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Pincer Metal Complexes
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Book Synopsis Pincer Compounds by : David Morales-Morales
Download or read book Pincer Compounds written by David Morales-Morales and published by Elsevier. This book was released on 2018-04-11 with total page 756 pages. Available in PDF, EPUB and Kindle. Book excerpt: Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen’s The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry—from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications. Describes the chemistry and applications of this important class of organometallic and coordination compounds Includes contributions from global leaders in the field, featuring pioneers in the area as well as emerging experts conducting exciting research on pincer complexes Highlights areas of promising and active research, including small molecule activation, earth abundant metals, and actinide chemistry
Book Synopsis The Chemistry of Pincer Compounds by : David Morales-Morales
Download or read book The Chemistry of Pincer Compounds written by David Morales-Morales and published by Elsevier. This book was released on 2011-08-11 with total page 467 pages. Available in PDF, EPUB and Kindle. Book excerpt: Pincer complexes are formed by the binding of a chemical structure to a metal atom with at least one carbon-metal bond. Usually the metal atom has three bonds to a chemical backbone, enclosing the atom like a pincer. The resulting structure protects the metal atom and gives it unique properties.The last decade has witnessed the continuous growth in the development of pincer complexes. These species have passed from being curiosity compounds to chemical chameleons able to perform a wide variety of applications. Their unique metal bound structures provide some of the most active catalysts yet known for organic transformations involving the activation of bonds. The Chemistry of Pincer Compounds details use of pincer compounds including homogeneous catalysis, enantioselective organic transformations, the activation of strong bonds, the biological importance of pincer compounds as potential therapeutic or pharmaceutical agents, dendrimeric and supported materials. * Describes the chemistry and applications of this important class of organometallic and coordination compounds* Covers the areas in which pincer complexes have had an impact* Includes information on more recent and interesting pincer compounds not just those that are well-known
Book Synopsis Pincer-Metal Complexes by : Akshai Kumar
Download or read book Pincer-Metal Complexes written by Akshai Kumar and published by Elsevier. This book was released on 2021-11-11 with total page 245 pages. Available in PDF, EPUB and Kindle. Book excerpt: Pincer-Metal Complexes: Applications in Catalytic Dehydrogenation Chemistry provides an overview of pincer-metal catalytic systems that transform hydrocarbons and their derivatives from an synthetic and mechanistic point-of-view. This book provides thorough coverage of the operating mechanisms and dehydrogenation catalyst compatibility in both functionalized and unfunctionalized hydrocarbon systems. In addition, it includes success stories of pincer-metal systems, as well as current and future challenges. The book is an ideal reference for researchers practicing synthetic organic chemistry, inorganic chemistry, organometallic chemistry and catalysis in academia and industry. In recent years there has been a surge in the research on hydrocarbon dehydrogenation catalytic systems that are compatible with polar substituents. This helps facilitate formulation of tandem processes that are not limited to hydrocarbon transformation but also to hydrocarbon functionalization in a single pot. Covers applications of pincer-metal complexes in organic transformations Includes pincer-group 8 and 9 metal complexes for alkane dehydrogenations Features a discussion of pincer-metal complexes for the dehydrogenation of functionalized hydrocarbons and electro-catalytic transformations
Book Synopsis Pincer and Pincer-Type Complexes by : Kálmán J. Szabó
Download or read book Pincer and Pincer-Type Complexes written by Kálmán J. Szabó and published by John Wiley & Sons. This book was released on 2014-06-10 with total page 389 pages. Available in PDF, EPUB and Kindle. Book excerpt: This new book on this hot topic summarizes the key achievements for the synthesis and catalytic applications of pincer and pincer-type complexes, providing readers with the latest research highlights. The editors have assembled an international team of leaders in the field, and their contributions focus on the application of various pincer complexes in modern organic synthesis and catalysis, such as C-C and C-X bond forming reactions, C-H bond functionalization, and the activation of small molecules, as well as asymmetric catalysis. A must-have for every synthetic chemist in both academia and industry intending to develop new catalysts and improved synthetic protocols.
Book Synopsis Organometallic Pincer Chemistry by : Gerard van Koten
Download or read book Organometallic Pincer Chemistry written by Gerard van Koten and published by Springer. This book was released on 2012-09-17 with total page 363 pages. Available in PDF, EPUB and Kindle. Book excerpt: Gerard van Koten: The Mono-anionic ECE-Pincer Ligand - a Versatile Privileged Ligand Platform: General Considerations.- Elena Poverenov, David Milstein: Non-Innocent Behavior of PCP and PCN Pincer Ligands of Late Metal Complexes.- Dean M. Roddick: Tuning of PCP Pincer Ligand Electronic and Steric Properties.- Gemma R. Freeman, J. A. Gareth Williams: Metal Complexes of Pincer Ligands: Excited States, Photochemistry, and Luminescence.- Davit Zargarian, Annie Castonguay, Denis M. Spasyuk: ECE-Type Pincer Complexes of Nickel.- Roman Jambor and Libor Dostál: The Chemistry of Pincer Complexes of 13 - 15 Main Group Elements.- Kálmán J. Szabo: Pincer Complexes as Catalysts in Organic Chemistry.- Jun-ichi Ito and Hisao Nishiyama: Optically Active Bis(oxazolinyl)phenyl Metal Complexes as Multi-potent Catalysts.- Anthony St. John, Karen I. Goldberg, and D. Michael Heinekey: Pincer Complexes as Catalysts for Amine Borane Dehydrogenation.- Dmitri Gelman and Ronit Romm: PC(sp3)P Transition Metal Pincer Complexes: Properties and Catalytic Applications.- Jennifer Hawk and Steve Craig: Physical Applications of Pincer Complexes.
Book Synopsis The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications by : Gerard van Koten
Download or read book The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications written by Gerard van Koten and published by Springer. This book was released on 2015-08-27 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.
Book Synopsis Transition Metal-Dinitrogen Complexes by : Yoshiaki Nishibayashi
Download or read book Transition Metal-Dinitrogen Complexes written by Yoshiaki Nishibayashi and published by John Wiley & Sons. This book was released on 2019-05-06 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive book that explores nitrogen fixation by using transition metal-dinitrogen complexes Nitrogen fixation is one of the most prominent fields of research in chemistry. This book puts the focus on the development of catalytic ammonia formation from nitrogen gas under ambient reaction conditions that has been recently repowered by some research groups. With contributions from noted experts in the field, Transition Metal-Dinitrogen Complexes offers an important guide and comprehensive resource to the most recent research and developments on the topic of nitrogen fixation by using transition metal-dinitrogen. The book is filled with the information needed to understand the synthesis of transition metal-dinitrogen complexes and their reactivity. This important book: -Offers a resource for understanding nitrogen fixation chemistry that is essential for explosives, pharmaceuticals, dyes, and all forms of life -Includes the information needed for anyone interested in the field of nitrogen fixation by using transition metal-dinitrogen complexes -Contains state-of-the-art research on synthesis of transition metal-dinitrogen complexes and their reactivity in nitrogen fixation -Incorporates contributions from well-known specialists and experts with an editor who is an innovator in the field of dinitrogen chemistry Written for chemists and scientists with an interest in nitrogen fixation, Transition Metal-Dinitrogen Complexes is a must-have resource to the burgeoning field of nitrogen fixation by using transition metal-dinitrogen complexes.
Book Synopsis Metal-Ligand Co-operativity by : Gerard van Koten
Download or read book Metal-Ligand Co-operativity written by Gerard van Koten and published by Springer Nature. This book was released on 2021-03-29 with total page 451 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of significant recent developments in the area of metal-ligand cooperativity, with a focus on pincer architectures. The various contributions highlight the widespread impact of M–L co-operativity phenomena on modern organometallic chemistry and catalyst development. The development of efficient and selective catalytic transformations relies on the understanding and fine control of the various elementary reactions that constitutes a catalytic cycle. Co-operative ligands, which actively participate in bond making and bond breaking together to the metal they support, open up new avenues in this area. In particular, buttressing a weak or reactive metal-ligand bond by flanking coordinating arms in a pincer ligand design is proving a versatile strategy to access robust metal complexes that exhibit unusual and selective reactivity patterns.
Book Synopsis Late Transition-metal Complexes Supported by Pincer Ligands by : Wilson D. Bailey
Download or read book Late Transition-metal Complexes Supported by Pincer Ligands written by Wilson D. Bailey and published by . This book was released on 2016 with total page 181 pages. Available in PDF, EPUB and Kindle. Book excerpt: Late transition-metal pincer complexes of primarily palladium(II) and platinum(II) have been investigated for their application as catalysts in partial oxidation reactions. The epoxidation of higher olefins using molecular oxygen as the oxidant has been targeted, and the individual reaction steps needed to accomplish this overall transformation are described herein, including: (1) hydrogenolysis of a metal hydroxide (M-OH) species to yield a metal hydride (M-H), (2) insertion of O2 into the M-H bond to form a metal hydroperoxide (M-OOH), and (3) O-atom transfer from the M-OOH to epoxides, yielding a M-OH and completing the catalytic cycle. Previous results from our group on these individual transformations using (tBuPCP)Pd and (tBuPCO)Pd fragments are also reviewed. The requirements for O2 insertion into PdII and PtII hydrides are discussed. An array of cationic, neutral, and anionic Pd-H and Pt-H complexes supported by a tBuPNP backbone were synthesized and evaluated for O2 insertion (tBuPNP = 2,6-bis-(di-tbutylphosphinomethyl)pyridine). Metal-ligand cooperation was observed in the activation of H2 to form neutral hydride complexes. The effect of ligand protonation/deprotonation on the trans influence experienced by the hydride ligand was investigated. No reaction with O2 was observed with the cationic hydrides, while the neutral and anionic forms reacted with O2 at the tBuPNP backbone. The synthesis and characterization of mono- and dinuclear Pd-OH complexes supported by a PCNR pincer ligand (PCNR = (1-(3-((di-tert-butylphosphino)methyl)phenyl)-1H-5-R-pyrazole), R = H, Me) is presented. When R = H, ligand pyrazole "rollover" C-H activation was observed, forming a mixed ligand (PCNH)Pd(μ-OH)Pd(PCC) dinuclear structure. This "rollover" was investigated using DFT computations. The mono- and dinuclear hydroxide species were evaluated for hydrogenolysis. The dinuclear compounds {[(PCNR)Pd]2(μ-OH)}[OTf] reacted under an H2 atmosphere to yield the corresponding dinuclear hydrides {[(PCNR)Pd]2(μ-H)}[OTf]. A mechanistic study on the hydrogenolysis of the μ-bridged hydroxide {[(PCNMe)Pd]2(μ-OH)}[OTf] revealed first order kinetics in both [Pd] and [H2]. Terminal hydrides were not detected, and reduction of the mononuclear hydroxide complexes (PCNR)Pd-OH to Pd0 was observed under H2. The reduction was proposed to proceed through displacement of the pyrazole arm, and was examined by DFT computations. Lastly, a new strategy to promote O-atom transfer from M-OOH to epoxides, the final step in the targeted catalytic cycle, is proposed. Preliminary studies on NNNPyz, NNNEt, and NNMe ligated PdII and PtII are discussed (NNNPyz = 2,6-bis(5-tbutyl-1H-pyrazol-3-yl)pyridine; NNNEt = 2-(5-tbutyl-1H-pyrazol-3-yl)-6-(diethylaminomethyl)pyridine; NNMe = 2-(5-tBu-1H-pyrazol-3-yl)-6-methylpyridine). The NNNPyz ligand, containing two acidic sites in proximity to the fourth site in the square plane, was found to protonate M-O2 complexes, chelate to the metal center and oxidize phosphine substrates. Similar reactivity was observed with NNNEt and NNMe, however hemilability of these ligands resulted in undesired coordination modes.
Book Synopsis Organometallic Chemistry and Catalysis by : Didier Astruc
Download or read book Organometallic Chemistry and Catalysis written by Didier Astruc and published by Springer Science & Business Media. This book was released on 2007-08-02 with total page 598 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume covers both basic and advanced aspects of organometallic chemistry of all metals and catalysis. In order to present a comprehensive view of the subject, it provides broad coverage of organometallic chemistry itself. The catalysis section includes the challenging activation and fictionalization of the main classes of hydrocarbons and the industrially crucial heterogeneous catalysis. Summaries and exercises are provides at the end of each chapter, and the answers to these exercises can be found at the back of the book. Beginners in inorganic, organic and organometallic chemistry, as well as advanced scholars and chemists from academia and industry will find much value in this title.
Book Synopsis Alkaline-Earth Metal Compounds by : Sjoerd Harder
Download or read book Alkaline-Earth Metal Compounds written by Sjoerd Harder and published by Springer. This book was released on 2013-07-20 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.
Book Synopsis Nitrogen Fixation by : Yoshiaki Nishibayashi
Download or read book Nitrogen Fixation written by Yoshiaki Nishibayashi and published by Springer. This book was released on 2017-07-03 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume presents a review of recent developments in nitrogen fixation using transition metal–dinitrogen complexes in the last decade. The authors are international experts in the corresponding field and each chapter discusses their latest achievements in the preparation of various transition metal–dinitrogen complexes and their reactivity. This volume will be helpful to researchers, teachers, and students who are interested in innovative and sustainable chemistry.
Book Synopsis A Textbook of Inorganic Chemistry – Volume 1 by : Mandeep Dalal
Download or read book A Textbook of Inorganic Chemistry – Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Book Synopsis Unconventional Pincer Ligands and Their Transition Metal Complexes by : Caitlin McQueen
Download or read book Unconventional Pincer Ligands and Their Transition Metal Complexes written by Caitlin McQueen and published by . This book was released on 2013 with total page 404 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis describes investigations into unconventional pincer systems incorporating non-classical central donor groups. Direct reaction of 1,3-bis(diphenylphosphinomethyl)-2,3-dihydro-1H-1,3,2-benzodiazaborole (dppBH) with metal complexes and subsequent ligand manipulations have provided novel ruthenium and, for the first time, osmium boryl pincer complexes. The boryl complexes thus prepared have been observed to undergo various subsequent reactions involving the chloride and triphenylphosphine co-ligands to give new complexes. Further reactions of dppBH with complexes dichlorotris(triphenylphosphine)ruthenium(II) and -osmium(II) resulted in the first examples of sigma-borane pincer complexes, which represent intercepted intermediates in the B-H activation process, affording rare structural data for an osmium sigma-borane complex. The B-H bond of the ruthenium complex could be readily cleaved upon ligand manipulation, such as substitution of triphenylphosphine with the pi-acidic carbonyl and isocyanide ligands, which gave the disubstituted boryl complexes via spontaneous loss of HCl. Attempts to isolate a 1,8-diaminonaphthalene-based borane analogue of dppBH proved unsuccessful, though the compound 1,3 bis(diphenylphosphinomethyl)-2,3-dihydroperimidine (PhDHP) was obtained as a side-product in one case. Further investigations into this compound resulted in the development of a convenient one-pot synthesis, which could be extended to the cyclohexyl analogue 1,3 bis(dicyclohexylphosphinomethyl)-2,3-dihydroperimidine (CyDHP). These compounds were observed to react with various platinum group metal complexes to give novel N-heterocyclic carbene (NHC) pincer complexes via double geminal C-H activation of the central methylene group, providing the first examples of perimidine-based NHC inclusion as the central equatorial group of a pincer system. Reactions of dihydroperimidines with group 8 complexes dichlorotris(triphenylphosphine)ruthenium(II) and -osmium(II) have thus provided the novel pincer NHC complexes. However, reactions of PhDHP with dichlorotris(triphenylphosphine)ruthenium and CyDHP with less electron-rich ruthenium precursors instead gave asymmetric PNP coordinated complexes, in which C-H activation had not occurred, though this could be induced thermally in one case. Reactions of PhDHP and CyDHP with chlorotris(triphenylphosphine)rhodium(I) gave 16-electron chloro rhodium(I) NHC pincer complexes, and their reactivity was investigated via co-ligand manipulations and a preliminary catalytic study. The latter revealed that, while this complex was not particularly efficient for most of the reactions investigated, in some cases simple modifications of the co-ligands could substantially improve catalytic activity. Reactions of the pro-ligands with iridium precursors instead favoured the formation of coordinatively saturated complexes. The reaction of CyDHP with chlorobis(cyclooctene)iridium(I) dimer resulted in a dihydrido chloro iridium(III) NHC pincer complex, while reaction with chlorocarbonylbis(triphenylphosphine)iridium(I) instead afforded a sigma perimidinyl hydrido complex, resulting from oxidative addition of only one C-H bond to the metal centre. This was subsequently shown to readily form an NHC complex upon hydride abstraction. It became apparent that, upon reaction of the dihydroperimidine pro-ligands with metal complexes, carbene formation occurs more readily for electron-rich systems, otherwise resulting in either single or no C-H activation. These observations have provided some insight into the mechanism of NHC formation via chelate-assisted C-H activation of these precursors.
Book Synopsis Activation and Functionalization of C-H Bonds by : Karen I. Goldberg
Download or read book Activation and Functionalization of C-H Bonds written by Karen I. Goldberg and published by ACS Symposium. This book was released on 2004 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Activation and Functionalization of C-H Bonds explores recent developments in the reaction chemistry of solution-phase transition-metal based systems with simple hydrocarbons and with more complex organic molecules. More than 20 internationally leading research groups contributed to this volume, and their chapters cover such topics as fundamental theoretical and mechanistic studies of C-H bond activation by metal complexes, catalytic systems for alkane functionalization, and new applications in synthetic organic chemistry. An introductory chapter offers an overview of stoichiometric and catalytic reactions of C-H bonds with transition metal complexes. The C-H bond is the most widespread linkage in organic chemistry, present in virtually every organic molecule. Unfortunately, C-H bonds are famously resistant to selective chemical transformations. The development of methods for their selective transformations has enormous potential value in fields ranging from the chemistry of fuels (for example, the conversion of methane to methanol) to the synthesis of the most complex organic molecules.
Book Synopsis Ligand Design in Metal Chemistry by : Mark Stradiotto
Download or read book Ligand Design in Metal Chemistry written by Mark Stradiotto and published by John Wiley & Sons. This book was released on 2016-09-01 with total page 448 pages. Available in PDF, EPUB and Kindle. Book excerpt: The design of ancillary ligands used to modify the structural and reactivity properties of metal complexes has evolved into a rapidly expanding sub-discipline in inorganic and organometallic chemistry. Ancillary ligand design has figured directly in the discovery of new bonding motifs and stoichiometric reactivity, as well as in the development of new catalytic protocols that have had widespread positive impact on chemical synthesis on benchtop and industrial scales. Ligand Design in Metal Chemistry presents a collection of cutting-edge contributions from leaders in the field of ligand design, encompassing a broad spectrum of ancillary ligand classes and reactivity applications. Topics covered include: Key concepts in ligand design Redox non-innocent ligands Ligands for selective alkene metathesis Ligands in cross-coupling Ligand design in polymerization Ligand design in modern lanthanide chemistry Cooperative metal-ligand reactivity P,N Ligands for enantioselective hydrogenation Spiro-cyclic ligands in asymmetric catalysis This book will be a valuable reference for academic researchers and industry practitioners working in the field of ligand design, as well as those who work in the many areas in which the impact of ancillary ligand design has proven significant, for example synthetic organic chemistry, catalysis, medicinal chemistry, polymer science and materials chemistry.
Download or read book Carbon Ligands written by Yves Canac and published by Mdpi AG. This book was released on 2021-06-30 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homogeneous catalysis owes its success, in large part, to the development of a wide range of ligands with well-defined electronic and steric properties, which have thus made it possible to adjust the behavior of many organometallic complexes. However, ligands used in catalysis have long been centered on elements of group 15, and it is only more recently that carbon ligands have proved to be valuable alternatives with the emergence of cyclic diaminocarbenes (NHC).This Special Issue aims to provide a contemporary overview of the advances in carbon ligand chemistry from fundamental aspects to applications.
