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Author : Casey O'Brien
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (144 download)
Download or read book Sulfur Poisoning of Pd and PdCu Alloy Hydrogen Separation Membranes written by Casey O'Brien and published by . This book was released on 2011 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Natalie Pomerantz
Publisher :
ISBN 13 :
Total Pages : 760 pages
Book Rating : 4.:/5 (916 download)
Download or read book Sulfur Poisoning and Tolerance of High Permeance Pd/Cu Alloy Membranes for Hydrogen Separation written by Natalie Pomerantz and published by . This book was released on 2010 with total page 760 pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract: This work investigated the long-term stability of sulfur tolerant Pd/Cu alloy membranes for hydrogen separation by performing characterizations lasting several thousand hours in H2, He and H2S/H2 atmospheres ranging in concentration from 0.2 - 50 ppm and temperatures ranging from 250 - 500°C. Two methods were used for fabricating the Pd/Cu membranes so that the sulfur tolerant fcc alloy would remain on the surface and minimize the decrease in hydrogen permeance inherent with fcc Pd/Cu alloys. The first method consisted of annealing a Pd/Cu bi-layer at high-temperatures and the second consisted of depositing a Pd/Cu/Pd tri-layer with an ultra-thin surface alloy. High temperature X-ray diffraction (HT-XRD) was employed to study the kinetics of the annealing process and atomic adsorption spectroscopy (AAS) was used to investigate the kinetics of the Cu deposition and Pd displacement of Cu. Upon the introduction of H2S, the permeance decrease observed was dependent upon the H2S feed concentration, and not the time of poisoning. However, after the recovery in pure H2 there was a portion of the permeance which could not be recovered due to adsorbed sulfur blocking H2 adsorption sites. The amount of recoverable permeance was dependent on the time of exposure to H2S and reached a limiting value which decreased with temperature. X-ray photoemission spectroscopy (XPS) was used to investigate poisoned samples and it was observed that the permeance not recovered at a given temperature in H2 was caused mostly by Cu sulfides. Both bi-layer and tri-layer membranes had hydrogen permeances which were higher than homogeneous Pd/Cu membranes of the same surface concentration. However, the tri-layer membranes performed as well as Pd membranes thus eliminating the disadvantage of alloying Pd with Cu without sacrificing sulfur tolerance.
Author : Chao-Huang Chen
Publisher :
ISBN 13 :
Total Pages : 866 pages
Book Rating : 4.:/5 (826 download)
Download or read book Sulfur Tolerance of Pd/Au Alloy Membranes for Hydrogen Separation from Coal Gas written by Chao-Huang Chen and published by . This book was released on 2012 with total page 866 pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract: This work provides a detailed characterization study on H2S poisoning of Pd and Pd/Au alloy composite membranes to obtain fundamental understandings of sulfur poisoning phenomena and preparation of sulfur tolerant membranes. The enhancement of the sulfur tolerance by alloying Pd with Au has been confirmed by both permeation test and microstructure analysis (SEM and XRD). While pure Pd membranes exhibited the permeance decline in the presence of H2S due to both sulfur adsorption and bulk Pd4S formation, Pd/Au alloy membranes showed the permeance loss merely resulted from the surface sulfur adsorption without bulk sulfide formation up to 55 ppm H2S. The XPS study confirmed that the H2S adsorption on the Pd/Au alloy surfaces was dissociative, and both surface Au and Pd sulfides were formed with the preferential Au-S bonding. The adsorption type of sulfur on the Pd/Au alloy surfaces was monolayer with a limited coverage, which increased with decreasing temperature. The permeance loss of Pd/Au membranes was essentially fully recoverable in H2, and the integrity of the membranes remained unaltered after the poisoning/recovery tests. Increasing Au composition in the Pd/Au membranes increased the sulfur tolerance. A Pd/Au alloy membrane of 16.7 wt% Au exhibited a permeance over 50% of its original value in the presence of 5 ppm H2S at 400°C, while a Pd membrane showed 85% permeance loss. The Pd/Au alloy membranes were fabricated by the Au displacement deposition, which had an empirical reaction order of 3.2 determined by the AAS. The HT-XRD study verified that the formed Pd/Au alloy layers were thermally stable up to 500°C.
Author :
Publisher :
ISBN 13 :
Total Pages : 7 pages
Book Rating : 4.:/5 (871 download)
Download or read book Palladium/Copper Alloy Composite Membranes for High Temperature Hydrogen Separation from Coal-Derived Gas Streams written by and published by . This book was released on 2001 with total page 7 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recent advances have shown that Pd-Cu composite membranes are not susceptible to the mechanical, embrittlement, and poisoning problems that have prevented widespread industrial use of Pd for high temperature H2 separation. These membranes consist of a thin (≈10 [mu]m) film of metal deposited on the inner surface of a porous metal or ceramic tube. Based on preliminary results, thin Pd60Cu40 films are expected to exhibit hydrogen flux up to ten times larger than commercial polymer membranes for H2 separation, and resist poisoning by H2S and other sulfur compounds typical of coal gas. Similar Pd-membranes have been operated at temperatures as high as 750 C. The overall objective of the proposed project is to demonstrate the feasibility of using sequential electroless plating to fabricate Pd60Cu40 alloy membranes on porous supports for H2 separation. These following advantages of these membranes for processing of coal-derived gas will be demonstrated: High H2 flux; Sulfur tolerant, even at very high total sulfur levels (1000 ppm); Operation at temperatures well above 500 C; and Resistance to embrittlement and degradation by thermal cycling. The proposed research plan is designed to providing a fundamental understanding of: Factors important in membrane fabrication; Optimization of membrane structure and composition; Effect of temperature, pressure, and gas composition on H2 flux and membrane selectivity; and How this membrane technology can be integrated in coal gasification-fuel cell systems.
Author : Angelo Basile
Publisher : John Wiley & Sons
ISBN 13 : 0470977574
Total Pages : 661 pages
Book Rating : 4.4/5 (79 download)
Download or read book Membranes for Membrane Reactors written by Angelo Basile and published by John Wiley & Sons. This book was released on 2010-12-20 with total page 661 pages. Available in PDF, EPUB and Kindle. Book excerpt: A membrane reactor is a device for simultaneously performing a reaction and a membrane-based separation in the same physical device. Therefore, the membrane not only plays the role of a separator, but also takes place in the reaction itself. This text covers, in detail, the preparation and characterisation of all types of membranes used in membranes reactors. Each membrane synthesis process used by membranologists is explained by well known scientists in their specific research field. The book opens with an exhaustive review and introduction to membrane reactors, introducing the recent advances in this field. The following chapters concern the preparation of both organic and inorganic, and in both cases, a deep analysis of all the techniques used to prepare membrane are presented and discussed. A brief historical introduction for each technique is also included, followed by a complete description of the technique as well as the main results presented in the international specialized literature. In order to give to the reader a summary look to the overall work, a conclusive chapter is included for collecting all the information presented in the previous chapters. Key features: Fills a gap in the market for a scientific book describing the preparation and characterization of all the kind of membranes used in membrane reactors Discusses an important topic - there is increasing emphasis on membranes in general, due to their use as energy efficient separation tools and the ‘green’ chemistry opportunities they offer Includes a review about membrane reactors, several chapters concerning the preparation organic, inorganic, dense, porous, and composite membranes and a conclusion with a comparison among the different membrane preparation techniques
Download or read book Surface Segregation in a PdCu Alloy Hydrogen Separation Membrane written by and published by . This book was released on 2007 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Separation of hydrogen from mixed gas streams is an important step for hydrogen generation technologies, including hydrocarbon reforming and coal/biomass gasification. Dense palladium-based membranes have received significant attention for this application because of palladium's ability to dissociatively adsorb molecular hydrogen at its surface for subsequent transport of hydrogen atoms through its bulk. Alloying palladium with minor components, like copper, has been shown to improve both the membrane's structural characteristics and resistance to poisoning of its catalytic surface [1]. Surface segregation--a composition difference between the bulk material and its surface--is common in alloys and can affect important surface processes. Rational design of alloy membranes requires that surface segregation be understood, and possibly controlled. In this work, we examine surface segregation in a polycrystalline Pd70Cu30 hydrogen separation membrane as a function of thermal treatment and adsorption of hydrogen sulfide.
Author : A Doukelis
Publisher : Elsevier
ISBN 13 : 1782422412
Total Pages : 403 pages
Book Rating : 4.7/5 (824 download)
Download or read book Palladium Membrane Technology for Hydrogen Production, Carbon Capture and Other Applications written by A Doukelis and published by Elsevier. This book was released on 2014-10-20 with total page 403 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thanks to their outstanding hydrogen selectivity, palladium membranes have attracted extensive R&D interest. They are a potential breakthrough technology for hydrogen production and also have promising applications in the areas of thermochemical biorefining. This book summarises key research in palladium membrane technologies, with particular focus on the scale-up challenges. After an introductory chapter, Part one reviews the fabrication of palladium membranes. Part two then focuses on palladium membrane module and reactor design. The final part of the book reviews the operation of palladium membranes for synthesis gas/hydrogen production, carbon capture and other applications. - Review of manufacture and design issues for palladium membranes - Discussion of the applications of palladium membrane technology, including solar steam reforming, IGCC plants, NGCC plants, CHP plants and hydrogen production - Examples of the technology in operation
Download or read book High Permeance Sulfur Tolerant Pd/Cu Alloy Membranes written by and published by . This book was released on 2014 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A method of making a membrane permeable to hydrogen gas (H.sub. 2.uparw.) is disclosed. The membrane is made by forming a palladium layer, depositing a layer of copper on the palladium layer, and galvanically displacing a portion of the copper with palladium. The membrane has improved resistance to poisoning by H.sub. 2S compared to a palladium membrane. The membrane also has increased permeance of hydrogen gas compared to palladium-copper alloys. The membrane can be annealed at a lower temperature for a shorter amount of time.
Author : Adolfo Iulianelli
Publisher : Elsevier
ISBN 13 : 0128173858
Total Pages : 488 pages
Book Rating : 4.1/5 (281 download)
Download or read book Current Trends and Future Developments on (Bio-) Membranes written by Adolfo Iulianelli and published by Elsevier. This book was released on 2020-07-22 with total page 488 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the last decade, the attention paid to the environmental protection has generated a considerable interest towards the development of new energy carriers and green energy production methods. Hydrogen as an energy carrier becomes a potential important source of energy due to its neutral environmental impact. However, its production, transformation and purification, presents a challenge in the so called hydrogen economy. Current Trends and Future Developments on (Bio-) Membranes gives a comprehensive review on the present state of the art of the hydrogen production and purification using new and alternative technologies stressing green processes and environment protection. The book covers green processes, renewable feedstocks utilization and membrane reactor technology for hydrogen production in line with new process intensification strategy. The book is divided in four sections, ie fundamentals of hydrogen generation, its impact on environmental issue, new applications involving hydrogen and its storage and distribution. The main scope of this book is to offer a new horizon on hydrogen generation and utilization. It stresses the role of new technologies for hydrogen generation, including the "micro-reactors technology for portable applications, their combination with high temperature fuel cells, the role of gas-separation for both hydrogen purification and CO2 sequestration, the exploitation of renewable sources (biogas, bioethanol and other renewables feedstocks) in reforming processes useful to generate hydrogen, membrane and membrane reactor technology as well as membrane bio-reactors etc. - Presents process intensification and commercialization of new and alternative hydrogen generation technologies - Relates new hydrogen production methods to their environmental impact - Outlines the fundamentals of hydrogen generation - Includes new developed technologies for hydrogen transport and storage
Author : J. Douglas Way
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (316 download)
Download or read book Palladium/Copper Alloy Composite Membranes for High Temperature Hydrogen Separation written by J. Douglas Way and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This report summarizes progress made during the a three year University Coal Research grant (DEFG26-03NT41792) at the Colorado School of Mines. The period of performance was September 1, 2003 through August of 2006. We made excellent progress toward our goal of contributing to the development of high productivity, sulfur tolerant composite metal membranes for hydrogen production and membrane reactors. Composite Pd and Pd alloy metal membranes with thin metal films (1-7 {micro}m) were prepared on porous stainless steel and ceramic supports that meet or exceed the DOE 2010 and 2015 pure hydrogen flux targets at differential pressure of only 20 psi. For example, a 2 {micro}m pure Pd membrane on a Pall AccuSep{reg_sign} substrate achieved an ideal H{sub 2}/N{sub 2} separation factor of over 6000, with a pure hydrogen flux of 210 SCFH/ft{sup 2} at only 20 psig feed pressure. Similar performance was achieved with a Pd{sub 80}Au{sub 20} composite membrane on a similar stainless steel substrate. Extrapolating the pure hydrogen flux of this PdAu membrane to the DOE Fossil Energy target conditions of 150 psia feed pressure and 50 psia permeate pressure gives a value of 508 SCFH/ft{sup 2}, exceeding the 2015 target. At these thicknesses, it is the support cost that will dominate the cost of a large scale module. In a direct comparison of FCC phase PdCu and PdAu alloys on identical supports, we showed that a Pd{sub 85}Au{sub 15} (mass %) alloy membrane is not inhibited by CO, CO{sub 2}, or steam present in a water-gas shift feed mixture at 400 C, has better resistance to sulfur than a Pd{sub 94}Cu{sub 6} membrane, and has over twice the hydrogen permeance.
Download or read book Sulfur Tolerant Pd/Cu and Pd/Au Alloy Membranes for H2 Separation with High Pressure CO2 for Sequestration written by and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The effect of H2S poisoning on Pd, Pd/Cu, and Pd/Au alloy composite membranes prepared by the electroless deposition method on porous Inconel supports was investigated to provide a fundamental understanding of the durability and preparation of sulfur tolerant membranes. X-ray photoelectron spectroscopy (XPS) studies showed that the exposure of pure Pd to 50 ppm H2S/H2 mixtures caused bulk sulfide formation at lower temperatures and surface sulfide formation at higher temperatures. Lower temperatures, longer exposure times, and higher H2S concentrations resulted in a higher degree of sulfidation. In a Pd membrane, the bulk sulfide formation caused a drastic irrecoverable H2 permeance decline and an irreparable loss in selectivity. Pd/Cu and Pd/Au alloy membranes exhibited permeance declines due to surface sulfide formation upon exposure to 50 ppm H2S/H2 gas mixtures. However in contrast to the pure Pd membrane, the permeances of the Pd/Cu and Pd/Au alloy membranes were mostly recovered in pure H2 and the selectivity of the Pd alloy layers remained essentially intact throughout the characterization in H2, He and H2S/H2 mixtures which lasted several thousand hours. The amount of irreversible sulfur poisoning decreased with increasing temperature due to the exothermicity of H2S adsorption. Longer exposure times increased the amount of irreversible poisoning of the Pd/Cu membrane but not the Pd/Au membrane. Pd/Au coupon studies of the galvanic displacement method showed that higher Au{sup 3+} concentrations, lower pH values, higher bath temperatures and stirring the bath at a rate of 200 rpm yielded faster displacement rates, more uniform depositions, and a higher Au content within the layers. While 400 C was found to be sufficient to form a Pd/Au alloy on the surface, high temperature X-ray diffraction (HTXRD) studies showed that even after annealing between 500-600 C, the Pd/Cu alloys could have part or all of the surface in the less sulfur resistant [beta] phase.
Download or read book Palladium Alloy Membranes for Hydrogen Separation written by and published by . This book was released on 2001 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Angelo Basile
Publisher : Elsevier
ISBN 13 : 0128183330
Total Pages : 414 pages
Book Rating : 4.1/5 (281 download)
Download or read book Current Trends and Future Developments on (Bio-) Membranes written by Angelo Basile and published by Elsevier. This book was released on 2020-01-05 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt: Current Trends and Future Developments in (Bio-) Membranes: Recent Advances in Metallic Membranes presents recent developments in metallic membranes used in membrane reactors to save energy. It also offers a comprehensive review of the present state-of-the-art on the fabrication and design of metallic membranes and membrane reactors, considering various applications. This book focuses on the structure, preparation, characterization and applications of metallic membranes and membrane reactors, as well as transport mechanisms and simulation aspects. As recent research has focused on the development of metallic membranes and their applications, this book is an ideal reference on different production procedures and their use. - Reviews metallic membranes research and applications - Outlines the mechanisms of metallic membrane based processes - Includes structure, preparation, characterization and properties of metallic membranes - Highlights various applications of metallic membranes in energy production
Author : E. Grell
Publisher : Springer Science & Business Media
ISBN 13 : 3642815375
Total Pages : 509 pages
Book Rating : 4.6/5 (428 download)
Download or read book Membrane Spectroscopy written by E. Grell and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 509 pages. Available in PDF, EPUB and Kindle. Book excerpt: The last 10 years have seen an enormous growth in our understanding of the molecular organisation of biological membranes. Experimental methods have been devised to meas ure the translational and rotational mobility of lipids and proteins, thereby furnishing a quantitative basis for the concept of membrane fluidity. Likewise, the asymmetry of bi layer membranes as evidenced by the asymmetric insertion of proteins and lipids has been put on firm experimental ground. At higher molecular resolution it has been possible to provide a detailed pi2ture of the molecular conformation and dynamics of lipids and, to some extent, even of small peptides embedded in a bilayer matrix. Many of these achieve ments would not have been possible without the application of modem spectroscopic methods. Since these techniques are scattered in a variety of specialized textbooks the present monograph attempts to describe the key spectroscopic methods employed in present-day membrane research at an intermediate level. There is no question that the elusive detailed structure of the biological membrane demands a multiplicity of experi mental approaches and that no single spectroscopic method can cover the full range of physical phenomena encountered in a membrane. Much confusion in the literature has arisen by undue generalizations without considering the frequency range or other limi tations of the methods employed. It is to be hoped that the present monograph with its comprehensive description of most modem spectroscopic techniques, will contribute to- .
Author : G. Alefeld
Publisher :
ISBN 13 :
Total Pages : 420 pages
Book Rating : 4.F/5 ( download)
Download or read book Hydrogen in Metals: Application-oriented properties written by G. Alefeld and published by . This book was released on 1978 with total page 420 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Klaus-Viktor Peinemann
Publisher : John Wiley & Sons
ISBN 13 : 3527622241
Total Pages : 304 pages
Book Rating : 4.5/5 (276 download)
Download or read book Membranes for Energy Conversion written by Klaus-Viktor Peinemann and published by John Wiley & Sons. This book was released on 2008-09-08 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: Focusing on recent developments in innovative energy conversion, this second volume features emerging applications with the capacity to transform the entire energy economy. Specific examples include the development of sulfonated polyarylether-type polymers as proton exchange membranes for high- and medium-temperature polymer electrode fuel cells (PEFC), with an entire section devoted to the rapidly expanding field of materials development for solid oxide fuel cells (SOFC). The result is a detailed and invaluable source of information for those involved in the chemical, material science and engineering fields of power generation.
Author : Thijs Peters
Publisher : MDPI
ISBN 13 : 3038977020
Total Pages : 190 pages
Book Rating : 4.0/5 (389 download)
Download or read book Pd-based Membranes written by Thijs Peters and published by MDPI. This book was released on 2019-03-26 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt: Palladium (Pd)-based membranes have received a great deal of attention from both academia and industry thanks to their ability to selectively separate hydrogen from gas streams. The integration of such membranes with appropriate catalysts in membrane reactors allows for hydrogen production with CO2 capture that can be applied in smaller bioenergy or combined heat and power (CHP) plants, as well as in large-scale power plants. Pd-based membranes are therefore regarded as a Key Enabling Technology (KET) to facilitate the transition towards a knowledge-based, low-carbon, and resource-efficient economy. This Special Issue of the journal Membranes on “Pd-based Membranes: Overview and Perspectives” contains nine peer-reviewed articles. Topics include manufacturing techniques, understanding of material phenomena, module and reactor design, novel applications, and demonstration efforts and industrial exploitation.
