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Author : Hong Hua
Publisher :
ISBN 13 :
Total Pages : 214 pages
Book Rating : 4.:/5 (647 download)
Download or read book Semi-continuous Emulsion Copolymerization of Styrene-butyl Acrylate with Methacrylic Acid written by Hong Hua and published by . This book was released on 2008 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : V. I. Eliseeva
Publisher : Springer Science & Business Media
ISBN 13 : 1468416413
Total Pages : 231 pages
Book Rating : 4.4/5 (684 download)
Download or read book Emulsion Polymerization and Its Applications in Industry written by V. I. Eliseeva and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 231 pages. Available in PDF, EPUB and Kindle. Book excerpt: There is a large body of Soviet work on emulsion polymerization, spanning a period of over three decades, that has been published primarily in the Russian language. Most of this has remained untranslated into English and hence un available to most other scientists. The value of this book lies primarily in the fact that it brings together the most important of these Soviet contributions, along with comment and analysis by the authors, who may be considered among the foremost authorities in this field in the Soviet Union. But the hundreds of literature citations go far beyond the borders of the Soviet Union and serve as an excellent bibliography of the world literature on emulsion polymerization up to the time this book was written. The book covers both fundamental and applied aspects. In the former are included discussions of particle formation mechanisms, a comprehensive theory of emulsion polymerization, copolymerization of polar monomers, and particle morphology and its implications with regard to derived film properties. Among the applied aspects are discussions of continuous emulsion polymerization, both tubular reactors and continuous stirred tank cascades, and various aspects con cerning the manufacture of some of the most important monomers, such as styrene, butadiene, vinyl acetate, methyl methacrylate, acrylonitrile, and chloroprene. This book will be an indispensable reference source for scientists who are entering the field as well as those who are experienced and who have wanted a ready access to this large body of literature.
Author : Mohamed S. El-Aasser
Publisher : Springer Science & Business Media
ISBN 13 : 9400981147
Total Pages : 250 pages
Book Rating : 4.4/5 (9 download)
Download or read book Emulsion Polymerization of Vinyl Acetate written by Mohamed S. El-Aasser and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 250 pages. Available in PDF, EPUB and Kindle. Book excerpt: It is particularly appropriate that this symposium on the emulsion polymeriza tion of vinyl acetate was held in recognition of the industrial importance of poly(vinyl acetate) and vinyl acetate copolymers, and their rather unique properties among emulsion polymers in general. Poly( vinyl acetate) latexes were the first synthetic polymer latexes to be made on a commercial scale: their production using polyvinyl alcohol as emulsifier began in Germany during the mid-1930s and has continued to the present day, growing steadily with the years. Indeed, poly(vinyl acetate) latexes prepared with polyvinyl alcohol are still one of the mainstays of the adhesives industry. With the passing of time, however, vinyl acetate copolymers have been developed: copolymers with maleate esters such as dibutyl maleate, acrylate esters such as ethyl acrylate and butyl acrylate, versatic acid esters, and, more recently, ethylene. These versatile copolymers have found increasing use in more sophisticated adhesives with specialized properties, adhesives for clay coatings on paper, carpet backing, and interior and exterior paints. Thus more than 45 years after the first commercial production of vinyl acetate latexes, their use is still growing, both in actual quantities and different applications. The industrial importance of vinyl acetate latexes makes the mechanism and kinetics of their emulsion polymerization of practical as well as scientific interest.
Author : Ki-Chang Lee
Publisher :
ISBN 13 :
Total Pages : 338 pages
Book Rating : 4.:/5 (18 download)
Download or read book Batch and Semi-continuous Emulsion Copolymerization of Vinylidene Chloride and N-butyl Methacrylate written by Ki-Chang Lee and published by . This book was released on 1987 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : David R. Bassett
Publisher :
ISBN 13 :
Total Pages : 632 pages
Book Rating : 4.:/5 (44 download)
Download or read book Emulsion Polymers and Emulsion Polymerization written by David R. Bassett and published by . This book was released on 1981 with total page 632 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Yildirim H. Erbil
Publisher : CRC Press
ISBN 13 : 142003880X
Total Pages : 338 pages
Book Rating : 4.4/5 (2 download)
Download or read book Vinyl Acetate Emulsion Polymerization and Copolymerization with Acrylic Monomers written by Yildirim H. Erbil and published by CRC Press. This book was released on 2000-03-22 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt: The versatility of the emulsion copolymerization reaction and the ability to control the properties of the final latices have led to rapid expansion both in the quantity of polyvinylacetate and vinyl acetate-acrylic copolymer latices and in their applications. Vinyl Acetate Emulsion Polymerization and Copolymerization with Acrylic Monomers provides
Author : Christopher D. Anderson
Publisher : iSmithers Rapra Publishing
ISBN 13 : 9781859573815
Total Pages : 160 pages
Book Rating : 4.5/5 (738 download)
Download or read book Emulsion Polymerisation and Latex Applications written by Christopher D. Anderson and published by iSmithers Rapra Publishing. This book was released on 2003 with total page 160 pages. Available in PDF, EPUB and Kindle. Book excerpt: The term latex covers emulsion polymers, polymer dispersions and polymer colloids. This review report provides a general overview of the emulsion polymerisation processes and explains how the resulting latices are used in industrial applications. The classes of emulsion polymers are surveyed and the commercial technologies and potential future uses discussed. An additional indexed section containing several hundred abstracts from the Polymer Library gives useful references for further reading.
Author : Glenn Lewis Shoaf
Publisher :
ISBN 13 :
Total Pages : 188 pages
Book Rating : 4.:/5 (162 download)
Download or read book Feasibility Study for Continuous Emulsion Copolymerization of Ethyl Acrylate and Methacrylic Acid written by Glenn Lewis Shoaf and published by . This book was released on 1987 with total page 188 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :
Publisher : ScholarlyEditions
ISBN 13 : 1464927162
Total Pages : 134 pages
Book Rating : 4.4/5 (649 download)
Download or read book Benzylidene Compounds: Advances in Research and Application: 2011 Edition written by and published by ScholarlyEditions. This book was released on 2012-01-09 with total page 134 pages. Available in PDF, EPUB and Kindle. Book excerpt: Benzylidene Compounds: Advances in Research and Application: 2011 Edition is a ScholarlyEditions™ eBook that delivers timely, authoritative, and comprehensive information about Benzylidene Compounds. The editors have built Benzylidene Compounds: Advances in Research and Application: 2011 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Benzylidene Compounds in this eBook to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Benzylidene Compounds: Advances in Research and Application: 2011 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.
Author : Gary W. Poehlein
Publisher : Springer
ISBN 13 : 9401747970
Total Pages : 271 pages
Book Rating : 4.4/5 (17 download)
Download or read book Science and Technology of Polymer Colloids written by Gary W. Poehlein and published by Springer. This book was released on 2013-12-19 with total page 271 pages. Available in PDF, EPUB and Kindle. Book excerpt: Science and Technology of Polymer Colloids G.W. Poehlein, R.H. Ottewill, J.W. Goodwin (editors) Polymer colloids, more commonly known as latexes, are important in the manufacture of synthetic elastomers, commodity polymers, surface coatings, adhesive and numerous specialty products. The significant growth of the commercial production of polymer latexes during the past decade has been due to a number of factors. First, water-based systems, especially paints and coatings, avoid many of the environ mental problems associated with the solvent-based systems. Second, polymer colloid products can be custom designed to meet a wide range of application requirements. Third, large scale emulsion polymeri zation proceeds smoothly and controllably with a wide range of monomers to produce stable polymer colloids of high molecular weight. Polymer colloids are also important in functional scientific studies. This importance arises from the spherical shape of the particles, range of attainable particle diameters and the uniformity of their size distribution, and the possibility of controlling and character izing the particle surface. Polymer colloids are useful as size standards in microscopy and in instrument calibration, and as carriers in antibody-enzyme diagnostic tests. As suspensions of uniform spherical particles, they are ideal experimental systems to test the series of colloidal phenomena as stability and coagulation, electric kinetic or rheological proper ties, and light scattering. In recent years, polymer colloids have received attention as models for many-body molecular phenomena, including the order-disorder transitions and the mechanics of crystalline phases.
Author : Lynley H. Guckian
Publisher :
ISBN 13 :
Total Pages : 96 pages
Book Rating : 4.:/5 (572 download)
Download or read book Synthesis of Styrene and Acrylic Emulsion Polymer Systems by Semi-continuous Seeded Polymerization Processes written by Lynley H. Guckian and published by . This book was released on 2004 with total page 96 pages. Available in PDF, EPUB and Kindle. Book excerpt: "The synthesis of monodisperse styrene and acrylic core-shell polymer particles by semi-continuous seeded emulsion polymerization processes was investigated. 120 and 140 nm homopoly(styrene) seed particles were made for each batch and monodisperse 300 and 400 nm core-shell particles were synthesized therefrom. Divinylbenzene and poly(dimethylsiloxane) were compositional variables that were studied as part of the synthesis. The addition of DVB significantly increased the gel content of the particles. The incorporation of poly(dimethylsilocane) appeared to plasticize the particles. The particle size, morphology, surface charge, molecular weight, percent gel content, and glass transition characteristics of the particles were evaluated. It was found that the surface charge of the particles was affected by increasing particle size and by incorporating poly(dimethylsiloxane) or acrylic functionality in the shell."--Abstract.
Author : Stéphane Roberge
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (953 download)
Download or read book Conjugated Linoleic Acid/Styrene/Butyl Acrylate Bulk and Emulsion Polymerization written by Stéphane Roberge and published by . This book was released on 2016 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The potential for conjugated linoleic acid (CLA) incorporation into pressure-sensitive adhesive (PSA) formulations was evaluated. A series of free radical bulk copolymerizations of CLA/styrene (Sty) and CLA/butyl acrylate (BA) were designed to allow the estimation of reactivity ratios. Bulk terpolymerizations of CLA/Sty/BA were also evaluated before moving to emulsion terpolymerizations of CLA/Sty/BA. The polymers were characterized for composition, conversion, molecular weight and glass transition temperature while latexes were characterized for viscosity, particle size, tack, peel strength, and shear strength. All experiments were performed at 80oC and monitored with attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy. While bulk experiments were monitored off-line, the emulsion experiments were monitored in-line. Absorbance peaks related to the monomers and polymer were tracked to provide conversion and polymer composition data using a multivariate calibration method. Off-line measurements using gravimetry and 1H-NMR spectroscopy were compared to the ATR-FTIR data and no significant differences were detected between the measurement methods. Pseudo-kinetic models, developed and validated with the copolymer experimental data, were used to estimate reactivity ratios. The copolymer pseudo-kinetic models were extended to a terpolymer pseudo-kinetic model and validated with experimental data. The pseudo-kinetic models incorporated the ability of oleic acid, a common impurity found in CLA, to trap electrons thus influencing the reaction kinetics significantly. The influence of terpolymer composition, chain transfer agent concentration, cross-linker concentration, molecular weight, viscosity and particle size on tack, peel strength and shear strength was investigated by using a constrained mixture design. The final forms of the resulting empirical models allowed the creation of 3D response surfaces for PSA performance optimization. The incorporation of 30 wt.% CLA into a practical PSA application suitable for the removable adhesives category was achieved.
Author : Gary W. Poehlein
Publisher : Springer
ISBN 13 :
Total Pages : 280 pages
Book Rating : 4.3/5 (91 download)
Download or read book Science and Technology of Polymer Colloids written by Gary W. Poehlein and published by Springer. This book was released on 1983 with total page 280 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Proceedings of the NATO Advanced Study Institute on Polymer Colloids, University of Bristol, Bristol, UK, June 28-July 8, 1982"--Verso t.p.
Author : Irja Piirma
Publisher :
ISBN 13 :
Total Pages : 480 pages
Book Rating : 4.3/5 (91 download)
Download or read book Emulsion Polymerization written by Irja Piirma and published by . This book was released on 1982 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : J.M. Asua
Publisher : Springer Science & Business Media
ISBN 13 : 9401155127
Total Pages : 571 pages
Book Rating : 4.4/5 (11 download)
Download or read book Polymeric Dispersions: Principles and Applications written by J.M. Asua and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 571 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive and up to date survey of the science and technology of polymeric dispersions. The book discusses the kinetics and mechanisms of polymerization in dispersed media, examines the processes controlling particle morphology, presents both off-line and on-line methods for the characterization of polymer colloids, considers reactor engineering and control, and covers a wide variety of applications, such as latex paint formulations, encapsulation of inorganic particles, reactive latexes, adhesives, paper coating, and biomedical and pharmaceutical applications. Audience: A valuable resource for scientists and engineers, academic and industrial, who are involved in the manufacture or application of polymeric dispersions.
Author : Wayne F. Reed
Publisher : John Wiley & Sons
ISBN 13 : 0470917385
Total Pages : 493 pages
Book Rating : 4.4/5 (79 download)
Download or read book Monitoring Polymerization Reactions written by Wayne F. Reed and published by John Wiley & Sons. This book was released on 2014-01-21 with total page 493 pages. Available in PDF, EPUB and Kindle. Book excerpt: Offers new strategies to optimize polymer reactions With contributions from leading macromolecular scientists and engineers, this book provides a practical guide to polymerization monitoring. It enables laboratory researchers to optimize polymer reactions by providing them with a better understanding of the underlying reaction kinetics and mechanisms. Moreover, it opens the door to improved industrial-scale reactions, including enhanced product quality and reduced harmful emissions. Monitoring Polymerization Reactions begins with a review of the basic elements of polymer reactions and their kinetics, including an overview of stimuli-responsive polymers. Next, it explains why certain polymer and reaction characteristics need to be monitored. The book then explores a variety of practical topics, including: Principles and applications of important polymer characterization tools, such as light scattering, gel permeation chromatography, calorimetry, rheology, and spectroscopy Automatic continuous online monitoring of polymerization (ACOMP) reactions, a flexible platform that enables characterization tools to be employed simultaneously during reactions in order to obtain a complete record of multiple reaction features Modeling of polymerization reactions and numerical approaches Applications that optimize the manufacture of industrially important polymers Throughout the book, the authors provide step-by-step strategies for implementation. In addition, ample use of case studies helps readers understand the benefits of various monitoring strategies and approaches, enabling them to choose the best one to match their needs. As new stimuli-responsive and "intelligent" polymers continue to be developed, the ability to monitor reactions will become increasingly important. With this book as their guide, polymer scientists and engineers can take full advantage of the latest monitoring strategies to optimize reactions in both the lab and the manufacturing plant.
Author : Edward Hollister Riddle
Publisher :
ISBN 13 :
Total Pages : 240 pages
Book Rating : 4.3/5 (91 download)
Download or read book Monomeric Acrylic Esters written by Edward Hollister Riddle and published by . This book was released on 1954 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt:
