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Structural Studies Of The Bonding Of Nitric Oxide In Transition Metal Complexes And The Syntheses Structure And Dynamic Nuclear Magnetic Resonance Behavior Of Some Rhi Complexes
Download Structural Studies Of The Bonding Of Nitric Oxide In Transition Metal Complexes And The Syntheses Structure And Dynamic Nuclear Magnetic Resonance Behavior Of Some Rhi Complexes full books in PDF, epub, and Kindle. Read online Structural Studies Of The Bonding Of Nitric Oxide In Transition Metal Complexes And The Syntheses Structure And Dynamic Nuclear Magnetic Resonance Behavior Of Some Rhi Complexes ebook anywhere anytime directly on your device. Fast Download speed and no annoying ads. We cannot guarantee that every ebooks is available!
Book Synopsis Structural Studies of the Bonding of Nitric Oxide in Transition Metal Complexes and the Syntheses, Structure, and Dynamic Nuclear Magnetic Resonance Behavior of Some Rh(I) Complexes by : Donald George Van Derveer
Download or read book Structural Studies of the Bonding of Nitric Oxide in Transition Metal Complexes and the Syntheses, Structure, and Dynamic Nuclear Magnetic Resonance Behavior of Some Rh(I) Complexes written by Donald George Van Derveer and published by . This book was released on 1974 with total page 242 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Reactivity of Nitric Oxide on Copper Surfaces by : Akitoshi Shiotari
Download or read book Reactivity of Nitric Oxide on Copper Surfaces written by Akitoshi Shiotari and published by Springer. This book was released on 2017-06-07 with total page 135 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides microscopic insights into chemical properties of NO on metal surfaces. NO/metal systems have been studied intensively to understand heterogeneous catalysis to detox exhaust NOx gas. The identification and componential analysis of various and mixed chemical species of NO adsorbed onto the surfaces have been significant challenges faced by conventional experimental techniques, such as vibrational spectroscopies. The author investigated "individual" NO molecules on Cu surfaces using low-temperature scanning tunneling microscopy (STM). STM not only provides information on the geometric, electronic, and vibrational properties at the single-molecule level; it is also able to manipulate molecules on surfaces to induce chemical reaction. Exploiting those techniques, the author chemically identified individual NO-related species on the surfaces and discovered new reaction processes for NO reduction, which provides microscopic insights into the catalytic mechanisms. The author also visualized wave functions of electrons in a valence orbital of NO and demonstrated that the wave functions are modified by the formation of covalent bonding or hydrogen bonding. This is, namely, "the visualization of quantum mechanics in real space," which is certainly worth reading. Furthermore, the book demonstrates that direct observation of valence orbitals helps to elucidate the reactivity of molecules adsorbed onto surfaces. This innovative approach to studying molecular properties will contribute to further development of STM and its related methods.
Book Synopsis The Synthesis and Dynamic Nuclear Magnetic Resonance Studies of Fluxional Transition Metal Complexes of Pyridyl Based Ligands by : Matthew Daniel Olsen
Download or read book The Synthesis and Dynamic Nuclear Magnetic Resonance Studies of Fluxional Transition Metal Complexes of Pyridyl Based Ligands written by Matthew Daniel Olsen and published by . This book was released on 1997 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis NMR Studies of Arene Transition Metal Complexes by : Catherine L. Higgitt
Download or read book NMR Studies of Arene Transition Metal Complexes written by Catherine L. Higgitt and published by . This book was released on 1998 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, Characterization and X-ray Structural Studies of Octahedral Transition Metal Complexes Incorporating the Novel Anionic Tridentate Ligand, Dimethyl(ethanolamino) (1-pyrazolyl)gallate, Me2Ga(OCH2CH2NH)(N2C3H3) by : Kenneth S. Chong
Download or read book Synthesis, Characterization and X-ray Structural Studies of Octahedral Transition Metal Complexes Incorporating the Novel Anionic Tridentate Ligand, Dimethyl(ethanolamino) (1-pyrazolyl)gallate, Me2Ga(OCH2CH2NH)(N2C3H3) written by Kenneth S. Chong and published by . This book was released on 1978 with total page 128 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Dynamic Nuclear Magnetic Resonance Studies of Transition Metal Complexes Involving Group VI Ligands by : Martin Booth
Download or read book Dynamic Nuclear Magnetic Resonance Studies of Transition Metal Complexes Involving Group VI Ligands written by Martin Booth and published by . This book was released on 1979 with total page 239 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Recent Research Developments in Chemistry and Biology of Nitric Oxide, 2008 by : Valeria Sorrenti
Download or read book Recent Research Developments in Chemistry and Biology of Nitric Oxide, 2008 written by Valeria Sorrenti and published by . This book was released on 2008-01-01 with total page 179 pages. Available in PDF, EPUB and Kindle. Book excerpt: Preface In the last two decades knowledge of organometallic compounds has expanded so rapidly that it constitutes a major branch of chemistry. Almost all branches of chemistry and material science now interface with organometallic chemistry--the study of compounds containing carbon-metal bonds. The subject is developing at an astonishing rate and in many directions. This book deals mainly with some structural aspects of organoboron and organosilicon and applications of organometallic compounds in carbonylation reactions. First two chapters describe some structural aspects of organoboron and organosilicon compounds. Chapter 1 describe the Macrocyclic boron species, synthesis and their stabilization through N-B dative bond. Chapter 2 reviews the structural determination of some hypervalent silicon compounds by NMR and X-ray diffaraction studies. Chapter 3 deals with recent trends in cobalt catalysed carbonylation reactions while chapter 4 describes the transition metal mediated cyclocarbonylation with special reference to alkynes, alkynyl ketones and enones derivatives. Last chapter reviews the synthesis of organometallic dendrimers and summarizes the application of organometallic dendritic molecules in catalysis with special reference to carbonylation and ring expansion reaction in organic synthesis.
Book Synopsis C-X Bond Formation by : Arkadi Vigalok
Download or read book C-X Bond Formation written by Arkadi Vigalok and published by Springer. This book was released on 2010-06-30 with total page 198 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contents: Kilian Muñiz: Transition Metal Catalyzed Electrophilic Halogenation of C-H bonds in alpha-Position to Carbonyl Groups; Arkadi Vigalok * and Ariela W Kaspi: Late Transition Metal-Mediated Formation of Carbon-Halogen Bonds; Paul Bichler and Jennifer A. Love*: Organometallic Approaches to Carbon-Sulfur Bond Formation; David S. Glueck: Recent Advances in Metal-Catalyzed C-P Bond Formation; Andrei N. Vedernikov: C-O Reductive Elimination from High Valent Pt and Pd Centers; Lukas Hintermann: Recent Developments in Metal-Catalyzed Additions of Oxygen Nucleophiles to Alkenes and Alkynes; Moris S. Eisen: Catalytic C-N, C-O and C-S bond formation promoted by organoactinide complexes.
Book Synopsis Complexes of Nitric Oxide by : Joseph Reed
Download or read book Complexes of Nitric Oxide written by Joseph Reed and published by . This book was released on 1979 with total page 210 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis A Carbon- 13 Nuclear Magnetic Resonance Study of the Bonding in Group VIb Transition Metal Organometallic Complexes by : George M. Bodner
Download or read book A Carbon- 13 Nuclear Magnetic Resonance Study of the Bonding in Group VIb Transition Metal Organometallic Complexes written by George M. Bodner and published by . This book was released on 1972 with total page 182 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Structural Studies of Transition Metal Carbonyl, Hydride, and Nitrosyl Complexes by : Robert Don Wilson
Download or read book Structural Studies of Transition Metal Carbonyl, Hydride, and Nitrosyl Complexes written by Robert Don Wilson and published by . This book was released on 1976 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Bioinspired Synthesis and Reactivity Studies of Nitric Oxide Iron Complexes by : Jennifer Hess
Download or read book Bioinspired Synthesis and Reactivity Studies of Nitric Oxide Iron Complexes written by Jennifer Hess and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The significant role that nitric oxide plays in human physiology is linked to the ability of NO to bind to iron forming mono-nitrosyl iron complexes. Protein-bound and low-molecular-weight dinitrosyl iron complexes (DNICs) are known to form in excess NO. Studies of such biological DNICs have relied on their paramagnetism and characteristic EPR signal of g value of 2.03. It has been suggested that DNICs act in vivo as NO storage (when protein-bound) and transfer agents (when released by, for example, free cysteine). Biological DNICs, mainly resulting from iron-sulfur cluster degradation, are difficult to extract and isolate, thereby preventing their full characterization. Thus, development of synthetic DNICs is a promising approach to model and better understand the formation and function of biological DNICs, the scope of donor ligands that might coexist with Fe(NO)2 units, the redox levels of bio-DNICs, and establish other spectroscopic techniques appropriate for characterization. A series of N-heterocyclic carbene (NHC) and imidazole (Imid) complexes has been characterized as mimics of histidine-containing DNICs. The pseudo-tetrahedral L2Fe(NO)2 complexes have NO stretching frequencies and redox potentials that suggest the NHCs are slightly better donors than Imids, however the two types of ligands have similar steric properties. Both the EPR-active, {Fe(NO)2}9 and the EPR-silent, {Fe(NO)2}10 states can be accessed and stabilized by the NHC. Nitric oxide transfer studies have shown that only the {Fe(NO)2}9 complexes are capable of transferring NO to a suitable NO trapping agent. Deprotonation of the distal nitrogen functionality in the imidazolate ligands of [(Imidazole)2Fe(NO)2]- leads to aggregation forming molecular squares of {Fe(NO)2}9 units bridged by the imidazolates. These interesting tetrameric complexes are examined by X-ray diffraction, EPR, and Mössbauer studies. The paramagnetic tetrameric complexes have multiple redox events observed by cyclic voltammetry. Mössbauer spectral data of the tetrameric complexes are compared with Mössbauer data obtained for a series of NHC-containing DNICs. Iron and cobalt-containing mononitrosyl N2S2 model complexes of the nitrile hydratase enzyme active site demonstrate sulfur-based reactivity resulting in the formation of polymetallic complexes. In all cases, shifts in the nitrosyl stretching frequencies demonstrate substantial transfer of electron density from the (NO)M(N2S2) moiety to the metal-acceptor site.
Book Synopsis Light-induced Release of Nitric Oxide and Carbon Monoxide from Metal Complexes by : Jingjing Liu
Download or read book Light-induced Release of Nitric Oxide and Carbon Monoxide from Metal Complexes written by Jingjing Liu and published by . This book was released on 2019 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present thesis focuses on the light-responsive nitric oxide releasing molecules (NORMs) and carbon monoxide releasing molecules (CORMs) based on transition metal ruthenium (Ru) and manganese (Mn) complexes. A general introduction and brief development of NORMs and CORMs are given in the first chapter. Chapter 2 describes series of photolabile {RuNO}6 nitrosyls containing carboxamido-N and pyridine donors which fluorine substitution at different positions within the molecules thereof. In this section, the synthesis and characterization of metal nitrosyls are introduced as well as the influence of fluoro-substitution on NO-releasing studies are also investigated. In addition, the photo behaviors and mechanism analysis of the fluorinated ruthenium carbonyl complexes with same ligands as {RuNO}6 nitrosyls are represented in chapter 3. Next, the Chapter 4-6 demonstrate water soluble photo-CORMs based on manganese(I) tricarbonyls center which conjugated to a fluorobenzene group, dabsyl chromophoric ligand and nitrobenzodiazole fluorophore group, respectively. A fluorinated manganese-based photo-CORM in chapter 4 combines with 19F spectroscopy, aiming to provide a new strategy for tracking the photolysis of donor molecules through the NMR spectral change. Furthermore, the photo-CORMs presented in chapter 5 and 6 release CO under irradiation with visible light, simultaneously achieving the colorimetric and/or fluorometric response.
Book Synopsis Synthesis and Multinuclear Magnetic Resonance Study of Some Tin(IV) Complexes of Pyridine-2-thiolate and Related Ligands, and the X-ray Structural Analysis of Sn(C5H4NS)4 C5H5NS by : Leslie C. Damude
Download or read book Synthesis and Multinuclear Magnetic Resonance Study of Some Tin(IV) Complexes of Pyridine-2-thiolate and Related Ligands, and the X-ray Structural Analysis of Sn(C5H4NS)4 C5H5NS written by Leslie C. Damude and published by . This book was released on 1990 with total page 44 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Nuclear magnetic resonance studies of hydrogen bonding and some related problems in structural organic chemistry by : Sture Forsen
Download or read book Nuclear magnetic resonance studies of hydrogen bonding and some related problems in structural organic chemistry written by Sture Forsen and published by . This book was released on 1962 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Structural Studies on Some Catalytically Relevant Transition Metal Complexes by : Joseph Raymond Missert
Download or read book Structural Studies on Some Catalytically Relevant Transition Metal Complexes written by Joseph Raymond Missert and published by . This book was released on 1983 with total page 69 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Reactions of Nitric Oxide with Transition Metal Alkyl Complexes by : A. R. Middleton
Download or read book Reactions of Nitric Oxide with Transition Metal Alkyl Complexes written by A. R. Middleton and published by . This book was released on 1980 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
