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Some Cationic Complexes Of Rhodium And Iridium
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Book Synopsis Some Cationic Complexes of Rhodium and Iridium by : T. A. Kuc
Download or read book Some Cationic Complexes of Rhodium and Iridium written by T. A. Kuc and published by . This book was released on 1973 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Catalytic Decarbonylation of Aldehydes Via Cationic Iridium and Rhodium (I) Complexes by : John Francis Genus
Download or read book The Catalytic Decarbonylation of Aldehydes Via Cationic Iridium and Rhodium (I) Complexes written by John Francis Genus and published by . This book was released on 1985 with total page 120 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Cobalt Rhodium and Iridium Cationic Complexes of Cyclic Polyolefins by : S. F. W. Lowrie
Download or read book Cobalt Rhodium and Iridium Cationic Complexes of Cyclic Polyolefins written by S. F. W. Lowrie and published by . This book was released on 1975 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Iridium Complexes in Organic Synthesis by : Luis A. Oro
Download or read book Iridium Complexes in Organic Synthesis written by Luis A. Oro and published by John Wiley & Sons. This book was released on 2008-12-03 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ranging from hydrogenation to hydroamination, cycloadditions and nanoparticles, this first handbook to comprehensively cover the topic of iridium in synthesis discusses the important advances in iridium-catalyzed reactions, namely the use of iridium complexes in enantioselective catalysis. A must for organic, complex and catalytic chemists, as well as those working with/on organometallics.
Book Synopsis The Chemistry of Ruthenium, Rhodium, Palladium, Osmium, Iridium and Platinum by : Stanley E. Livingstone
Download or read book The Chemistry of Ruthenium, Rhodium, Palladium, Osmium, Iridium and Platinum written by Stanley E. Livingstone and published by Elsevier. This book was released on 2017-01-31 with total page 225 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Ruthenium, Rhodium, Palladium, Osmium, Iridium and Platinum
Book Synopsis Synthesis and Characterization of Some Rhodium and Iridium Alkyl Complexes by : Matthew Albert Kulzick
Download or read book Synthesis and Characterization of Some Rhodium and Iridium Alkyl Complexes written by Matthew Albert Kulzick and published by . This book was released on 1984 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Cationic Binuclear Rhodium and Iridium Complexes by : Steven H. DeVries
Download or read book Cationic Binuclear Rhodium and Iridium Complexes written by Steven H. DeVries and published by . This book was released on 1981 with total page 114 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Synthesis and Characterization of Some Cationic Rhodium (III) Complexes Containing Ditertiary Arsines by : Edward Julius Davis
Download or read book The Synthesis and Characterization of Some Cationic Rhodium (III) Complexes Containing Ditertiary Arsines written by Edward Julius Davis and published by . This book was released on 1973 with total page 76 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Complexes Diène Du Rhodium Et de L'iridium Portant Des Ligands Diphénylphosphinoferrocényl Thioéther by : Ekaterina Kozinets
Download or read book Complexes Diène Du Rhodium Et de L'iridium Portant Des Ligands Diphénylphosphinoferrocényl Thioéther written by Ekaterina Kozinets and published by . This book was released on 2015 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: New diene rhodium complexes with diphenylphosphinoferrocenylthioether ligands [Rh(P,SR)(diene)]X (diene = COD, NBD; X = Cl-, BF4-) were synthesized and fully characterized. The molecular structure of the cationic complexes [Rh(P,SR)(diene)]+BF4- shows a slightly distorted square planar geometry. For the chloride complexes, [Rh(P,SR)(diene)Cl], a combination of NMR and IR spectroscopy and DFT calculations points to a four coordinate square planar geometry with the diene ligand, the chlorine and the phosphorus atoms in the coordination sphere and with a dangling thioether function. It was found that rhodium complexes [Rh(P,SR)(diene)]X are good structural and functional models to study the ketone asymmetric hydrogenation mechanism catalyzed by the iridium complexes [Ir(P,SBut)(COD)Cl]. For the [Rh(P,SBut)(diene)]X derivatives the rate of hydrogenation and the nantioselectivity change in the order COD-Cl > COD-BF4 > NBD-BF4 > NBD-Cl. For the complexes with the NBD ligand the activity/enantioselectivity change in the order But ” Et > Ph > Bz. By use of parahydrogen NMR spectrometry, it was established that the catalyst activation involves the reaction of the rhodium complexes [Rh(P,SBut)(diene)]X with dihydrogen, which occurs in two steps through the generation of an intermediate [Rh(P,SR)(alkene-alkyl)]([Rh(P,SR)(1-kappa-4,5-eta-C8H13)] for the COD complexes) followed by the formation of a solvated complex [Rh(P,SR)(Solv)2]+ (Solv = MeOH, MeCN, acetone). Hydrogenation of the NBD ligand proceeds faster than that of the COD ligand. The rhodium complex [Rh(P,SBut)(MeOH)2]+ promotes a very rapid H/D exchange between H2 and the deuterated solvent via a dihydride species [Rh(P,SBut)(MeOH)2H2]+, which is accessible according to the DFT calculations. Addition of L (py or MeCN) to the solution of [Rh(P,SBut)(diene)]X in the presence of H2 at low temperature results in the formation of a diastereomeric dihydride species [Rh(P,SBut)L2H2]+, the structure of which was established on the basis of the NMR spectroscopic data.
Book Synopsis Medicinal Organometallic Chemistry by : Gérard Jaouen
Download or read book Medicinal Organometallic Chemistry written by Gérard Jaouen and published by Springer Science & Business Media. This book was released on 2010-09-14 with total page 305 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contents: Gérard Jaouen, Nils Metzler-Nolte : Introduction ; Stéphane GIBAUD and Gérard JAOUEN: Arsenic - based drugs: from Fowler’s solution to modern anticancer chemotherapy; Ana M. Pizarro, Abraha Habtemariam and Peter J. Sadler : Activation Mechanisms for Organometallic Anticancer Complexes; Angela Casini, Christian G. Hartinger, Alexey A. Nazarov, Paul J. Dyson : Organometallic antitumour agents with alternative modes of action; Elizabeth A. Hillard, Anne Vessières, Gerard Jaouen : Ferrocene functionalized endocrine modulators for the treatment of cancer; Megan Hogan and Matthias Tacke : Titanocenes – Cytotoxic and Anti-Angiogenic Chemotherapy Against Advanced Renal-Cell Cancer; Seann P. Mulcahy and Eric Meggers : Organometallics as Structural Scaffolds for Enzyme Inhibitor Design; Christophe Biot and Daniel Dive : Bioorganometallic Chemistry and Malaria; Nils Metzler-Nolte : Biomedical applications of organometal-peptide conjugates; Roger Alberto : Organometallic Radiopharmaceuticals; Brian E. Mann : Carbon Monoxide – an essential signaling molecule.
Book Synopsis Synthesis and Organometallic Chemistry of Rhodium and Iridium Complexes of Macrocyclic PCP and POCOP Pincer Ligands by : Baptiste Leforestier
Download or read book Synthesis and Organometallic Chemistry of Rhodium and Iridium Complexes of Macrocyclic PCP and POCOP Pincer Ligands written by Baptiste Leforestier and published by . This book was released on 2020 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Comprehensive Organometallic Chemistry II: Cobalt, rhodium, and iridium by :
Download or read book Comprehensive Organometallic Chemistry II: Cobalt, rhodium, and iridium written by and published by . This book was released on 1995 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Analytical Chemistry of the Noble Metals by : F. E. Beamish
Download or read book The Analytical Chemistry of the Noble Metals written by F. E. Beamish and published by Elsevier. This book was released on 2013-10-22 with total page 624 pages. Available in PDF, EPUB and Kindle. Book excerpt: Analytical Chemistry, Volume 24: The Analytical Chemistry of the Noble Metals describes the procedures for the separation, extraction, and analysis of noble metals. This book is composed of seven chapters, and begins with a survey on the influence of metallurgical factors on the susceptibility of platinum and gold metals to various corrosive agents. The succeeding chapter provides the methods of isolation of osmium and ruthenium from associated platinum metals and from base metals. A chapter examines the application of gravimetric methods for the separation of seven noble metals, including ruthenium, osmium, rhodium, iridium, palladium, platinum, and gold. Other chapters consider the procedures for volumetric, spectrophotometric, and spectrochemical analysis of noble metals. The concluding chapter describes the features and attributes of the equipment for noble metal analysis. This book is of value to analytical chemists and workers and researchers in metallurgy.
Book Synopsis Synthesis and Organometallic Chemistry of Rhodium and Iridium Complexes of Macrocyclic PNP and PONOP Pincer Ligands by : Thomas M. Hood
Download or read book Synthesis and Organometallic Chemistry of Rhodium and Iridium Complexes of Macrocyclic PNP and PONOP Pincer Ligands written by Thomas M. Hood and published by . This book was released on 2020 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Polyhedron written by and published by . This book was released on 1987 with total page 1564 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Organometallic Chemistry by : Ionel Haiduc
Download or read book Organometallic Chemistry written by Ionel Haiduc and published by Walter de Gruyter GmbH & Co KG. This book was released on 2022-05-09 with total page 608 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides the reader with a comprehensive introduction to the topic of organometallic chemistry. With an easy to follow structure covering both nontransition metals and transition metals as well as the applications of organometallic reagents in organic synthesis, this book is a must-have for the organometallic chemist.
Book Synopsis The Chemistry and Crystal Structures of Some Phosphino-ether Complexes of Rhodium and Iridium by : John Cutliffe Jeffery
Download or read book The Chemistry and Crystal Structures of Some Phosphino-ether Complexes of Rhodium and Iridium written by John Cutliffe Jeffery and published by . This book was released on 2020 with total page 510 pages. Available in PDF, EPUB and Kindle. Book excerpt: