Polyoxomolybdates As Green Catalysts For Aerobic Oxidation

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Polyoxomolybdates as Green Catalysts for Aerobic Oxidation

Author : Anjali Patel
Publisher : Springer
ISBN 13 : 3319129880
Total Pages : 63 pages
Book Rating : 4.3/5 (191 download)

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Book Synopsis Polyoxomolybdates as Green Catalysts for Aerobic Oxidation by : Anjali Patel

Download or read book Polyoxomolybdates as Green Catalysts for Aerobic Oxidation written by Anjali Patel and published by Springer. This book was released on 2014-11-22 with total page 63 pages. Available in PDF, EPUB and Kindle. Book excerpt: Heterogeneously catalyzed selective oxidations of alcohols is a highly topical field. The first chapter of this brief describes the importance of the selective oxidation of alcohols and advantages of heterogeneous catalysts over conventional catalysts, use of environmentally benign oxidants, and the design of selective catalysts by tailoring of polyoxometalates at the molecular level. Chapter 2 describes synthesis, characterization 11-molybdophosphate based supported materials and their use as heterogeneous catalysts for oxidation of alcohols with molecular oxygen under solvent free mild reaction condition. ZrO2, Al2O3, MCM-41 and zeolite Hβ were used as supports. Chapter 3 describes synthesis, characterization of transition metals (Mn, Co, Ni, Cu)- substituted phosphomolybdates and their use as heterogeneous catalysts for oxidation of alcohols with molecular oxygen under solvent free mild reaction condition. Chapter 4 describes conclusive remarks for present catalytic systems.

Frontiers of Green Catalytic Selective Oxidations

Author : Konstantin P. Bryliakov
Publisher : Springer Nature
ISBN 13 : 9813297514
Total Pages : 295 pages
Book Rating : 4.8/5 (132 download)

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Book Synopsis Frontiers of Green Catalytic Selective Oxidations by : Konstantin P. Bryliakov

Download or read book Frontiers of Green Catalytic Selective Oxidations written by Konstantin P. Bryliakov and published by Springer Nature. This book was released on 2019-10-02 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: The demand for novel efficient and environmentally sustainable chemo, regio- and stereoselective catalyst systems for the oxidation of organic substrates is continuously growing in line with toughening economic and environmental constraints. This book addresses these issues; it consists of eleven chapters written by world-recognized experts in green and sustainable oxidation catalysis. The most urgent and challenging topics, in the judgment of the editor, such as green asymmetric epoxidations, sulfoxidatiuons, C–H oxidations; oxidation catalysis by polyoxometalates and oxidations in non-conventional solvents, etc. have been critically reviewed in this book. Both fundamental aspects, such as catalysts design, catalytic properties, nature of catalytically active sites and reaction mechanisms, and practical outlook of the oxidations have been addressed by the authors. The book appeals to a broad readership, particularly graduate students, employees of universities and research organizations, and industrial researchers, particularly those working in the areas of homogeneous oxidation catalysis, asymmetric synthesis, organocatalysis, sustainable catalytic processes and green chemistry, mechanisms of catalytic reactions, synthesis of bioactive compounds, biomimetic chemistry, etc. Konstantin Bryliakov is Leading Researcher at the Boreskov Institute of Catalysis. In 2016, he was elected Honorary Professor of the Russian Academy of Sciences.

Leveraging Heterogeneous Metal on Nitrogen-doped Carbon Materials for Aerobic Oxidation Catalysis

Author : Melissa Nicole Hall
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (145 download)

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Book Synopsis Leveraging Heterogeneous Metal on Nitrogen-doped Carbon Materials for Aerobic Oxidation Catalysis by : Melissa Nicole Hall

Download or read book Leveraging Heterogeneous Metal on Nitrogen-doped Carbon Materials for Aerobic Oxidation Catalysis written by Melissa Nicole Hall and published by . This book was released on 2024 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical redox reactions serve as an important class of transformations for the modernchemist, and advancements in homogeneous and heterogeneous catalysis are ever expanding the synthetic toolbox. Nonprecious metal catalysts and "green" reagents are sought after for their economic and environmental advantages to synthetic chemistries, and bridging seemingly disparate fields can lead to intriguing insights and developments. For decades, first-row transition metals incorporated into nitrogen-doped carbon (MNCs) have been studied for electrochemical oxygen reduction as leading alternatives to platinum in fuel cells, and more recently, MNCs have been used as catalysts for aerobic oxidation reactions in the context of organic synthesis. In this approach, protons and electrons from chemical bonds in organic molecules are used to promote oxygen reduction as balanced redox half reactions. This body of work describes our recent developments with MNC materials and their applications in organic synthesis. Chapter 1 offers an overview of MNC synthesis and characterization followed by a synopsisof the application of MNC catalysts to thermal organic transformations. This provides important context for Chapter 2 wherein we disclose our recently developed protocol for the incorporation of atomically-dispersed iron sites into nitrogen-doped carbon frameworks. The resulting MNC materials are then characterized in a cross-laboratory study targeting the quantification of active sites on MNCs prepared via diverse synthetic protocols. Chapter 3 presents the development of catalytic conditions for the formation of diazo compounds using oxygen as the terminal oxidant, initially by means of homogeneous copper catalysts. We then leveraged MNC catalysts for the same transformation and paired the formation of diazo compounds with enantioselective carbene transfer to achieve C-H insertion and cyclopropanation. This new MNC reactivity is further showcased in a flow reactor with gram-scale synthesis of diazo compounds. Chapter 4 describes ongoing work seeking to understand MNC-catalyzed hydrazone oxidation, including mechanistic insights, structure-activity relationships, and broadening this reactivity to other transformations involving proton-coupled electron transfers.

Polyoxometalate Chemistry

Author :
Publisher : Academic Press
ISBN 13 : 0128111062
Total Pages : 360 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Polyoxometalate Chemistry by :

Download or read book Polyoxometalate Chemistry written by and published by Academic Press. This book was released on 2017-02-17 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyoxometalate Chemistry continues a long-running series that describes recent advances in scientific research, in particular, in the field of inorganic chemistry. Several highly regarded experts, mostly from academia, contribute on specific topics. The current issue focuses on recent advances in the development and application of polyoxometalate complexes in areas such as solution chemistry, self-organization, solar fuels, non-aqueous chemistry, spintronics, nanoscience and catalysis. Presents a single monograph on recent developments in polyoxometalate chemistry as written by scientific leaders in this field Concise and informative presentations cover a wide range of topics in this field of chemistry Contains detailed literature references, enabling the reader to move on to the source of the reported work where more details can be found Provides a solid presentation of a hard-cover book of excellent technical quality

Zeolite Synthesis

Author : Mario L. Occelli
Publisher :
ISBN 13 :
Total Pages : 672 pages
Book Rating : 4.:/5 (44 download)

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Book Synopsis Zeolite Synthesis by : Mario L. Occelli

Download or read book Zeolite Synthesis written by Mario L. Occelli and published by . This book was released on 1989 with total page 672 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume is a complete progress report on the various aspects of zeolite synthesis on a molecular level. It provides many examples that illustrate how zeolites can be crystallized and what the important parameters are that control crystallization. Forty-two chapters cover such topics as: crystallization techniques; gel chemistry; crystal size and morphology; the role of organic compounds; and novel synthesis procedures. It offers a complete review of zeolite synthesis as well as the latest finding in this important field. Contains benchmark contributions from many notable pioneers in the field, including R.M. Barrer, H. Robson, and Robert Milton.

Copper Catalysis in Organic Synthesis

Author : Gopinathan Anilkumar
Publisher : John Wiley & Sons
ISBN 13 : 3527347372
Total Pages : 504 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Copper Catalysis in Organic Synthesis by : Gopinathan Anilkumar

Download or read book Copper Catalysis in Organic Synthesis written by Gopinathan Anilkumar and published by John Wiley & Sons. This book was released on 2020-12-07 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt: The most current information on growing field of copper catalysis Copper Catalysis in Organic Synthesis contains an up-to-date overview of the most important reactions in the presence of copper catalysts. The contributors—noted experts on the topic—provide an introduction to the field of copper catalysis, reviewing its development, scope, and limitations, as well as providing descriptions of various homo- and cross-coupling reactions. In addition, information is presented on copper-catalyzed C–H activation, amination, carbonylation, trifluoromethylation, cyanation, and click reactions. Comprehensive in scope, the book also describes microwave-assisted and multi-component transformations as well as copper-catalyzed reactions in green solvents and continuous flow reactors. The authors highlight the application of copper catalysis in asymmetric synthesis and total synthesis of natural products and heterocycles as well as nanocatalysis. This important book: Examines copper and its use in organic synthesis as a more cost-effective and sustainable for researchers in academia and industry Offers the first up-to-date book to explore copper as a first line catalyst for many organic reactions Presents the most significant developments in the area, including cross-coupling reactions, C–H activation, asymmetric synthesis, and total synthesis of natural products and heterocycles Contains over 20 contributions from leaders in the field Written for catalytic chemists, organic chemists, natural products chemists, pharmaceutical chemists, and chemists in industry, Copper Catalysis in Organic Synthesis offers a book on the growing field of copper catalysis, covering cross-coupling reactions, C–H activation, and applications in the total synthesis of natural products.

Handbook Of Advanced Methods And Processes In Oxidation Catalysis: From Laboratory To Industry

Author : Daniel Duprez
Publisher : World Scientific
ISBN 13 : 1783263342
Total Pages : 1035 pages
Book Rating : 4.7/5 (832 download)

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Book Synopsis Handbook Of Advanced Methods And Processes In Oxidation Catalysis: From Laboratory To Industry by : Daniel Duprez

Download or read book Handbook Of Advanced Methods And Processes In Oxidation Catalysis: From Laboratory To Industry written by Daniel Duprez and published by World Scientific. This book was released on 2014-07-24 with total page 1035 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers a comprehensive overview of the most recent developments in both total oxidation and combustion and also in selective oxidation. For each topic, fundamental aspects are paralleled with industrial applications. The book covers oxidation catalysis, one of the major areas of industrial chemistry, outlining recent achievements, current challenges and future opportunities. One distinguishing feature of the book is the selection of arguments which are emblematic of current trends in the chemical industry, such as miniaturization, use of alternative, greener oxidants, and innovative systems for pollutant abatement. Topics outlined are described in terms of both catalyst and reaction chemistry, and also reactor and process technology.

Metal Organic Frameworks as Heterogeneous Catalysts

Author : Francesc X. Llabrés i Xamena
Publisher : Royal Society of Chemistry
ISBN 13 : 1849735727
Total Pages : 446 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Metal Organic Frameworks as Heterogeneous Catalysts by : Francesc X. Llabrés i Xamena

Download or read book Metal Organic Frameworks as Heterogeneous Catalysts written by Francesc X. Llabrés i Xamena and published by Royal Society of Chemistry. This book was released on 2013-07-01 with total page 446 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book examines the latest research and discovery in the use of MOFs in catalysis, highlighting the extent to which these materials have been embraced by the community.

Modern Oxidation Methods

Author : Jan-Erling Bäckvall
Publisher : John Wiley & Sons
ISBN 13 : 3527604642
Total Pages : 350 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Modern Oxidation Methods by : Jan-Erling Bäckvall

Download or read book Modern Oxidation Methods written by Jan-Erling Bäckvall and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 350 pages. Available in PDF, EPUB and Kindle. Book excerpt: At the very latest, with the award of the 2001 Nobel Prize for work on asymmetric oxidation, there has been a need for a comprehensive book on such methods. Edited by J.-E. Backvall, one of the world's leaders in the field, this book fills that gap by covering the topic, from classical to green chemistry methods. He has put together a plethora of well-established authors from all over the world who cover every important aspect in high-quality contributions -- whether aerobic oxidation or transition metal-catalyzed epoxidation of alkenes. By providing an overview of this huge topic, this book represents an unparalleled aid for any chemist working in the field. Chapters include: Recent Developments in the Osmium-Catalyzed Dihydroxylation of Olefins Transition Metal-Catalyzed Epoxidation of Alkenes Organocatalytic Oxidation - Ketone-Catalyzed Asymmetric Epoxidation of Olefins Modern Oxidation of Alcohols using environmentally Benign Oxidants Aerobic Oxidations and Related Reactions Catalyzed by N-Hydroxyphthalimide Ruthenium-Catalyzed Oxidation of Alkenes, Alcohols, Amines, Amides, b-Lactams, Phenols, and Hydrocarbons Selective Oxidations of Sulfides and Amines Liquid Phase Oxidation Reactions Catalyzed by Polyoxometalates Oxidation of Carbonyl Compounds Mn-catalysed Oxidation with Hydrogen Peroxide

Polyoxometalate Molecular Science

Author : Juan J. Borrás-Almenar
Publisher : Springer Science & Business Media
ISBN 13 : 9401000913
Total Pages : 473 pages
Book Rating : 4.4/5 (1 download)

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Book Synopsis Polyoxometalate Molecular Science by : Juan J. Borrás-Almenar

Download or read book Polyoxometalate Molecular Science written by Juan J. Borrás-Almenar and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 473 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyoxometalates (POMs) form a large, distinctive class of molecular inorganic compounds of unrivaled electronic versatility and structural variation, with impacts ranging from chemistry, catalysis, and materials science to biology, and medicine. This book covers the basic principles governing the structure, bonding and reactivity of these metal-oxygen cluster anions and the major developments in their molecular science. The book comprises three sections. The first covers areas ranging from topological principles via synthesis and stability to reactivity in solution. It also focuses on the physical methods currently used to extract information on the molecular and electronic structures as well as the physical properties of these clusters. The second part reviews different types of POMs, focusing on those systems that currently impact other areas of interest, such as supramolecular chemistry, nanochemistry and molecular magnetism. The third section is devoted to POM-based materials and their applications and prospects in catalysis and materials science.

Green Chemistry: Synthesis of Bioactive Heterocycles

Author : K. L. Ameta
Publisher : Springer
ISBN 13 : 8132218507
Total Pages : 418 pages
Book Rating : 4.1/5 (322 download)

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Book Synopsis Green Chemistry: Synthesis of Bioactive Heterocycles by : K. L. Ameta

Download or read book Green Chemistry: Synthesis of Bioactive Heterocycles written by K. L. Ameta and published by Springer. This book was released on 2014-06-17 with total page 418 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book presents a succinct summary of methods for the synthesis and biological activities of various different-sized bioactive heterocycles using different green chemistry synthetic methodologies, like microwave, ultrasonic, water mediated, ionic liquids, etc. The book also provides an insight of how green chemistry techniques are specific to the bioactive heterocyclic compounds.

Selective Catalysis for Renewable Feedstocks and Chemicals

Author : Kenneth M. Nicholas
Publisher : Springer
ISBN 13 : 3319086545
Total Pages : 265 pages
Book Rating : 4.3/5 (19 download)

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Book Synopsis Selective Catalysis for Renewable Feedstocks and Chemicals by : Kenneth M. Nicholas

Download or read book Selective Catalysis for Renewable Feedstocks and Chemicals written by Kenneth M. Nicholas and published by Springer. This book was released on 2014-09-13 with total page 265 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.

Polyoxometalate Chemistry From Topology via Self-Assembly to Applications

Author : M.T. Pope
Publisher : Springer Science & Business Media
ISBN 13 : 0306476258
Total Pages : 421 pages
Book Rating : 4.3/5 (64 download)

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Book Synopsis Polyoxometalate Chemistry From Topology via Self-Assembly to Applications by : M.T. Pope

Download or read book Polyoxometalate Chemistry From Topology via Self-Assembly to Applications written by M.T. Pope and published by Springer Science & Business Media. This book was released on 2007-05-08 with total page 421 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work incorporates contributions from polyoxometalate scientists, and presents a summary of research developments in this field. Topics discussed include synthetic strategies leading to functionalized organic polyoxometalate derivatives, oxothioanions, and supramolecular assemblies.

Industrial Organic Chemistry

Author : Klaus Weissermel
Publisher : John Wiley & Sons
ISBN 13 : 3527614591
Total Pages : 481 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Industrial Organic Chemistry by : Klaus Weissermel

Download or read book Industrial Organic Chemistry written by Klaus Weissermel and published by John Wiley & Sons. This book was released on 2008-07-11 with total page 481 pages. Available in PDF, EPUB and Kindle. Book excerpt: 'Ideal for getting an overview of applied organic chemistry' This bestselling standard, now in its 3rd completely revised English edition, is an excellent source of technological and economic information on the most important precursors and intermediates used in the chemical industry. Right and left columns containing synopsis of the main text and statistical data, and numerous fold-out flow diagrams ensure optimal didactic presentation of complex chemical processes. The translation into eight languages, the four German and three English editions clearly evidence the popularity of this book. '... it is where I look first to get a quick overview of the manufacturing process of a product... Weissermel/Arpe has been serving me for years as an indispensable reference work.' (Berichte der Bunsengesellschaft für Physikalische Chemie) 'Whether student or scientist, theorist or practician - everyboby interested in industrial organic chemistry will appreciate this work.' (farbe + lack) '...it should be ready to hand to every chemist or process engineer envolved directly or indirectly with industrial organic chemistry . It should be in the hand of every higher-graduate student, especially if chemical technology is not part of the study, like in many college universities...' (Tenside-Surfactants-Detergents)

Green Chemistry and Catalysis

Author : R. A. Sheldon
Publisher : John Wiley & Sons
ISBN 13 : 3527611010
Total Pages : 448 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Green Chemistry and Catalysis by : R. A. Sheldon

Download or read book Green Chemistry and Catalysis written by R. A. Sheldon and published by John Wiley & Sons. This book was released on 2007-06-27 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first book to focus on catalytic processes from the viewpoint of green chemistry presents every important aspect: · Numerous catalytic reductions and oxidations methods · Solid-acid and solid-base catalysis · C-C bond formation reactions · Biocatalysis · Asymmetric catalysis · Novel reaction media like e.g. ionic liquids, supercritical CO2 · Renewable raw materials Written by Roger A. Sheldon -- without doubt one of the leaders in the field with much experience in academia and industry -- and his co-workers, the result is a unified whole, an indispensable source for every scientist looking to improve catalytic reactions, whether in the college or company lab.

Catalytic Oxidations with Hydrogen Peroxide as Oxidant

Author : G. Strukul
Publisher : Springer Science & Business Media
ISBN 13 : 940170984X
Total Pages : 287 pages
Book Rating : 4.4/5 (17 download)

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Book Synopsis Catalytic Oxidations with Hydrogen Peroxide as Oxidant by : G. Strukul

Download or read book Catalytic Oxidations with Hydrogen Peroxide as Oxidant written by G. Strukul and published by Springer Science & Business Media. This book was released on 2013-03-14 with total page 287 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hydrogen peroxide is a chemical that is becoming increasingly fashionable as an oxidant, both in industry and in academia and whose production is expected to increase significantly in the next few years. This growth in interest is largely due to environmental considerations related to the clean nature of hydrogen peroxide as an oxidant, its by-product being only water. To date this chemical has largely been employed as a non-selective oxidant in operations like the bleaching of paper, cellulose and textiles, or in the formulation of detergents, and only to a minimal extent in the manufacture of organic chemicals. This book has been organized to cover the different aspects of the chemistry of hydrogen peroxide. The various chapters into which the book is divided have been written critically by the authors with the general aim of stimulating new ideas and emphasizing those aspects that are likely to lead to new developments in organic synthesis in the coming future.

Nanotechnology in Oil and Gas Industries

Author : Tawfik Abdo Saleh
Publisher : Springer
ISBN 13 : 3319606301
Total Pages : 343 pages
Book Rating : 4.3/5 (196 download)

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Book Synopsis Nanotechnology in Oil and Gas Industries by : Tawfik Abdo Saleh

Download or read book Nanotechnology in Oil and Gas Industries written by Tawfik Abdo Saleh and published by Springer. This book was released on 2017-10-06 with total page 343 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a powerful source to develop new, rapid and highly efficient materials for the application in various fields of oil and gas. It focuses on the synthesis, characterization and applications of various Nanomaterials, presenting the state-of-the-art in developments and innovations in nanocomposites. This book provides the complete practical and theoretical information about the synthesis of nanoparticles with potential use in the field of oil and gas.