emission characteristics, applications and related challenges. The third part focuses on the recent developments in ion transport membranes and their performance in both oxygen separation units and oxygen transport reactors (OTRs). The fourth part presents novel approaches for clean combustion in gas turbines and boilers. Computational modelling and optimization of combustion in gas turbine combustors and boiler furnaces are presented in the fifth part with some numerical results and detailed analyses.

Fischer-Tropsch Technology

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Publisher : Elsevier
ISBN 13 : 0080472796
Total Pages : 722 pages
Book Rating : 4.0/5 (84 download)

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Book Synopsis Fischer-Tropsch Technology by : André Steynberg

Download or read book Fischer-Tropsch Technology written by André Steynberg and published by Elsevier. This book was released on 2004-10-30 with total page 722 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fischer-Tropsch Technology is a unique book for its state-of-the-art approach to Fischer Tropsch (FT) technology. This book provides an explanation of the basic principles and terminology that are required to understand the application of FT technology. It also contains comprehensive references to patents and previous publications. As the first publication to focus on theory and application, it is a contemporary reference source for students studying chemistry and chemical engineering. Researchers and engineers active in the development of FT technology will also find this book an invaluable source of information. * Is the first publication to cover the theory and application for modern Fischer Tropsch technology * Contains comprehensive knowledge on all aspects relevant to the application of Fischer Tropsch technology* No other publication looks at past, present and future applications

Structured Catalysts and Reactors

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Publisher : CRC Press
ISBN 13 : 1420028006
Total Pages : 828 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Structured Catalysts and Reactors by : Andrzej Cybulski

Download or read book Structured Catalysts and Reactors written by Andrzej Cybulski and published by CRC Press. This book was released on 2005-11-02 with total page 828 pages. Available in PDF, EPUB and Kindle. Book excerpt: Interest in structured catalysts is steadily increasing due to the already proven, as well as potential, advantages of these catalysts. Updating the comprehensive coverage of the first edition published in 1998 with the latest science and applications, Structured Catalysts and Reactors, Second Edition gives detailed information on all aspect

Catalysis

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Publisher : Royal Society of Chemistry
ISBN 13 : 1788014545
Total Pages : 376 pages
Book Rating : 4.7/5 (88 download)

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Book Synopsis Catalysis by : James Spivey

Download or read book Catalysis written by James Spivey and published by Royal Society of Chemistry. This book was released on 2019-03-15 with total page 376 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysts are required for a variety of applications and researchers are increasingly challenged to find cost effective and environmentally benign catalysts to use. This volume looks at modern approaches to catalysis and reviews the extensive literature including direct methane conversion, nanocomposite catalysts for transformation of biofuels into syngas and hydrogen, and catalytic wet air oxidation technology for industrial wastewater treatment. Appealing broadly to researchers in academia and industry, it will be of great benefit to any researcher wanting a succinct reference on developments in this area now and looking to the future.

Advanced Nanomaterials for Catalysis and Energy

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Publisher : Elsevier
ISBN 13 : 012814808X
Total Pages : 590 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Advanced Nanomaterials for Catalysis and Energy by : Vladislav A. Sadykov

Download or read book Advanced Nanomaterials for Catalysis and Energy written by Vladislav A. Sadykov and published by Elsevier. This book was released on 2018-08-27 with total page 590 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advanced Nanomaterials for Catalysis and Energy: Synthesis, Characterization and Applications outlines new approaches to the synthesis of nanomaterials (synthesis in flow conditions, laser electrodispersion of single metals or alloys on carbon or oxide supports, mechanochemistry, sol-gel routes, etc.) to provide systems with a narrow particle size distribution, controlled metal-support interaction and nanocomposites with uniform spatial distribution of domains of different phases, even in dense sintered materials. Methods for characterization of real structure and surface properties of nanomaterials are discussed, including synchrotron radiation diffraction and X-ray photoelectron spectroscopy studies, neutronography, transmission/scanning electron microscopy with elemental analysis, and more. The book covers the effect of nanosystems' composition, bulk and surface properties, metal-support interaction, particle size and morphology, deposition density, etc. on their functional properties (transport features, catalytic activity and reaction mechanism). Finally, it includes examples of various developed nanostructured solid electrolytes and mixed ionic-electronic conductors as materials in solid oxide fuel cells and asymmetric supported membranes for oxygen and hydrogen separation. - Outlines synthetic and characterization methods for nanocatalysts - Relates nanocatalysts' properties to their specific applications - Proposes optimization methods aiming at specific applications

Plasma Catalysis

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Publisher : MDPI
ISBN 13 : 3038977500
Total Pages : 248 pages
Book Rating : 4.0/5 (389 download)

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Book Synopsis Plasma Catalysis by : Annemie Bogaerts

Download or read book Plasma Catalysis written by Annemie Bogaerts and published by MDPI. This book was released on 2019-04-02 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt: Plasma catalysis is gaining increasing interest for various gas conversion applications, such as CO2 conversion into value-added chemicals and fuels, N2 fixation for the synthesis of NH3 or NOx, methane conversion into higher hydrocarbons or oxygenates. It is also widely used for air pollution control (e.g., VOC remediation). Plasma catalysis allows thermodynamically difficult reactions to proceed at ambient pressure and temperature, due to activation of the gas molecules by energetic electrons created in the plasma. However, plasma is very reactive but not selective, and thus a catalyst is needed to improve the selectivity. In spite of the growing interest in plasma catalysis, the underlying mechanisms of the (possible) synergy between plasma and catalyst are not yet fully understood. Indeed, plasma catalysis is quite complicated, as the plasma will affect the catalyst and vice versa. Moreover, due to the reactive plasma environment, the most suitable catalysts will probably be different from thermal catalysts. More research is needed to better understand the plasma–catalyst interactions, in order to further improve the applications.

Advances in Nanocomposites

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Publisher : BoD – Books on Demand
ISBN 13 : 9533071656
Total Pages : 984 pages
Book Rating : 4.5/5 (33 download)

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Book Synopsis Advances in Nanocomposites by : Boreddy Reddy

Download or read book Advances in Nanocomposites written by Boreddy Reddy and published by BoD – Books on Demand. This book was released on 2011-04-19 with total page 984 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Nanocomposites - Synthesis, Characterization and Industrial Applications was conceived as a comprehensive reference volume on various aspects of functional nanocomposites for engineering technologies. The term functional nanocomposites signifies a wide area of polymer/material science and engineering, involving the design, synthesis and study of nanocomposites of increasing structural sophistication and complexity useful for a wide range of chemical, physicochemical and biological/biomedical processes. "Emerging technologies" are also broadly understood to include new technological developments, beginning at the forefront of conventional industrial practices and extending into anticipated and speculative industries of the future. The scope of the present book on nanocomposites and applications extends far beyond emerging technologies. This book presents 40 chapters organized in four parts systematically providing a wealth of new ideas in design, synthesis and study of sophisticated nanocomposite structures.

The Changing Landscape of Hydrocarbon Feedstocks for Chemical Production

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Author :
Publisher : National Academies Press
ISBN 13 : 0309444799
Total Pages : 137 pages
Book Rating : 4.3/5 (94 download)

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Book Synopsis The Changing Landscape of Hydrocarbon Feedstocks for Chemical Production by : National Academies of Sciences, Engineering, and Medicine

Download or read book The Changing Landscape of Hydrocarbon Feedstocks for Chemical Production written by National Academies of Sciences, Engineering, and Medicine and published by National Academies Press. This book was released on 2016-12-10 with total page 137 pages. Available in PDF, EPUB and Kindle. Book excerpt: A decade ago, the U.S. chemical industry was in decline. Of the more than 40 chemical manufacturing plants being built worldwide in the mid-2000s with more than $1 billion in capitalization, none were under construction in the United States. Today, as a result of abundant domestic supplies of affordable natural gas and natural gas liquids resulting from the dramatic rise in shale gas production, the U.S. chemical industry has gone from the world's highest-cost producer in 2005 to among the lowest-cost producers today. The low cost and increased supply of natural gas and natural gas liquids provides an opportunity to discover and develop new catalysts and processes to enable the direct conversion of natural gas and natural gas liquids into value-added chemicals with a lower carbon footprint. The economic implications of developing advanced technologies to utilize and process natural gas and natural gas liquids for chemical production could be significant, as commodity, intermediate, and fine chemicals represent a higher-economic-value use of shale gas compared with its use as a fuel. To better understand the opportunities for catalysis research in an era of shifting feedstocks for chemical production and to identify the gaps in the current research portfolio, the National Academies of Sciences, Engineering, and Medicine conducted an interactive, multidisciplinary workshop in March 2016. The goal of this workshop was to identify advances in catalysis that can enable the United States to fully realize the potential of the shale gas revolution for the U.S. chemical industry and, as a result, to help target the efforts of U.S. researchers and funding agencies on those areas of science and technology development that are most critical to achieving these advances. This publication summarizes the presentations and discussions from the workshop.