Principles and Applications of Stereochemistry

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Author :
Publisher : Routledge
ISBN 13 : 1351422057
Total Pages : 269 pages
Book Rating : 4.3/5 (514 download)

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Book Synopsis Principles and Applications of Stereochemistry by : Michael North

Download or read book Principles and Applications of Stereochemistry written by Michael North and published by Routledge. This book was released on 2017-10-19 with total page 269 pages. Available in PDF, EPUB and Kindle. Book excerpt: A thorough understanding of stereochemistry is essential for the comprehension of almost all aspects of modern organic chemistry. It is also of great significance in many biochemical and medicinal disciplines, since the stereoisomers of a compound can have dramatically different biological properties. This text explains how the different properties of stereoisomers of a compound arise, and what processes can be used to prepare and analyze stereoisomerically pure compounds. It also presents prominent coverage of the stereochemistry of inorganic and organometallic compounds, which is likely to increase in importance, as these compounds are used as symmetric catalysts in asymmetric synthesis. Modern stereochemical terminology is used throughout, although reference is also made to older terms which are still widely used. A set of problems at the end of each chapter aims to further the reader's understanding of how the content can be applied. The book is designed mainly as a textbook for undergraduate students and as a reference source for more advanced levels, but is also intended for academic and professional organic chemists.

Stereochemistry of Organic Compounds

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Author :
Publisher : John Wiley & Sons
ISBN 13 :
Total Pages : 554 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Stereochemistry of Organic Compounds by : D. Nasipuri

Download or read book Stereochemistry of Organic Compounds written by D. Nasipuri and published by John Wiley & Sons. This book was released on 1991 with total page 554 pages. Available in PDF, EPUB and Kindle. Book excerpt: This text deals with the new concepts and terminology that have been introduced into the treatment of organic stereochemistry over the last decade. Organic reaction mechanisms, as they relate to stereochemistry, are included, and the pericyclic reaction using the frontier molecular orbital approach is explained. The text does not assume a strong grounding in organic chemistry and will therefore be useful to a broader spectrum of students - both graduate and undergraduate. The volume features numerous illustrations and programmed problems.

Dynamic Stereochemistry of Chiral Compounds

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Publisher : Royal Society of Chemistry
ISBN 13 : 0854042466
Total Pages : 534 pages
Book Rating : 4.8/5 (54 download)

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Book Synopsis Dynamic Stereochemistry of Chiral Compounds by : Christian Wolf

Download or read book Dynamic Stereochemistry of Chiral Compounds written by Christian Wolf and published by Royal Society of Chemistry. This book was released on 2008 with total page 534 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive overview of fundamental concepts of asymmetric synthesis along with in-depth discussion. Recent developments that address important synthetic challenges are presented and highlighted with hundreds of examples.

Stereochemistry

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Publisher : Elsevier
ISBN 13 : 012821063X
Total Pages : 622 pages
Book Rating : 4.1/5 (282 download)

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Book Synopsis Stereochemistry by : Anil V. Karnik

Download or read book Stereochemistry written by Anil V. Karnik and published by Elsevier. This book was released on 2021-07-21 with total page 622 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stereochemistry: A Three-Dimensional Insight draws on the knowledge of its expert authors, providing a systematic treatment on the fundamental aspects of stereochemistry, covering conformational aspects, configurational aspects, effects of bulkiness, stereoelectronic effects on properties of molecules, and the genesis of enantiomerism, among other topics. Visuals and exercises are included to consolidate the principles learned, and the contents are carefully structured to prepare readers for predicting and organizing reaction components to obtain desired stereochemical outcomes. This book is an indispensable guide for all those exploring stereochemistry within their work. The principles of stereochemistry are fundamental to understanding chemical behavior and can provide insights into a whole range of problems, from unusual selectivity and unexpected behaviors, to abnormally fast reactions and surprising biochemical preferences. However, understanding and exploring these 3D effects can be difficult within a 2D medium. This book has been designed to address this problem, providing foundational guidance on the principles and applications of stereochemistry that are fully supported by multimedia visuals. Combines foundational concepts and definitions with examples of stereochemistry in practice Highlights the conformational and configurational impact of atomic arrangement on chemical behavior Outlines methods of analysis Provides practical exercises and detailed multimedia visuals to support learning

Stereochemistry

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Author :
Publisher : Elsevier
ISBN 13 : 1483278654
Total Pages : 300 pages
Book Rating : 4.4/5 (832 download)

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Book Synopsis Stereochemistry by : M. Nógrádi

Download or read book Stereochemistry written by M. Nógrádi and published by Elsevier. This book was released on 2013-10-22 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stereochemistry: Basic Concepts and Applications is a three-chapter text that introduces the basic principles and concepts of stereochemistry, as well as its application to organic chemistry application. Chapter 1 describes first the stereochemistry of the ground state, specifically the configuration and conformation of organic compounds, as well as the most important methods for its investigation. This chapter also deals with the kinetics of conformational changes and provides an overview of the so-called "applied stereochemistry". Chapter 2 focuses on the analysis of the internal motions of the molecules and of the corresponding activation energies. This chapter also examines the principles of intramolecular symmetry. Chapter 3 considers the stereochemical aspect of several enzymic processes and the stereoisomerism of monotonic polymers and inorganic complexes. This book will be of great value to organic chemists and organic chemistry graduate students.

Organic Stereochemistry

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Publisher : John Wiley & Sons
ISBN 13 : 3527338225
Total Pages : 336 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Organic Stereochemistry by : Hua-Jie Zhu

Download or read book Organic Stereochemistry written by Hua-Jie Zhu and published by John Wiley & Sons. This book was released on 2015-08-10 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: Adopting a novel approach to the topic by combining theoretical knowledge and practical results, this book presents the most popular and useful computational and experimental methods applied for studying the stereochemistry of chemical reactions and compounds. The text is clearly divided into three sections on fundamentals, spectroscopic and computational techniques, and applications in organic synthesis. The first part provides a brief introduction to the field of chirality and stereochemistry, while the second part covers the different methodologies, such as optical rotation, electronic circular dichroism, vibrational circular dicroism, and Raman spectroscopy. The third section then goes on to describe selective examples in organic synthesis, classified by reaction type, i.e. enantioselective, chemoselective and stereoselective reactions. A final chapter on total synthesis of natural products rounds off the book. A valuable reference for researchers in academia and industry working in the field of organic synthesis, computational chemistry, spectroscopy or medicinal chemistry.

Principles of Organic Chemistry

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Publisher : Academic Press
ISBN 13 : 0128026340
Total Pages : 496 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Principles of Organic Chemistry by : Robert J. Ouellette

Download or read book Principles of Organic Chemistry written by Robert J. Ouellette and published by Academic Press. This book was released on 2015-02-13 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: Class-tested and thoughtfully designed for student engagement, Principles of Organic Chemistry provides the tools and foundations needed by students in a short course or one-semester class on the subject. This book does not dilute the material or rely on rote memorization. Rather, it focuses on the underlying principles in order to make accessible the science that underpins so much of our day-to-day lives, as well as present further study and practice in medical and scientific fields. This book provides context and structure for learning the fundamental principles of organic chemistry, enabling the reader to proceed from simple to complex examples in a systematic and logical way. Utilizing clear and consistently colored figures, Principles of Organic Chemistry begins by exploring the step-by-step processes (or mechanisms) by which reactions occur to create molecular structures. It then describes some of the many ways these reactions make new compounds, examined by functional groups and corresponding common reaction mechanisms. Throughout, this book includes biochemical and pharmaceutical examples with varying degrees of difficulty, with worked answers and without, as well as advanced topics in later chapters for optional coverage. Incorporates valuable and engaging applications of the content to biological and industrial uses Includes a wealth of useful figures and problems to support reader comprehension and study Provides a high quality chapter on stereochemistry as well as advanced topics such as synthetic polymers and spectroscopy for class customization

Chemical Structure, Spatial Arrangement

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Publisher : Routledge
ISBN 13 : 1351952455
Total Pages : 424 pages
Book Rating : 4.3/5 (519 download)

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Book Synopsis Chemical Structure, Spatial Arrangement by : Peter J. Ramberg

Download or read book Chemical Structure, Spatial Arrangement written by Peter J. Ramberg and published by Routledge. This book was released on 2017-05-15 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: Offering a comprehensive narrative of the early history of stereochemistry, Dr Ramberg explores the reasons for and the consequences of the fundamental change in the meaning of chemical formulas with the emergence of stereochemistry during the last quarter of the nineteenth century. As yet relatively unexplored by historians, the development of stereochemistry - the study of the three-dimensional properties of molecules - provides a superb case study for exploring the meaning and purpose of chemical formulas, as it entailed a significant change in the meaning of chemical formulas from the purely chemical conception of 'structure' to the physico-chemical conception of molecules provided by the tetrahedral carbon atom. This study is the first to treat the emergence of the unique visual language of organic chemistry between 1830 and 1874 to place in context the near simultaneous proposal of the tetrahedral carbon atom by J.H. van 't Hoff and J.A. Le Bel in 1874. Dr Ramberg then examines the research programs in stereochemistry by Johannes Wislicenus, Arthur Hantzsch, Victor Meyer, Carl Bischoff, Emil Fischer and Alfred Werner, showing how the emergence of stereochemistry was a logical continuation of established research traditions in chemistry. In so doing, he also illustrates the novel and controversial characteristics of stereochemical ideas, especially the unprecedented use of mechanistic and dynamic principles in chemical explanation.

Stereochemistry of Organic Compounds

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Author :
Publisher : New Age International
ISBN 13 : 9788122405705
Total Pages : 596 pages
Book Rating : 4.4/5 (57 download)

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Book Synopsis Stereochemistry of Organic Compounds by : D. Nasipuri

Download or read book Stereochemistry of Organic Compounds written by D. Nasipuri and published by New Age International. This book was released on 1994 with total page 596 pages. Available in PDF, EPUB and Kindle. Book excerpt: During Recent Years, Stereochemistry Has Undergone A Phenomenal Growth Both In Theory And Practice, With A Concomitant Increase Of Interest Among The Organic Chemists, Biological Chemists, Medicinal Chemists, And Pharmacologists. The Present Text Provides An Up-To-Date, Coherent; And Comprehensive Account Of The Subject Starting From The Fundamentals And Leading Up To The Latest Development As Far As Practicable. Emphasis Has Been Placed On Symmetry-Based Approach To Molecular Chirality, Stereochemical Terminologies (Modern Stereochemistry Is Replete, With Them), Topicity And Prostereoisomerism, Conformational Analysis, Dynamic Stereochemistry, Chiroptical Properties, And Assignment Of Absolute Configuration To Chiral Molecules.Dynamic Stereochemistry Has Been Discussed With Reference To Conformation-Reactivity Correlation, Stereoselective Syntheses, And Pericyclic Reactions. A Large Cross Section Of Organic Reactions With Stereochemical Implication Has Been Incorporated. Attempts Have Been Made To Familiarise The Readers With Modem Instrumental Techniques, Nuclear Magnetic Resonance In Particular, Used For Stereochemical Investigation. Each Chapter Is Provided With A Summary Which Highlights The Main Points Of The Text. Selective References, Mostly Of Textbooks, Monographs, Review Articles, And Significant Original Papers Have Been Given Extending Sometimes To Early 1991.The Book Is Expected To Fulfil The Long-Felt Need For A Comprehensive Text On Modern Organic Stereochemistry Which Is Conspicuously Absent Since The Publication Of Professor Eliels Book In 1962. The Text May Be Adopted At Any Stage Of The University Teaching And At The Same Time Be Useful To The Practising Organic Chemists.

Guide to Organic Stereochemistry

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Author :
Publisher : Prentice Hall
ISBN 13 :
Total Pages : 268 pages
Book Rating : 4.4/5 (91 download)

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Book Synopsis Guide to Organic Stereochemistry by : Sheila R. Buxton

Download or read book Guide to Organic Stereochemistry written by Sheila R. Buxton and published by Prentice Hall. This book was released on 1996 with total page 268 pages. Available in PDF, EPUB and Kindle. Book excerpt: Takes the reader step-by-step from the structures of simple molecules, such as methane, to the basic shapes of biologically important macromolecules, such as proteins and nucleic acids. Deals with the concept of chirality, which is often overlooked by many texts. Chirality is approached by firstly explaining the stereochemistry of compounds with one stereogenic centre, then dealing with compounds having two or more stereogenic centres before focusing on compounds possessing axes of chirality. The importance of stereochemistry in a wide variety of transformations (for example addition reactions, eliminations, and cycloadditions), is discussed. The final chapters describe the application of stereocontrol in asymmetric synthesis, indicating the use of chiral auxiliaries and chiral catalysts in modern chemistry.

Stereochemistry of Coordination Compounds

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Publisher : John Wiley & Sons
ISBN 13 : 9780471955993
Total Pages : 272 pages
Book Rating : 4.9/5 (559 download)

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Book Synopsis Stereochemistry of Coordination Compounds by : Alexander von Zelewsky

Download or read book Stereochemistry of Coordination Compounds written by Alexander von Zelewsky and published by John Wiley & Sons. This book was released on 1996-06-03 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: This well-illustrated and well-referenced book provides a systematic introduction to the modern aspects of the topographical stereochemistry of coordination compounds, which are made up of metal ions surrounded by other non-metal atoms, ions and molecules.

Phosphorous-31 NMR

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Publisher : Academic Press
ISBN 13 : 0080918417
Total Pages : 619 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Phosphorous-31 NMR by : David G. Gorenstein

Download or read book Phosphorous-31 NMR written by David G. Gorenstein and published by Academic Press. This book was released on 2012-12-02 with total page 619 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phosphorous-31 NMR: Principles and Applications focuses on the evolution of phosphorus-31 nuclear magnetic resonance (NMR) as a widely applied spectroscopic probe of the structure and dynamics of phosphorus-containing compounds. The selection first offers information on the principles and empirical observations of phosphorus-31 chemical shifts and the principles and applications of phosphorus-31 spin-spin coupling constants. Discussions focus on introduction and basic principles, directly bonded phosphorus coupling constants, and two-bond and three-bond coupling constants. The text then ponders on phosphorus-31 NMR of enzyme complexes and paramagnetic probes of enzyme complexes with phosphorus-containing compounds. The manuscript elaborates on the use of chiral thiophosphates and the stereochemistry of enzymatic phosphoryl transfer and DNA and RNA conformations. Topics include helix-coil transitions, sequence dependence of double-stranded DNA conformations, dynamic behavior of RNA and DNA, biological and genetic significance, and stereochemical problems studied with chiral thiophosphates. The conformation and dynamics of nucleic acids and phosphoproteins, relaxation behavior of nucleic acids, and theory and applications of solid-state phosphorus-31 NMR to nucleic acids are also discussed. The selection is a valuable reference for readers interested in the principles and applications of phosphorus-31 nuclear magnetic resonance.

NMR of Paramagnetic Molecules

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Publisher : Elsevier
ISBN 13 : 1483272451
Total Pages : 695 pages
Book Rating : 4.4/5 (832 download)

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Book Synopsis NMR of Paramagnetic Molecules by : G. N. La Mar

Download or read book NMR of Paramagnetic Molecules written by G. N. La Mar and published by Elsevier. This book was released on 2013-10-22 with total page 695 pages. Available in PDF, EPUB and Kindle. Book excerpt: NMR of Paramagnetic Molecules: Principles and Applications is a compendium of papers that discusses the physical principles behind the technique of nuclear magnetic resonance, as well as, evaluates the scope and limitation of the applications of NMR in chemistry and biology. These papers emphasize the applications of the technique in chemistry and biochemistry where it widely used, particularlyon NMR experiments in the liquid state. Some papers describe the theoretical factors governing the resonance position and linewidth, and then also interpret magnetic resonance parameters in terms of electronic structure. Another paper investigates the gap between the mathematical complexities of earlier experiments and the operational aspects of chemical information from the spectra. Examples show studies in biochemical molecules and process in events where contact interactions are present either as a result of intrinsic molecular paramagnetism or are just induced through the addition of suitable paramagnetic probes. One paper presents the definitive and controversial results involving stereochemistry and deuterium NMR. This collection of papers will prove useful for nuclear physicists, researchers, and academicians in the field of nuclear physics.

Taste Chemistry

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Publisher : Springer Science & Business Media
ISBN 13 : 1461526663
Total Pages : 633 pages
Book Rating : 4.4/5 (615 download)

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Book Synopsis Taste Chemistry by : R.S. Shallenberger

Download or read book Taste Chemistry written by R.S. Shallenberger and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 633 pages. Available in PDF, EPUB and Kindle. Book excerpt: The object ofthis text is to examine, and elaborate on the meaning of the established premise that 'taste is a chemical sense.' In particular, the major effort is directed toward the degree to which chemical principles apply to phenomena associated with the inductive (recognition) phase of taste. A second objective is to describe the structure and properties of compounds with varying taste that allow decisions to be made with respect to the probable nature of the recognition chemistry for the different tastes, and the probable nature of the receptor(s) for those tastes. A final objective is to include appropriate interdisciplinary observations that have application to solving problems related to the chemical nature of taste. Taste is the most easily accessible chemical structure-biological activity relationship, and taste chemistry studies, i.e. the chemistry of sweetness, saltiness, sourness, and bitterness, have application to general biology, physiology, and pharmacology. Because it involves sensory perception, taste is also of interest to psychologists, and has application to the food and agricultural industries. The largest portion of the text is directed toward sweetness as, due to economic and other factors, the majority of the scientific studies are concerned with sweetness. The text begins with a prologue to describe the problems associated with the study of taste chemistry. Then, there is an introductory chapter to serve as an overview of the general interdisciplinary knowledge of the subject. It is followed by a chapter on the fundamental chemical principles that apply to taste induction chemistry.

Ord and Cd in Chemistry and Biochemistry

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Publisher : Elsevier
ISBN 13 : 0323159419
Total Pages : 241 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Ord and Cd in Chemistry and Biochemistry by : Pierre Crabbe

Download or read book Ord and Cd in Chemistry and Biochemistry written by Pierre Crabbe and published by Elsevier. This book was released on 2012-12-02 with total page 241 pages. Available in PDF, EPUB and Kindle. Book excerpt: ORD and CD in Chemistry and Biochemistry: An Introduction essentially presents the necessary foreword and theoretical foundation for the useful application of optical rotatory dispersion (ORD) and circular dichroism (CD) to certain common chemical problems. This book emphasizes the precision of ORD and CD data in terms of stereochemical information. The book begins with some historical references and a concise review of basic principles on stereochemistry. It further delves onto the phenomena of optical activity. Also included are the definitions and units commonly used in ORD and CD. The book also discusses optical properties of polymers, organometallic, and inorganic derivatives; and some of the aspects of magnetic optical rotator dispersion (MORD) and magnetic circular dichroism (MCD). A table that presents wavelength range of the Cotton effects of most chromophoric groupings concludes the book. This monograph is a helpful reference to students as well as professionals from both chemistry and biochemistry fields of science.

Stereochemistry of Organic Compounds

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 0471016705
Total Pages : 1296 pages
Book Rating : 4.4/5 (71 download)

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Book Synopsis Stereochemistry of Organic Compounds by : Ernest L. Eliel

Download or read book Stereochemistry of Organic Compounds written by Ernest L. Eliel and published by John Wiley & Sons. This book was released on 1994-09-28 with total page 1296 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stereochemistry of Organic Compounds The first fully referenced, comprehensive book on this subject in more than thirty years, Stereochemistry of Organic Compounds contains up-to-date coverage and insightful exposition of all important new concepts, developments, and tools in the rapidly advancing field of stereochemistry, including: * Asymmetric and diastereoselective synthesis * Conformational analysis * Properties of enantiomers and racemates * Separation and analysis of enantiomers and diastereoisomers * Developments in spectroscopy (including NMR), chromatography, and molecular mechanics as applied to stereochemistry * Prostereoisomerism * Conceptual foundations of stereochemistry, including terminology and symmetry concepts * Chiroptical properties Written by the leading authorities in the field, the text includes more than 4,000 references, 1,000 illustrations, and a glossary of stereochemical terms.

Rules for the Nomenclature of Organic Chemistry

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Author :
Publisher : Elsevier
ISBN 13 : 1483284506
Total Pages : 21 pages
Book Rating : 4.4/5 (832 download)

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Book Synopsis Rules for the Nomenclature of Organic Chemistry by : L. C. Cross

Download or read book Rules for the Nomenclature of Organic Chemistry written by L. C. Cross and published by Elsevier. This book was released on 2013-09-17 with total page 21 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rules for the Nomenclature of Organic Chemistry: Section E: Stereochemistry (Recommendations 1974) deals with the main principles of stereochemistry. The rules discussed in this section have two main objects, namely, to prescribe, for basic views, terms that may provide a common language in all aspects of stereochemistry; and to define the ways in which these terms may be incorporated into the names of individual compounds. This book discusses the steric structure of a compound, which is denoted by an affix or affixes to the name that does not prescribe the stereochemistry. This text explains that isomers are termed stereoisomers when they differ only in the arrangement of the atoms in space. This book explains as well that the terms relative stereochemistry and relative configuration are used to describe the positions of substituents on different atoms in a molecule relative to one another. This book is a valuable resource for organic chemists.