Symmetry In Inorganic And Coordination Compounds

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Symmetry in Inorganic and Coordination Compounds

Author : Franca Morazzoni
Publisher : Springer Nature
ISBN 13 : 3030629961
Total Pages : 196 pages
Book Rating : 4.0/5 (36 download)

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Book Synopsis Symmetry in Inorganic and Coordination Compounds by : Franca Morazzoni

Download or read book Symmetry in Inorganic and Coordination Compounds written by Franca Morazzoni and published by Springer Nature. This book was released on 2021-04-28 with total page 196 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book addresses the nature of the chemical bond in inorganic and coordination compounds. In particular, it explains how general symmetry rules can describe chemical bond of simple inorganic molecules. Since the complexity of studying even simple molecules requires approximate methods, this book introduces a quantum mechanical treatment taking into account the geometric peculiarities of the chemical compound. In the case of inorganic molecules, a convenient approximation comes from symmetry, which constrains both the electronic energies and the chemical bonds. The book also gives special emphasis on symmetry rules and compares the use of symmetry operators with that of Hamiltonian operators. Where possible, the reactivity of molecules is also rationalized in terms of these symmetry properties. As practical examples, electronic spectroscopy and magnetism give experimental confirmation of the predicted electronic energy levels. Adapted from university lecture course notes, this book is the ideal companion for any inorganic chemistry course dealing with group theory.

symmetry In Coordination Chemistry

Author : John P. Jr. Fackler
Publisher : Elsevier
ISBN 13 : 0323161006
Total Pages : 152 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis symmetry In Coordination Chemistry by : John P. Jr. Fackler

Download or read book symmetry In Coordination Chemistry written by John P. Jr. Fackler and published by Elsevier. This book was released on 2012-12-02 with total page 152 pages. Available in PDF, EPUB and Kindle. Book excerpt: Symmetry in Coordination Chemistry provides a comprehensive discussion of molecular symmetry. It attempts to bridge the gap between the elementary ideas of bonding and structure learned by freshmen, and those more sophisticated concepts used by the practicing chemist. The book emphasizes the use of symmetry in describing the bonding and structure of transition metal coordination compounds. The book begins with a review of basic concepts such as molecular symmetry, coordination numbers, symmetry classification, and point group symmetry. This is followed by separate chapters on the electronic, atomic, and magnetic properties of d-block transition elements; the representation of orbital symmetries in a manner consistent with the point group of a molecule. Also included are discussions of vibrational symmetry; crystal field theory, ligand field theory, and molecular orbital theory; and the chemistry of a select few d-block transition elements and their compounds. This book is meant to supplement the traditional course work of junior-senior inorganic students. It is for them that the problems and examples have been chosen.

Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part B

Author : Kazuo Nakamoto
Publisher : John Wiley & Sons
ISBN 13 : 9780470405871
Total Pages : 400 pages
Book Rating : 4.4/5 (58 download)

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Book Synopsis Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part B by : Kazuo Nakamoto

Download or read book Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part B written by Kazuo Nakamoto and published by John Wiley & Sons. This book was released on 2009-01-16 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: The 6th edition of this classic comprises the most comprehensive guide to infrared and Raman spectra of inorganic, organometallic, bioinorganic, and coordination compounds. From fundamental theories of vibrational spectroscopy to applications in a variety of compound types, it is extensively updated. Part B details applications of Raman and IR spectroscopy to larger and complex systems. It covers interactions of cisplatin and other metallodrugs with DNA and cytochrome c oxidase and peroxidase. This is a great reference for chemists and medical professionals working with infrared or Raman spectroscopies and for graduate students.

Symmetry in Inorganic Chemistry

Author : Paul B. Dorain
Publisher :
ISBN 13 :
Total Pages : 140 pages
Book Rating : 4.:/5 (42 download)

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Book Synopsis Symmetry in Inorganic Chemistry by : Paul B. Dorain

Download or read book Symmetry in Inorganic Chemistry written by Paul B. Dorain and published by . This book was released on 1965 with total page 140 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Low-Frequency Vibrations of Inorganic and Coordination Compounds

Author : John R. Ferraro
Publisher : Springer Science & Business Media
ISBN 13 : 1468418092
Total Pages : 316 pages
Book Rating : 4.4/5 (684 download)

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Book Synopsis Low-Frequency Vibrations of Inorganic and Coordination Compounds by : John R. Ferraro

Download or read book Low-Frequency Vibrations of Inorganic and Coordination Compounds written by John R. Ferraro and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the course of far-infrared investigations of inorganic and coordina tion compounds at Argonne National Laboratory in the years 1962-1966, it became apparent that no suitable book existed which correlated and dis cussed the important vibrations occurring in this region for these molecules. Early in 1967 the initial steps were taken to write such a book. Then, in 1968, an excellent text by Professor David M. Adams entitled Metal-Ligand and Related Vibrations was published. At this point serious consideration was given to discontinuing work on this book. However, upon examination of Adams' book, it became clear that the references covered only the period to 1966. This field of research is accelerating so tremendously, and the period 1966-1969 has seen so many new studies, that upon reconsideration it was decided to continue writing this text. The references in this book, particularly in the last several chapters, include many papers published in 1969. However, the proliferation of the far-infrared literature has made it impossible to present all the published material that has any bearing on the subject. Many titles do not pertain primarily to the far-infrared region as such, and some of this research has been omitted for this reason. Organometallic compounds have been neglected since the author feels that adequate reviews of that subject are available. Other studies may be missing simply because, owing to space limitations, only the more important researches could be considered. Of course, "importance" may, in this case, reflect the author's interest and prejudices.

Making and Breaking Symmetry in Chemistry

Author : Michael J McGlinchey
Publisher : World Scientific Publishing Company
ISBN 13 : 9789811286698
Total Pages : 0 pages
Book Rating : 4.2/5 (866 download)

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Book Synopsis Making and Breaking Symmetry in Chemistry by : Michael J McGlinchey

Download or read book Making and Breaking Symmetry in Chemistry written by Michael J McGlinchey and published by World Scientific Publishing Company. This book was released on 2023-11 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The elucidation of reaction mechanisms generally requires the carefully designed control of molecular symmetry to distinguish between the many possible reaction pathways. Making and Breaking Symmetry in Chemistry emphasises the crucial role played by symmetry in modern synthetic chemistry. After discussion of a number of famous classical experiments, the advances brought about by the introduction of new techniques, in particular NMR spectroscopy, are exemplified in numerous cases taken from the recent literature. Experimental verification of many of the predictions made in Woodward and Hoffmann's explication of the Conservation of Orbital Symmetry are described. Applications that involve the breaking of molecular symmetry to resolve these and other mechanistic problems in organic, inorganic and organometallic chemistry are presented in the first sections of the book, together with many examples of the detection of hitherto hidden rearrangement processes. Subsequently, under the aegis of making molecular symmetry, examples of the preparation of highly symmetrical molecules found in the organic, organometallic or inorganic domains are discussed. These include Platonic hydrocarbons or boranes, tetrahedranes, cubanes, prismanes, dodecahedrane, fullerene fragments such as corannulene, sumanene or semibuckminsterfullerene, and other systems of unusual geometries or bonding characteristics (Möbius strips, molecular brakes and gears, Chauvin's carbomers, Fitjer's rotanes, persubstituted rings, metal-metal multiple bonds, etc.). The text also contains vignettes of many of the scientists who made these major advances, as well as short sections that briefly summarise key features of important topics that underpin the more descriptive material. These include some aspects of chirality, NMR spectroscopy, and the use of isotopic substitution to break molecular symmetry. A brief appendix on point group symmetry and nomenclature is also helpfully provided.

Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part A

Author : Kazuo Nakamoto
Publisher : John Wiley & Sons
ISBN 13 : 9780470405796
Total Pages : 350 pages
Book Rating : 4.4/5 (57 download)

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Book Synopsis Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part A by : Kazuo Nakamoto

Download or read book Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part A written by Kazuo Nakamoto and published by John Wiley & Sons. This book was released on 2008-12-22 with total page 350 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Sixth Edition of this classic work comprises the most comprehensive and current guide to infrared and Raman spectra of inorganic, organometallic, bioinorganic, and coordination compounds. From fundamental theories of vibrational spectroscopy to applications in a variety of compound types, this has been extensively updated. New topics include the theoretical calculations of vibrational frequencies (DFT method), chemical synthesis by matrix co-condensation reactions, time-resolved Raman spectroscopy, and more. This volume is a core reference for chemists and medical professionals working with infrared or Raman spectroscopies and an excellent textbook for graduate courses.

Coordination Chemistry

Author : Tomoaki Tanase
Publisher : Royal Society of Chemistry
ISBN 13 : 1837673268
Total Pages : 434 pages
Book Rating : 4.8/5 (376 download)

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Book Synopsis Coordination Chemistry by : Tomoaki Tanase

Download or read book Coordination Chemistry written by Tomoaki Tanase and published by Royal Society of Chemistry. This book was released on 2024-10-16 with total page 434 pages. Available in PDF, EPUB and Kindle. Book excerpt: New to coordination chemistry and looking for some straightforward resources? In this long-established field of science, developments have continued between disciplines. Thus, modern coordination chemistry is recognized as an interdisciplinary molecular science that has developed at the intersection of inorganic and organic chemistry. Translated from the original Japanese, this accessible book is for undergraduate and graduate students and young researchers new to coordination chemistry. It explores transition metal complexes involving d and f orbitals and is structured as a step-by-step guide. It starts with the basics, as the foundation of the topic, progressing in complexity to explain some of the recent interdisciplinary developments. Important analytical methods related to the contents are introduced for completeness. You need look no further for concise and easy-to-understand explanations of coordination chemistry.

Chemical Applications of Symmetry and Group Theory

Author : Rakshit Ameta
Publisher : CRC Press
ISBN 13 : 1771883995
Total Pages : 392 pages
Book Rating : 4.7/5 (718 download)

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Book Synopsis Chemical Applications of Symmetry and Group Theory by : Rakshit Ameta

Download or read book Chemical Applications of Symmetry and Group Theory written by Rakshit Ameta and published by CRC Press. This book was released on 2016-11-03 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: As the structure and behavior of molecules and crystals depend on their different symmetries, group theory becomes an essential tool in many important areas of chemistry. It is a quite powerful theoretical tool to predict many basic as well as some characteristic properties of molecules. Whereas quantum mechanics provide solutions of some chemical problems on the basis of complicated mathematics, group theory puts forward these solutions in a very simplified and fascinating manner. Group theory has been successfully applied to many chemical problems. Students and teachers of chemical sciences have an invisible fear from this subject due to the difficulty with the mathematical jugglery. An active sixth dimension is required to understand the concept as well as to apply it to solve the problems of chemistry. This book avoids mathematical complications and presents group theory so that it is accessible to students as well as faculty and researchers. Chemical Applications of Symmetry and Group Theory discusses different applications to chemical problems with suitable examples. The book develops the concept of symmetry and group theory, representation of group, its applications to I.R. and Raman spectroscopy, U.V spectroscopy, bonding theories like molecular orbital theory, ligand field theory, hybridization, and more. Figures are included so that reader can visualize the symmetry, symmetry elements, and operations.

A Textbook of Inorganic Chemistry – Volume 1

Author : Mandeep Dalal
Publisher : Dalal Institute
ISBN 13 : 8193872002
Total Pages : 482 pages
Book Rating : 4.1/5 (938 download)

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Book Synopsis A Textbook of Inorganic Chemistry – Volume 1 by : Mandeep Dalal

Download or read book A Textbook of Inorganic Chemistry – Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory; dπ -pπ bonds; Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions; Trends in stepwise constants; Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand; Chelate effect and its thermodynamic origin; Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes; Mechanisms for ligand replacement reactions; Formation of complexes from aquo ions; Ligand displacement reactions in octahedral complexes- acid hydrolysis, base hydrolysis; Racemization of tris chelate complexes; Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes; The trans effect; Theories of trans effect; Mechanism of electron transfer reactions – types; outer sphere electron transfer mechanism and inner sphere electron transfer mechanism; Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory; Molecular orbital theory: octahedral, tetrahedral or square planar complexes; π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals; Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states); Calculation of Dq, B and β parameters; Effect of distortion on the d-orbital energy levels; Structural evidence from electronic spectrum; John-Tellar effect; Spectrochemical and nephalauxetic series; Charge transfer spectra; Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry; Guoy’s method for determination of magnetic susceptibility; Calculation of magnetic moments; Magnetic properties of free ions; Orbital contribution, effect of ligand-field; Application of magneto-chemistry in structure determination; Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes; Wade’s rules; Carboranes; Metal carbonyl clusters - low nuclearity carbonyl clusters; Total electron count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls: structure and bonding; Vibrational spectra of metal carbonyls for bonding and structure elucidation; Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.

Symmetry (Group Theory) and Mathematical Treatment in Chemistry

Author : Takashiro Akitsu
Publisher : BoD – Books on Demand
ISBN 13 : 1789233143
Total Pages : 188 pages
Book Rating : 4.7/5 (892 download)

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Book Synopsis Symmetry (Group Theory) and Mathematical Treatment in Chemistry by : Takashiro Akitsu

Download or read book Symmetry (Group Theory) and Mathematical Treatment in Chemistry written by Takashiro Akitsu and published by BoD – Books on Demand. This book was released on 2018-07-18 with total page 188 pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of this book Symmetry (Group Theory) and Mathematical Treatment in Chemistry is to be a graduate school-level text about introducing recent research examples associated with symmetry (group theory) and mathematical treatment in inorganic or organic chemistry, physical chemistry or chemical physics, and theoretical chemistry. Chapters contained can be classified into mini-review, tutorial review, or original research chapters of mathematical treatment in chemistry with brief explanation of related mathematical theories. Keywords are symmetry, group theory, crystallography, solid state, topology, molecular structure, electronic state, quantum chemistry, theoretical chemistry, and DFT calculations.

Symmetry and Spectroscopy

Author : Daniel C. Harris
Publisher : Courier Corporation
ISBN 13 : 9780486661445
Total Pages : 588 pages
Book Rating : 4.6/5 (614 download)

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Book Synopsis Symmetry and Spectroscopy by : Daniel C. Harris

Download or read book Symmetry and Spectroscopy written by Daniel C. Harris and published by Courier Corporation. This book was released on 1989-01-01 with total page 588 pages. Available in PDF, EPUB and Kindle. Book excerpt: Informal, effective undergraduate-level text introduces vibrational and electronic spectroscopy, presenting applications of group theory to the interpretation of UV, visible, and infrared spectra without assuming a high level of background knowledge. 200 problems with solutions. Numerous illustrations. "A uniform and consistent treatment of the subject matter." — Journal of Chemical Education.

Symmetry and Structure

Author : Sidney F. A. Kettle
Publisher : John Wiley & Sons
ISBN 13 : 9780470516188
Total Pages : 436 pages
Book Rating : 4.5/5 (161 download)

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Book Synopsis Symmetry and Structure by : Sidney F. A. Kettle

Download or read book Symmetry and Structure written by Sidney F. A. Kettle and published by John Wiley & Sons. This book was released on 2008-03-11 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt: Building on the foundation of the Second Edition, Symmetry and Structure: Readable Group Theory for Chemists, Third Edition turns the complex and potentially difficult subject of group theory into an accessible and readable account of this core area of chemistry. By using a diagrammatical approach and demonstrating the physical principles involved in understanding group theory, the text provides a non-mathematical, yet thorough, treatment of this broad topic. This new edition has been fully revised and updated to include a much more three-dimensional and accurate visualization of many of the key topics. The chapter on octahedral molecules is extended to cover the important topic of the ligand field theory of octahedral transition metal complexes. Problems and summaries are included at the end of each chapter, the book provides detailed answers to frequently asked questions, and numerous diagrams and tables are featured for ease of reading and to enhance student understanding. Symmetry and Structure: Readable Group Theory for Chemists, Third Edition is an essential textbook for all students, researchers and lecturers in chemistry, biochemistry, chemical engineering, physics and material science.

Symmetry and Spectroscopy of Molecules

Author : K. Veera Reddy
Publisher : New Age International
ISBN 13 : 8122424511
Total Pages : 28 pages
Book Rating : 4.1/5 (224 download)

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Book Synopsis Symmetry and Spectroscopy of Molecules by : K. Veera Reddy

Download or read book Symmetry and Spectroscopy of Molecules written by K. Veera Reddy and published by New Age International. This book was released on 2007 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Symmetry through the Eyes of a Chemist

Author : Magdolna Hargittai
Publisher : Springer Science & Business Media
ISBN 13 : 1402056281
Total Pages : 528 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Symmetry through the Eyes of a Chemist by : Magdolna Hargittai

Download or read book Symmetry through the Eyes of a Chemist written by Magdolna Hargittai and published by Springer Science & Business Media. This book was released on 2009-02-28 with total page 528 pages. Available in PDF, EPUB and Kindle. Book excerpt: It is gratifying to launch the third edition of our book. Its coming to life testi?es about the task it has ful?lled in the service of the com- nity of chemical research and learning. As we noted in the Prefaces to the ?rst and second editions, our book surveys chemistry from the point of view of symmetry. We present many examples from ch- istry as well as from other ?elds to emphasize the unifying nature of the symmetry concept. Our aim has been to provide aesthetic pl- sure in addition to learning experience. In our ?rst Preface we paid tribute to two books in particular from which we learned a great deal; they have in?uenced signi?cantly our approach to the subject matter of our book. They are Weyl’s classic, Symmetry, and Shubnikov and Koptsik’s Symmetry in Science and Art. The structure of our book has not changed. Following the Int- duction (Chapter 1), Chapter 2 presents the simplest symmetries using chemical and non-chemical examples. Molecular geometry is discussed in Chapter 3. The next four chapters present gro- theoretical methods (Chapter 4) and, based on them, discussions of molecular vibrations (Chapter 5), electronic structures (Chapter 6), and chemical reactions (Chapter 7). For the last two chapters we return to a qualitative treatment and introduce space-group sym- tries (Chapter 8), concluding with crystal structures (Chapter 9). For the third edition we have further revised and streamlined our text and renewed the illustrative material.

Introduction to Coordination Chemistry

Author : Geoffrey A. Lawrance
Publisher : John Wiley & Sons
ISBN 13 : 1118681401
Total Pages : 307 pages
Book Rating : 4.1/5 (186 download)

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Book Synopsis Introduction to Coordination Chemistry by : Geoffrey A. Lawrance

Download or read book Introduction to Coordination Chemistry written by Geoffrey A. Lawrance and published by John Wiley & Sons. This book was released on 2013-03-15 with total page 307 pages. Available in PDF, EPUB and Kindle. Book excerpt: At the heart of coordination chemistry lies the coordinate bond, in its simplest sense arising from donation of a pair of electrons from a donor atom to an empty orbital on a central metalloid or metal. Metals overwhelmingly exist as their cations, but these are rarely met ‘naked’ – they are clothed in an array of other atoms, molecules or ions that involve coordinate covalent bonds (hence the name coordination compounds). These metal ion complexes are ubiquitous in nature, and are central to an array of natural and synthetic reactions. Written in a highly readable, descriptive and accessible style Introduction to Coordination Chemistry describes properties of coordination compounds such as colour, magnetism and reactivity as well as the logic in their assembly and nomenclature. It is illustrated with many examples of the importance of coordination chemistry in real life, and includes extensive references and a bibliography. Introduction to Coordination Chemistry is a comprehensive and insightful discussion of one of the primary fields of study in Inorganic Chemistry for both undergraduate and non-specialist readers.

Symmetry in Inorganic and Coordination Compounds

Author : Franca Morazzoni
Publisher :
ISBN 13 : 9783030629977
Total Pages : 0 pages
Book Rating : 4.6/5 (299 download)

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Book Synopsis Symmetry in Inorganic and Coordination Compounds by : Franca Morazzoni

Download or read book Symmetry in Inorganic and Coordination Compounds written by Franca Morazzoni and published by . This book was released on 2021 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book addresses the nature of the chemical bond in inorganic and coordination compounds. In particular, it explains how general symmetry rules can describe chemical bond of simple inorganic molecules. Since the complexity of studying even simple molecules requires approximate methods, this book introduces a quantum mechanical treatment taking into account the geometric peculiarities of the chemical compound. In the case of inorganic molecules, a convenient approximation comes from symmetry, which constrains both the electronic energies and the chemical bonds. The book also gives special emphasis on symmetry rules and compares the use of symmetry operators with that of Hamiltonian operators. Where possible, the reactivity of molecules is also rationalized in terms of these symmetry properties. As practical examples, electronic spectroscopy and magnetism give experimental confirmation of the predicted electronic energy levels. Adapted from university lecture course notes, this book is the ideal companion for any inorganic chemistry course dealing with group theory.