Author : Ronald R. Goforth
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (143 download)
Book Synopsis Rapid Temperature Programming and Pyrolysis Gas Chromatography by : Ronald R. Goforth
Download or read book Rapid Temperature Programming and Pyrolysis Gas Chromatography written by Ronald R. Goforth and published by . This book was released on 1967 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: A system has been developed whereby a pyrogram may be obtained for each separated component in a gas chromatographic effluent. These pyrograms may be used for "fingerprint" identifications of the peaks on a chromatogram. During the development of this system the characteristics of a low- pressure-drop packed column were examined as well as gas phase pyrolysis and rapid temperature programming. Linear temperature programming with program rates up to 400°C per minute was developed and used with a wide range of carrier gas flow rates. Retention temperatures predicted from isothermal data were verified. The importance of correc tly specifying the flow rate during rapid temperature programming became apparent during the investigation when predicted retention temperatures were otherwise less than the experimentally observed values. Pyrolyzer design for gas phase pyrolysis was considered. The temperature profile for a tubular pyrolyzer was examined experimentally. The effects of temperature and residence time on gas phase pyrolysis were studied using several hydrocarbons.