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Reactions Of Platinum Complexes With Dimethylamine Borane
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Book Synopsis Reactions of Platinum Complexes with Dimethylamine-borane by : Shawn Michael Robinson
Download or read book Reactions of Platinum Complexes with Dimethylamine-borane written by Shawn Michael Robinson and published by . This book was released on 2012 with total page 168 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis describes a study of the reactions of platinum complexes with dimethylamine-borane (DMAB) as models for alkane activation. It is concluded that sigmaborane complexes of platinum(II) or platinum(IV) will be difficult to synthesize or even to detect as intermediates in hydride transfer from boranes to platinum. The complex [PtMe(O2CCF3)(bpy)] reacts with DMAB to form an intermediate [PtMeH(bpy)] complex, which undergoes reductive elimination of methane with further degradation to give platinum(0) and free 2,2'-bipyridine. The addition of methyl acrylate to the reaction allowed the trapping of the platinum-hydride, producing [PtCl(CHMeCO2Me)(bpy)] and [Pt(CHMeCO2Me)2(bpy)]. Oxidative addition of methyl iodide produced the complex [PtMe(CHMeCO2Me)Cl(I)(bpy)]. As well, the reaction of [Pt(O2CCF3)2(dppe)] with DMAB afforded the [Pt( -H)(dppe)]2[O2CCF3]2 complex. These complexes are characterized by NMR spectroscopy, with additional structural information obtained from the crystal structure of [PtMe(CHMeCO2Me)Cl(I)(bpy)]. Complexes [PtMe3(OTf)(bpy)] and [PtMe3(OTf)(bu2bpy)] react with DMAB to afford [PtMe3(Me2NH)(bpy)]+, [Pt2Me6( -H)(bpy)2]+, [PtMe3(Me2NH)(bu2bpy)]+, and [Pt2Me6( -H)(bu2bpy)2]+. The addition of dibenzoyl peroxide to [PtMe2(bpy)] yielded [PtMe2(OBn)2(bpy)]. The reaction of [PtMe3(OTf)(dmpe)] with DMAB afforded the [PtMe4(dmpe)] complex. These complexes are characterized by NMR spectroscopy.
Book Synopsis Nanobiotechnology by : Christof M. Niemeyer
Download or read book Nanobiotechnology written by Christof M. Niemeyer and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 491 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanotechnology is the key technology of the 21st century. The possibility to exploit the structures and processes of biomolecules for novel functional materials, biosensors, bioelectronics and medical applications has created the rapidly growing field of nanobiotechnology. Designed as a broad survey of the field, this book combines contributions from bioorganic and bioinorganic chemistry, molecular biology, materials science and bioanalytics to fathom the full scope of current and future developments. It is divided into four main sections: * Interphase Systems * Protein-based Nanostructures * DNA-based Nanostructures * Nanoanalytics Each chapter describes in detail currently available methods and contains numerous references to the primary literature, making this the perfect "field guide" for chemists, biologists and materials scientists who want to explore the fascinating world of nanobiotechnology.
Book Synopsis Nanomaterials for Hydrogen Storage Applications by : Fatih Şen
Download or read book Nanomaterials for Hydrogen Storage Applications written by Fatih Şen and published by Elsevier. This book was released on 2020-09-09 with total page 286 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanomaterials for Hydrogen Storage Applications introduces nanomaterials and nanocomposites manufacturing and design for hydrogen storage applications. The book covers the manufacturing, design, characterization techniques and hydrogen storage applications of a range of nanomaterials. It outlines fundamental characterization techniques for nanocomposites to establish their suitability for hydrogen storage applications. Offering a sound knowledge of hydrogen storage application of nanocomposites, this book is an important resource for both materials scientists and engineers who are seeking to understand how nanomaterials can be used to create more efficient energy storage solutions. Assesses the characterization, design, manufacture and application of different types of nanomaterials for hydrogen storage Outlines the major challenges of using nanomaterials in hydrogen storage Discusses how the use of nanotechnology is helping engineers create more effective hydrogen storage systems
Book Synopsis The Chemistry of Platinum and Palladium: with Particular Reference to Complexes of the Elements by : F. R. Hartley
Download or read book The Chemistry of Platinum and Palladium: with Particular Reference to Complexes of the Elements written by F. R. Hartley and published by . This book was released on 1973 with total page 570 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Reactions of Vinyl Platinum Complexes by : Zhandong Zhong
Download or read book Reactions of Vinyl Platinum Complexes written by Zhandong Zhong and published by . This book was released on 1991 with total page 518 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Reactions of Amine Boranes and Related Compounds: (i) Mechanism of Dehydrogenation of Dimethylamine Borane (II) Synthesis of Trimethylamine Chlorobora by : James William Wiggins
Download or read book Reactions of Amine Boranes and Related Compounds: (i) Mechanism of Dehydrogenation of Dimethylamine Borane (II) Synthesis of Trimethylamine Chlorobora written by James William Wiggins and published by Sagwan Press. This book was released on 2018-02-08 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work has been selected by scholars as being culturally important, and is part of the knowledge base of civilization as we know it. This work was reproduced from the original artifact, and remains as true to the original work as possible. Therefore, you will see the original copyright references, library stamps (as most of these works have been housed in our most important libraries around the world), and other notations in the work. This work is in the public domain in the United States of America, and possibly other nations. Within the United States, you may freely copy and distribute this work, as no entity (individual or corporate) has a copyright on the body of the work. As a reproduction of a historical artifact, this work may contain missing or blurred pages, poor pictures, errant marks, etc. Scholars believe, and we concur, that this work is important enough to be preserved, reproduced, and made generally available to the public. We appreciate your support of the preservation process, and thank you for being an important part of keeping this knowledge alive and relevant.
Book Synopsis Nanocarbon and Its Composites by : Anish Khan
Download or read book Nanocarbon and Its Composites written by Anish Khan and published by Woodhead Publishing. This book was released on 2018-11-30 with total page 874 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanocarbon and Its Composites: Preparation, Properties and Applications provides a detailed and comprehensive review of all major innovations in the field of nanocarbons and their composites, including preparation, properties and applications. Coverage is broad and quite extensive, encouraging future research in carbon-based materials, which are in high demand due to the need to develop more sustainable, recyclable and eco-friendly methods for materials. Chapters are written by eminent scholars and leading experts from around the globe who discuss the properties and applications of carbon-based materials, such as nanotubes (buckytubes), fullerenes, cones, horns, rods, foams, nanodiamonds and carbon black, and much more. Chapters provide cutting-edge, up-to-date research findings on the use of carbon-based materials in different application fields and illustrate how to achieve significant enhancements in physical, chemical, mechanical and thermal properties. Demonstrates systematic approaches and investigations from design, synthesis, characterization and applications of nanocarbon based composites Aims to compile information on the various aspects of synthesis, properties and applications of nano-carbon based materials Presents a useful reference and technical guide for university academics and postgraduate students (Masters and Ph.D.)
Book Synopsis Exploring the Bonding and Reaction Chemistry of Gold and Platinum Complexes by : Bruce Wayne Flint
Download or read book Exploring the Bonding and Reaction Chemistry of Gold and Platinum Complexes written by Bruce Wayne Flint and published by . This book was released on 2001 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt: Platinum complexes have been synthesized and characterized. Relative Pt-X Bond Dissociation Energies (BDE's) for these complexes have been calculated from experimentally measured equilibrium and organic BDE's. Changes in relative BDE's are noted when ligands for the complexes are exchanged. Oxygen atom transfer reactions by a new platinum hydroxo catalyst have been studied. This catalyst is generated by the reaction of a platinum oxo complex with water and catalytically activates the reaction of the this complex with ethylene. The kinetics of this reaction have been studied and a reaction pathway has been proposed. The synthesis and characterization of a series of heteroatom substituted gold imido complexes have been reported. It has been demonstrated that the stability of gold imido complexes has a linear free energy relationship with the donor strength of the adjacent phosphine ligand. The decomposition of the complex involves the release of a free nitrene. Larger phosphine ligands retard the decomposition, and the decomposition is blocked by alkylation of the hydrazido ligand.
Book Synopsis American Doctoral Dissertations by :
Download or read book American Doctoral Dissertations written by and published by . This book was released on 1977 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Mechanistic studies of reactions of some platinum metal complexes by : David Huw Vaughan
Download or read book Mechanistic studies of reactions of some platinum metal complexes written by David Huw Vaughan and published by . This book was released on 1968 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis A Study of Substitution Reactions of Platinum (II) Complexes in Solvents of High Dielectric Constants by : Keh-Chi Tsai
Download or read book A Study of Substitution Reactions of Platinum (II) Complexes in Solvents of High Dielectric Constants written by Keh-Chi Tsai and published by . This book was released on 1966 with total page 108 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Reaction Chemistry of Fisher-Type Rhenacyclobutadiene and N̳3 Trimethylenemethane Platinum Complexes by : Véronique Plantevin
Download or read book Reaction Chemistry of Fisher-Type Rhenacyclobutadiene and N̳3 Trimethylenemethane Platinum Complexes written by Véronique Plantevin and published by . This book was released on 1995 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Nanophotocatalysis and Environmental Applications by : Inamuddin
Download or read book Nanophotocatalysis and Environmental Applications written by Inamuddin and published by Springer. This book was released on 2019-03-29 with total page 273 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents photocatalysis as a state-of-art technology in energy production and conversion. The ever increasing demand for energy with growing economies has led to a dearth of energy sources. The exhaustive dependability on non-renewable resources of energy has not just depleted them but also lead to the birth of secondary problems such as pollution and climate change. The photoactive processes have opened a new window for the production of green energy and helped in environmental sustainability. The harnessing of renewable sources especially sun and water for fuel production and noxious gases reduction solve both the issues of pollution mitigation and energy crisis.
Book Synopsis Progress in Inorganic Chemistry, Volume 11 by : Stephen J. Lippard
Download or read book Progress in Inorganic Chemistry, Volume 11 written by Stephen J. Lippard and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive series of volumes on inorganic chemistry provides inorganic chemists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Every volume reports recent progress with a significant, up-to-date selection of papers by internationally recognized researchers, complemented by detailed discussions and complete documentation. Each volume features a complete subject index and the series includes a cumulative index as well.
Book Synopsis Some Reactions of Zerovalent Platinum and Palladium Complexes by : Nuhad Salibi Akl
Download or read book Some Reactions of Zerovalent Platinum and Palladium Complexes written by Nuhad Salibi Akl and published by . This book was released on 1971 with total page 186 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Reactions of Aminoboron Compounds with Palladium and Platinum Complexes by : Christopher Martin Vogels
Download or read book Reactions of Aminoboron Compounds with Palladium and Platinum Complexes written by Christopher Martin Vogels and published by . This book was released on 1999 with total page 12 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Reactions of Platinum (II) Amine Complexes with Amino Acids and Peptides by : Paul David Prenzler
Download or read book Reactions of Platinum (II) Amine Complexes with Amino Acids and Peptides written by Paul David Prenzler and published by . This book was released on 1992 with total page 178 pages. Available in PDF, EPUB and Kindle. Book excerpt:
