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Surface Reactions On Stoichiometric And Defective Titanium Dioxide
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Book Synopsis Surface Reactions on Stoichiometric and Defective Titanium Dioxide by : Enrique Farfan-Arribas
Download or read book Surface Reactions on Stoichiometric and Defective Titanium Dioxide written by Enrique Farfan-Arribas and published by . This book was released on 2004 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Defects at Oxide Surfaces by : Jacques Jupille
Download or read book Defects at Oxide Surfaces written by Jacques Jupille and published by Springer. This book was released on 2015-02-09 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the basics and characterization of defects at oxide surfaces. It provides a state-of-the-art review of the field, containing information to the various types of surface defects, describes analytical methods to study defects, their chemical activity and the catalytic reactivity of oxides. Numerical simulations of defective structures complete the picture developed. Defects on planar surfaces form the focus of much of the book, although the investigation of powder samples also form an important part. The experimental study of planar surfaces opens the possibility of applying the large armoury of techniques that have been developed over the last half-century to study surfaces in ultra-high vacuum. This enables the acquisition of atomic level data under well-controlled conditions, providing a stringent test of theoretical methods. The latter can then be more reliably applied to systems such as nanoparticles for which accurate methods of characterization of structure and electronic properties have yet to be developed. The book gives guidance to tailor oxide surfaces by controlling the nature and concentration of defects. The importance of defects in the physics and chemistry of metal oxide surfaces is presented in this book together with the prominent role of oxides in common life. The book contains contributions from leaders in the field. It serves as a reference for experts and beginners in the field.
Book Synopsis Surface Chemistry to Control Bulk Reaction Dynamics of Native Point Defects in Rutile Titanium Dioxide by : Kandis Leslie Gilliard
Download or read book Surface Chemistry to Control Bulk Reaction Dynamics of Native Point Defects in Rutile Titanium Dioxide written by Kandis Leslie Gilliard and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Surface Modifications and Growth of Titanium Dioxide for Photo-Electrochemical Water Splitting by : John Alexander
Download or read book Surface Modifications and Growth of Titanium Dioxide for Photo-Electrochemical Water Splitting written by John Alexander and published by Springer. This book was released on 2016-05-21 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt: This outstanding thesis provides a wide-ranging overview of the growth of titanium dioxide thin films and its use in photo-electrochemicals such as water splitting. The context for water splitting is introduced with the theory of semiconductor-liquid junctions, which are dealt with in detail. In particular plasmonic enhancement of TiO2 by the addition of gold nanoparticles is considered in depth, including a thorough and critical review of the literature, which discusses the possible mechanisms that may be at work. Plasmonic enhancement is demonstrated with gold nanoparticles on Nb-doped TiO2. Finally, the use of temperature and pressure to control the phase and morphology of thin films grown by pulsed laser deposition is presented.
Book Synopsis The Phase Stability, Surface Structure and Defect Chemistry of Titanium Dioxide from First Principles Techniques by : Joseph Muscat
Download or read book The Phase Stability, Surface Structure and Defect Chemistry of Titanium Dioxide from First Principles Techniques written by Joseph Muscat and published by . This book was released on 1999 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Titanium Dioxide by : Hafiz Muhammad Ali
Download or read book Titanium Dioxide written by Hafiz Muhammad Ali and published by BoD – Books on Demand. This book was released on 2022-03-02 with total page 246 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a comprehensive overview of titanium dioxide, including recent advances and applications. It focuses on the compound’s uses in environmental remediation, photocatalytic materials, rechargeable lithium-ion batteries, thin films, energy storage, semiconductors, and much more. This volume is a useful resource for researchers, scientists, engineers, and students.
Book Synopsis Heterogeneous Photocatalysis by : M. Schiavello
Download or read book Heterogeneous Photocatalysis written by M. Schiavello and published by . This book was released on 1997-10-09 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photocatalysis is a reaction which is accelerated by light while a heterogeneous reaction consists of two phases ( a solid and a liquid for example). Heterogeneous Photocatalysis is a fast developing science which to date has not been fully detailed in a monograph. This title discusses the basic principles of heterogeneous photocatalysis and describes the bulk and surface properties of semiconductors. Applications of various types of photoreactions are described and the problems related to the modeling and design of photoreactors are covered.
Book Synopsis The Role of Interstitials and Surface Defects on Oxidation and Reduction Reactions on Titania by : Stephen C. Jensen
Download or read book The Role of Interstitials and Surface Defects on Oxidation and Reduction Reactions on Titania written by Stephen C. Jensen and published by . This book was released on 2013 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis focuses on understanding the influence of defect sites in titanium dioxide that drive many types of thermal and photochemical reactions. Two of the most common defects in vacuum are titanium interstitials and oxygen vacancies. Molecular oxygen fills oxygen vacancies and creates oxygen adatoms. We broadly investigate reduction and oxidation reactions of oxygenates driven by titanium interstitials and oxygen adatoms. First, we focus on the thermal chemistry of oxygen adatoms with butyrophenone and find that it reacts with the adatoms to form a strongly bound complex. The large difference in mobility between complexed and uncomplexed butyrophenone, and the corrugated nature of the TiO2(110) surface plane, allows a confined one-dimensional gas to persist, which is characterized by scanning tunneling microscopy (STM). Next, we focus on the reductive coupling of benzaldehyde to stilbene that is driven by titanium interstitials. The diolate intermediate of the reaction is identified by STM and the thermodynamic preference of molecular oxygen to interact with titanium interstitials is exploited to selectively reverse the benzaldehyde diolate intermediates. Additionally, we investigate the photo-oxidative coupling of methanol to methyl formate, the photo-oxidation of butyrophenone and the photo-stability of benzoate. Finally, we identify a water splitting mechanism on reduced titania that creates oxygen adatoms. We demonstrate that the photo-generated oxygen adatoms thermally react with titanium interstitials to make TiOx islands and drive the photo-oxidation of formaldehyde and butyrophenone. Methods used include temperature programmed reaction spectroscopy, STM, and density functional theory.
Book Synopsis Spillover and Mobility of Species on Solid Surfaces by : A. Guerrero-Ruiz
Download or read book Spillover and Mobility of Species on Solid Surfaces written by A. Guerrero-Ruiz and published by Elsevier. This book was released on 2001-08-02 with total page 501 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Spillover and Mobility of Species and Solid Surfaces" collects the papers which were presented at the Fifth International Conference Spillover, either as oral or poster contributions, as well as the summaries of the invited lectures. This congress and its publication in the Studies on Surface Science and Catalysis series follow the tradition of previous conferences on spillover, initiated in Lyon, 1983, and continued in Leipzig, 1989, Kyoto 1993 and Dalian, 1997. For the fifth conference, held in S.L. el Escorial (Madrid), the organising committee has attempted to compile representative contributions which illustrate the advances in understanding the spillover phenomenon since 1997. Spillover is a process taking place during the interface of gas reactant molecules (mainly hydrogen and oxygen) on solid surfaces. However, different contributions to the more general area of the chemistry at surfaces, related with the mobility and migration of species, diffusion through membranes, fuel cell catalysts, etc., have also been included. In fact the title of the present volume summarizes this attempt to extend the conference topics towards dynamics at surfaces.Among the 70 contributions received, the 56 accepted papers were selected on the basis of the reports of at least two international reviewers, according to standards comparable to those applied for other specialised journals. These papers are from 21 different countries.
Book Synopsis Updates on Titanium Dioxide by : Bochra Bejaoui
Download or read book Updates on Titanium Dioxide written by Bochra Bejaoui and published by BoD – Books on Demand. This book was released on 2023-08-30 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: Titanium dioxide (TiO2) has received a lot of attention due to its inexpensive cost, benign nature, and great photocatalytic potential. TiO2 has numerous applications, including in photocatalysts, Li-ion batteries, solar cells, and medical research. However, its performance is unsatisfactory due to a variety of issues, including a wide band gap (3.01 to 3.2 eV) and quick electron–hole pair recombination (1012 to 1011 s). Many efforts have been made to improve the qualities of TiO2, such as structural and dopant changes, which expand its applications. This book focuses on the properties of TiO2-modified nanoparticles, including their synthesis, alterations, and applications.
Book Synopsis Adsorption on Ordered Surfaces of Ionic Solids and Thin Films by : Hans-Joachim Freund
Download or read book Adsorption on Ordered Surfaces of Ionic Solids and Thin Films written by Hans-Joachim Freund and published by Springer Science & Business Media. This book was released on 2013-03-07 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: Adsorption on Ordered Surfaces of Ionic Solids and Thin Films introduces to a new and topical field of surface science for which rather little experience is available at present. It reviews the recent results of the employed analytical methods comprising all modern surface techniques including scanning tunneling microscopy and various kinds of electron spectroscopies. The present status of this new, clearly defined field of surface science is nearly completely overviewed by contributions from most of the research groups active in this field. The book is meant as a basis for the expected rapid development in this area with applications in catalysis, thin-film and semiconductor technology, sensors, electrochemistry, controlled preparation of ultrathin epitaxial surfaces, and interfaces of insultors as well as future molecular electronics.
Download or read book Oxide Surfaces written by and published by Elsevier. This book was released on 2001-05-21 with total page 677 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book is a multi-author survey (in 15 chapters) of the current state of knowledge and recent developments in our understanding of oxide surfaces. The author list includes most of the acknowledged world experts in this field. The material covered includes fundamental theory and experimental studies of the geometrical, vibrational and electronic structure of such surfaces, but with a special emphasis on the chemical properties and associated reactivity. The main focus is on metal oxides but coverage extends from 'simple' rocksalt materials such as MgO through to complex transition metal oxides with different valencies.
Book Synopsis Surface Science Research by : Charles P. Norris
Download or read book Surface Science Research written by Charles P. Norris and published by Nova Publishers. This book was released on 2005 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt: This new book covers the physics and chemistry of surfaces. The scope includes the structure, thermodynamics, and mobility of clean surfaces, as well as the interaction of gas molecules with solid surfaces. The energetic particle interactions that are the basis for the majority of techniques developed to reveal the structure and chemistry of surfaces are explored including auger electron spectroscopy, photoelectron spectroscopy, inelastic scattering of electrons and ions, low energy electron diffraction, scanning probe microscopy, and interfacial segregation. Crystal nucleation and growth are also considered. Principles such as adsorption, desorption and reactions between adsorbates are examined, with coverage also of new developments in the growth of epitaxial, and Langmuir-Blodgett films, as well as treatment of the etching of surfaces. Modern analytical techniques and applications to thin films and nanostructures are included. The latest in-depth research from around the world is presented.
Book Synopsis Hard X-ray Photoelectron Spectroscopy (HAXPES) by : Joseph Woicik
Download or read book Hard X-ray Photoelectron Spectroscopy (HAXPES) written by Joseph Woicik and published by Springer. This book was released on 2015-12-26 with total page 576 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides the first complete and up-to-date summary of the state of the art in HAXPES and motivates readers to harness its powerful capabilities in their own research. The chapters are written by experts. They include historical work, modern instrumentation, theory and applications. This book spans from physics to chemistry and materials science and engineering. In consideration of the rapid development of the technique, several chapters include highlights illustrating future opportunities as well.
Book Synopsis Visible-Light-Active Photocatalysis by : Srabanti Ghosh
Download or read book Visible-Light-Active Photocatalysis written by Srabanti Ghosh and published by John Wiley & Sons. This book was released on 2018-06-11 with total page 624 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive and timely overview of this important and hot topic, with special emphasis placed on environmental applications and the potential for solar light harvesting. Following introductory chapters on environmental photocatalysis, water splitting, and applications in synthetic chemistry, further chapters focus on the synthesis and design of photocatalysts, solar energy conversion, and such environmental aspects as the removal of water pollutants, photocatalytic conversion of CO2. Besides metal oxide-based photocatalysts, the authors cover other relevant material classes including carbon-based nanomaterials and novel hybrid materials. Chapters on mechanistic aspects, computational modeling of photocatalysis and Challenges and perspectives of solar reactor design for industrial applications complete this unique survey of the subject. With its in-depth discussions ranging from a comprehensive understanding to the engineering of materials and applied devices, this is an invaluable resource for a range of disciplines.
Book Synopsis The Role of Non-Stoichiometry in the Functional Properties of Oxide Materials by : Maria Veronica Ganduglia-Pirovano
Download or read book The Role of Non-Stoichiometry in the Functional Properties of Oxide Materials written by Maria Veronica Ganduglia-Pirovano and published by Frontiers Media SA. This book was released on 2019-12-09 with total page 160 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Nanostructured Photocatalyst via Defect Engineering by : Vitaly Gurylev
Download or read book Nanostructured Photocatalyst via Defect Engineering written by Vitaly Gurylev and published by Springer Nature. This book was released on 2021-10-28 with total page 388 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book helps readers comprehend the principles and fundamentals of defect engineering toward realization of an efficient photocatalyst. The volume consists of two parts, each of which addresses a particulate type of defects. The first, larger section provides a comprehensive and rigorous treatment of the behaviour and nature of intrinsic defects. The author describes how their controlled introduction and consequent manipulation over concentration, distribution, nature and diffusion is one of the most effective and practical methodologies to modify the properties and characteristics of target photocatalytic materials. The second part of the book explains the formation of extrinsic defects in the form of metallic and non-metallic dopants and gives a detailed description of their characteristics as this approach is also often used to fabricate an efficient photocatalyst. Filling the gap in knowledge on the correlation between introduction of defects in various semiconducting materials and their photocatalytic performance, the book is ideal for graduate students, academics and researchers interested in photocatalysts, defect engineering, clean energy, hydrogen production, nanoscale advanced functional materials, CO2 deactivation, and semiconductor engineering.