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Author : Gregory S. Owens
Publisher :
ISBN 13 :
Total Pages : 6 pages
Book Rating : 4.:/5 (455 download)
Download or read book Rhenium Oxo Complexes in Catalytic Oxidations written by Gregory S. Owens and published by . This book was released on 2000 with total page 6 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Shi'ang Cai
Publisher :
ISBN 13 :
Total Pages : 400 pages
Book Rating : 4.:/5 (26 download)
Download or read book Synthesis, Structure and Reactivity Studies of High Oxidation-state Rhenium-oxo Complexes written by Shi'ang Cai and published by . This book was released on 1990 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : B. Meunier
Publisher : Springer
ISBN 13 : 3540465928
Total Pages : 327 pages
Book Rating : 4.5/5 (44 download)
Download or read book Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations written by B. Meunier and published by Springer. This book was released on 2003-09-04 with total page 327 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume is a description of the current knowledge on the different metal-oxo and metal-peroxo species involved in catalytic oxidations. The series contains critical reviews of the present position and future trends, and short and concise reports written by the world’s renowned experts.
Author : Alexander Thomas Radosevich
Publisher :
ISBN 13 :
Total Pages : 952 pages
Book Rating : 4.:/5 (35 download)
Download or read book Application of Rhenium- and Vanadium-oxo Complexes as Catalysts in Organic Synthesis written by Alexander Thomas Radosevich and published by . This book was released on 2007 with total page 952 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Michael Salvatore Sangi
Publisher :
ISBN 13 :
Total Pages : 198 pages
Book Rating : 4.:/5 (35 download)
Download or read book Development of Rhenium(v)-oxo Catalysts for the Enantioselective Oxidation of Sulfides to Sulfoxides written by Michael Salvatore Sangi and published by . This book was released on 2007 with total page 198 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : William P. Griffith
Publisher : Springer Science & Business Media
ISBN 13 : 1402093780
Total Pages : 274 pages
Book Rating : 4.4/5 (2 download)
Download or read book Ruthenium Oxidation Complexes written by William P. Griffith and published by Springer Science & Business Media. This book was released on 2010-11-03 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ruthenium Oxidation Complexes explores ruthenium complexes, particularly those in higher oxidation states, which function as useful and selective organic oxidation catalysts. Particular emphasis is placed on those systems which are of industrial significance. The preparation, properties and applications of the ruthenium complexes are described, followed by a presentation of their oxidative properties and summary of the different mechanisms involved in the organic oxidations (e.g. oxidations of alcohols, alkenes, arenes and alkynes, alkanes, amines, ethers, phopshines and miscellaneous substrates). Moreover, future trends and developments in the area are discussed. This monograph is aimed at inorganic, organic, industrial and catalysis chemists, especially those who wish to carry out specific organic oxidations using catalytic methods.
Author : Jessica Lee Smeltz
Publisher :
ISBN 13 :
Total Pages : 249 pages
Book Rating : 4.:/5 (871 download)
Download or read book Synthesis and Characterization of Rhenium Complexes for Use in Catalytic Oxidation, Reduction, and Carbonylation Reactions written by Jessica Lee Smeltz and published by . This book was released on 2013 with total page 249 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Tiow-Gan Ong
Publisher :
ISBN 13 :
Total Pages : 466 pages
Book Rating : 4.:/5 (446 download)
Download or read book The Synthesis, Characterization and Reactivity of High Oxidation State Rhenium Imido and Oxo Complexes written by Tiow-Gan Ong and published by . This book was released on 2000 with total page 466 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Ana Santos
Publisher :
ISBN 13 : 9783934767225
Total Pages : 205 pages
Book Rating : 4.7/5 (672 download)
Download or read book Rhenium and Molybdenum Oxo Complexes written by Ana Santos and published by . This book was released on 2000 with total page 205 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Kimberly Ann Brittingham
Publisher :
ISBN 13 :
Total Pages : 176 pages
Book Rating : 4.:/5 (467 download)
Download or read book Kinetics and Mechanisms of the Oxidation of Rhenium(V) Oxo and Thiolato Complexes by Alkyl Hydroperoxides and Orthoquinones written by Kimberly Ann Brittingham and published by . This book was released on 2000 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aqueous methyldioxorhenium (MDO), prepared in situ from methyltrioxorhenium (MTO) and hypophosphorous acid, abstracts an oxygen atom from tertiary alkyl hydroperoxides. This regenerates MTO and forms the tertiary alcohol with rate constants 3.71 X 104 L mol−1 s−1 (t-BuOOH) and 3.47 X 104 L mol−1 s−1 (t-AmOOH) at 25.0 0C in aqueous 1.0 M HOTf. In a separate study, the concomitant slow decomposition of alkyl hydroperoxides and MTO (to ReO4−) was investigated. The rate law is v = k[MTO][ROOH]/[H+], with k = 7.4 x 10−5 s−1 (R = t-Bu) and k = 8.4 x 10−5 s−1 (R = t-Am) at 25.0 0C in aq. solution at [Mu] 1.0 M. 1H NMR spectroscopy and GC revealed organic products suggestive of radical reactions. The products from t- BuOOH are acetone, methanol, tert-butyl methyl ether, methane, ethane, and tert-butyl methyl peroxide. With CH2DReO3, it could be shown that both t-BuOOH and MTO were sources of the methane.
Author : Jukka Jokela
Publisher :
ISBN 13 :
Total Pages : 214 pages
Book Rating : 4.:/5 (895 download)
Download or read book High Oxidation State Rhenium Oxo Diolato Complexes written by Jukka Jokela and published by . This book was released on 1997 with total page 214 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Daniel Duprez
Publisher : World Scientific
ISBN 13 : 1783263342
Total Pages : 1035 pages
Book Rating : 4.7/5 (832 download)
Download or read book Handbook Of Advanced Methods And Processes In Oxidation Catalysis: From Laboratory To Industry written by Daniel Duprez and published by World Scientific. This book was released on 2014-07-24 with total page 1035 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers a comprehensive overview of the most recent developments in both total oxidation and combustion and also in selective oxidation. For each topic, fundamental aspects are paralleled with industrial applications. The book covers oxidation catalysis, one of the major areas of industrial chemistry, outlining recent achievements, current challenges and future opportunities. One distinguishing feature of the book is the selection of arguments which are emblematic of current trends in the chemical industry, such as miniaturization, use of alternative, greener oxidants, and innovative systems for pollutant abatement. Topics outlined are described in terms of both catalyst and reaction chemistry, and also reactor and process technology.
Author : Xiao-Yu Yang
Publisher : John Wiley & Sons
ISBN 13 : 1119580552
Total Pages : 500 pages
Book Rating : 4.1/5 (195 download)
Download or read book Photoenergy and Thin Film Materials written by Xiao-Yu Yang and published by John Wiley & Sons. This book was released on 2019-03-26 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a fundamental discussion, latest research & developments, and the future of thin films and photoenergy materials, two developing areas that have the potential to spearhead the future of industry. Photoenergy materials are expected to be a next generation key material to provide secure, safe, sustainable and affordable energy. Photoenergy devices are known to convert the sunlight into electricity. This type of devices is very much simple in design with having a major advantage with their structure as stand-alone systems to provide outputs up to megawatts. They have been applied as a power source, solar home systems, remote buildings, water pumping, megawatt scale power plants, satellites, communications, and space vehicles. With such a list of enormous applications, the demand for photoenergy devices is growing every year. On the other hand, thin films coating, which can be defined as fusion of surface science, materials science, and applied physics, are progressing as a unified discipline of scientific industry. A thin film can be termed as a very fine or thin layer of material coated on a particular surface, that can be in the range of a nanometer in thickness to several micrometers in size. Thin films are being applied it a number of fields ranging from protection purposes to electronic semiconductor devices.
Author : Franc Meyer
Publisher : Springer
ISBN 13 : 3540372105
Total Pages : 258 pages
Book Rating : 4.5/5 (43 download)
Download or read book Organometallic Oxidation Catalysis written by Franc Meyer and published by Springer. This book was released on 2007-01-30 with total page 258 pages. Available in PDF, EPUB and Kindle. Book excerpt: In many of the processes of oxidation catalysis, species with metal-carbon bonds are formed as key intermediates, and these processes represent the primary focus of this volume. An important aspect covered by some of the contributors is the use of organic ligands to achieve efficient oxidation catalysis. Each volume of "Topics in Organometallic Chemistry" provides a comprehensive summary and critical overview of a specific topic in organometallic chemistry.
Author : Yan Huang
Publisher :
ISBN 13 :
Total Pages : 160 pages
Book Rating : 4.:/5 (671 download)
Download or read book Synthesis, Kinetic and Photocatalytic Studies of Porphyrin-ruthenium-oxo Complexes written by Yan Huang and published by . This book was released on 2008 with total page 160 pages. Available in PDF, EPUB and Kindle. Book excerpt: Macrocyclic ligand-complexed transition metal-oxo intermediates are the active oxidizing species in a variety of important biological and catalytic oxidation reactions. Many transition metal catalysts have been designed to mimic the predominant oxidation catalysts in Nature, namely the cytochrome P450 enzymes. Ruthenium porphyrin complexes have been the center of the research and have successfully been utilized, as catalysts, in major oxidation reactions such as the hydroxylation of alkanes. This study focuses on kinetic and photocatalytic studies of oxidation reactions with wellcharacterized high-valent ruthenium-oxo porphyrin complexes. The trans-dioxoruthenium(VI) porphyrins have been among the best characterized metal-oxo intermediates and their involvement as the active oxidant in the hydrocarbon oxidation have been extensively studied. Following the literature known methods, a series of trans-dioxoruthenium(VI) porphyrin complexes (3a-b) were synthesized and spectroscopically characterized by UV-vis, IR and lH-NMR. In addition to the well-known chemical methods, we developed a novel photochemical approach for generation of trans-dioxoruthenium(VI) porphyrins with visible light. The fast kinetic study of two-electron oxidations of para-substituted phenyl methyl sulfides by these dioxoruthenium(VI) species was conducted by using stopped-flow spectroscopy. Results showed that the decay of trans--dioxoruthenium(VI) porphyrins in the presence of reactive sulfides follows a biexponential process. The reactivity order in the series of dioxoruthenium complexes follows TPFPP> TPP> TMP, consistent with expectations based on the electrophilic nature of high-valent metal-oxo species. Moreover, the sulfoxidation reactions are 3 to 4 orders of magnitude faster than the well-known epoxidation reactions. In addition, several ruthenium porphyrins were used as the catalysts in the competitive oxidation reactions to identify the kinetically competent oxidants during catalytic turnover conditions.
Author :
Publisher : Academic Press
ISBN 13 : 0128121866
Total Pages : 510 pages
Book Rating : 4.1/5 (281 download)
Download or read book Advances in Organometallic Chemistry written by and published by Academic Press. This book was released on 2017-06-08 with total page 510 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Organometallic Chemistry, Volume 67 contains authoritative review articles of worldwide known researchers on the field of organometallic chemistry, covering topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. Updates in this new volume include chapters on Group 6 Metal Fischer Carbene Complexes: Versatile Synthetic Building Blocks, Recent Advances in Transition-Metal-Catalyzed Cross-Coupling Reactions With Tosylhydrazones,Oxidative Functionalization of Late Transition Metal-Carbon Bond, and Biaryl Synthesis via C–H Bond Activation: Strategies and Methods. This book will benefit a wide range of researchers involved in organometallic chemistry, including those working on synthetic protocols, mechanistic studies and practical applications. Contains contributions from leading authorities in the field of organometallic chemistry Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more Informs and updates readers on all the latest developments in the field Carefully edited to provide easy-to-read material
Author :
Publisher : ScholarlyEditions
ISBN 13 : 1464990557
Total Pages : 2682 pages
Book Rating : 4.4/5 (649 download)
Download or read book Transition Elements—Advances in Research and Application: 2012 Edition written by and published by ScholarlyEditions. This book was released on 2012-12-26 with total page 2682 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition Elements—Advances in Research and Application: 2012 Edition is a ScholarlyEditions™ eBook that delivers timely, authoritative, and comprehensive information about Transition Elements. The editors have built Transition Elements—Advances in Research and Application: 2012 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Transition Elements in this eBook to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Transition Elements—Advances in Research and Application: 2012 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.
