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Process Development For Permanganate Addition During Oxidative Leaching Of Hanford Tanks Sludges
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Book Synopsis Process Development for Permanganate Addition During Oxidative Leaching of Hanford Tanks Sludges by :
Download or read book Process Development for Permanganate Addition During Oxidative Leaching of Hanford Tanks Sludges written by and published by . This book was released on 2007 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Previous Bechtel National, Incorporated (BNI)-sponsored studies have targeted optimizing sodium permanganate for the selective oxidation of chromium from washed Hanford tank sludges (Rapko et al. 2004; Rapko et al. 2005). The recommendation from previous work was that contact with sodium permanganate in a minimally caustic solution, i.e., 0.1 to 0.25 M [OH-] initially, provided maximum Cr dissolution while minimizing concomitant Pu dissolution. At the request of BNI, further work on oxidative alkaline leaching was performed.
Book Synopsis Effect of Antifoam Agent on Oxidative Leaching of Hanford Tank Sludge Simulants by :
Download or read book Effect of Antifoam Agent on Oxidative Leaching of Hanford Tank Sludge Simulants written by and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Oxidative leaching of simulant tank waste containing an antifoam agent (AFA) to reduce the chromium content of the sludge was tested using permanganate as the oxidant in 0.25 M NaOH solutions. AFA is added to the waste treatment process to prevent foaming. The AFA, Dow Corning Q2-3183A, is a surface-active polymer that consists of polypropylene glycol, polydimethylsiloxane, octylphenoxy polyethoxy ethanol, treated silica, and polyether polyol. Some of the Hanford Tank Waste Treatment and Immobilization Plant (WTP) waste slurries contain high concentrations of undissolved solids that would exhibit undesirable behavior without AFA addition. These tests were conducted to determine the effect of the AFA on oxidative leaching of Cr(III) in waste by permanganate. It has not previously been determined what effect AFA has on the permanganate reaction. This study was conducted to determine the effect AFA has on the oxidation of the chromium, plus plutonium and other criticality-related elements, specifically Fe, Ni and Mn. During the oxidative leaching process, Mn is added as liquid permanganate solution and is converted to an insoluble solid that precipitates as MnO2 and becomes part of the solid waste. Caustic leaching was performed followed by an oxidative leach at either 25°C or 45°C. Samples of the leachate and solids were collected at each step of the process. Initially, Battelle-Pacific Northwest Division (PNWD) was contracted by Bechtel National, Inc. to perform these further scoping studies on oxidative alkaline leaching. The data obtained from the testing will be used by the WTP operations to develop procedures for permanganate dosing of Hanford tank sludge solids during oxidative leaching. Work was initially conducted under contract number 24590-101-TSA-W000-00004. In February 2007, the contract mechanism was switched to Pacific Northwest National Laboratory (PNNL) operating Contract DE-AC05-76RL01830. In summary, this report describes work focused on determining the effect of AFA on chromium oxidation by permanganate with Hanford sludge simulant.
Book Synopsis Laboratory Demonstration of the Pretreatment Process with Caustic and Oxidative Leaching Using Actual Hanford Tank Waste by :
Download or read book Laboratory Demonstration of the Pretreatment Process with Caustic and Oxidative Leaching Using Actual Hanford Tank Waste written by and published by . This book was released on 2009 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This report describes the bench-scale pretreatment processing of actual tank waste materials through the entire baseline WTP pretreatment flowsheet in an effort to demonstrate the efficacy of the defined leaching processes on actual Hanford tank waste sludge and the potential impacts on downstream pretreatment processing. The test material was a combination of reduction oxidation (REDOX) tank waste composited materials containing aluminum primarily in the form of boehmite and dissolved S saltcake containing Cr(III)-rich entrained solids. The pretreatment processing steps tested included caustic leaching for Al removal solids crossflow filtration through the cell unit filter (CUF) stepwise solids washing using decreasing concentrations of sodium hydroxide with filtration through the CUF oxidative leaching using sodium permanganate for removing Cr solids filtration with the CUF follow-on solids washing and filtration through the CUF ion exchange processing for Cs removal evaporation processing of waste stream recycle for volume reduction combination of the evaporated product with dissolved saltcake. The effectiveness of each process step was evaluated by following the mass balance of key components (such as Al, B, Cd, Cr, Pu, Ni, Mn, and Fe), demonstrating component (Al, Cr, Cs) removal, demonstrating filterability by evaluating filter flux rates under various processing conditions (transmembrane pressure, crossflow velocities, wt% undissolved solids, and PSD) and filter fouling, and identifying potential issues for WTP. The filterability was reported separately (Shimskey et al. 2008) and is not repeated herein.
Download or read book EFRT M12 Issue Resolution written by and published by . This book was released on 2009 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Pacific Northwest National Laboratory (PNNL) has been tasked by Bechtel National Inc. (BNI) on the River Protection Project-Hanford Tank Waste Treatment and Immobilization Plant (RPP-WTP) project to perform research and development activities to resolve technical issues identified for the Pretreatment Facility (PTF). The Pretreatment Engineering Platform (PEP) was designed and constructed and is to be operated as part of a plan to respond to issue M12, "Undemonstrated Leaching Processes." The PEP is a 1/4.5-scale test platform designed to simulate the WTP pretreatment caustic leaching, oxidative leaching, ultrafiltration solids concentration, and slurry washing processes. The PEP replicates the WTP leaching processes using prototypic equipment and control strategies. The PEP also includes non-prototypic ancillary equipment to support the core processing. Two operating scenarios are currently being evaluated for the ultrafiltration process (UFP) and leaching operations. The first scenario has caustic leaching performed in the UFP-2 ultrafiltration feed vessels (i.e., vessel UFP-VSL-T02A in the PEP; and vessels UFP-VSL-00002A and B in the WTP PTF). The second scenario has caustic leaching conducted in the UFP-1 ultrafiltration feed preparation vessels (i.e., vessels UFP-VSL-T01A and B in the PEP; vessels UFP-VSL-00001A and B in the WTP PTF). In both scenarios, 19-M sodium hydroxide solution (NaOH, caustic) is added to the waste slurry in the vessels to dissolve solid aluminum compounds (e.g., gibbsite, boehmite). Caustic addition is followed by a heating step that uses direct steam injection to accelerate the leaching process. Following the caustic leach, the vessel contents are cooled using vessel cooling jackets and/or external heat exchangers. The main difference between the two scenarios is that for leaching in UFP1, the 19-M NaOH is added to un-concentrated waste slurry (3 to 8 wt% solids), while for leaching in UFP2, the slurry is concentrated to nominally 20 wt% solids using cross-flow ultrafiltration before the addition of caustic. For wastes that have significantly high chromium content, the caustic leaching and slurry dewatering is followed by adding sodium permanganate to UFP-VSL-T02A, and the slurry is subjected to oxidative leaching at nominally ambient temperature. The purpose of the oxidative leaching is to selectively oxidize the poorly alkaline-soluble Cr(III) believed to be the insoluble form in Hanford tank sludge to the much more alkaline-soluble Cr(VI), e.g., chromate. The work described in this report provides the test results that are related to the efficiency of the oxidative leaching process to support process modeling based on tests performed with a Hanford waste simulant. The tests were completed both at the lab-bench scale and in the PEP. The purpose of this report is to summarize the results from both scales that are related to oxidative leaching chemistry to support a scale factor for the submodels to be used in the G2 model, which predicts WTP operating performance. Owing to schedule constraints, the PEP test data to be included in this report are limited to those from Integrated Tests A (T01 A/B caustic leaching) and B (T02A caustic leaching).
Book Synopsis Principles and Practices of in Situ Chemical Oxidation Using Permanganate by : Robert L. Siegrist
Download or read book Principles and Practices of in Situ Chemical Oxidation Using Permanganate written by Robert L. Siegrist and published by . This book was released on 2001 with total page 376 pages. Available in PDF, EPUB and Kindle. Book excerpt: - Chapter 1: An overview of chemical oxidation including its development and application for in situ treatment of contaminated sites. The oxidation chemistry of Fenton's reagent, permanganate, and ozone are highlighted along with optional methods of oxidant delivery for in situ application. The results of lab-and field-scale applications are summarized.- Chapter 2: A description of the principles and processes of chemical oxidation using potassium or sodium permanganate for organic chemical degradation, including reaction stoichiometry, equilibria, and kinetics, as well as the effects of environmental factors.- Chapter 3: Information provided on the effects of permanganate on the behavior of metals.- Chapter 4: A discussion of the potential for permeability loss and other secondary effects during in situ oxidation using permanganate.- Chapter 5: A description of optional methods of oxidant delivery for in situ remediation.- Chapter 6: A description of a process for evaluation, design, and implementation of permanganate systems.- Chapter 7: A detailed description of five different applications of an in situ chemical oxidation using potassium or sodium permanganate.- Chapter 8: Highlights of the current status and future directions of this remediation technology.
Book Synopsis Refinement of the Alkaline/oxidative Leaching Process to Separate Chromium and Aluminum from Hanford High Level Nuclear Tank Waste by : Jennifer E. Holland
Download or read book Refinement of the Alkaline/oxidative Leaching Process to Separate Chromium and Aluminum from Hanford High Level Nuclear Tank Waste written by Jennifer E. Holland and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Development of Alkaline Oxidative Dissolution Methods for Chromium(III) Compounds Present in Hanford Site Tank Sludges by : N. N. Krot
Download or read book Development of Alkaline Oxidative Dissolution Methods for Chromium(III) Compounds Present in Hanford Site Tank Sludges written by N. N. Krot and published by . This book was released on 1999 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Caustic Leaching of Hanford Tank T-110 Sludge by : Gregg J. Lumetta
Download or read book Caustic Leaching of Hanford Tank T-110 Sludge written by Gregg J. Lumetta and published by . This book was released on 2002 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Research and Technology by : Goddard Space Flight Center
Download or read book Research and Technology written by Goddard Space Flight Center and published by . This book was released on 1990 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Groundwater and Soil Cleanup by : National Research Council
Download or read book Groundwater and Soil Cleanup written by National Research Council and published by National Academies Press. This book was released on 1999-11-21 with total page 301 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a comprehensive, up-to-date review of technologies for cleaning up contaminants in groundwater and soil. It provides a special focus on three classes of contaminants that have proven very difficult to treat once released to the subsurface: metals, radionuclides, and dense nonaqueous-phase liquids such as chlorinated solvents. Groundwater and Soil Cleanup was commissioned by the Department of Energy (DOE) as part of its program to clean up contamination in the nuclear weapons production complex. In addition to a review of remediation technologies, the book describes new trends in regulation of contaminated sites and assesses DOE's program for developing new subsurface cleanup technologies.
Book Synopsis Methods for the Minimization of Radioactive Waste from Decontamination and Decommissioning of Nuclear Facilities by : International Atomic Energy Agency
Download or read book Methods for the Minimization of Radioactive Waste from Decontamination and Decommissioning of Nuclear Facilities written by International Atomic Energy Agency and published by . This book was released on 2001 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: Simple text and photographs introduce the life of George Washington Carver.
Book Synopsis Decommissioning Techniques for Research Reactors by : International Atomic Energy Agency
Download or read book Decommissioning Techniques for Research Reactors written by International Atomic Energy Agency and published by . This book was released on 1994 with total page 124 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the first report published by the IAEA which provides guidance on the preparation and implementation of the decommissioning of different types of research reactor. Different construction and operational features of research reactors have a major impact on the decommissioning techniques required. This report offers information on the conclusions drawn from a number of completed projects and identifies their similarities and differences. It is complemented by a computerized research reactor databank. Staff requirements, decommissioning costs waste activity are presented graphically according to reactor thermal power and integrated energy.
Book Synopsis Radioactive Waste Forms for the Future by : Werner Lutze
Download or read book Radioactive Waste Forms for the Future written by Werner Lutze and published by North Holland. This book was released on 1988 with total page 802 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume presents a compilation of important information on the full range of radioactive waste forms that have been developed, or at least suggested, for the incorporation of high-level nuclear waste. Many of the results were published in the ''gray literature'' of final reports of national laboratories or in various, generally less available, proceedings volumes. This is the first publication to draw information on nuclear waste forms for high-level wastes together into a single volume. Although borosilicate glass has become the standard waste form, additional research in this compound is still necessary. With improved technology (particularly processing technologies) and with a more detailed knowledge of repository conditions, glasses and second generation waste forms with improved performance properties can be developed. Sustained research programs on nuclear waste form development will yield results that can only add to public confidence and the final, safe disposal of nuclear waste. The aim of this volume is to provide a 'spring board' for these future research efforts. A detailed presentation is given on the properties and performance of non-crystalline waste forms (borosilicate glass, sintered glass, and lead-iron phosphate glass), and crystalline waste forms (Synroc, tailored ceramics, TiO 2 - ceramic matrix, glass-ceramics and FUETAP concrete). A chapter on Novel Waste Forms reviews a number of methods that warrant further development because of their potential superior performance and unique applications. The final chapter includes a tabulated comparison of important waste form properties and an extended discussion on the corrosion process and radiation damage effects for each waste form. Of particular interest is a performance assessment of nuclear waste borosilicate glass and the crystalline ceramic Synroc. This is the first detailed attempt to compare these two important waste forms on the basis of their materials properties. The discussion emphasizes the difficulties in making such a comparison and details the types of data that are required. Each chapter has been written by an expert and includes a current compilation of waste form properties with an extensive list of references. This volume will provide a stimulus for future research as well as useful reference material for scientists working in the field of nuclear waste disposal and materials science.
Book Synopsis Mineral Processing and the Environment by : G.P. Gallios
Download or read book Mineral Processing and the Environment written by G.P. Gallios and published by Springer Science & Business Media. This book was released on 2013-04-17 with total page 407 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mineral processing technologies have been used for decades to protect the environment and many examples of such applications are given here. The book covers four major subject areas: fundamentals; environmental pollution and its prevention; separation processes; and innovative techniques. Audience: Scientists, engineers and technologists conducting both applied and basic research into the different environmental aspects of mineral processing.
Book Synopsis Standardization of Potassium Permanganate Solution by Sodium Oxalate by : Russell Smith McBridge
Download or read book Standardization of Potassium Permanganate Solution by Sodium Oxalate written by Russell Smith McBridge and published by . This book was released on 1913 with total page 32 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :United States. Department of Energy. Division of Nuclear Power Development Publisher : ISBN 13 : Total Pages :354 pages Book Rating :4.F/5 ( download)
Book Synopsis PWR steam generator chemical cleaning by : United States. Department of Energy. Division of Nuclear Power Development
Download or read book PWR steam generator chemical cleaning written by United States. Department of Energy. Division of Nuclear Power Development and published by . This book was released on 1978 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Green Solvents for Chemistry by : William M. Nelson
Download or read book Green Solvents for Chemistry written by William M. Nelson and published by Oxford University Press. This book was released on 2003-03-27 with total page 402 pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of this book is to introduce the use of green solvents throughout chemistry and to provide a comprehensive reference for solvents currently applicable in green chemistry. The first section covers solvents in chemical perspective, and the second section is a guide to green solvents. Overall, this volume defines characteristics of green solvents and their current usage, and explores their importance ecologically and economically. It includes a full range of commercial, industrial, and academic green solvents, and discusses solvents in specific commercial and non-commercial practices. Green Solvents for Chemistry differs from other works on solvents in that only solvents for green chemistry are included along with their chemical properties and toxicological issues.
