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Salt Effects On Stable Isotope Partitioning And Their Geochemical Implications For Geothermal Brines
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Book Synopsis Salt Effects on Stable Isotope Partitioning and Their Geochemical Implications for Geothermal Brines by :
Download or read book Salt Effects on Stable Isotope Partitioning and Their Geochemical Implications for Geothermal Brines written by and published by . This book was released on 1994 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The effects of dissolved salts (NaCI, KCI, MgCl2, CaCI2, Na2SO4, MgSO4, and their mixtures) on oxygen and hydrogen isotope partitioning between brines and coexisting phases (vapor and calcite) were experimentally determined at 50-350° C and 300° C, respectively. In liquid-vapor equilibration experiments, for all of the salts studied, the hydrogen isotope fractionation factors between the salt solutions and vapor decreased appreciably (up to 20{permille}) compared to pure water-vapor. Except for KCI solutions at 500 C, the oxygen isotope fractionation factors between salt solutions and vapor were higher (up to 4{permille}) than, or very close to, that of pure water. The observed isotope salt effects are all linear with the molalities of the solutions. Mixed salt solutions mimicking natural geothermal brines exhibit salt effects additive of those of individual salts. The isotope exchange experiments of calcite-water at 300°C and 1 kbar yielded a fractionation factor of 5.9+0.3{permille} for pure water and effects of NaCl consistent with those obtained from the liquid-vapor equilibration experiments. The isotope salt effects observed in this study are too large to be ignored, and must be taken into account for isotopic studies of geothermal systems (i.e., estimation of isotope ratios and temperatures of deep-seated geothermal brines).
Book Synopsis Salt Effects on Isotope Partitioning and Their Geochemical Implications by :
Download or read book Salt Effects on Isotope Partitioning and Their Geochemical Implications written by and published by . This book was released on 1996 with total page 6 pages. Available in PDF, EPUB and Kindle. Book excerpt: Essential to the use of stable isotopes as natural tracers and geothermometers is the knowledge of equilibrium isotope partitioning between different phases and species, which is usually a function of temperature only. The one exception known to date is oxygen and hydrogen isotope fractionation between liquid water and other phases (steam, gases, minerals), which changes upon the addition of salts to water, i.e., the isotope salt salt effect. Our knowledge of this effect, the difference between activity and composition (a-X) of isotopic water molecules in salt solutions, is very limited and controversial, especially at elevated temperatures. For the last several years, we have been conducting a detailed, systematic experimental study at Oak Ridge National Laboratory to determine the isotope salt effects from room temperature to elevated temperatures (currently to 500°C). From this effort, a simple, coherent picture of the isotope salt effect is emerging, that differs markedly from the complex results reported in the literature. In this communication, we present an overview on the isotope salt effect, obtained chiefly from our study. Observed isotope salt effects in salt solutions are significant even at elevated temperatures. The importance and implications of the isotope salt effect for isotopic studies of brine-dominated systems are also discussed in general terms.
Book Synopsis Stable Isotope Geochemistry by : John W. Valley
Download or read book Stable Isotope Geochemistry written by John W. Valley and published by Walter de Gruyter GmbH & Co KG. This book was released on 2018-12-17 with total page 676 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 43 of Reviews in Mineralogy and Geochemistry follows the 1986 Reviews in Mineralogy (Vol. 16) in approach but reflects significant changes in the field of Stable Isotope Geochemistry. In terms of new technology, new sub-disciplines, and numbers of researchers, the field has changed more in the past decade than in any other since that of its birth. Unlike the 1986 volume, which was restricted to high temperature fields, this book covers a wider range of disciplines. However, it would not be possible to fit a comprehensive review into a single volume. Our goal is to provide state-of-the-art reviews in chosen subjects that have emerged or advanced greatly since 1986. This volume was prepared for Short Course on Stable Isotope Geochemistry presented November 2-4, 2001 in conjunction with the annual meetings of the Geological Society of America in Boston, Massachusetts.
Book Synopsis Federal Geothermal Research Program Update, Fiscal Year 1995 by : Geothermal Research Program (U.S.)
Download or read book Federal Geothermal Research Program Update, Fiscal Year 1995 written by Geothermal Research Program (U.S.) and published by . This book was released on 1996 with total page 492 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Energy Research Abstracts written by and published by . This book was released on 1994 with total page 586 pages. Available in PDF, EPUB and Kindle. Book excerpt: Semiannual, with semiannual and annual indexes. References to all scientific and technical literature coming from DOE, its laboratories, energy centers, and contractors. Includes all works deriving from DOE, other related government-sponsored information, and foreign nonnuclear information. Arranged under 39 categories, e.g., Biomedical sciences, basic studies; Biomedical sciences, applied studies; Health and safety; and Fusion energy. Entry gives bibliographical information and abstract. Corporate, author, subject, report number indexes.
Download or read book Workshop Report written by and published by . This book was released on with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Synerjy written by and published by . This book was released on 1991 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Government Reports Announcements & Index by :
Download or read book Government Reports Announcements & Index written by and published by . This book was released on 1994 with total page 1028 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Geochemical and Isotopic Characterization of Shallow Basinal Brines from the Makgadikgadi Pans Complex, Northeastern Botswana by : Loago N. Molwalefhe
Download or read book Geochemical and Isotopic Characterization of Shallow Basinal Brines from the Makgadikgadi Pans Complex, Northeastern Botswana written by Loago N. Molwalefhe and published by . This book was released on 2003 with total page 126 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Summaries of Physical Research in the Geosciences by :
Download or read book Summaries of Physical Research in the Geosciences written by and published by . This book was released on 1988-12 with total page 152 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Volcanic Lakes written by Dmitri Rouwet and published by Springer. This book was released on 2015-03-02 with total page 526 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book aims to give an overview on the present state of volcanic lake research, covering topics such as volcano monitoring, the chemistry, dynamics and degassing of acidic crater lakes, mass-energy-chemical-isotopic balance approaches, limnology and degassing of Nyos-type lakes, the impact on the human and natural environment, the eruption products and impact of crater lake breaching eruptions, numerical modeling of gas clouds and lake eruptions, thermo-hydro-mechanical and deformation modeling, CO2 fluxes from lakes, volcanic lakes observed from space, biological activity, continuous monitoring techniques, and some aspects more. We hope to offer an updated manual on volcanic lake research, providing classic research methods, and point towards a more high-tech approach of future volcanic lake research and continuous monitoring.
Book Synopsis The Geochemistry of Stable Chlorine and Bromine Isotopes by : Hans Eggenkamp
Download or read book The Geochemistry of Stable Chlorine and Bromine Isotopes written by Hans Eggenkamp and published by Springer. This book was released on 2014-08-25 with total page 174 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides detailed information on the history, analysis and applications of chlorine and bromine isotope geochemistry. Chlorine and bromine are geochemically unique as they prefer to exist as single charged negative ions. For this reason isotope fractionation reflects mostly processes that are not related to changes in the redox state and this fractionation is generally modest. The book will describe the processes that are most easily detected using these isotopes. Also isotope variations, and processes that cause them, measured in oxidised species such as perchlorates and in organic molecules will be described in this book.
Download or read book Geochemistry written by William M. White and published by John Wiley & Sons. This book was released on 2013-01-22 with total page 1218 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a comprehensive introduction to the field of geochemistry. The book first lays out the ‘geochemical toolbox’: the basic principles and techniques of modern geochemistry, beginning with a review of thermodynamics and kinetics as they apply to the Earth and its environs. These basic concepts are then applied to understanding processes in aqueous systems and the behavior of trace elements in magmatic systems. Subsequent chapters introduce radiogenic and stable isotope geochemistry and illustrate their application to such diverse topics as determining geologic time, ancient climates, and the diets of prehistoric peoples. The focus then broadens to the formation of the solar system, the Earth, and the elements themselves. Then the composition of the Earth itself becomes the topic, examining the composition of the core, the mantle, and the crust and exploring how this structure originated. A final chapter covers organic chemistry, including the origin of fossil fuels and the carbon cycle’s role in controlling Earth’s climate, both in the geologic past and the rapidly changing present. Geochemistry is essential reading for all earth science students, as well as for researchers and applied scientists who require an introduction to the essential theory of geochemistry, and a survey of its applications in the earth and environmental sciences. Additional resources can be found at: www.wiley.com/go/white/geochemistry
Author :Philip A. E. Pogge von Strandmann Publisher :Cambridge University Press ISBN 13 :1108997627 Total Pages :51 pages Book Rating :4.1/5 (89 download)
Book Synopsis Lithium Isotopes by : Philip A. E. Pogge von Strandmann
Download or read book Lithium Isotopes written by Philip A. E. Pogge von Strandmann and published by Cambridge University Press. This book was released on 2021-08-26 with total page 51 pages. Available in PDF, EPUB and Kindle. Book excerpt: Lithium isotopes are a relatively novel tracer of present and past silicate weathering processes. Given that silicate weathering is the primary long-term method by which CO2 is removed from the atmosphere, Li isotope research is going through an exciting phase. We show the weathering processes that fractionate dissolved and sedimentary Li isotope ratios, focusing on weathering intensity and clay formation. We then discuss the carbonate and silicate archive potential of past seawater δ7Li. These archives have been used to examine Li isotope changes across both short and long timescales. The former can demonstrate the rates at which the climate is stabilised from perturbations via weathering, a fundamental piece of the puzzle of the long-term carbon cycle.
Download or read book Geothermal Energy Update written by and published by . This book was released on 1978 with total page 750 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Role of Halogens in Terrestrial and Extraterrestrial Geochemical Processes by : Daniel E. Harlov
Download or read book The Role of Halogens in Terrestrial and Extraterrestrial Geochemical Processes written by Daniel E. Harlov and published by Springer. This book was released on 2018-01-30 with total page 1029 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book summarizes the knowledge and experiences concerning the role of halogens during various geochemical processes, such as diagenesis, ore-formation, magma evolution, metasomatism, mineralization, and metamorphism in the crust and mantle of the Earth. It comprises the role of halogens in other terrestrial worlds like volatile-rich asteroids, Mars, and the ice moons of Jupiter and Saturn. Review chapters outline and expand upon the basis of our current understanding regarding how halogens contribute to the geochemical/geophysical evolution and stability of terrestrial worlds overall.
Download or read book Geotitles written by and published by . This book was released on 1990 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt:
