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Soft X Ray Emission And Resonant Inelastic Scattering Study Of Polycyclic Hydrocarbons
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Book Synopsis Soft X-ray emission and resonant inelastic scattering study of polycyclic hydrocarbons by : Ricardo Scherer
Download or read book Soft X-ray emission and resonant inelastic scattering study of polycyclic hydrocarbons written by Ricardo Scherer and published by GRIN Verlag. This book was released on 2019-08-27 with total page 139 pages. Available in PDF, EPUB and Kindle. Book excerpt: Doctoral Thesis / Dissertation from the year 2002 in the subject Physics - Experimental Physics, grade: 1, University of Cologne (2. Physikalisches Institut), language: English, abstract: This thesis comprises a detailed study of the electronic properties of the polycyclic hydrocarbons tetracene, perylene and coronene. The at room temperature grown organic layers consisted of a up to several hundred nanometer thickness, and have been studied with the experimental techniques soft x-ray emission spectroscopy (SXES) and NEXAFS-spectroscopy by means of synchrotron radiation. In particular, resonant inelastic scattering (RIXS) was employed in order to obtain possible band structure or MO-symmetry information of the studied systems. The studied materials consist of large organic molecules, evaporated under high vacuum on silicon wafers. The goal was to figure out, whether inside these organic layers the hydrocarbon molecules polymerize and form a band structure or if the hydrocarbon molecules do not interact with each other and retain their original molecular like symmetry and behavior. The discrete peaks in the hydrocarbon NEXAFS-spectra could be assigned by comparison with the literature to chemical shifted C1s→ π∗ transitions, caused by different chemical surrounded C-atoms. Hence, due to excitation on a certain π∗-resonance only C1s-electrons of equal C-atoms can be excited, which leads to a site selective excitation. The fluorescent decay of the created hole, which is as well localized on these former excited C-atoms was recorded energy dispersed in the SXE-spectrometer. This method is usually referred to as SXE. Therefore, the local MO-density was recorded. Hartree-Fock based ground state MO-calculations have been performed for each molecule, in order to simulate the SXE-spectra. Good agreement between experiment and simulation was shown, under the strict retainment of symmetry selection rules along the transitions. This result states, that the different hydrocarbon molecules conserve their symmetry and structure in an up to several hundred nanometer thick organic layer. Only in the region of the valence band maximum (π-states) weak indications for a band dispersion could be observed.
Book Synopsis Resonant Inelastic X-ray Scattering at Small Hydrocarbon Molecules by : Franz Hennies
Download or read book Resonant Inelastic X-ray Scattering at Small Hydrocarbon Molecules written by Franz Hennies and published by . This book was released on 2006 with total page 170 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Polycyclic Aromatic Hydrocarbons by :
Download or read book Polycyclic Aromatic Hydrocarbons written by and published by National Academies Press. This book was released on 1983-01-01 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Quasi-zero Dimensional CuB2O4 written by and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: We explore the general phenomenology of resonant inelastic scattering (RIXS) using CuB2O4, a network of CuO4 plaquettes electronically isolated by B{sup +3} ions. Spectra show a small number of well-separated features, and we exploit the simple electronic structure to explore RIXS phenomenology by developing a calculation which allows for intermediate-state effects ignored in standard approaches. These effects are found to be non-negligible and good correspondence between our model and experiment leads to a simple picture of such phenomenology as the genesis of d --> d excitations at the K edge and intermediate-state interference effects.
Book Synopsis Polycyclic Aromatic Hydrocarbons and Astrophysics by : A. Léger
Download or read book Polycyclic Aromatic Hydrocarbons and Astrophysics written by A. Léger and published by Springer. This book was released on 2011-09-26 with total page 402 pages. Available in PDF, EPUB and Kindle. Book excerpt: The near Infra-Red emission of the Interstellar Medium is a very puzzling subject. In the brightest regions, where spectroscopic observa tions are possible from the ground, several bands (3.3 - 3.4 - 6.2 - 7.7 - 8.6 - 11.3 ~m) have been observed since 1973. The absence of satisfying explanation was so obvious that they were called "Unidenti fied IR Emission Bands". The puzzle still increased when were known the first results of the general IR sky survey made by the satellite IRAS. On a large scale, the near IR emission of the Interstellar medium was expected to be very small but it was observed to be about one third of the total IR emission for our own galaxy ..• The situation has moved in 1984 when it was suggested that a class of stable organic molecules, the Polycyclic Aromatic Hydrocarbons (PAH's) could be at the origin of this near IR emission. Initially based on the required refractory character of particules that should be heated to high temperature without subliming, this hypothesis leads to a sugges tive spectroscopic similarity with the observed astronomical bands. This hypothesis is attractive and it has many implications, for ins tance, the PAHs would be the most abundant organic molecules in the universe. However, many points have to be clarified and the different consequences of this suggestion should be explored.
Book Synopsis Development of Resonant Inelastic X-ray Scattering Spectroscopy by : Sarah Hobbs
Download or read book Development of Resonant Inelastic X-ray Scattering Spectroscopy written by Sarah Hobbs and published by . This book was released on 2012 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Chemical Abstracts written by and published by . This book was released on 2002 with total page 2364 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Publications by : United States. National Bureau of Standards
Download or read book Publications written by United States. National Bureau of Standards and published by . This book was released on 1969 with total page 788 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Publications of the National Institute of Standards and Technology ... Catalog by : National Institute of Standards and Technology (U.S.)
Download or read book Publications of the National Institute of Standards and Technology ... Catalog written by National Institute of Standards and Technology (U.S.) and published by . This book was released on 1970 with total page 554 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Energy Research Abstracts written by and published by . This book was released on 1987 with total page 718 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book NBS Special Publication written by and published by . This book was released on 1968 with total page 800 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Scientific and Technical Aerospace Reports by :
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on with total page 1050 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Hydrogen in Matter by : Ganapati Rao Myneni
Download or read book Hydrogen in Matter written by Ganapati Rao Myneni and published by American Institute of Physics. This book was released on 2006-06-09 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrogen plays a key role in materials, beneficial in some cases, problematic in others. A detailed understanding of hydrogen-based interactions is vital to improvements and possible new applications. This book presents the proceedings of the International Symposium on Hydrogen in Matter (ISOHIM) incorporating contributions focused on semiconductors, normal metal conductors, superconductors, and vacuum systems that deal with hydrogen-matter issues. Broad discussion includes liquid hydrogen storage containers for hydrogen powered vehicles.
Book Synopsis Publications of the National Bureau of Standards by : United States. National Bureau of Standards
Download or read book Publications of the National Bureau of Standards written by United States. National Bureau of Standards and published by . This book was released on 1968 with total page 544 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Publications of the National Bureau of Standards ... Catalog by : United States. National Bureau of Standards
Download or read book Publications of the National Bureau of Standards ... Catalog written by United States. National Bureau of Standards and published by . This book was released on 1968 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Publications of the National Bureau of Standards, 1968-1969 by : Betty L. Oberholtzer
Download or read book Publications of the National Bureau of Standards, 1968-1969 written by Betty L. Oberholtzer and published by . This book was released on 1970 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Comprehensive Dissertation Index by :
Download or read book Comprehensive Dissertation Index written by and published by . This book was released on 1973 with total page 964 pages. Available in PDF, EPUB and Kindle. Book excerpt: