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Stereochemistry And Organic Reactions
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Book Synopsis Stereochemistry and Organic Reactions by : Dipak Kumar Mandal
Download or read book Stereochemistry and Organic Reactions written by Dipak Kumar Mandal and published by Academic Press. This book was released on 2021-04-21 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stereochemistry and Organic Reactions: Conformation, Configuration, Stereoelectronic Effects and Asymmetric Synthesis provides coverage on the stereochemistry of reactions of all mechanistic types, ranging from ionic, pericyclic and transition metal-catalyzed to radical and photochemical. Chapters cover acyclic molecules, cyclic molecules, the stereochemistry of organic reactions, the perturbation molecular orbital theory for the origin of stereoelectronic effects, and an introduction to the principles of stereoselectivity and hierarchical levels of asymmetric synthesis. Each chapter includes problems that reinforce main themes, making it valuable to students, teachers and researchers working in organic, biological and medicinal chemistry, as well as biologists, pharmacologists, polymer chemists and chemists. Presents a holistic and unified approach to stereochemical understanding and predictions, covering reactions of all mechanistic classes Includes two background chapters on perturbation theory and stereoselective principles, along with asymmetric designs Features novel rules and mnemonics to delineate product stereochemistry Includes up-to-date coverage with over 1300 selective references
Book Synopsis Stereochemistry of Organic Compounds by : D. Nasipuri
Download or read book Stereochemistry of Organic Compounds written by D. Nasipuri and published by New Age International. This book was released on 1994 with total page 596 pages. Available in PDF, EPUB and Kindle. Book excerpt: During Recent Years, Stereochemistry Has Undergone A Phenomenal Growth Both In Theory And Practice, With A Concomitant Increase Of Interest Among The Organic Chemists, Biological Chemists, Medicinal Chemists, And Pharmacologists. The Present Text Provides An Up-To-Date, Coherent; And Comprehensive Account Of The Subject Starting From The Fundamentals And Leading Up To The Latest Development As Far As Practicable. Emphasis Has Been Placed On Symmetry-Based Approach To Molecular Chirality, Stereochemical Terminologies (Modern Stereochemistry Is Replete, With Them), Topicity And Prostereoisomerism, Conformational Analysis, Dynamic Stereochemistry, Chiroptical Properties, And Assignment Of Absolute Configuration To Chiral Molecules.Dynamic Stereochemistry Has Been Discussed With Reference To Conformation-Reactivity Correlation, Stereoselective Syntheses, And Pericyclic Reactions. A Large Cross Section Of Organic Reactions With Stereochemical Implication Has Been Incorporated. Attempts Have Been Made To Familiarise The Readers With Modem Instrumental Techniques, Nuclear Magnetic Resonance In Particular, Used For Stereochemical Investigation. Each Chapter Is Provided With A Summary Which Highlights The Main Points Of The Text. Selective References, Mostly Of Textbooks, Monographs, Review Articles, And Significant Original Papers Have Been Given Extending Sometimes To Early 1991.The Book Is Expected To Fulfil The Long-Felt Need For A Comprehensive Text On Modern Organic Stereochemistry Which Is Conspicuously Absent Since The Publication Of Professor Eliels Book In 1962. The Text May Be Adopted At Any Stage Of The University Teaching And At The Same Time Be Useful To The Practising Organic Chemists.
Book Synopsis Stereochemistry of Organic Compounds by : Ernest L. Eliel
Download or read book Stereochemistry of Organic Compounds written by Ernest L. Eliel and published by John Wiley & Sons. This book was released on 1994-09-28 with total page 1296 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stereochemistry of Organic Compounds The first fully referenced, comprehensive book on this subject in more than thirty years, Stereochemistry of Organic Compounds contains up-to-date coverage and insightful exposition of all important new concepts, developments, and tools in the rapidly advancing field of stereochemistry, including: * Asymmetric and diastereoselective synthesis * Conformational analysis * Properties of enantiomers and racemates * Separation and analysis of enantiomers and diastereoisomers * Developments in spectroscopy (including NMR), chromatography, and molecular mechanics as applied to stereochemistry * Prostereoisomerism * Conceptual foundations of stereochemistry, including terminology and symmetry concepts * Chiroptical properties Written by the leading authorities in the field, the text includes more than 4,000 references, 1,000 illustrations, and a glossary of stereochemical terms.
Book Synopsis Organic Reactions Stereochemistry And Mechanism (Through Solved Problems) by : P S Kalsi
Download or read book Organic Reactions Stereochemistry And Mechanism (Through Solved Problems) written by P S Kalsi and published by New Age International. This book was released on 2007 with total page 612 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Book Provides A Self-Study Of Different Topics Of Organic Chemistry Viab Problem Solving. The Present 4Th Edition Has Been Completely Rewritten According To The Organic Chemistry Syllabus Of The Net (Csir) Examination. This Necessitated The Deletion Of Several Topics From The Third Edition And Incorporation Of New Ones. Emphasis Has Been Laid On A Variety Of New Reactions, Name Reactions, Reagents In Organic Synthesis And Incorporation Of Their Knowledge In The Entire Coverage Of Organic Chemistry In A Unique Way.A Thorough Study Of The Book Is Expected To Help The Student To Excel Not Only In The University Examination Including The Net Examination, But Also In His Learning Of Various Topics And Before Interview Boards. Several Topics Like Aromaticity, Pericyclic Reactions And Heterocyclic Chemistry Have Now Been Brought Up To Date And The Material Provided Is Complete In Itself.The Presentation Has Been So Designed So As To Thread Through The Entire Organic Chemistry By The Application Of The Knowledge Learnt In One Topic To Newer Situations In Other Topics. The Present Revised Edition Also Includes Numerous Important Developments Since The Third Edition Of The Book Was Published.
Book Synopsis Stereochemistry of Organic Compounds by : D. Nasipuri
Download or read book Stereochemistry of Organic Compounds written by D. Nasipuri and published by John Wiley & Sons. This book was released on 1991 with total page 554 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text deals with the new concepts and terminology that have been introduced into the treatment of organic stereochemistry over the last decade. Organic reaction mechanisms, as they relate to stereochemistry, are included, and the pericyclic reaction using the frontier molecular orbital approach is explained. The text does not assume a strong grounding in organic chemistry and will therefore be useful to a broader spectrum of students - both graduate and undergraduate. The volume features numerous illustrations and programmed problems.
Download or read book Stereochemistry written by M. Nógrádi and published by Elsevier. This book was released on 2013-10-22 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stereochemistry: Basic Concepts and Applications is a three-chapter text that introduces the basic principles and concepts of stereochemistry, as well as its application to organic chemistry application. Chapter 1 describes first the stereochemistry of the ground state, specifically the configuration and conformation of organic compounds, as well as the most important methods for its investigation. This chapter also deals with the kinetics of conformational changes and provides an overview of the so-called "applied stereochemistry". Chapter 2 focuses on the analysis of the internal motions of the molecules and of the corresponding activation energies. This chapter also examines the principles of intramolecular symmetry. Chapter 3 considers the stereochemical aspect of several enzymic processes and the stereoisomerism of monotonic polymers and inorganic complexes. This book will be of great value to organic chemists and organic chemistry graduate students.
Book Synopsis Introduction to Stereochemistry by : Kurt Mislow
Download or read book Introduction to Stereochemistry written by Kurt Mislow and published by Courier Corporation. This book was released on 2012-06-11 with total page 210 pages. Available in PDF, EPUB and Kindle. Book excerpt: Molecular shape, form, and symmetry play a central role in organic chemistry, and this text presents a brief introduction to the conceptual basis of stereochemistry. Its focus lies in the fundamentals of structural stereochemistry, rather than the dynamic aspects that are more relevant to reaction mechanisms. The three-part treatment deals with structure and symmetry, stereoisomerism, and the separation and configuration of stereoisomers. The first section reviews molecular architecture, relating empirical bonding geometries to the hybridization of the central carbon atom. Students receive a nonrigorous treatment of symmetry elements and point groups, with particular focus on the presence or absence of reflection symmetry. The second section classifies stereoisomers according to symmetry properties and to the nature of their barriers; it also discusses the dependence of optical activity on structure and concludes with an examination of topological isomerism. The third and final section explores the conceptual basis of asymmetric syntheses and kinetic resolutions. Each of the major sections features a series of exercises that reinforce and extend the preceding material, and answers are provided. Preface to the Dover edition. Answers to Exercises. Bibliography. Index.
Book Synopsis Organic Mechanisms by : Reinhard Bruckner
Download or read book Organic Mechanisms written by Reinhard Bruckner and published by Springer Science & Business Media. This book was released on 2010-01-20 with total page 873 pages. Available in PDF, EPUB and Kindle. Book excerpt: This English edition of a best-selling and award-winning German textbook Reaction Mechanisms: Organic Reactions · Stereochemistry · Modern Synthetic Methods is aimed at those who desire to learn organic chemistry through an approach that is facile to understand and easily committed to memory. Michael Harmata, Norman Rabjohn Distinguished Professor of Organic Chemistry (University of Missouri) surveyed the accuracy of the translation, made certain contributions, and above all adapted its rationalizations to those prevalent in the organic chemistry community in the English-speaking world. Throughout the book fundamental and advanced reaction mechanisms are presented with meticulous precision. The systematic use of red "electron-pushing arrows" allows students to follow each transformation elementary step by elementary step. Mechanisms are not only presented in the traditional contexts of rate laws and substituent effects but, whenever possible, are illustrated using practical, useful and state-of-the-art reactions. The abundance of stereoselective reactions included in the treatise makes the reader familiar with key concepts of stereochemistry. The fundamental topics of the book address the needs of upper-level undergraduate students, while its advanced sections are intended for graduate-level audiences. Accordingly, this book is an essential learning tool for students and a unique addition to the reference desk of practicing organic chemists, who as life-long learners desire to keep abreast of both fundamental and applied aspects of our science. In addition, it will well serve ambitious students in chemistry-related fields such as biochemistry, medicinal chemistry and pharmaceutical chemistry. From the reviews: "Professor Bruckner has further refined his already masterful synthetic organic chemistry classic; the additions are seamless and the text retains the magnificent clarity, rigour and precision which were the hallmark of previous editions. The strength of the book stems from Professor Bruckner’s ability to provide lucid explanations based on a deep understanding of physical organic chemistry and to limit discussion to very carefully selected reaction classes illuminated by exquisitely pertinent examples, often from the recent literature. The panoply of organic synthesis is analysed and dissected according to fundamental structural, orbital, kinetic and thermodynamic principles with an effortless coherence that yields great insight and never over-simplifies. The perfect source text for advanced Undergraduate and Masters/PhD students who want to understand, in depth, the art of synthesis ." Alan C. Spivey, Imperial College London "Bruckner’s ‘Organic Mechanisms’ accurately reflects the way practicing organic chemists think and speak about organic reactions. The figures are beautifully drawn and show the way organic chemists graphically depict reactions. It uses a combination of basic valence bond pictures with more sophisticated molecular orbital treatments. It handles mechanisms both from the "electron pushing perspective" and from a kinetic and energetic view. The book will be very useful to new US graduate students and will help bring them to the level of sophistication needed to be serious researchers in organic chemistry." Charles P. Casey, University of Wisconsin-Madison "This is an excellent advanced organic chemistry textbook that provides a key resource for students and teachers alike." Mark Rizzacasa, University of Melbourne, Australia.
Book Synopsis Guide to Organic Stereochemistry by : Sheila R. Buxton
Download or read book Guide to Organic Stereochemistry written by Sheila R. Buxton and published by Prentice Hall. This book was released on 1996 with total page 268 pages. Available in PDF, EPUB and Kindle. Book excerpt: Takes the reader step-by-step from the structures of simple molecules, such as methane, to the basic shapes of biologically important macromolecules, such as proteins and nucleic acids. Deals with the concept of chirality, which is often overlooked by many texts. Chirality is approached by firstly explaining the stereochemistry of compounds with one stereogenic centre, then dealing with compounds having two or more stereogenic centres before focusing on compounds possessing axes of chirality. The importance of stereochemistry in a wide variety of transformations (for example addition reactions, eliminations, and cycloadditions), is discussed. The final chapters describe the application of stereocontrol in asymmetric synthesis, indicating the use of chiral auxiliaries and chiral catalysts in modern chemistry.
Book Synopsis Basic Concepts in Organic Stereochemistry by : Sunil Kumar Talapatra
Download or read book Basic Concepts in Organic Stereochemistry written by Sunil Kumar Talapatra and published by Springer Nature. This book was released on 2023-01-01 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book discusses essential stereochemical concepts associated with organic molecules (natural or synthetic), as reflected in the course of their many reactions, their mechanisms, their asymmetric synthesis, biosynthesis, and biological activities. This treatise provides useful insights and understanding of the chiral/achiral designations (nomenclatures), the stereochemical features, and related properties of the natural and synthetic products. Without having an adequate knowledge of stereochemical concepts, it will not be possible to understand and appreciate the stereochemistry of natural or synthetic products. Thus, essential static and dynamic aspects of stereochemistry with sufficient illustrative examples along with discussions are presented. The structure of the monograph allows for easy selection of separate topics for reading and teaching. This book will also provide an idea of basic stereochemical concepts, as applied to organic molecules in general as well as to organic ligands in coordination complexes, and will, therefore, be valuable resources to teachers and students of advanced undergraduates and post-graduates, researchers, and professionals.
Book Synopsis Stereochemistry of Organic Compounds by : V.K. Ahluwalia
Download or read book Stereochemistry of Organic Compounds written by V.K. Ahluwalia and published by Springer Nature. This book was released on 2022-01-04 with total page 615 pages. Available in PDF, EPUB and Kindle. Book excerpt: This textbook provides a simple approach to understand the various complex aspects of stereochemistry. It deals with basic static stereochemistry and gives an overview of the different isomeric forms and nomenclatures. With simple writing style and many examples, this book covers the topics such as stereochemistry of hydrocarbons, alkenes, cycloalkenes, optically active compounds, trivalent carbon, fused, bridged and caged rings and related compounds. This textbook also covers the additional topics such as optical rotatory dispersion and circular dichroism, steroechemistry of elimination reactions, substitution reactions, rearrangement reactions and pericyclic reactions. The book includes pedagogical features like end-of-chapter problems and key concepts to help students in self-learning. The textbook is extremely useful for the senior undergraduate and postgraduate students pursuing course in chemistry, especially organic chemistry. Besides, this book will also be a useful reference book for professionals working in various chemical industries, biotechnology, bioscience and pharmacy.
Book Synopsis Organic Stereochemistry by : Hua-Jie Zhu
Download or read book Organic Stereochemistry written by Hua-Jie Zhu and published by John Wiley & Sons. This book was released on 2015-08-10 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: Adopting a novel approach to the topic by combining theoretical knowledge and practical results, this book presents the most popular and useful computational and experimental methods applied for studying the stereochemistry of chemical reactions and compounds. The text is clearly divided into three sections on fundamentals, spectroscopic and computational techniques, and applications in organic synthesis. The first part provides a brief introduction to the field of chirality and stereochemistry, while the second part covers the different methodologies, such as optical rotation, electronic circular dichroism, vibrational circular dicroism, and Raman spectroscopy. The third section then goes on to describe selective examples in organic synthesis, classified by reaction type, i.e. enantioselective, chemoselective and stereoselective reactions. A final chapter on total synthesis of natural products rounds off the book. A valuable reference for researchers in academia and industry working in the field of organic synthesis, computational chemistry, spectroscopy or medicinal chemistry.
Book Synopsis Stereochemistry Conformation and Mechanism by : P. S. Kalsi
Download or read book Stereochemistry Conformation and Mechanism written by P. S. Kalsi and published by New Age International. This book was released on 2008 with total page 41 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stereochemistry has always occupied a central position and is pivotal to the practice of organic chemistry. A solid understanding of this subject is indeed critical to subsequent success in a science career. Stereochemistry is, therefore, a core constituent both at the undergraduate and postgraduate chemistry courses. This seventh edition is extensively revised and enlarged by adding new material to take account of recent developments and extensive amendments have been made to improve clarity. The key features of this new addition are: a brand new design. Incorporation of basic principles in boxes directly links the students to the main text;, and a large number of exercises with their solutions have been now added in each chapter. These exercises are set at appropriate places so that the students can test their command of a particular topic. New problems have been added at the end of each chapter. Chemical illustrations have been modified and developed for clarity and information. Generally the figures contain text as well, to decrease the need to refer back and forth to the text and for better understanding.
Book Synopsis Computer Representation of the Stereochemistry of Organic Molecules by : DAVIS
Download or read book Computer Representation of the Stereochemistry of Organic Molecules written by DAVIS and published by Birkhäuser. This book was released on 2013-11-11 with total page 149 pages. Available in PDF, EPUB and Kindle. Book excerpt: The role of the computer in the practice of organic chemistry has been firmly established over the past decade. Its uses as a large scale information storage and retrieval device in chemistry have been too numerous to mention. More recently, the applicability of computers to the problem of discovering valid and reasonable synthesis routes for organic molecules has been demonstrated. This has been both as an adjunct to the 1 chemist in the on-line interactive mode ,2,3 and also as a wholly computer-directed system seeking to simulate the intelligent prob- 4 lem-solving activity of the human organic synthetic chemist. ,5 In all of these computer applications to organic chemistry, it has been necessary to devise some computer-compatible repres- tation of an organic molecule that is both canonical and c- venient for table look-ups. This is in order that entities that have been constructed at different times under different circumstances can be identified and classified, with identical molecules being recognized as such even if their connection matrices list the elements of the molecule in different orders. E. J. Corey and W. T. Wipke, Science, 166, 178 (1969). 2 E. J. Corey, W. T. Wipke, R. D. Cramer III and W. J. Howe, J. Americ. Chern. Soc. , 94, 421 (1972) and 431 (1972). 3 E. J. Corey, R. D. Cramer III and W. J. Howe, ~. Americ. Chern. Soc. , 94, 440 (1972). 4 H. L. Gelernter, N. S. Sridharan and A. J.
Book Synopsis Basic Organic Stereochemistry by : Ernest L. Eliel
Download or read book Basic Organic Stereochemistry written by Ernest L. Eliel and published by Wiley-Interscience. This book was released on 2001-04-11 with total page 712 pages. Available in PDF, EPUB and Kindle. Book excerpt: A Practical Introduction to Stereochemistry Stereoisomers are compounds with the same chemical formula and connectivity but with different arrangements of their atoms in 3-dimensional space. Stereochemistry encompasses the study of stereoisomers and their properties. Despite having an identical chemical formula, stereoisomers can have drastically different biological, medicinal, and chemical properties. Basic Organic Stereochemistry explains in clear, concise terms the concepts and properties of stereoisomers. Ideal both as a text for advanced undergraduate or graduate students and as a handy guide for researchers in industry, this superb text covers: * Polarimetry and optical rotation * Internal coordinates, configuration, and conformation * Nature of stereoisomers * Barriers between stereoisomers and residual stereoisomers * Symmetry operators and symmetry point groups * Properties of stereoisomers and stereoisomer discrimination * Separation of stereoisomers, resolution, and racemization Suitable for students in organic and biological chemistry, Basic Organic Stereochemistry is unparalleled as a convenient text.
Book Synopsis Stereochemistry of Radical Reactions by : Dennis P. Curran
Download or read book Stereochemistry of Radical Reactions written by Dennis P. Curran and published by John Wiley & Sons. This book was released on 2008-09-26 with total page 294 pages. Available in PDF, EPUB and Kindle. Book excerpt: As little as a decade ago, radicals were regarded as interesting reactive intermediates with little synthetic use. However, recent results show that radicals have an enormous potential for applications in stereoselective reactions - it's all a matter of knowing what method to use and how to apply it. Three world experts in the field have combined their expertise and present the concepts to understand and even to predict the course of stereoselective radical reactions. In addition, guidelines are established which will enable the readers to plan and carry out their own stereoselective syntheses with radicals. A comprehensive list of references provides an easy access to the primary literature. The Stereochemistry of Radical Reactions is a highly topical introduction to this burgeoning field of research. Both advanced students and researchers active in the field will welcome this book as a source of concepts and ideas.
Book Synopsis Stereochemistry and Mechanism Through Solved Problems by : P. S. Kalsi
Download or read book Stereochemistry and Mechanism Through Solved Problems written by P. S. Kalsi and published by . This book was released on 1994-01-01 with total page 342 pages. Available in PDF, EPUB and Kindle. Book excerpt:
