Pulsed Field Gradient Multidimensional NMR Studies of Polyethylene Based Copolymers at High Temperature

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Publisher :
ISBN 13 :
Total Pages : 132 pages
Book Rating : 4.:/5 (957 download)

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Book Synopsis Pulsed Field Gradient Multidimensional NMR Studies of Polyethylene Based Copolymers at High Temperature by : Tong Zhang

Download or read book Pulsed Field Gradient Multidimensional NMR Studies of Polyethylene Based Copolymers at High Temperature written by Tong Zhang and published by . This book was released on 2001 with total page 132 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Multidimensional NMR Studies of Poly(ethylene-co-1-octene) Copolymers and Poly(ethylene-co-vinyl Acetate-co-carbon Monoxide) Terpolymers

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Publisher :
ISBN 13 :
Total Pages : 140 pages
Book Rating : 4.:/5 (97 download)

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Book Synopsis Multidimensional NMR Studies of Poly(ethylene-co-1-octene) Copolymers and Poly(ethylene-co-vinyl Acetate-co-carbon Monoxide) Terpolymers by : Anuttra Nuamthanom

Download or read book Multidimensional NMR Studies of Poly(ethylene-co-1-octene) Copolymers and Poly(ethylene-co-vinyl Acetate-co-carbon Monoxide) Terpolymers written by Anuttra Nuamthanom and published by . This book was released on 2007 with total page 140 pages. Available in PDF, EPUB and Kindle. Book excerpt: The comonomer and stereo-sequences of poly(ethylene-co-1-octene) samples with varying 1-octene content and degree of tacticity were investigated using high-temperature (120 °C) one- and two- dimensional (1D and 2D) nuclear magnetic resonance (NMR) techniques on a 750 MHz instrument. The techniques used include quantitative 13C NMR, pulsed-field-gradient (PFG) 1H -13C heteronuclear single quantum coherence (gHSQC), heteronuclear multiple bond correlation (gHMBC) and heteronuclear single quantum coherence-total correlation spectroscopy (gHSQC-TOCSY). Diffusion-ordered 2D NMR spectroscopy (DOSY) was used to confirm that the copolymer samples were not mixtures of two copolymers with different MW. Quantitative analysis of octene content was determined from quantitative 13C NMR experiments. The degree of tacticity was established by quantitative volume integration of 2D gHSQC NMR spectra. The comonomer sequence distributions and the resonance assignments of poly(ethylene-co-vinyl acetate-co-carbon monoxide), polyEVC* terpolymer prepared from 13C-labeled carbon monoxide were also investigated using high temperature (120 °C) multidimensional (1D, 2D and 3D) NMR experiments on the same spectrometer. The NMR techniques used include 1D- 1H, 13C, 2D- gHSQC, gHMBC, gHSQC-TOCSY, 3D-gHCACX and 3D-gHCACX-HH-TOCSY NMR experiments. With 13C labeling of the polymer combined with high resolution multidimensional NMR experiments, pentad monomer sequence assignments can be made for the carbon monoxide (C)-centered pentads. The degradation of polyEVC* was also examined by 1D and 2D NMR. The NMR spectra show that [alpha], [beta]-unsaturated carbonyl groups are a degradation product in this terpolymer, arising from elimination of acetic acid from CV dyads.

Nuclear Magnetic Resonance

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Publisher : Royal Society of Chemistry
ISBN 13 : 0854043527
Total Pages : 620 pages
Book Rating : 4.8/5 (54 download)

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Book Synopsis Nuclear Magnetic Resonance by : G. A. Webb

Download or read book Nuclear Magnetic Resonance written by G. A. Webb and published by Royal Society of Chemistry. This book was released on 2005 with total page 620 pages. Available in PDF, EPUB and Kindle. Book excerpt: For those wanting to become rapidly acquainted with specific areas of NMR, this title provides unrivalled scope of coverage.

Maro Polymer Notes

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Publisher :
ISBN 13 :
Total Pages : 280 pages
Book Rating : 4.:/5 (31 download)

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Book Synopsis Maro Polymer Notes by :

Download or read book Maro Polymer Notes written by and published by . This book was released on 2000 with total page 280 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Engineered Materials Abstracts

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ISBN 13 :
Total Pages : 274 pages
Book Rating : 4.3/5 (91 download)

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Download or read book Engineered Materials Abstracts written by and published by . This book was released on 1994-02 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt:

NMR Spectroscopy of Polymers

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Publisher : OUP USA
ISBN 13 : 9780841226678
Total Pages : 0 pages
Book Rating : 4.2/5 (266 download)

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Book Synopsis NMR Spectroscopy of Polymers by : H.N. Cheng

Download or read book NMR Spectroscopy of Polymers written by H.N. Cheng and published by OUP USA. This book was released on 2012-04-19 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Includes review and papers on the latest advances by acknowledged leaders and active researchers in nuclear magnetic resonance (NMR) spectroscopy

Scientific and Technical Aerospace Reports

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ISBN 13 :
Total Pages : 1190 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Scientific and Technical Aerospace Reports by :

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1982 with total page 1190 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Multidimensional Solid-State NMR and Polymers

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Publisher : Elsevier
ISBN 13 : 0080925626
Total Pages : 501 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Multidimensional Solid-State NMR and Polymers by : Klaus Schmidt-Rohr

Download or read book Multidimensional Solid-State NMR and Polymers written by Klaus Schmidt-Rohr and published by Elsevier. This book was released on 2012-12-02 with total page 501 pages. Available in PDF, EPUB and Kindle. Book excerpt: NMR spectroscopy is the most valuable and versatile analytical tool in chemistry. While excellent monographs exist on high-resolution NMR in liquids and solids, this is the first book to address multidimensional solid-state NMR. Multidimensional techniques enable researchers to obtain detailed information about the structure, dynamics, orientation, and phase separation of solids, which provides the basis of a better understanding of materials properties on the molecular level.Dramatic progress-much of it pioneered by the authors-has been achieved in this area, especially in synthetic polymers. Solid-state NMR now favorably competes with well-established techniques, such as light, x-ray, or neutron scattering, electron microscopy, and dielectric and mechanical relaxation.The application of multidimensional solid-state NMR inevitably involves use of concepts from different fields of science. This book also provides the first comprehensive treatment of both the new experimental techniques and the theoretical concepts needed in more complex data analysis. The text addresses spectroscopists and polymer scientists by treating the subject on different levels; descriptive, technical, and mathematical approaches are used when appropriate. It presents an overview of new developments with numerous experimental examples and illustrations, which will appeal to readers interested in both the information content as well as the potential of solid-state NMR. The book also contains many previously unpublished details that will be appreciated by those who want to perform the experiments. The techniques described are applicable not only to the study of synthetic polymers but to numerous problems in solid-state physics, chemistry, materials science, and biophysics. - Presents original theories and new perspectives on scattering techniques - Provides a systematic treatment of the whole subject - Gives readers access to previously unpublished material - Includes extensive illustrations

Scientific and Technical Aerospace Reports

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ISBN 13 :
Total Pages : 1142 pages
Book Rating : 4.E/5 ( download)

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Book Synopsis Scientific and Technical Aerospace Reports by :

Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1988 with total page 1142 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Experimental Approaches of NMR Spectroscopy

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Publisher : Springer
ISBN 13 : 9811059667
Total Pages : 634 pages
Book Rating : 4.8/5 (11 download)

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Book Synopsis Experimental Approaches of NMR Spectroscopy by : The Nuclear Magnetic Resonance Society of Japan

Download or read book Experimental Approaches of NMR Spectroscopy written by The Nuclear Magnetic Resonance Society of Japan and published by Springer. This book was released on 2017-11-23 with total page 634 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes the advanced developments in methodology and applications of NMR spectroscopy to life science and materials science. Experts who are leaders in the development of new methods and applications of life and material sciences have contributed an exciting range of topics that cover recent advances in structural determination of biological and material molecules, dynamic aspects of biological and material molecules, and development of novel NMR techniques, including resolution and sensitivity enhancement. First, this book particularly emphasizes the experimental details for new researchers to use NMR spectroscopy and pick up the potentials of NMR spectroscopy. Second, the book is designed for those who are involved in either developing the technique or expanding the NMR application fields by applying them to specific samples. Third, the Nuclear Magnetic Resonance Society of Japan has organized this book not only for NMR members of Japan but also for readers worldwide who are interested in using NMR spectroscopy extensively.

Chemical Abstracts

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ISBN 13 :
Total Pages : 2616 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Chemical Abstracts by :

Download or read book Chemical Abstracts written by and published by . This book was released on 2002 with total page 2616 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Index Medicus

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ISBN 13 :
Total Pages : 2002 pages
Book Rating : 4.:/5 (319 download)

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Book Synopsis Index Medicus by :

Download or read book Index Medicus written by and published by . This book was released on 2004 with total page 2002 pages. Available in PDF, EPUB and Kindle. Book excerpt: Vols. for 1963- include as pt. 2 of the Jan. issue: Medical subject headings.

Gas Phase NMR

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Publisher : Royal Society of Chemistry
ISBN 13 : 1782623817
Total Pages : 419 pages
Book Rating : 4.7/5 (826 download)

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Book Synopsis Gas Phase NMR by : Karol Jackowski

Download or read book Gas Phase NMR written by Karol Jackowski and published by Royal Society of Chemistry. This book was released on 2016-02-09 with total page 419 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the recent NMR studies with the application of gaseous molecules. Among the comprehensively discussed aspects of the area it includes in particular: new multinuclear experiments that deliver spectral parameters of isolated molecules and provide the most accurate values of nuclear magnetic shielding, isotropic spin–spin coupling and relaxation times; advanced, precise and correct theoretical descriptions of spectral parameters of molecules as well as the application of gas-phase NMR measurements to chemical analysis and medicine. The progress of research in these fields is enormous and has rapidly changed our knowledge and understanding of molecular parameters in NMR spectroscopy. For example, accurate studies of the shielding for isolated molecules allow the exact determination of nuclear magnetic dipole moments, the calculated values of spectral parameters can be verified by precise gas-phase NMR measurements, and the application of hyperpolarized noble gases provides excellent MRI pictures of lungs. Aimed at graduates and researchers in spectroscopy, analytical chemistry and those researching the applications of NMR in medicine, this book presents the connections between sophisticated experiments, the theory of magnetic parameters and the exploration of new methods in practice.

Proton Conductors

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Publisher : Cambridge University Press
ISBN 13 : 9780521383172
Total Pages : 618 pages
Book Rating : 4.3/5 (831 download)

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Book Synopsis Proton Conductors by : Philippe Colomban

Download or read book Proton Conductors written by Philippe Colomban and published by Cambridge University Press. This book was released on 1992-09-25 with total page 618 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book gives a comprehensive review of proton conductors, including theory, techniques, the materials themselves and applications.

Nondestructive Characterization of Materials

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Publisher : Springer Science & Business Media
ISBN 13 : 3642840035
Total Pages : 894 pages
Book Rating : 4.6/5 (428 download)

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Book Synopsis Nondestructive Characterization of Materials by : Paul Höller

Download or read book Nondestructive Characterization of Materials written by Paul Höller and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 894 pages. Available in PDF, EPUB and Kindle. Book excerpt: Engineering structures for reliable function and safety have to be designed such that operational mechanical loads are compensated for by stresses in the components bearable by the materials used. Vhat is "bearable"? First of all it depends on the properties of the chosen materials as well as on several other parameters, e.g. temperature, corrosivity of the environment, elapsed or remaining serviceable life, unexpected deterioration of materials, whatever the source and nature of such deterioration may be: defects, loss of strength, embrittlement, wastage, etc. DEFECTS and PROPERTIES of materials currently determine loadability. Therefore in addition to nondestructive testing for defects there is also a need for nondestructive testing of properties. The third type of information to be supplied by nondestructive measurement pertains to STRESS STATES under OPERATIONAL LOADS, i.e. LOAD-INDUCED plus RESIDUAL STRESSES. Residual stresses normally cannot be calculated; they have to be measured nondestructively; well-approved elastomechanical finite element codes are available and used for calculating load-induced stresses; for redundancy and reliability, engineers, however, need procedures and instrumentation for experimental checks.

Broadband Dielectric Spectroscopy

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Publisher : Springer Science & Business Media
ISBN 13 : 3642561209
Total Pages : 740 pages
Book Rating : 4.6/5 (425 download)

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Book Synopsis Broadband Dielectric Spectroscopy by : Friedrich Kremer

Download or read book Broadband Dielectric Spectroscopy written by Friedrich Kremer and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 740 pages. Available in PDF, EPUB and Kindle. Book excerpt: Both an introductory course to broadband dielectric spectroscopy and a monograph describing recent dielectric contributions to current topics, this book is the first to cover the topic and has been hotly awaited by the scientific community.

NMR Spectroscopy Techniques

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Publisher : Marcel Dekker
ISBN 13 :
Total Pages : 392 pages
Book Rating : 4.:/5 (319 download)

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Book Synopsis NMR Spectroscopy Techniques by : C. R. Dybowski

Download or read book NMR Spectroscopy Techniques written by C. R. Dybowski and published by Marcel Dekker. This book was released on 1987 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: