Science Of Synthesis Cross Coupling And Heck Type Reactions Vol 2

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Science of Synthesis: Cross Coupling and Heck-Type Reactions Vol. 2

Author : John Wolfe
Publisher : Thieme
ISBN 13 : 3131790814
Total Pages : 993 pages
Book Rating : 4.1/5 (317 download)

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Book Synopsis Science of Synthesis: Cross Coupling and Heck-Type Reactions Vol. 2 by : John Wolfe

Download or read book Science of Synthesis: Cross Coupling and Heck-Type Reactions Vol. 2 written by John Wolfe and published by Thieme. This book was released on 2014-05-14 with total page 993 pages. Available in PDF, EPUB and Kindle. Book excerpt: In Science of Synthesis: Cross Coupling and Heck-Type Reactions, expert authors present and discuss the best and most reliable methods currently available for the formation of new carbon-carbon and carbon-heteroatom bonds using these reactions, highlighted with representative experimental procedures. Together, the three volumes of Cross Coupling and Heck-Type Reactions provide an extensive overview of the current state of the art in this field of central importance in modern chemistry, and are an invaluable resource for the practicing synthetic organic chemist. This volume is focused on the formation of carbon-heteroatom bonds and carbon-carbon bonds of acidic C-H nucleophiles. The chapters are intended to provide the reader with a practical guide to the most efficient, reliable, and useful metal-catalyzed cross-coupling reactions that generate C-N, C-P, C-O, C-S, C-B, C-Si, C-CN, and C-F bonds, and C-C bonds adjacent to carbonyl functional groups. The most up-to-date and modern methods are included, including those that facilitate replacement of typically unreactive C-H bonds with carbon-heteroatom bonds. This volume is part of a 3-volume set: Cross Coupling and Heck-Type Reactions Workbench Edition General information about Science of Synthesis

Science of Synthesis: Cross Coupling and Heck-Type Reactions Vol. 3

Author : Mats Larhed
Publisher : Thieme
ISBN 13 : 313179111X
Total Pages : 1564 pages
Book Rating : 4.1/5 (317 download)

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Book Synopsis Science of Synthesis: Cross Coupling and Heck-Type Reactions Vol. 3 by : Mats Larhed

Download or read book Science of Synthesis: Cross Coupling and Heck-Type Reactions Vol. 3 written by Mats Larhed and published by Thieme. This book was released on 2014-05-14 with total page 1564 pages. Available in PDF, EPUB and Kindle. Book excerpt: In Science of Synthesis: Cross Coupling and Heck-Type Reactions, expert authors present and discuss the best and most reliable methods currently available for the formation of new carbon-carbon and carbon-heteroatom bonds using these reactions, highlighted with representative experimental procedures. Together, the three volumes of Cross Coupling and Heck-Type Reactions provide an extensive overview of the current state of the art in this field of central importance in modern chemistry, and are an invaluable resource for the practicing synthetic organic chemist. This volume provides comprehensive coverage of the different classes of Heck-type reactions. It describes the state-of-the-art developments in each area whilst critically evaluating the strengths and weaknesses of the different methods. In accordance with the growing demand for synthetic efficiency and practicality in organic synthesis, many of these newly developed Heck-type methods feature operationally convenient conditions, high catalytic efficiency, and high levels of chemical, regiochemical, and stereochemical control. Metal-catalyzed C-H functionalization has also been developed into a powerful tool for organic synthesis, providing for original C-C disconnections in retrosynthetic analysis and improving the overall efficiency of the desired transformations. This volume also summarizes the most important concepts and methods in this hot research area. This volume is part of a 3-volume set: Cross Coupling and Heck-Type Reactions Workbench Edition General information about Science of Synthesis

Science of Synthesis: Advances in Organoboron Chemistry towards Organic Synthesis

Author : E. Fernández
Publisher : Thieme
ISBN 13 : 3132429732
Total Pages : 582 pages
Book Rating : 4.1/5 (324 download)

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Book Synopsis Science of Synthesis: Advances in Organoboron Chemistry towards Organic Synthesis by : E. Fernández

Download or read book Science of Synthesis: Advances in Organoboron Chemistry towards Organic Synthesis written by E. Fernández and published by Thieme. This book was released on 2020-05-22 with total page 582 pages. Available in PDF, EPUB and Kindle. Book excerpt: The widespread use of organoboron compounds justifies the efforts devoted to their synthesis, as well as toward developing an understanding of their reactivity. The nature of the mono- or diboron species is of paramount importance in determining the reversible covalent binding properties of the boron atom with both nucleophiles and electrophiles. By wedding the rich chemical potential of organoboron compounds to the ubiquity of organic scaffolds, advanced borylation reactions have the potential to open unprecedented synthetic alternatives, and new knowledge in the field should encourage chemists to use organoboron compounds. In this volume, the main objective is to provide a collection of the most useful, practical, and reliable methods, reported mainly within the last decade, for boron activation and boron reactivity. The volume covers the main concepts of organoboron compounds and includes experimental procedures, enabling newcomers to the field the instant and reliable application of the new tools in synthesis. Rather than aiming for a comprehensive coverage, the most advanced solutions for challenging transformations are introduced. To this end, a team of pioneers and leaders in the field have been assembled who discuss both the practical and conceptual aspects of this rapidly growing field.

Palladium-Catalyzed Coupling Reactions

Author : Árpád Molnár
Publisher : John Wiley & Sons
ISBN 13 : 3527648305
Total Pages : 531 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Palladium-Catalyzed Coupling Reactions by : Árpád Molnár

Download or read book Palladium-Catalyzed Coupling Reactions written by Árpád Molnár and published by John Wiley & Sons. This book was released on 2013-02-14 with total page 531 pages. Available in PDF, EPUB and Kindle. Book excerpt: This handbook and ready reference brings together all significant issues of practical importance in selected topics discussing recent significant achievements for interested readers in one single volume. While covering homogeneous and heterogeneous catalysis, the text is unique in focusing on such important aspects as using different reaction media, microwave techniques or catalyst recycling. It also provides a comprehensive treatment of key issues of modern-day coupling reactions having emerged and matured in recent years and emphasizes those topics that show potential for future development, such as continuous flow systems, water as a reaction medium, and catalyst immobilization, among others. With its inclusion of large-scale applications in the pharmaceutical industry, this will equally be of great interest to industrial chemists. From the contents * Palladium-Catalyzed Cross-Coupling Reactions - A General Introduction * High-turnover Heterogeneous Palladium Catalysts in Coupling Reactions: the Case of Pd Loaded on Dealuminated Y Zeolites Palladium-Catalyzed Coupling Reactions with Magnetically Separable Nanocatalysts * The Use of Ordered Porous Solids as Support Materials in Palladium-Catalyzed Cross-Coupling Reactions * Coupling Reactions Induced by Polymer-Supported Catalysts * Coupling Reactions in Ionic Liquids * Cross-Coupling Reactions in Aqueous Media * Microwave-Assisted Synthesis in C-C and C-Heteroatom Coupling Reactions * Catalyst Recycling in Palladium-Catalyzed Carbon-Carbon Coupling Reactions * Nature of the True Catalytic Species in Carbon-Carbon Coupling Reactions with * Heterogeneous Palladium Precatalysts * Coupling Reactions in Continuous Flow Systems * Large-Scale Applications of Palladium-Catalyzed Couplings in the Pharmaceutical Industry

Science of Synthesis: Biocatalysis in Organic Synthesis Vol. 2

Author : Kurt Faber
Publisher : Thieme
ISBN 13 : 3131766417
Total Pages : 1000 pages
Book Rating : 4.1/5 (317 download)

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Book Synopsis Science of Synthesis: Biocatalysis in Organic Synthesis Vol. 2 by : Kurt Faber

Download or read book Science of Synthesis: Biocatalysis in Organic Synthesis Vol. 2 written by Kurt Faber and published by Thieme. This book was released on 2015-03-11 with total page 1000 pages. Available in PDF, EPUB and Kindle. Book excerpt: The three Science of Synthesis volumes on "Biocatalysis in Organic Synthesis" present a broad contemporary overview on the state-of-the-art in enzymatic methods for asymmetric synthesis suitable for academics and industrial researchers working in the field of organic synthesis. The goal is to start a new wave of enthusiasm for biocatalysis in the broader community and to give an overview of the field. "Biocatalysis in Organic Synthesis" offers critical reviews of organic transformations by experts, including experimental procedures. The organization is based on the type of reaction performed under biocatalysis. Volume 2 covers reactions involving the formation of C-C bonds. Addition of carbon nucleophiles at C-O and C-N double bonds are reviewed, as are methods for the formation of C-C bonds at arenes and additions to C-C double bonds. Other chapters present transamination and reductive amination reactions, reduction of carbonyl compounds, and the uses of epoxides in biocatalysis.

Science of Synthesis: Knowlege Updates 2021/2

Author : E. Fernandez
Publisher : Thieme
ISBN 13 : 3132442070
Total Pages : 506 pages
Book Rating : 4.1/5 (324 download)

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Book Synopsis Science of Synthesis: Knowlege Updates 2021/2 by : E. Fernandez

Download or read book Science of Synthesis: Knowlege Updates 2021/2 written by E. Fernandez and published by Thieme. This book was released on 2021-05-21 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Science of Synthesis Editorial Board, together with the volume editors and authors, is constantly reviewing the whole field of synthetic organic chemistry as presented in Science of Synthesis and evaluating significant developments in synthetic methodology. Several annual volumes updating content across all categories ensure that you always have access to state-of-the-art synthetic methodology.

Metal Catalyzed Cross-Coupling Reactions and More

Author : Armin de Meijere
Publisher : John Wiley & Sons
ISBN 13 : 3527655603
Total Pages : 1640 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Metal Catalyzed Cross-Coupling Reactions and More by : Armin de Meijere

Download or read book Metal Catalyzed Cross-Coupling Reactions and More written by Armin de Meijere and published by John Wiley & Sons. This book was released on 2013-12-04 with total page 1640 pages. Available in PDF, EPUB and Kindle. Book excerpt: This three volume book is the follow-up handbook to the bestselling volume "Metal-Catalyzed Cross-Coupling Reactions", the definitive reference in the field. In line with the enormous developments in this area, this is not a new edition, but rather a new book in three volumes with over 50% more content. This new content includes C-H activation, shifting the focus away from typical cross-coupling reactions, while those topics and chapters found in de Meijere/Diederich's book have been updated and expanded. With its highly experienced editor team and the list of authors reading like an international Who's-Who in the field, this work will be of great interest to every synthetic chemist working in academia and industry.

Science of Synthesis: Dual Catalysis in Organic Synthesis 1

Author : G. A. Molander
Publisher : Thieme
ISBN 13 : 3132429783
Total Pages : 490 pages
Book Rating : 4.1/5 (324 download)

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Book Synopsis Science of Synthesis: Dual Catalysis in Organic Synthesis 1 by : G. A. Molander

Download or read book Science of Synthesis: Dual Catalysis in Organic Synthesis 1 written by G. A. Molander and published by Thieme. This book was released on 2020-05-22 with total page 490 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of dual catalysis has developed rapidly over the last decade, and these volumes define its impact on organic synthesis. The most important, basic concepts of synergistic, dual catalytic cycles are introduced, providing newcomers to the field with reliable information on this new approach to facilitating the synthesis of organic molecules. Background information and reliable procedures for challenging transformations in synthesis are presented, applying the concept of cooperative dual catalysis as a means of increasing molecular complexity in the most efficient manner. The most useful, practical, and reliable methods for dual catalysis combining metal catalysts, organocatalysts, photocatalysts, and biocatalysts are presented.

Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis Vol. 2

Author : Steven Nolan
Publisher : Thieme
ISBN 13 : 3132414034
Total Pages : 816 pages
Book Rating : 4.1/5 (324 download)

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Book Synopsis Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis Vol. 2 by : Steven Nolan

Download or read book Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis Vol. 2 written by Steven Nolan and published by Thieme. This book was released on 2017-06-14 with total page 816 pages. Available in PDF, EPUB and Kindle. Book excerpt: The field of N-heterocyclic carbenes, whether in transition-metal catalysis or organocatalysis, is rapidly evolving towards applications, but is also still very active on the catalyst development front. Significant advances have been made over the past two decades and the development of these reactions has dramatically improved the efficiency of organic synthesis. N-Heterocyclic carbene based catalysts are now widely applied in the area of synthesis of both natural products and therapeutic agents. "Science of Synthesis: N-Heterocyclic Carbenes in Catalytic Organic Synthesis" presents the most commonly used and significant metal- or non-metal-catalyzed reactions for modern organic synthesis. The basic principles and current state-of-the-art of the methods are covered. Scope, limitations, and mechanism of these reactions are discussed and key experimental procedures are included. Typical examples of target synthesis are often provided to show the utility and inspire further applications.

Science of Synthesis: Catalytic Oxidation in Organic Synthesis

Author :
Publisher :
ISBN 13 : 9783132012318
Total Pages : pages
Book Rating : 4.0/5 (123 download)

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Book Synopsis Science of Synthesis: Catalytic Oxidation in Organic Synthesis by :

Download or read book Science of Synthesis: Catalytic Oxidation in Organic Synthesis written by and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Classics in Stereoselective Synthesis

Author : Erick M. Carreira
Publisher : John Wiley & Sons
ISBN 13 : 9783527324521
Total Pages : 664 pages
Book Rating : 4.3/5 (245 download)

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Book Synopsis Classics in Stereoselective Synthesis by : Erick M. Carreira

Download or read book Classics in Stereoselective Synthesis written by Erick M. Carreira and published by John Wiley & Sons. This book was released on 2009-02-09 with total page 664 pages. Available in PDF, EPUB and Kindle. Book excerpt: Die wichtigsten und nützlichsten Methoden der modernen stereoselektiven Synthese sind in diesem Band zusammengefasst. Viele anschauliche Beispiele für die Darstellung von Wirkstoffen und Naturstoffen regen zur gezielten Abwandlung und Integration in eigene Synthesewege an. Dabei geht es den Autoren weniger darum, das Gebiet in seiner Gesamtheit darzustellen; vielmehr versuchen sie, die wirklich grundlegenden Ansätze auszuwählen, die jeder organische Synthesechemiker kennen und anwenden sollte.

Cross-Coupling Reactions

Author : Norio Miyaura
Publisher : Springer
ISBN 13 : 354045313X
Total Pages : 253 pages
Book Rating : 4.5/5 (44 download)

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Book Synopsis Cross-Coupling Reactions by : Norio Miyaura

Download or read book Cross-Coupling Reactions written by Norio Miyaura and published by Springer. This book was released on 2003-07-01 with total page 253 pages. Available in PDF, EPUB and Kindle. Book excerpt: In 1972, a very powerful catalytic cycle for carbon-carbon bond formation was 2 first discovered by the coupling reaction of Grignard reagents at the sp -carbon. Over the past 30 years, the protocol has been substantially improved and expanded to other coupling reactions of Li,B,N,O,Al,Si,P,S,Cu,Mn,Zn,In,Sn, and Hg compounds. These reactions provided an indispensable and simple methodology for preparative organic chemists. Due to the simplicity and rel- bility in the carbon-carbon, carbon-heteroatom, and carbon-metalloid bo- formations,as well as high efficiency of the catalytic process,the reactions have been widely employed by organic chemists in various fields. Application of the protocol ranges from various syntheses of complex natural products to the preparation of biologically relevant molecules including drugs, and of sup- molecules, and to functional materials. The reactions on solid surfaces allow robot synthesis and combinatorial synthesis. Now, many organic chemists do not hesitate to use transition metal complexes for the transformation of org- ic molecules. Indeed, innumerable organic syntheses have been realized by the catalyzed reactions of transition metal complexes that are not achievable by t- ditional synthetic methods. Among these, the metal-catalyzed cross-coupling reactions have undoubtedly contributed greatly to the development of such a new area of “metal-catalyzed organic syntheses”. An excellent monograph for the cross-coupling reactions and other met- catalyzed C-C bond-forming reactions recently appeared in Metal-catalyzed Cross-coupling Reactions (Wiley-VCH,1998).

Science of Synthesis: Cross-Dehydrogenative Coupling

Author : Debabrata Maiti
Publisher : Georg Thieme Verlag
ISBN 13 : 3132455253
Total Pages : 686 pages
Book Rating : 4.1/5 (324 download)

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Book Synopsis Science of Synthesis: Cross-Dehydrogenative Coupling by : Debabrata Maiti

Download or read book Science of Synthesis: Cross-Dehydrogenative Coupling written by Debabrata Maiti and published by Georg Thieme Verlag. This book was released on 2023-09-06 with total page 686 pages. Available in PDF, EPUB and Kindle. Book excerpt: Comprehensive overview of strategies and applications of cross-dehydrogenative coupling methods Cross-Dehydrogenative Coupling (CDC) represents a type of coupling reaction for the construction of a C−C bond or C−heteroatom (C–X) bond directly from C−H and X−H bonds present in the precursors. Since this genre of coupling reaction obviates the need for substrate prefunctionalization, it has an added advantage of high efficiency, atom economy, and environmental friendliness. CDC reactions are triggered by transition-metal catalysts or simply by an oxidants, or by either photocatalysis or electrocatalysis, leading to a hetero- or homo-coupled products with the removal of two hydrogens. Over the years, several CDC strategies have been developed that has made it possible to construct bonds between carbon-hydrogen (C–H) bonds of diverse hybridization. CDC has also streamlined the synthesis and functionalization of various nitrogen, oxygen, and sulfur-containing heterocycles. This volume features a series of chapters systematically covering methods and strategies in CDC, organized primarily on the type of bond being formed. In addition, particular aspects of CDC are highlighted in devoted chapters on topics such as mechanistic aspects, electrochemical and flow methods, transformations in water, natural product synthesis, and enantioselective protocols.

Handbook of Organopalladium Chemistry for Organic Synthesis

Author : Ei-ichi Negishi
Publisher : John Wiley & Sons
ISBN 13 : 0471473812
Total Pages : 1657 pages
Book Rating : 4.4/5 (714 download)

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Book Synopsis Handbook of Organopalladium Chemistry for Organic Synthesis by : Ei-ichi Negishi

Download or read book Handbook of Organopalladium Chemistry for Organic Synthesis written by Ei-ichi Negishi and published by John Wiley & Sons. This book was released on 2003-11-24 with total page 1657 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organized to provide maximum utility to the bench synthetic chemist. The editor is well-known for his work in exploring, developing, and applying organopalladium chemistry. Contributors include over 24 world authorities in the field.

Enzyme Cascade Design and Modelling

Author : Selin Kara
Publisher : Springer Nature
ISBN 13 : 3030657183
Total Pages : 181 pages
Book Rating : 4.0/5 (36 download)

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Book Synopsis Enzyme Cascade Design and Modelling by : Selin Kara

Download or read book Enzyme Cascade Design and Modelling written by Selin Kara and published by Springer Nature. This book was released on 2021-02-24 with total page 181 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a comprehensive overview of the recent developments achieved in the field of chemo/enzymatic cascades with topics spanning from design (in vitro and in vivo) to kinetic- and process modelling as well as process control. Opportunities and challenges of building multi-step chemo/enzymatic reactions are discussed, whereby the latter are critically assessed in each chapter and methods to ease the implementation are explored. Both, multi-enzymatic cascades and chemo-enzymatic cascades are presented with the motivation of combining the strengths of these two worlds (e.g. selectivity, activity and robustness) not neglecting the obstacles and challenges of such endeavour. Furthermore, the use of non-conventional media for catalytic cascade reactions, recent achievements and potential for future developments in a technical environment are addressed.

Palladium-Catalyzed Modification of Nucleosides, Nucleotides and Oligonucleotides

Author : Anant R. Kapdi
Publisher : Elsevier
ISBN 13 : 012811293X
Total Pages : 360 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Palladium-Catalyzed Modification of Nucleosides, Nucleotides and Oligonucleotides by : Anant R. Kapdi

Download or read book Palladium-Catalyzed Modification of Nucleosides, Nucleotides and Oligonucleotides written by Anant R. Kapdi and published by Elsevier. This book was released on 2018-06-04 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: Palladium-Catalyzed Modification of Nucleosides, Nucleotides and Oligonucleotides describes the procedures and protocols related to the modification of nucleosides, nucleotides and oligonucleotides via Pd-mediated cross-coupling processes. The book highlights the growing area of nucleic acid modification and how Pd-mediated coupling reactions can assist this development. Users will find key synthetic protocols for these reactions in this latest volume in the Latest Trends in Palladium Chemistry series. As most of the research in the field of antiviral agents has centered on the use of modified nucleosides that have exhibited promising activity, this book provides an up-to-date reference for both professionals in industry and other interested parties. - Provides synthetic routes for useful nucleoside molecules, information otherwise found only through time-consuming literature searches - Covers metal-mediated and metal-catalyzed cross coupling processes of nucleosides and related compounds - Includes Suzuki-Miyaura, Stille and Sonogashira reactions, as well as C-H bond functionalization - Highlights the growing area of nucleic acid modification and how Pd-mediated coupling reactions can assist

Advances in Cross-Coupling Reactions

Author : José Pérez Sestelo
Publisher : MDPI
ISBN 13 : 3039435671
Total Pages : 234 pages
Book Rating : 4.0/5 (394 download)

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Book Synopsis Advances in Cross-Coupling Reactions by : José Pérez Sestelo

Download or read book Advances in Cross-Coupling Reactions written by José Pérez Sestelo and published by MDPI. This book was released on 2020-12-03 with total page 234 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this Special Issue, recent advances in cross-coupling reactions are presented in the form of original research articles, reviews, and short communications. These contributions cover different topics in this area, including novel coupling reactions, reaction conditions, synthetic alternatives, metal ligands, and applications for new pharmaceutical compounds and organic materials. In particular, the reviews deal with methodologies such as the synthesis of diarylketones through palladium catalysis and the most relevant examples of Suzuki–Miyaura and Buchwald–Hartwig coupling reactions in the synthesis of bioactive compounds. The synthetic utility of cross-coupling reactions for the synthesis of medium-size rings and the utility of Stille and Suzuki coupling reactions for the synthesis of new molecular machines based on sterically hindered anthracenyl trypticenyl units are also summarized. The original research articles present the synthesis of 2-alkynylpyrrols by inverse Sonogashira coupling and the synthesis of indoles under oxidative dearomative cross-dehydrogenative conditions. The efficient combination of iridium-catalyzed C–H borylation of aryl halides with the Sonogashira coupling and a sequential iridium-catalyzed borylation of NH-free pyrroles followed by a Suzuki–Miyaura reaction are included. The synthesis of aryl propionic acids, a common structural motif in medicinal chemistry, and the synthesis of new organic dyes are also covered.