Quinoxaline Schiff Base Complexes & Their Catalytic Activity Studies

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Publisher : LAP Lambert Academic Publishing
ISBN 13 : 9783659794698
Total Pages : 244 pages
Book Rating : 4.7/5 (946 download)

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Book Synopsis Quinoxaline Schiff Base Complexes & Their Catalytic Activity Studies by : Vasudevan Nair Arun

Download or read book Quinoxaline Schiff Base Complexes & Their Catalytic Activity Studies written by Vasudevan Nair Arun and published by LAP Lambert Academic Publishing. This book was released on 2015-10-22 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt: The research work deals with studies on the synthesis, characterization and catalytic activities of some transition metal complexes of the Schiff bases derived from 3-hydroxyquinoxaline-2-carboxaldehyde. Schiff bases which are considered as 'privileged ligands' have the ability to stabilize different metals in different oxidation states and thus regulate the performance of metals in a large variety of catalytic transformations. The catalytic activity of the Schiff base complexes is highly dependant on the environment about the metal center and their conformational flexibility. Therefore it is to be expected that the introduction of bulky substituents near the coordination sites might lead to low symmetry complexes with enhanced catalytic properties. With this view new transition metal complexes of Schiff bases derived from 3-hydroxyquinoxaline-2-carboxaldehyde have been synthesised. These Schiff bases have more basic donor nitrogen atoms and the presence of the quinoxaline ring may be presumed to build a favourable topography and electronic environment in the immediate coordination sphere of the metal.

Schiff Base Metal Complexes

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 3527839461
Total Pages : 229 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Schiff Base Metal Complexes by : Pranjit Barman

Download or read book Schiff Base Metal Complexes written by Pranjit Barman and published by John Wiley & Sons. This book was released on 2023-05-11 with total page 229 pages. Available in PDF, EPUB and Kindle. Book excerpt: Schiff Base Metal Complexes Schiff bases are compounds created from a condensed amino compounds, which frequently form complexes with metal ions. They have diverse applications in biology, catalysis, material science and industry. Understanding these compounds, their properties, and the available methods for synthesizing them is a key to unlocking industrial innovation. Schiff Base Metal Complexes provides a comprehensive overview of these compounds. It introduces the compounds and their properties before discussing their various synthesizing methods. A survey of existing and potential applications gives a complete picture and makes this a crucial guide for researchers and industry professionals looking to work with Schiff base complexes. Schiff Base Metal Complexes readers will also find: A systematic and organized structure designed to make information instantly accessible Detailed coverage of thermal synthesis, photochemical synthesis, and more Challenges with different methods described in order to help readers make the correct choice for their own work Schiff Base Metal Complexes is a useful reference for organic chemists, materials scientists, and researchers or industry professionals working with organometallics.

Vanillin- Aminoquinoline Schiff Bases and their Co(II), Ni(II) and Cu(II) Complexes

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Author :
Publisher : Lulu.com
ISBN 13 : 0359913911
Total Pages : 282 pages
Book Rating : 4.3/5 (599 download)

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Book Synopsis Vanillin- Aminoquinoline Schiff Bases and their Co(II), Ni(II) and Cu(II) Complexes by : Dr. S. N. Battin

Download or read book Vanillin- Aminoquinoline Schiff Bases and their Co(II), Ni(II) and Cu(II) Complexes written by Dr. S. N. Battin and published by Lulu.com. This book was released on with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Structural and Biological Applications of Schiff Base Metal Complexes

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Author :
Publisher : CRC Press
ISBN 13 : 1000865444
Total Pages : 265 pages
Book Rating : 4.0/5 (8 download)

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Book Synopsis Structural and Biological Applications of Schiff Base Metal Complexes by : Pallavi Jain

Download or read book Structural and Biological Applications of Schiff Base Metal Complexes written by Pallavi Jain and published by CRC Press. This book was released on 2023-05-31 with total page 265 pages. Available in PDF, EPUB and Kindle. Book excerpt: Coordination compounds have been well-known for their wide variety of applications for over a century, as well as enhancing the researcher’s interest and concern in evaluating their action mechanism. It is certainly one of the most intensely discussed research topics. Coordination compounds involve different metal-ion-ligand phenomenon. The involved metal ions play a significant role in structural association and functioning of several processes in the genetic and metabolism system. In recent years, Schiff base ligands have gained significant interest and received a keen interest of many researchers. Schiff’s base ligands have been recognized to hold a wide variety of biological and medicinal activities due to the presence of donor atoms. They have proved exceptional pharmalogical actions such as antimicrobial, anti-tuberclosis, antiplatelet, antidiabetic, antiarthritis, antioxidant, anti-inflammatory, anticancer, antiviral, antimalarial, and analgesic. These biologically active Schiff base ligands have also been shown to inhibit enzyme mobilization and, when bound to a metal ion, exhibit enhanced biological activity, making them useful in a number of fields. As a result, metal complexes of Schiff base ligands are gaining popularity due to their unique properties and functionalities. Schiff base complex-based research for educational and industrial purposes is booming, and the number of publications is gradually increasing. Despite these interests, there is currently no detailed book on Schiff base metal complexes that covers the structures, biological activities, and other non-biological perspectives. This book delves into the structures of Schiff base metal complexes, which are critical in assessing the biological viability of any complex. It also highlights their biological significance in pharma and drug discovery like antibacterial, antifungal, anticancer, anti-inflammatory, anti-arthritis, anti-diabetic, antioxidants, anti-proliferative, antitumor, anticancer, antiviral. The fundamentals of metal complexes are described, as well as an up-to-date outline of developments in synthesis, characterization methods, properties- chemical, thermal, optical, structural, and applications. This book also discusses the other applications of Schiff base metal complexes: as sensor (luminescent, electrochemical, and biosensor), as pigments in dying and paint industries, as photocatalyst to improve the degradation rate. Features : This book would be useful for academia, researchers and engineers working in the area of Schiff base and their metal complexes. This book will give an in-depth account of the properties of Schiff base and their metal complexes. This book will discuss the details of synthesis methods for Schiff base and their metal complexes. This book will cover emerging trends in the use of Schiff base metal complexes in the industry. This book will provide an overview of the wider biological applications of Schiff base metal complexes

Schiff Base Complexes for Catalytic Application

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Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (139 download)

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Book Synopsis Schiff Base Complexes for Catalytic Application by : Dileep R

Download or read book Schiff Base Complexes for Catalytic Application written by Dileep R and published by . This book was released on 2019 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Primary amines are combined with an aldehyde group to generate Schiff base compounds, which are called condensation imine products. This class of compounds has a general structure, R-C=NR\´, where R and R\´ represent alkyl/aryl/cyclohexyl/heterocyclic group. These compounds contain an azomethine group that is basic in nature due to, (i) the presence of lone pair of electrons on the nitrogen and (ii) electron-donating nature of the double bond. Hence, these compounds, as ligands, participate in the formation of metal complexes. The presence of lone pair of electrons on the nitrogen atom and the hybridization involved explains the physical, chemical, and spectral properties of nitrogen-containing moieties. In the case of (sp2) hybridization (trigonal structure), the lone pair of electrons occupies either a symmetrical unhybridized 2p orbital that is perpendicular to the plane of trigonal hybrids or a symmetrical hybrid orbital, whose axis is in the plane, leaving behind only the π-electrons in the unhybridized 2p orbital. A very similar type of hybridization is experienced by the nitrogen atom in the azomethine group. Traditional phosphine complexes of nickel, palladium, and platinum, particularly those of palladium, have played an extremely important role in the development of homogeneous catalysis. Schiff base complexes as catalysts have been studied for various organic transformations such as oxidation, epoxidation, reduction, coupling reactions, polymerization reactions, hydroformylations, and many more.

Structural and Biological Applications of Schiff Base Metal Complexes

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Author :
Publisher : CRC Press
ISBN 13 : 1000865460
Total Pages : 360 pages
Book Rating : 4.0/5 (8 download)

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Book Synopsis Structural and Biological Applications of Schiff Base Metal Complexes by : Pallavi Jain

Download or read book Structural and Biological Applications of Schiff Base Metal Complexes written by Pallavi Jain and published by CRC Press. This book was released on 2023-05-31 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: Coordination compounds have been well-known for their wide variety of applications for over a century, as well as enhancing the researcher’s interest and concern in evaluating their action mechanism. It is certainly one of the most intensely discussed research topics. Coordination compounds involve different metal-ion-ligand phenomenon. The involved metal ions play a significant role in structural association and functioning of several processes in the genetic and metabolism system. In recent years, Schiff base ligands have gained significant interest and received a keen interest of many researchers. Schiff’s base ligands have been recognized to hold a wide variety of biological and medicinal activities due to the presence of donor atoms. They have proved exceptional pharmalogical actions such as antimicrobial, anti-tuberclosis, antiplatelet, antidiabetic, antiarthritis, antioxidant, anti-inflammatory, anticancer, antiviral, antimalarial, and analgesic. These biologically active Schiff base ligands have also been shown to inhibit enzyme mobilization and, when bound to a metal ion, exhibit enhanced biological activity, making them useful in a number of fields. As a result, metal complexes of Schiff base ligands are gaining popularity due to their unique properties and functionalities. Schiff base complex-based research for educational and industrial purposes is booming, and the number of publications is gradually increasing. Despite these interests, there is currently no detailed book on Schiff base metal complexes that covers the structures, biological activities, and other non-biological perspectives. This book delves into the structures of Schiff base metal complexes, which are critical in assessing the biological viability of any complex. It also highlights their biological significance in pharma and drug discovery like antibacterial, antifungal, anticancer, anti-inflammatory, anti-arthritis, anti-diabetic, antioxidants, anti-proliferative, antitumor, anticancer, antiviral. The fundamentals of metal complexes are described, as well as an up-to-date outline of developments in synthesis, characterization methods, properties- chemical, thermal, optical, structural, and applications. This book also discusses the other applications of Schiff base metal complexes: as sensor (luminescent, electrochemical, and biosensor), as pigments in dying and paint industries, as photocatalyst to improve the degradation rate. Features : This book would be useful for academia, researchers and engineers working in the area of Schiff base and their metal complexes. This book will give an in-depth account of the properties of Schiff base and their metal complexes. This book will discuss the details of synthesis methods for Schiff base and their metal complexes. This book will cover emerging trends in the use of Schiff base metal complexes in the industry. This book will provide an overview of the wider biological applications of Schiff base metal complexes

Synthesis, Characterisation and Biological Activity Studies of Organo-bridged Metal Schiff Base Complexes with Qinoxaline Derivative

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Publisher :
ISBN 13 :
Total Pages : 378 pages
Book Rating : 4.:/5 (981 download)

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Book Synopsis Synthesis, Characterisation and Biological Activity Studies of Organo-bridged Metal Schiff Base Complexes with Qinoxaline Derivative by : Reagan Lehlogonolo Mohlala

Download or read book Synthesis, Characterisation and Biological Activity Studies of Organo-bridged Metal Schiff Base Complexes with Qinoxaline Derivative written by Reagan Lehlogonolo Mohlala and published by . This book was released on 2016 with total page 378 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Chiral Amino Alcohol Based Schiff Base Complexes

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Publisher : LAP Lambert Academic Publishing
ISBN 13 : 9783846581575
Total Pages : 148 pages
Book Rating : 4.5/5 (815 download)

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Book Synopsis Chiral Amino Alcohol Based Schiff Base Complexes by : Pradeep Parameswaran

Download or read book Chiral Amino Alcohol Based Schiff Base Complexes written by Pradeep Parameswaran and published by LAP Lambert Academic Publishing. This book was released on 2012-02 with total page 148 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work reports some original and significant contributions on chiral coordination complexes. Complexes of chiral amino alcohols based Schiff base ligands with biologically and catalytically important metal ions have been developed and studied with respect to their structural, spectroscopic, supramolecular and catalytic properties. The importance of chiral amino alcohol based Schiff base ligands in coordination chemistry is briefly discussed in the introduction chapter. Synthetic details and spectroscopic characterization data of some new chiral Schiff base ligands and their metal complexes are presented in chapter two. Detailed studies on a series of biologically and catalytically relevant chiral Mn(IV) complexes form the content of the third chapter. A series of interesting mixed valence multinuclear cobalt complexes of chiral amino alcohol based ligands has been described in chapter four. Studies on some chiral copper complexes highlighting their structural and supramolecular properties are presented in fifth chapter. Finally, the work is concluded giving an overall summary as the sixth chapter.

Quinoxalines

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Publisher : Springer
ISBN 13 : 3319297732
Total Pages : 451 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis Quinoxalines by : Vakhid A. Mamedov

Download or read book Quinoxalines written by Vakhid A. Mamedov and published by Springer. This book was released on 2016-04-26 with total page 451 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book reviews the fundamental aspects of quinoxaline chemistry: synthesis, reactions, mechanisms, structure, properties, and uses. The first four chapters present a survey of the developments in quinoxaline chemistry since the publication of the monograph on “Condensed Pyrazines” by Cheeseman and Cookson in 1979. These chapters give comprehensive coverage of all the methods of the synthesis of quinoxalines and the important quinoxaline-containing ring systems such as thiazolo[3,4-a]-, pyrrolo[1,2-a]-, and imidazo[1,5-a]quinoxalines. Chapter five describes many new methods for the construction of quinoxaline macrocycles, which are important in applications such as optical devices and materials. The final chapter reviews all previously known rearrangements of heterocyclic systems that lead to benzimidazole derivatives. Mamedov critically analyses these transformations to reveal a novel acid-catalyzed rearrangement of quinoxalinones giving 2-heteroarylbenzimidazoles and 1-heteroarylbenzimidazolones in the presence of nucleophilic reactants (MAMEDOV Heterocycle Rearrangement). This book is of interest to researchers in the fields of heterocyclic and synthetic organic chemistry.

Indian Journal of Chemistry

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Publisher :
ISBN 13 :
Total Pages : 654 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Indian Journal of Chemistry by :

Download or read book Indian Journal of Chemistry written by and published by . This book was released on 1998 with total page 654 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Diamines—Advances in Research and Application: 2012 Edition

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Author :
Publisher : ScholarlyEditions
ISBN 13 : 1481606271
Total Pages : 89 pages
Book Rating : 4.4/5 (816 download)

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Book Synopsis Diamines—Advances in Research and Application: 2012 Edition by :

Download or read book Diamines—Advances in Research and Application: 2012 Edition written by and published by ScholarlyEditions. This book was released on 2012-12-26 with total page 89 pages. Available in PDF, EPUB and Kindle. Book excerpt: Diamines—Advances in Research and Application: 2012 Edition is a ScholarlyEditions™ eBook that delivers timely, authoritative, and comprehensive information about Diamines. The editors have built Diamines—Advances in Research and Application: 2012 Edition on the vast information databases of ScholarlyNews.™ You can expect the information about Diamines in this eBook to be deeper than what you can access anywhere else, as well as consistently reliable, authoritative, informed, and relevant. The content of Diamines—Advances in Research and Application: 2012 Edition has been produced by the world’s leading scientists, engineers, analysts, research institutions, and companies. All of the content is from peer-reviewed sources, and all of it is written, assembled, and edited by the editors at ScholarlyEditions™ and available exclusively from us. You now have a source you can cite with authority, confidence, and credibility. More information is available at http://www.ScholarlyEditions.com/.

Schiff Base in Organic, Inorganic and Physical Chemistry

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Publisher : BoD – Books on Demand
ISBN 13 : 1803556781
Total Pages : 210 pages
Book Rating : 4.8/5 (35 download)

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Book Synopsis Schiff Base in Organic, Inorganic and Physical Chemistry by : Takashiro Akitsu

Download or read book Schiff Base in Organic, Inorganic and Physical Chemistry written by Takashiro Akitsu and published by BoD – Books on Demand. This book was released on 2023-03-08 with total page 210 pages. Available in PDF, EPUB and Kindle. Book excerpt: A Schiff base (imine -N=CH-) is a part of a popular group of organic compounds prepared form primary amines and aldehyde. Many studies have been carried out on Schiff bases not only as organic compounds but also as ligands for metal complexes. In this context, this book provides a comprehensive, interdisciplinary review of Schiff base compounds, with an emphasis on the latest advances. It compiles research results, commentary, reviews, and more dealing with preparation, spectroscopy, crystallography, (asymmetric) synthetic roles, physical properties (magnets, optics, etc.), computational chemistry, and theoretical chemistry. The book focuses on Schiff base and its strong connection to organic chemistry, biochemistry, and polymer materials chemistry. It covers three topics: Schiff base of organic chemistry, Schiff base of inorganic chemistry, and Schiff base of functional or biological materials.

Structure Determination from Powder Diffraction Data

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Publisher : OUP Oxford
ISBN 13 : 0198500912
Total Pages : 358 pages
Book Rating : 4.1/5 (985 download)

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Book Synopsis Structure Determination from Powder Diffraction Data by : William I. F. David

Download or read book Structure Determination from Powder Diffraction Data written by William I. F. David and published by OUP Oxford. This book was released on 2002 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: Our understanding of the properties of materials, from drugs and proteins to catalysts and ceramics, is almost always based on structural information. This book describes the new developments in the realm of powder diffraction which make it possible for scientists to obtain such information even from polycrystalline materials. Written and edited by experts active in the field, and covering both the fundamental and applied aspects of structure solution from powder diffraction data, this book guides both novices and experienced practitioners alike through the maze of possibilities.

Stability and Applications of Coordination Compounds

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Publisher : BoD – Books on Demand
ISBN 13 : 1838800573
Total Pages : 178 pages
Book Rating : 4.8/5 (388 download)

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Book Synopsis Stability and Applications of Coordination Compounds by : Abhay Nanda Srivastva

Download or read book Stability and Applications of Coordination Compounds written by Abhay Nanda Srivastva and published by BoD – Books on Demand. This book was released on 2020-07-08 with total page 178 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the current era of incessant developing needs for the betterment and ease in living style for humans, technology is seeking upgraded, well structured materials for utilization in various fields of human-wellness such as medication, energy, environment protection and cleaning, food security etc. In the same direction, chemists are doing very well at synthesizing compounds and materials from different groups of chemicals. Among them, coordination compounds also play a key role in serving humanity as these compounds have a wide range of applications in health care from antimicrobial to anticancer, bioengineering, bio-mimetic models, catalysis, photosensitized materials etc. Along with development of stable coordination compounds, their extensive structural studies are also in the main line of work for researchers. Twenty-nine authors from different countries have contributed their scientific views and work in magnifying the importance and scope of coordination compounds in the present book entitled “Stability and Applications of Coordination Compounds”. I hope that the book will achieve its target of supplementing the community of researchers and readers working in the field of coordination chemistry.

Indian Science Abstracts

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Publisher :
ISBN 13 :
Total Pages : 990 pages
Book Rating : 4.8/5 (39 download)

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Book Synopsis Indian Science Abstracts by :

Download or read book Indian Science Abstracts written by and published by . This book was released on 2008-05 with total page 990 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Organic Syntheses Based on Name Reactions and Unnamed Reactions

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Publisher : Elsevier
ISBN 13 : 1483287343
Total Pages : 462 pages
Book Rating : 4.4/5 (832 download)

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Book Synopsis Organic Syntheses Based on Name Reactions and Unnamed Reactions by : Alfred Hassner

Download or read book Organic Syntheses Based on Name Reactions and Unnamed Reactions written by Alfred Hassner and published by Elsevier. This book was released on 2013-10-22 with total page 462 pages. Available in PDF, EPUB and Kindle. Book excerpt: Synthetically useful organic reactions or reagents are often referred to by the name of the discoverer(s) or developer(s). Older name reactions are described in text books, but more recently developed synthetically useful reactions that may have been associated occasionally with a name are not always well known. For neither of the above are experimental procedures or references easy to find. In this monograph approximately 500 name reactions are included, of which over 200 represent newer name reactions and modern reagents. Each of these reactions are extremely useful for the contemporary organic chemistry researcher in industry or academic institutions. This book provides the information in an easily accessible form. In addition to seminal references and reviews, one or more examples for each name reaction are provided and a complete typical experimental procedure is included, to enable the student or researcher to immediately evaluate reaction conditions. Besides an alphabetical listing of reactions and reagents, cross references permit the organic practitioner to find those name reactions or reagents that enable specific transformations, such as, conversion of amines to nitriles, stereoselective reduction, fluoroalkylation, phenol alkynylation, asymmetric syntheses, allylic alkylation, nucleoside synthesis, cyclopentanation, hydrozirconation, to name a few. Emphasis has been placed on stereoselective and regioselective transformations as well as on enantioselective processes. The listing of reactions and reagents is supported by four indexes.

Photochemistry

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Publisher : Royal Society of Chemistry
ISBN 13 : 1849735808
Total Pages : 371 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Photochemistry by : Angelo Albini

Download or read book Photochemistry written by Angelo Albini and published by Royal Society of Chemistry. This book was released on 2013 with total page 371 pages. Available in PDF, EPUB and Kindle. Book excerpt: Annotation 'Photochemistry' reviews photo-induced processes that have relevance to the wide-ranging academic and commercial disciplines, and interests in chemistry, physics, biology and technology.