Pyrolysis of Lignocellulosic Materials with Waste Plastic to Produce Bio-Oil with High Liquid Yield and Chemicals

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Publisher :
ISBN 13 :
Total Pages : 32 pages
Book Rating : 4.:/5 (129 download)

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Book Synopsis Pyrolysis of Lignocellulosic Materials with Waste Plastic to Produce Bio-Oil with High Liquid Yield and Chemicals by : Witchakorn Charusiri

Download or read book Pyrolysis of Lignocellulosic Materials with Waste Plastic to Produce Bio-Oil with High Liquid Yield and Chemicals written by Witchakorn Charusiri and published by . This book was released on 2020 with total page 32 pages. Available in PDF, EPUB and Kindle. Book excerpt: The pyrolyzation of waste plastic and lignocellulosic material feedstocks increases the hydrogen/carbon ratio of the plastic-biomass mixture for feedstock pyrolysis and may be advantageous for the refinement of the properties of the pyrolyzed oil, which can be directly used as fuel without any upgrade requirements by catalytic hydrodeoxygenation reactions. In this paper, high-density polyethylene (HDPE) and brown salwood were tested in a custom-built laboratory-scale fixed-bed reactor to investigate the co-pyrolysis reaction at a temperature ranging from 500 to 650 °C, nitrogen sweeping flow rate ranging from 40 to 160 mL min -1 , and HDPE to biomass ratio ranging from 0.1 to 0.9. The results reveal that the temperature mostly influences the pyrolysis products, whereas increasing the temperature to 600 °C encourages pyrolysis oil production, and its yield reaches 48.13 wt.%, which decreases to 27.92 wt.% as the reaction temperature increases to 650 °C due to secondary cracking reactions producing noncondensable gas rich in hydrocarbons. Physicochemical analysis of the pyrolyzed organic phase revealed a gross calorific heating value up to approximately 38.19 MJ kg -1 . Additionally, co-pyrolysis with HDPE improved the production of furans, and acid derivatives were obtained in the aqueous fraction via the thermal conversion of hemicellulose and lignin, whereas the obtained char exhibited a notably low surface area and few superficial micropores.

Production of Biofuels and Chemicals with Pyrolysis

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Author :
Publisher : Springer Nature
ISBN 13 : 9811527326
Total Pages : 456 pages
Book Rating : 4.8/5 (115 download)

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Book Synopsis Production of Biofuels and Chemicals with Pyrolysis by : Zhen Fang

Download or read book Production of Biofuels and Chemicals with Pyrolysis written by Zhen Fang and published by Springer Nature. This book was released on 2020-10-27 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a collection of studies on state-of-art techniques for converting biomass to chemical products by means of pyrolysis, which are widely applicable to the valorization of biomass. In addition to discussing the fundamentals and mechanisms for producing bio-oils, chemicals, gases and biochar using pyrolysis, it outlines key reaction parameters and reactor configurations for various types of biomass. Written by leading experts and providing a broad range of perspectives on cutting-edge applications, the book is a comprehensive reference guide for academic researchers and industrial engineers in the fields of natural renewable materials, biorefinery of lignocellulose, biofuels, and environmental engineering, and a valuable resource for university students in the fields of chemical engineering, material science and environmental engineering.

Recycling of Solid Waste for Biofuels and Bio-chemicals

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Publisher : Springer
ISBN 13 : 9811001502
Total Pages : 429 pages
Book Rating : 4.8/5 (11 download)

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Book Synopsis Recycling of Solid Waste for Biofuels and Bio-chemicals by : Obulisamy Parthiba Karthikeyan

Download or read book Recycling of Solid Waste for Biofuels and Bio-chemicals written by Obulisamy Parthiba Karthikeyan and published by Springer. This book was released on 2016-08-10 with total page 429 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the latest advances in and current research perspectives on the field of urban/industrial solid waste recycling for bio-energy and bio-fuel recovery. It chiefly focuses on five main thematic areas, namely bioreactor landfills coupled with energy and nutrient recovery; microbial insights into anaerobic digestion; greenhouse emission assessment; pyrolysis techniques for special waste treatment; and industrial waste stabilization options. In addition, it compiles the results of case studies and solid waste management perspectives from different countries.

Pre-treatment Methods of Lignocellulosic Biomass for Biofuel Production

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Publisher : CRC Press
ISBN 13 : 1000481549
Total Pages : 59 pages
Book Rating : 4.0/5 (4 download)

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Book Synopsis Pre-treatment Methods of Lignocellulosic Biomass for Biofuel Production by : Shyamal Roy

Download or read book Pre-treatment Methods of Lignocellulosic Biomass for Biofuel Production written by Shyamal Roy and published by CRC Press. This book was released on 2021-08-31 with total page 59 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioconversion of lignocellulosic biomass to biofuel is materially obstructed by the compositional and chemical complexity of biomaterials, resulting in a challenge in using these as raw materials for the biofuel production process. This book explains various lignocellulosic biomass pre-treatment methods with emphasis on concepts, practicability, mechanisms of action, and advantages and disadvantages and potential for industrial applications. It also highlights the main challenges and suggests possible ways to make these pre-treatment technologies feasible for the biofuel industry. Features Presents different pre-treatment technologies available for lignocellulosic biomass in a concise manner. Covers use of different pre-treatment methods in laboratory to industrial scales. Includes combined pre-treatment and deep eutectic solvents methods. Discusses problems related to industrial adaptation and corresponding economics of different techniques. Explores significant fuels and chemicals derived from lignocellulosic biomass. This book is aimed at graduate students and researchers working on biomass conversion, characterization, cellulose, hemicellulose, lignin, microbial enzymes, fermentation technology, and industrial biotechnology.

Biomass Pyrolysis Liquids Upgrading and Utilization

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Publisher : Springer Science & Business Media
ISBN 13 : 9401138443
Total Pages : 381 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Biomass Pyrolysis Liquids Upgrading and Utilization by : A.V. Bridgwater

Download or read book Biomass Pyrolysis Liquids Upgrading and Utilization written by A.V. Bridgwater and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biomass pyrolysis has been practised for centuries in the manufacture of charcoal for industry and leisure. Only in the last two decades, however, has attention focussed on a better understanding of the science and technology, with the resultant benefits of better designed and controlled processes that give high yields of liquid products. These liquids, or 'bio-oil' as it is referred to, can be used in a variety of ways: -combustion to replace conventional fuel oil in boilers, process equipment such as kilns and in gas turbines for power generation; -upgrading by hydrotreating or with zeolites to gasoline, diesel and other hydrocarbon fuels, of chemicals; --extraction and upgrading to fuel additives and chemical specialities. Any charcoal produced can also be utilised to form char- water slurries, analogous to coal-water slurries, or bioi-oil slurries which may be used as liquid fuels in many combustion applications. A group of experts was set up in the EC Energy from Biomass programme to evaluate the status and opportunities for deriving useful liquid products from biomass pyrolysis. This book is a report of their findings and conclusions. It forms an authoritative guide to the wide range of technologies employed in biomass pyrolysis, and product upgrading, utilisation and characterisation. Recommendations and conclusions are included to identify promising areas of research and development that will be of value to researchers, planners and companies throughout the world.

Pyrolysis Bio-oil as a Renewable Fuel and Source of Chemicals

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (131 download)

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Book Synopsis Pyrolysis Bio-oil as a Renewable Fuel and Source of Chemicals by : Eid Musa Alsbou

Download or read book Pyrolysis Bio-oil as a Renewable Fuel and Source of Chemicals written by Eid Musa Alsbou and published by . This book was released on 2014 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Bio-oil is a liquid fuel that can be produced from various lignocellulosic feedstocks via fast pyrolysis. It is a complex mixture comprised of hundreds of highly oxygenated organic compounds originating from lignin and carbohydrates and is recognized as a clean renewable bio-fuel, an attractive alternative to fossil fuels. It can be easily transported and used directly in boilers and modified turbines or upgraded/fractionated for drop in fuels or chemical production. Proper bio-oil characterization is important in optimizing the pyrolysis process, bio-oil upgrading and utilization, and its stabilization for long-term storage. With this in mind, research has been undertaken to develop better techniques to rapidly profile the composition of whole bio-oil samples, and an accelerated aging study performed to determine why bio-oil is unstable upon storage. Pyrolysis-GC/MS and TLC-FID were used as tools to differentiate bio-oils of different lignocellulosic biomasses, and among thermal-cracking (upgrading) fractions. Results showed that birch bio-oil had high syringol derivatives compared to pine and barley straw bio-oils which had higher guaiacol and non-methoxy-phenolic compounds, respectively, compared with birch bio-oil. TLC-FID was successful in bio-oil differentiation, showing diagnostic chromatographic profile differences. Direct infusion-ESI-ion trap MS and ESI-ion trap MS2 were successfully used in the analysis of forest-residue bio-oil and reference bio-oils from cellulose and hardwood lignin dissolved in methanol:water. NH4Cl can be used as a dopant to distinguish carbohydrate-derived products from other bio-oil components. NaOH and NaCl dopants resulted in the highest intensity peaks in negative ion mode and positive mode, respectively. Tandem MS, that is, ESI-Ion Trap MS2 was a successful tool for the confirmation of individual target ions such as levoglucosan and cellobiosan and for structural insight into lignin products. In accelerated aging (at 80 °C for 1, 3 and 7 days) studies, the physical and chemical properties of bio-oil from ash wood (produced from a pilot-scale auger pyrolyzer) and birch wood (lab-scale pyrolyzer) were monitored in order to identify the factors responsible for bio-oil instability. Water content, viscosity, and decomposition temperature (by TGA) increased for both bio-oil samples with aging. Chemical analysis showed reduction in amount of most of the bio-oil components as aging progressed, typically for are olefins and aldehydes. The oils remained a single phase throughout until the 7th day.

Catalytic Biomass to Renewable Biofuels and Biomaterials

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Publisher : MDPI
ISBN 13 : 3039363123
Total Pages : 208 pages
Book Rating : 4.0/5 (393 download)

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Book Synopsis Catalytic Biomass to Renewable Biofuels and Biomaterials by : Yi-Tong Wang

Download or read book Catalytic Biomass to Renewable Biofuels and Biomaterials written by Yi-Tong Wang and published by MDPI. This book was released on 2020-11-13 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biomass is the only renewable carbon source that can be converted into high value-added carbon products. This book presents a collection of studies on the conversion of catalytic biomass to renewable biofuels and biomaterials by chemical conversion, co-combustion technology, and biological conversion technology. The fundamentals and mechanisms of catalytic materials design, process optimization, product development, and by-product utilization are outlined. All articles were contributed by experts in catalysis and bioenergy fields to provide readers with a broad range of perspectives on cutting-edge applications. This book is an ideal reference guide for academic researchers and engineering technicians in the fields of catalytic material synthesis, biomass energy conversion, enzyme catalysis, pyrolysis, combustion, vaporization, and fermentation. It can also be used as a comprehensive reference source for university students in renewable energy science and engineering, agricultural engineering, thermal engineering, chemical engineering, material science, and environmental engineering. This book contains 12 articles: (1) “Catalytic Biomass to Renewable Biofuels and Biomaterials”; (2) “Experimental Design to Improve Cell Growth and Ethanol Production in Syngas Fermentation by Clostridium carboxidivorans”; (3) “Glycerol Acetylation Mediated by Thermally Hydrolysed Biosolids-Based Material”; (4) “Influence of Base-Catalyzed Organosolv Fractionation of Larch Wood Sawdust on Fraction Yields and Lignin Properties”; (5) “Ca-based Catalysts for the Production of High-Quality Bio-Oils from the Catalytic Co-Pyrolysis of Grape Seeds and Waste Tyres”; (6) “Synthesis of Diesel and Jet Fuel Range Cycloalkanes with Cyclopentanone and Furfural”; (7) “Gel-Type and Macroporous Cross-Linked Copolymers Functionalized with Acid Groups for the Hydrolysis of Wheat Straw Pretreated with an Ionic Liquid”; (8) “Role of Humic Acid Chemical Structure Derived from Different Biomass Feedstocks on Fe(III) Bioreduction Activity: Implication for Sustainable Use of Bioresources”; (9) “Selective Production of Terephthalonitrile and Benzonitrile via Pyrolysis of Polyethylene Terephthalate (PET) with Ammonia over Ca(OH)2/Al2O3 Catalysts”; (10) “Experimental Studies on Co-Combustion of Sludge and Wheat Straw”; (11) “Carbonate-Catalyzed Room-Temperature Selective Reduction of Biomass-Derived 5-Hydroxymethylfurfural into 2,5-Bis(hydroxymethyl)furan”; (12) “Clostridium sp. as Bio-Catalyst for Fuels and Chemicals Production in a Biorefinery Context”.

Pyrolysis of Biomass for Fuels and Chemicals

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Author :
Publisher : Academic Press
ISBN 13 : 0128182148
Total Pages : 296 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Pyrolysis of Biomass for Fuels and Chemicals by : Akwasi A. Boateng

Download or read book Pyrolysis of Biomass for Fuels and Chemicals written by Akwasi A. Boateng and published by Academic Press. This book was released on 2020-05-27 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt: Pyrolysis of Biomass for Fuels and Chemicals provides a thorough overview of thermochemical conversion of biomass to fuels and chemicals via the pyrolysis platform. The book covers the principles underlying pyrolysis of biomass from the chemical engineering perspective. It discusses thermal-only pyrolysis, the traditional pyrolysis process under inert atmosphere with no catalyst, and the role of catalytic pyrolysis and tail gas reactive pyrolysis in resolving the instability issues associated with product distribution. The addresses condensed phase upgrading where the oil produced can be upgraded for stability or hydrogenated to drop-in transportation fuels, as well as feedstock selection, including opportunity fuels/feedstocks. Finally, pilot and demonstration scale projects from around the world are examined, and some immediate applications of pyrolysis oils in combustion systems are analyzed. Engineering researchers and professionals in the bioenergy, biochemical, and petrochemical fields find in this book a complete resource for understanding the relationships between possible technologies, applications, costs, and products value, as they tackle the challenges for large scale adoption of pyrolysis for the production of 2nd generation biofuels and biochemicals. PhD students in areas of energy, chemical, mechanical, and materials engineering will also benefit from fundamental and applied research in a concise format that can save them time and serve as a reference through bioenergy conversion courses. Covers thermal only pyrolysis, catalytic pyrolysis, and tail gas reactive pyrolysis Examines the relationships between technologies, applications, costs and products value, and end-use Offers a cradle-to-grave approach that includes coverage of feedstocks, their compositional traits, and how they affect conversion technologies with regard to yields, quality of pyrolysis fuel intermediates, and subsequent upgrade to drop-in fuels

Biorefinery of Alternative Resources: Targeting Green Fuels and Platform Chemicals

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Publisher : Springer Nature
ISBN 13 : 9811518041
Total Pages : 503 pages
Book Rating : 4.8/5 (115 download)

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Book Synopsis Biorefinery of Alternative Resources: Targeting Green Fuels and Platform Chemicals by : Sonil Nanda

Download or read book Biorefinery of Alternative Resources: Targeting Green Fuels and Platform Chemicals written by Sonil Nanda and published by Springer Nature. This book was released on 2020-03-31 with total page 503 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book summarizes recent advances in the processing of waste biomass resources to produce biofuels and biochemicals. Worldwide interest in clean energy sources, environmental protection, and mitigating global warming is rapidly gaining momentum and spurring on the search for alternative energy sources, especially for the transportation and industrial sectors. This book reviews the opportunities presented by low-cost organic waste materials, discussing their suitability for alternative fuel and fine chemical production, physicochemical characterization, conversion technologies, feedstock and fuel chemistry, refining technologies, fuel upgrading, residue management, and the circular economy. In addition, it explores applied aspects of biomass conversion by highlighting several significant thermochemical, hydrothermal and biological technologies. In summary, the book offers comprehensive and representative descriptions of key fuel processing technologies, energy conversion and management, waste valorization, eco-friendly waste remediation, biomass supply chain, lifecycle assessment, techno-economic analysis and the circular bioeconomy.

Fast Pyrolysis of Biomass

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Publisher : Royal Society of Chemistry
ISBN 13 : 1788011864
Total Pages : 291 pages
Book Rating : 4.7/5 (88 download)

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Book Synopsis Fast Pyrolysis of Biomass by : Robert C Brown

Download or read book Fast Pyrolysis of Biomass written by Robert C Brown and published by Royal Society of Chemistry. This book was released on 2017-06-30 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fast pyrolysis and related catalytic pyrolysis are of increasing interest as pathways to advanced biofuels that closely mimic traditional petroleum products. Research has moved from empirical investigations to more fundamental studies of pyrolysis mechanisms. Theories on the chemical and physical pathways from plant polymers to pyrolysis products have proliferated as a result. This book brings together the latest developments in pyrolysis science and technology. It examines, reviews and challenges the unresolved and sometimes controversial questions about pyrolysis, helping advance the understanding of this important technology and stimulating discussion on the various competing theories of thermal deconstruction of plant polymers. Beginning with an introduction to the biomass-to-biofuels process via fast pyrolysis and catalytic pyrolysis, chapters address prominent questions such as whether free radicals or concerted reactions dominate deconstruction reactions. Finally, the book concludes with an economic analysis of fast pyrolysis versus catalytic pyrolysis. This book will be of interest to advanced students and researchers interested in the science behind renewable fuel technology, and particularly the thermochemical processing of biomass.

Sustainable Catalytic Conversion of Biomass for the Production of Biofuels and Bioproducts

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Publisher : MDPI
ISBN 13 : 3039364332
Total Pages : 216 pages
Book Rating : 4.0/5 (393 download)

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Book Synopsis Sustainable Catalytic Conversion of Biomass for the Production of Biofuels and Bioproducts by : Gabriel Morales

Download or read book Sustainable Catalytic Conversion of Biomass for the Production of Biofuels and Bioproducts written by Gabriel Morales and published by MDPI. This book was released on 2020-12-02 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biomass is widely considered as a potential alternative to dwindling fossil fuel reserves. There is a large variety of biomass sources (oleaginous, lignocellulosic, algae, etc.), with many possible conversion routes and products. Currently, biomass is not just viewed as a source of biofuels, but also as an interesting feedstock for the production of bio-based chemicals that could largely replace petrochemicals. In this context, the search for new sustainable and efficient alternatives to fossil sources is gaining increasing relevance within the chemical industry. There, the role of catalysis is often critical for the development of clean and sustainable processes, aiming to produce commodity chemicals or liquid fuels with a high efficiency and atom economy. This book gathers works at the cutting edge of investigation in the application of catalysis, for the sustainable conversion of biomass into biofuels and bio-based chemicals.

Lignocellulosic Precursors Used in the Synthesis of Activated Carbon

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Publisher : BoD – Books on Demand
ISBN 13 : 9535101978
Total Pages : 104 pages
Book Rating : 4.5/5 (351 download)

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Book Synopsis Lignocellulosic Precursors Used in the Synthesis of Activated Carbon by : Virginia Hernández Montoya

Download or read book Lignocellulosic Precursors Used in the Synthesis of Activated Carbon written by Virginia Hernández Montoya and published by BoD – Books on Demand. This book was released on 2012-02-29 with total page 104 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present book discusses the principal lignocellulosic precursors used in the elaboration of activated carbons in different countries such as Asia, America, Europe and Africa; the different methods and experimental conditions employed in the synthesis of activated carbons, including one analysis of the principal stages of the preparation such as carbonization and activation (i.e., chemical or physical activation). Also, the recent and more specialized techniques used in the characterization of activated carbons are discussed in this book. For example, the techniques employed to determine textural parameters (mercury porosimetry and gas adsorption isotherms at 77 K) and different spectroscopies to determine chemical functionality (Raman, FT-IR, etc.) and other X-Ray techniques. Additionally, an overview of the application of activated carbons obtained from lignocellulosic precursors for wastewater treatment. Specifically, the analysis and discussion are focused on the advantages and capabilities of activated carbons for the removal of relevant toxic compounds and pollutants from water such as heavy metals, dyes, phenol, etc. Finally, the use of pyrolysis method for the valorization of two Mexican typical agricultural wastes (orange peel and pecan nut shell) for energy and carbon production is considered in this book.

Biomass, Biofuels, Biochemicals

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Publisher : Elsevier
ISBN 13 : 0128202963
Total Pages : 361 pages
Book Rating : 4.1/5 (282 download)

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Book Synopsis Biomass, Biofuels, Biochemicals by : Thallada Bhaskar

Download or read book Biomass, Biofuels, Biochemicals written by Thallada Bhaskar and published by Elsevier. This book was released on 2021-01-22 with total page 361 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biomass, Biofuels, Biochemicals: Lignin Biorefinery discusses the scientific and technical information relating to the structure and physico-chemical characteristics of lignin. The book covers the different processes (biological, thermal and catalytic routes) available for lignin conversion into specialty chemicals or fuels, activity relationships, and how optimized process parameters help establish the feasible size of the commercial plant in a centralized or decentralized model. In addition, the advantages and limitations of different technologies are discussed, considering local energy, chemicals, biopolymers, drug intermediates, activated carbons, and much more. - Includes information on the most advanced and innovative processes for lignin conversion - Covers information on biochemical and thermo-chemical processes for lignin valorization - Provides information on lignin chemistry and its conversion into high value chemicals and fuels - Presents a book designed as a text book, not merely a collection of research articles

Thermochemical Processing of Biomass

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Publisher : John Wiley & Sons
ISBN 13 : 1119417570
Total Pages : 426 pages
Book Rating : 4.1/5 (194 download)

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Book Synopsis Thermochemical Processing of Biomass by : Robert C. Brown

Download or read book Thermochemical Processing of Biomass written by Robert C. Brown and published by John Wiley & Sons. This book was released on 2019-05-28 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive examination of the large number of possible pathways for converting biomass into fuels and power through thermochemical processes Bringing together a widely scattered body of information into a single volume, this book provides complete coverage of the many ways that thermochemical processes are used to transform biomass into fuels, chemicals and power. Fully revised and updated, this new edition highlights the substantial progress and recent developments that have been made in this rapidly growing field since publication of the first edition and incorporates up-to-date information in each chapter. Thermochemical Processing of Biomass: Conversion into Fuels, Chemicals and Power, 2nd Edition incorporates two new chapters covering: condensed phased reactions of thermal deconstruction of biomass and life cycle analysis of thermochemical processing systems. It offers a new introductory chapter that provides a more comprehensive overview of thermochemical technologies. The book also features fresh perspectives from new authors covering such evolving areas as solvent liquefaction and hybrid processing. Other chapters cover combustion, gasification, fast pyrolysis, upgrading of syngas and bio-oil to liquid transportation fuels, and the economics of thermochemically producing fuels and power, and more. Features contributions by a distinguished group of European and American researchers offering a broad and unified description of thermochemical processing options for biomass Combines an overview of the current status of thermochemical biomass conversion as well as engineering aspects to appeal to the broadest audience Edited by one of Biofuels Digest’s "Top 100 People" in bioenergy for six consecutive years Thermochemical Processing of Biomass: Conversion into Fuels, Chemicals and Power, 2nd Edition will appeal to all academic researchers, process chemists, and engineers working in the field of biomass conversion to fuels and chemicals. It is also an excellent book for graduate and advanced undergraduate students studying biomass, biofuels, renewable resources, and energy and power generation.

Liquid Biofuels

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Publisher : John Wiley & Sons
ISBN 13 : 1119791987
Total Pages : 754 pages
Book Rating : 4.1/5 (197 download)

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Book Synopsis Liquid Biofuels by : Krushna Prasad Shadangi

Download or read book Liquid Biofuels written by Krushna Prasad Shadangi and published by John Wiley & Sons. This book was released on 2021-06-29 with total page 754 pages. Available in PDF, EPUB and Kindle. Book excerpt: Compiled by a well-known expert in the field, Liquid Biofuels provides a profound knowledge to researchers about biofuel technologies, selection of raw materials, conversion of various biomass to biofuel pathways, selection of suitable methods of conversion, design of equipment, selection of operating parameters, determination of chemical kinetics, reaction mechanism, preparation of bio-catalyst: its application in bio-fuel industry and characterization techniques, use of nanotechnology in the production of biofuels from the root level to its application and many other exclusive topics for conducting research in this area. Written with the objective of offering both theoretical concepts and practical applications of those concepts, Liquid Biofuels can be both a first-time learning experience for the student facing these issues in a classroom and a valuable reference work for the veteran engineer or scientist. The description of the detailed characterization methodologies along with the precautions required during analysis are extremely important, as are the detailed description about the ultrasound assisted biodiesel production techniques, aviation biofuels and its characterization techniques, advance in algal biofuel techniques, pre-treatment of biomass for biofuel production, preparation and characterization of bio-catalyst, and various methods of optimization. The book offers a comparative study between the various liquid biofuels obtained from different methods of production and its engine performance and emission analysis so that one can get the utmost idea to find the better biofuel as an alternative fuel. Since the book covers almost all the field of liquid biofuel production techniques, it will provide advanced knowledge to the researcher for practical applications across the energy sector. A valuable reference for engineers, scientists, chemists, and students, this volume is applicable to many different fields, across many different industries, at all levels. It is a must-have for any library.

Pyrolysis of Biomass

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Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 3110386127
Total Pages : 445 pages
Book Rating : 4.1/5 (13 download)

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Book Synopsis Pyrolysis of Biomass by : Shurong Wang

Download or read book Pyrolysis of Biomass written by Shurong Wang and published by Walter de Gruyter GmbH & Co KG. This book was released on 2016-12-05 with total page 445 pages. Available in PDF, EPUB and Kindle. Book excerpt: With the development of societies fossil energy is no longer the only energy resource, and increasing attention had been paid to alternative energy. Biomass is considered to be one of the alternatives due to efficiency and low cost. This book presents biomass pyrolysis behavior for three main components: Cellulose, Hemicellulose and Lignin, and discusses the influence of mineral salts , zeolite catalysts and metal oxide on their pyrolysis.

Primary and Secondary Reactions of Cellulose Melt Pyrolysis

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Author :
Publisher :
ISBN 13 :
Total Pages : 102 pages
Book Rating : 4.:/5 (93 download)

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Book Synopsis Primary and Secondary Reactions of Cellulose Melt Pyrolysis by : Alex D. Paulsen

Download or read book Primary and Secondary Reactions of Cellulose Melt Pyrolysis written by Alex D. Paulsen and published by . This book was released on 2014 with total page 102 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fast pyrolysis of biomass is a next-generation biofuels production process that is capable of converting solid lignocellulosic materials (in their raw form) to a transportable liquid (bio-oil) which can be catalytically hydrogenated to fuels and chemicals. Pyrolysis reactors depolymerize solid biomass by heating the feedstock (in the absence of oxygen) up to high temperatures (400 - 600 °C) to produce a short-lived intermediate liquid phase (only a few seconds), which ultimately breaks down to form small (1-6 carbon) oxygenates. These vapor-products can then be condensed at room temperature to produce liquid bio-oil. While biomass fast pyrolysis has enormous potential to produce renewable fuels, an understanding of the fundamental chemistry and transport processes of biomass pyrolysis to produce bio-oil is not available in the literature. This work utilizes co-pyrolysis and isotopic labeling to study the liquid-phase secondary reactions of levoglucosan to form anhydrosugars, pyrans, and light oxygenates. Isotopic labeling studies also reveal that hydrogen exchange is a critical component of levoglucosan deoxygenation. Next, the effects of pyrolysis reaction temperature and sample length scale are discussed. These studies revealed that the yield of total furan rings (i.e., all products containing a five-membered furan ring) does not change significantly with increased reaction temperature compared to other pyrolysis products, such as light oxygenates and anhydrosugars. However, the functional groups bound to the furan ring (e.g., alcohols and aldehydes) are easily cleaved to produce smaller furans. This chemistry was targeted by impregnating cellulose with palladium on carbon to selectively decarbonylate oxygenated furans within liquid intermediate cellulose to form deoxygenated furans resulting in a more stable bio-oil. The last part of this thesis, a new experimental technique, Spatiotemporally-Resolved Diffuse Reflectance in situ Spectroscopy of Particles (STR-DRiSP), which is capable of measuring biomass composition during fast pyrolysis with high spatial (ten micron) and temporal (one millisecond) resolution is developed. Compositional data were compared with a comprehensive two-dimensional single particle model. The STR-DRiSP technique can be used to determine the transport-limited kinetic parameters of biomass decomposition for a wide variety of biomass feedstocks.