Stereochemistry of Radical Reactions

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Publisher : John Wiley & Sons
ISBN 13 : 3527615229
Total Pages : 294 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Stereochemistry of Radical Reactions by : Dennis P. Curran

Download or read book Stereochemistry of Radical Reactions written by Dennis P. Curran and published by John Wiley & Sons. This book was released on 2008-09-26 with total page 294 pages. Available in PDF, EPUB and Kindle. Book excerpt: As little as a decade ago, radicals were regarded as interesting reactive intermediates with little synthetic use. However, recent results show that radicals have an enormous potential for applications in stereoselective reactions - it's all a matter of knowing what method to use and how to apply it. Three world experts in the field have combined their expertise and present the concepts to understand and even to predict the course of stereoselective radical reactions. In addition, guidelines are established which will enable the readers to plan and carry out their own stereoselective syntheses with radicals. A comprehensive list of references provides an easy access to the primary literature. The Stereochemistry of Radical Reactions is a highly topical introduction to this burgeoning field of research. Both advanced students and researchers active in the field will welcome this book as a source of concepts and ideas.

Radical Reactions in Organic Synthesis

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Publisher : Oxford Chemistry Masters
ISBN 13 : 9780198502418
Total Pages : 280 pages
Book Rating : 4.5/5 (24 download)

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Book Synopsis Radical Reactions in Organic Synthesis by : Samir Z. Zard

Download or read book Radical Reactions in Organic Synthesis written by Samir Z. Zard and published by Oxford Chemistry Masters. This book was released on 2003 with total page 280 pages. Available in PDF, EPUB and Kindle. Book excerpt: Samir Zard provides a description of radical reactions and their applications in organic synthesis. This book shows that an with an elementary knowledge of kinetic and some common sense, it is possible to harness radicals into a tremendously powerful tool for solving synthetic problems.

Stereochemistry and Organic Reactions

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Publisher : Academic Press
ISBN 13 : 0128240938
Total Pages : 640 pages
Book Rating : 4.1/5 (282 download)

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Book Synopsis Stereochemistry and Organic Reactions by : Dipak Kumar Mandal

Download or read book Stereochemistry and Organic Reactions written by Dipak Kumar Mandal and published by Academic Press. This book was released on 2021-04-21 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stereochemistry and Organic Reactions: Conformation, Configuration, Stereoelectronic Effects and Asymmetric Synthesis provides coverage on the stereochemistry of reactions of all mechanistic types, ranging from ionic, pericyclic and transition metal-catalyzed to radical and photochemical. Chapters cover acyclic molecules, cyclic molecules, the stereochemistry of organic reactions, the perturbation molecular orbital theory for the origin of stereoelectronic effects, and an introduction to the principles of stereoselectivity and hierarchical levels of asymmetric synthesis. Each chapter includes problems that reinforce main themes, making it valuable to students, teachers and researchers working in organic, biological and medicinal chemistry, as well as biologists, pharmacologists, polymer chemists and chemists. Presents a holistic and unified approach to stereochemical understanding and predictions, covering reactions of all mechanistic classes Includes two background chapters on perturbation theory and stereoselective principles, along with asymmetric designs Features novel rules and mnemonics to delineate product stereochemistry Includes up-to-date coverage with over 1300 selective references

Advanced Free Radical Reactions for Organic Synthesis

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Author :
Publisher : Elsevier
ISBN 13 : 9780080524252
Total Pages : 270 pages
Book Rating : 4.5/5 (242 download)

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Book Synopsis Advanced Free Radical Reactions for Organic Synthesis by : Hideo Togo

Download or read book Advanced Free Radical Reactions for Organic Synthesis written by Hideo Togo and published by Elsevier. This book was released on 2004-01-14 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free radical reactions have become increasingly important and a very attractive tool in organic synthesis in the last two decades, due to their powerful, selective, specific, and mild reaction abilities. Advanced Free Radical Reactions for Organic Synthesis reviews information on all types of practical radical reactions, e.g. cyclizations, additions, hydrogen-atom abstractions, decarboxylation reactions. The book usefully provides experimental details for the most important reactions as well as numerous references to the original literature. By covering both the fundamentals and synthetic applications it is therefore suitable for both new and experienced researchers, chemists, biochemists, natural product chemists and graduate students. This title is the definitive guide to radical chemistry for all scientists. Introduces and reviews the use of radicals to perform synthetic transformations Practical details are provided for the most important methods Numerous references to the original literature

The Stereochemistry of Radical Addition Reactions

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Publisher :
ISBN 13 :
Total Pages : 260 pages
Book Rating : 4.:/5 (89 download)

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Book Synopsis The Stereochemistry of Radical Addition Reactions by : Donald Wayne Larsen

Download or read book The Stereochemistry of Radical Addition Reactions written by Donald Wayne Larsen and published by . This book was released on 1960 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Organic Mechanisms

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Publisher : Springer Science & Business Media
ISBN 13 : 3642036503
Total Pages : 873 pages
Book Rating : 4.6/5 (42 download)

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Book Synopsis Organic Mechanisms by : Reinhard Bruckner

Download or read book Organic Mechanisms written by Reinhard Bruckner and published by Springer Science & Business Media. This book was released on 2010-01-20 with total page 873 pages. Available in PDF, EPUB and Kindle. Book excerpt: This English edition of a best-selling and award-winning German textbook Reaction Mechanisms: Organic Reactions · Stereochemistry · Modern Synthetic Methods is aimed at those who desire to learn organic chemistry through an approach that is facile to understand and easily committed to memory. Michael Harmata, Norman Rabjohn Distinguished Professor of Organic Chemistry (University of Missouri) surveyed the accuracy of the translation, made certain contributions, and above all adapted its rationalizations to those prevalent in the organic chemistry community in the English-speaking world. Throughout the book fundamental and advanced reaction mechanisms are presented with meticulous precision. The systematic use of red "electron-pushing arrows" allows students to follow each transformation elementary step by elementary step. Mechanisms are not only presented in the traditional contexts of rate laws and substituent effects but, whenever possible, are illustrated using practical, useful and state-of-the-art reactions. The abundance of stereoselective reactions included in the treatise makes the reader familiar with key concepts of stereochemistry. The fundamental topics of the book address the needs of upper-level undergraduate students, while its advanced sections are intended for graduate-level audiences. Accordingly, this book is an essential learning tool for students and a unique addition to the reference desk of practicing organic chemists, who as life-long learners desire to keep abreast of both fundamental and applied aspects of our science. In addition, it will well serve ambitious students in chemistry-related fields such as biochemistry, medicinal chemistry and pharmaceutical chemistry. From the reviews: "Professor Bruckner has further refined his already masterful synthetic organic chemistry classic; the additions are seamless and the text retains the magnificent clarity, rigour and precision which were the hallmark of previous editions. The strength of the book stems from Professor Bruckner’s ability to provide lucid explanations based on a deep understanding of physical organic chemistry and to limit discussion to very carefully selected reaction classes illuminated by exquisitely pertinent examples, often from the recent literature. The panoply of organic synthesis is analysed and dissected according to fundamental structural, orbital, kinetic and thermodynamic principles with an effortless coherence that yields great insight and never over-simplifies. The perfect source text for advanced Undergraduate and Masters/PhD students who want to understand, in depth, the art of synthesis ." Alan C. Spivey, Imperial College London "Bruckner’s ‘Organic Mechanisms’ accurately reflects the way practicing organic chemists think and speak about organic reactions. The figures are beautifully drawn and show the way organic chemists graphically depict reactions. It uses a combination of basic valence bond pictures with more sophisticated molecular orbital treatments. It handles mechanisms both from the "electron pushing perspective" and from a kinetic and energetic view. The book will be very useful to new US graduate students and will help bring them to the level of sophistication needed to be serious researchers in organic chemistry." Charles P. Casey, University of Wisconsin-Madison "This is an excellent advanced organic chemistry textbook that provides a key resource for students and teachers alike." Mark Rizzacasa, University of Melbourne, Australia.

Organic Reactions Stereochemistry And Mechanism (Through Solved Problems)

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Author :
Publisher : New Age International
ISBN 13 : 9788122417661
Total Pages : 612 pages
Book Rating : 4.4/5 (176 download)

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Book Synopsis Organic Reactions Stereochemistry And Mechanism (Through Solved Problems) by : P S Kalsi

Download or read book Organic Reactions Stereochemistry And Mechanism (Through Solved Problems) written by P S Kalsi and published by New Age International. This book was released on 2007 with total page 612 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Book Provides A Self-Study Of Different Topics Of Organic Chemistry Viab Problem Solving. The Present 4Th Edition Has Been Completely Rewritten According To The Organic Chemistry Syllabus Of The Net (Csir) Examination. This Necessitated The Deletion Of Several Topics From The Third Edition And Incorporation Of New Ones. Emphasis Has Been Laid On A Variety Of New Reactions, Name Reactions, Reagents In Organic Synthesis And Incorporation Of Their Knowledge In The Entire Coverage Of Organic Chemistry In A Unique Way.A Thorough Study Of The Book Is Expected To Help The Student To Excel Not Only In The University Examination Including The Net Examination, But Also In His Learning Of Various Topics And Before Interview Boards. Several Topics Like Aromaticity, Pericyclic Reactions And Heterocyclic Chemistry Have Now Been Brought Up To Date And The Material Provided Is Complete In Itself.The Presentation Has Been So Designed So As To Thread Through The Entire Organic Chemistry By The Application Of The Knowledge Learnt In One Topic To Newer Situations In Other Topics. The Present Revised Edition Also Includes Numerous Important Developments Since The Third Edition Of The Book Was Published.

Half a Century of Free Radical Chemistry

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Publisher : Cambridge University Press
ISBN 13 : 9780521445801
Total Pages : 180 pages
Book Rating : 4.4/5 (458 download)

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Book Synopsis Half a Century of Free Radical Chemistry by : Derek H. R. Barton

Download or read book Half a Century of Free Radical Chemistry written by Derek H. R. Barton and published by Cambridge University Press. This book was released on 1993-04-15 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes the experience over 25 years of the senior author with the chemistry of organic free radicals. It begins with a mechanistic study of industrial importance on the pyrolysis of chlorinated alkanes. It continues with a theory on the biosynthesis of phenolate derived alkaloids involving phenolate radical coupling. There follows 20 years of practical work to prove the theory correct, especially in the case of morphine alkaloids. The book then describes the work on nitrile photolysis (Barton reaction) which involved the invention of new radical chemistry leading to a simple synthesis of the important hormone, aldosterone. There follows a description of the invention of an important new method for the deoxygenation of biologically important molecules, especially sugars and nucleosides, using radical chemistry applied to thiocarbonyl derivatives. Some years later, in a logical extension to carboxylic acids, another new reaction was invented which provides carbon, nitrogen, oxygen and other radicals under mild conditions. A final chapter summarizes recent applications of thiocarbonyl group derived radical reactions by other authors.

Advanced Organic Chemistry

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Publisher : Springer Science & Business Media
ISBN 13 : 0387448977
Total Pages : 1213 pages
Book Rating : 4.3/5 (874 download)

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Book Synopsis Advanced Organic Chemistry by : Francis A. Carey

Download or read book Advanced Organic Chemistry written by Francis A. Carey and published by Springer Science & Business Media. This book was released on 2007-06-13 with total page 1213 pages. Available in PDF, EPUB and Kindle. Book excerpt: The two-part, fifth edition of Advanced Organic Chemistry has been substantially revised and reorganized for greater clarity. The material has been updated to reflect advances in the field since the previous edition, especially in computational chemistry. Part A covers fundamental structural topics and basic mechanistic types. It can stand-alone; together, with Part B: Reaction and Synthesis, the two volumes provide a comprehensive foundation for the study in organic chemistry. Companion websites provide digital models for study of structure, reaction and selectivity for students and exercise solutions for instructors.

Radicals in Synthesis I

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Publisher : Springer
ISBN 13 : 9783642068416
Total Pages : 0 pages
Book Rating : 4.0/5 (684 download)

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Book Synopsis Radicals in Synthesis I by : Andreas Gansäuer

Download or read book Radicals in Synthesis I written by Andreas Gansäuer and published by Springer. This book was released on 2010-11-25 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This series presents critical reviews of the present position and future trends in modern chemical research. It contains short and concise reports on chemistry, each written by a world renowned expert. This publication is still valid and useful after five or ten years. Scientists and practitioners in the mentioned fields and in industry will benefit from this series. Further information as well as the electronic version of the whole content is available at: springerlink.com

The Stereochemistry of Isomerization of Organoboranes and the Stereochemistry of Radical Addition Reactions

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Publisher :
ISBN 13 :
Total Pages : 204 pages
Book Rating : 4.:/5 (89 download)

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Book Synopsis The Stereochemistry of Isomerization of Organoboranes and the Stereochemistry of Radical Addition Reactions by : Barbara June Shortreed

Download or read book The Stereochemistry of Isomerization of Organoboranes and the Stereochemistry of Radical Addition Reactions written by Barbara June Shortreed and published by . This book was released on 1962 with total page 204 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Organic Reaction Mechanisms

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Publisher : CRC Press
ISBN 13 : 1351989707
Total Pages : 562 pages
Book Rating : 4.3/5 (519 download)

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Book Synopsis Organic Reaction Mechanisms by : Michael Edenborough

Download or read book Organic Reaction Mechanisms written by Michael Edenborough and published by CRC Press. This book was released on 2017-12-21 with total page 562 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text is designed to teach students how to write organic reaction mechanisms. It starts from the absolute basics - counting the numbers of electrons around a simple atom. Then, in small steps, the text progresses to advanced mechanisms. the end, all the major mechanistic routes have been covered. The text is in the form of interactive sections, which are designed to facilitate the assimilation of the information conveyed, so that by the end the student should already know the contents without the need for extensive revision.

Stereochemistry of Radical Addition Reactions [I.]

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Publisher :
ISBN 13 :
Total Pages : 256 pages
Book Rating : 4.:/5 (89 download)

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Book Synopsis Stereochemistry of Radical Addition Reactions [I.] by : King Lau Howe

Download or read book Stereochemistry of Radical Addition Reactions [I.] written by King Lau Howe and published by . This book was released on 1957 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Radicals in Synthesis III

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Publisher : Springer Science & Business Media
ISBN 13 : 3642281230
Total Pages : 460 pages
Book Rating : 4.6/5 (422 download)

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Book Synopsis Radicals in Synthesis III by : Markus Heinrich

Download or read book Radicals in Synthesis III written by Markus Heinrich and published by Springer Science & Business Media. This book was released on 2012-02-21 with total page 460 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boron-Doped Diamond Electrodes for Electroorganic Chemistry, by Siegfried R. Waldvogel, Stamo Mentizi und Axel Kirste.- Modern Developments in Aryl Radical Chemistry, by Gerald Pratsch und Markus R. Heinrich.- Radical Additions to Chiral Hydrazones: Stereoselectivity and Functional Group Compatibility, by Gregory K. Friestad.- Hydrogen Atom Donors: Recent Developments, by Andreas Gansäuer, Lei Shi, Matthias Otte, Inga Huth, Antonio Rosales, Iris Sancho-Sanz, Natalia M. Padial und J. Enrique Oltra.- Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions? - A Fruitful Interplay Anyway Part 1. Radical Catalysis by Group 4 to Group 7 Elements, by Ullrich Jahn.- Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions? - A Fruitful Interplay Anyway Part 2. Radical Catalysis by Group 8 and 9 Elements, by Ullrich Jahn.- Radicals in Transition Metal Catalyzed Reactions? Transition Metal Catalyzed Radical Reactions?: A Fruitful Interplay Anyway Part 3: Catalysis by Group 10 and 11 Elements and Bimetallic Catalysis, by Ullrich Jahn.-

Advanced Organic Chemistry

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Publisher : Springer Science & Business Media
ISBN 13 : 1461397952
Total Pages : 829 pages
Book Rating : 4.4/5 (613 download)

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Book Synopsis Advanced Organic Chemistry by : Francis A. Carey

Download or read book Advanced Organic Chemistry written by Francis A. Carey and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 829 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this edition, like that of the earlier ones, is to provide the basis for a deeper understanding of the structures of organic compounds and the mechanisms of organic reactions. The level is aimed at advanced undergraduates and beginning graduate students. Our goals are to solidify the student's understanding of basic concepts provided by an introduction to organic chemistry and to present more information and detail, including quantitative information, than can be presented in the first course in organic chemistry. The first three chapters consider the fundamental topi~s of bonding theory, stereochemistry, and conformation. Chapter 4 discusses the techniques that are used to study and characterize reaction mechanisms. Chapter 9 focuses on aromaticity and the structural basis of aromatic stabilization. The remaining chapters consider basic reaction types, including substituent effects and stereochemistry. As compared to the earlier editions, there has been a modest degree of reorganization. The emergence of free-radical reactions in synthesis has led to the inclusion of certain aspects of free-radical chemistry in Part B. The revised chapter, Chapter 12, empha sizes the distinctive mechanistic and kinetic aspects of free-radical reactions. The synthetic applications will be considered in Part B. We have also split the topics of aromaticity and the reactions of aromatic compounds into two separate chapters, Chapters 9 and 10. This may facilitate use of Chapter 9, which deals with the nature of aromaticity, at an earlier stage if an instructor so desires.

Advanced Organic Chemistry

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Publisher : Springer Science & Business Media
ISBN 13 : 1461397979
Total Pages : 817 pages
Book Rating : 4.4/5 (613 download)

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Book Synopsis Advanced Organic Chemistry by : Francis A. Carey

Download or read book Advanced Organic Chemistry written by Francis A. Carey and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 817 pages. Available in PDF, EPUB and Kindle. Book excerpt: The main theme of Part B is the description of synthetically useful reactions and the illustration of their application. We have attempted to update the material to reflect the most important advances in synthetic methodology. Because of the extensive developments in the use of organic derivatives of transition metals, as well as of silicon and tin, we have separated the organometallic material into three chapters. Chapter 7 emphasizes organolithium and organomagnesium chemistry and also considers the group lIB metals. Transition metal chemistry is discussed in Chapter 8, with emphasis on copper and palladium intermediates. In Chapter 9, the carbon-carbon bond-forming reactions of organoboranes, silanes, and stannanes are discussed. The increased importance of free-radical reactions in synthesis has led to the incorporation of a section on radical reactions into Chapter 10, in which carbocations, carbenes, and nitrenes are also discussed. Certainly a major advance in synthetic chemistry during the 1980s was the development of methods for enantioselective synthesis. We have increased the level of attention to stereochemistry in the discussion of many reactions. In areas in which new stereoselective methods have been well developed, such as in aldol condensa tions, hydroboration, catalytic reduction, and epoxidation, we discuss these methods. The final chapter discusses some of the general issues which must be addressed in multistep synthesis and provides some illustrative syntheses which can provide the basis for more detailed study of this aspect of synthetic chemistry.

Pericyclic Reactions

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Publisher :
ISBN 13 : 9780191849558
Total Pages : 118 pages
Book Rating : 4.8/5 (495 download)

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Book Synopsis Pericyclic Reactions by : Ian Fleming

Download or read book Pericyclic Reactions written by Ian Fleming and published by . This book was released on 2015 with total page 118 pages. Available in PDF, EPUB and Kindle. Book excerpt: In contrast to the common ionic and radical reactions of organic chemistry, pericyclic reactions are a third distinct class. They have cyclic transition structures in which all bond-forming and bond-breaking takes place in concert, without the formation of an intermediate.