Phosphinoamide Ligands For The Synthesis Of Early Transition Metal Organometallic Complexes

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The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications

Author : Gerard van Koten
Publisher : Springer
ISBN 13 : 3319229273
Total Pages : 381 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications by : Gerard van Koten

Download or read book The Privileged Pincer-Metal Platform: Coordination Chemistry & Applications written by Gerard van Koten and published by Springer. This book was released on 2015-08-27 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Phosphorus-31 NMR Spectroscopy

Author : Olaf Kühl
Publisher : Springer Science & Business Media
ISBN 13 : 3540791183
Total Pages : 138 pages
Book Rating : 4.5/5 (47 download)

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Book Synopsis Phosphorus-31 NMR Spectroscopy by : Olaf Kühl

Download or read book Phosphorus-31 NMR Spectroscopy written by Olaf Kühl and published by Springer Science & Business Media. This book was released on 2008-08-22 with total page 138 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nuclear Magnetic Resonance is a powerful tool, especially for the identification of 1 13 hitherto unknown organic compounds. H- and C-NMR spectroscopy is known and applied by virtually every synthetically working Organic Chemist. Con- quently, the factors governing the differences in chemical shift values, based on chemical environment, bonding, temperature, solvent, pH, etc. , are well understood, and specialty methods developed for almost every conceivable structural challenge. Proton and carbon NMR spectroscopy is part of most bachelors degree courses, with advanced methods integrated into masters degree and other graduate courses. In view of this universal knowledge about proton and carbon NMR spectr- copy within the chemical community, it is remarkable that heteronuclear NMR is still looked upon as something of a curiosity. Admittedly, most organic compounds contain only nitrogen, oxygen, and sulfur atoms, as well as the obligatory hydrogen and carbon atoms, elements that have an unfavourable isotope distribution when it comes to NMR spectroscopy. Each of these three elements has a dominant isotope: 14 16 32 16 32 N (99. 63% natural abundance), O (99. 76%), and S (95. 02%), with O, S, and 34 14 S (4. 21%) NMR silent. N has a nuclear moment I = 1 and a sizeable quadrupolar moment that makes the NMR signals usually very broad and dif cult to analyse.

Olefin Polymerization

Author : Walter Kaminsky
Publisher : Wiley-VCH
ISBN 13 : 9783527317424
Total Pages : 0 pages
Book Rating : 4.3/5 (174 download)

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Book Synopsis Olefin Polymerization by : Walter Kaminsky

Download or read book Olefin Polymerization written by Walter Kaminsky and published by Wiley-VCH. This book was released on 2006-08-18 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: With an enormous velocity, olefin polymerization has expanded to one of the most significant fields in polymers since the first industrial use about 50 years ago. In 2005, 100 million tons of polyolefins were produced - the biggest part was catalyzed by metallorganic compounds. The Hamburg Macromolecular Symposium 2005 with the title "Olefin Polymerization" involved topics such as new catalysts and cocatalysts, kinetics, mechanism and polymer reaction engineering, synthesis of special polymers, and characterization of polyolefins. The conference combined scientists from different disciplines to discuss latest research results of polymers and to offer each other the possibility of cooperation. This is reflected in this volume, which contains invited lectures and selected posters presented at the symposium.

Metal-Ligand Interactions

Author : N. Russo
Publisher : Springer Science & Business Media
ISBN 13 : 9400901550
Total Pages : 557 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Metal-Ligand Interactions by : N. Russo

Download or read book Metal-Ligand Interactions written by N. Russo and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 557 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Ligand Interactions - Structure and Reactivity emphasizes the experimental determination of structure and dynamics, supported by the theoretical and computational approaches needed to establish the concepts and guide the experiments. Leading experts present masterly surveys of: clusters, inorganic complexes, surfaces, catalysis, ab initio theory, density functional theory,semiempirical methods, and dynamics. Besides the presentations of the fields of study themselves, the papers also bring out those aspects that impinge on, or could benefit from, progress in other disciplines. Refined in the fire of an interactive and stimulating conference, the papers presented here represent the state of the art of current research.

Spectroelectrochemistry

Author : Wolfgang Kaim
Publisher : Royal Society of Chemistry
ISBN 13 : 0854045503
Total Pages : 247 pages
Book Rating : 4.8/5 (54 download)

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Book Synopsis Spectroelectrochemistry by : Wolfgang Kaim

Download or read book Spectroelectrochemistry written by Wolfgang Kaim and published by Royal Society of Chemistry. This book was released on 2008 with total page 247 pages. Available in PDF, EPUB and Kindle. Book excerpt: A practical guidebook illustrating the applications of spectroelectrochemistry to the understanding of redox reactions through identification of their intermediaries and products.

Catalytic Cascade Reactions

Author : Peng-Fei Xu
Publisher : John Wiley & Sons
ISBN 13 : 1118016025
Total Pages : 440 pages
Book Rating : 4.1/5 (18 download)

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Book Synopsis Catalytic Cascade Reactions by : Peng-Fei Xu

Download or read book Catalytic Cascade Reactions written by Peng-Fei Xu and published by John Wiley & Sons. This book was released on 2013-11-11 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: Demonstrates the advantages of catalytic cascade reactions for synthesizing natural products and pharmaceuticals Riding the wave of green chemistry, catalytic cascade reactions have become one of the most active research areas in organic synthesis. During a cascade reaction, just one reaction solvent, one workup procedure, and one purification step are needed, thus significantly increasing synthetic efficiency. Featuring contributions from an international team of pioneers in the field, Catalytic Cascade Reactions demonstrates the versatility and application of these reactions for synthesizing valuable compounds. The book examines both organocatalysis and transition-metal catalysis reactions, bringing readers up to date with the latest discoveries and activities in all major areas of catalytic cascade reaction research. Catalytic Cascade Reactions begins with three chapters dedicated to organocatalytic cascade reactions, exploring amines, Brønsted acids, and the application of organocatalytic cascade reactions in natural product synthesis and drug discovery. Next, the book covers: Gold-catalyzed cascade reactions Cascade reactions catalyzed by ruthenium, iron, iridium, rhodium, and copper Palladium-catalyzed cascade reactions of alkenes, alkynes, and allenes Application of transition-metal catalyzed cascade reactions in natural product synthesis and drug discovery Engineering mono- and multifunctional nanocatalysts for cascade reactions Multiple-catalyst-promoted cascade reactions All chapters are thoroughly referenced, providing quick access to important original research findings and reviews so that readers can explore individual topics in greater depth. Drawing together and analyzing published findings scattered across the literature, this book provides a single source that encapsulates our current understanding of catalytic cascade processes. Moreover, it sets the stage for the development of new catalytic cascade reactions and their applications.

Molecular Metal-Metal Bonds

Author : Stephen T. Liddle
Publisher : John Wiley & Sons
ISBN 13 : 3527335412
Total Pages : 590 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Molecular Metal-Metal Bonds by : Stephen T. Liddle

Download or read book Molecular Metal-Metal Bonds written by Stephen T. Liddle and published by John Wiley & Sons. This book was released on 2015-06-22 with total page 590 pages. Available in PDF, EPUB and Kindle. Book excerpt: Systematically covering all the latest developments in the field, this is a comprehensive and handy introduction to metal-metal bonding. The chapters follow a uniform, coherent structure for a clear overview, allowing readers easy access to the information. The text covers such topics as synthesis, properties, structures, notable features, reactivity and examples of applications of the most important compounds in each group with metal-metal bonding throughout the periodic table. With its general remarks at the beginning of each chapter, this is a must-have reference for all molecular inorganic chemists, including PhD students and postdocs, as well as more experienced researchers.

Molecular Catalysts

Author : Lutz H. Gade
Publisher : John Wiley & Sons
ISBN 13 : 3527673296
Total Pages : 632 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Molecular Catalysts by : Lutz H. Gade

Download or read book Molecular Catalysts written by Lutz H. Gade and published by John Wiley & Sons. This book was released on 2014-06-30 with total page 632 pages. Available in PDF, EPUB and Kindle. Book excerpt: Highlighting the key aspects and latest advances in the rapidly developing field of molecular catalysis, this book covers new strategies to investigate reaction mechanisms, the enhancement of the catalysts' selectivity and efficiency, as well as the rational design of well-defined molecular catalysts. The interdisciplinary author team with an excellent reputation within the community discusses experimental and theoretical studies, along with examples of improved catalysts, and their application in organic synthesis, biocatalysis, and supported organometallic catalysis. As a result, readers will gain a deeper understanding of the catalytic transformations, allowing them to adapt the knowledge to their own investigations. With its ideal combination of fundamental and applied research, this is an essential reference for researchers and graduate students both in academic institutions and in the chemical industry. With a foreword by Nobel laureate Roald Hoffmann.

Alkaline-Earth Metal Compounds

Author : Sjoerd Harder
Publisher : Springer
ISBN 13 : 3642362702
Total Pages : 282 pages
Book Rating : 4.6/5 (423 download)

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Book Synopsis Alkaline-Earth Metal Compounds by : Sjoerd Harder

Download or read book Alkaline-Earth Metal Compounds written by Sjoerd Harder and published by Springer. This book was released on 2013-07-20 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Activation and Functionalization of C-H Bonds

Author : Karen I. Goldberg
Publisher : ACS Symposium
ISBN 13 : 9780841238497
Total Pages : 0 pages
Book Rating : 4.2/5 (384 download)

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Book Synopsis Activation and Functionalization of C-H Bonds by : Karen I. Goldberg

Download or read book Activation and Functionalization of C-H Bonds written by Karen I. Goldberg and published by ACS Symposium. This book was released on 2004 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Activation and Functionalization of C-H Bonds explores recent developments in the reaction chemistry of solution-phase transition-metal based systems with simple hydrocarbons and with more complex organic molecules. More than 20 internationally leading research groups contributed to this volume, and their chapters cover such topics as fundamental theoretical and mechanistic studies of C-H bond activation by metal complexes, catalytic systems for alkane functionalization, and new applications in synthetic organic chemistry. An introductory chapter offers an overview of stoichiometric and catalytic reactions of C-H bonds with transition metal complexes. The C-H bond is the most widespread linkage in organic chemistry, present in virtually every organic molecule. Unfortunately, C-H bonds are famously resistant to selective chemical transformations. The development of methods for their selective transformations has enormous potential value in fields ranging from the chemistry of fuels (for example, the conversion of methane to methanol) to the synthesis of the most complex organic molecules.

Frustrated Lewis Pairs I

Author : Gerhard Erker
Publisher : Springer
ISBN 13 : 364236697X
Total Pages : 354 pages
Book Rating : 4.6/5 (423 download)

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Book Synopsis Frustrated Lewis Pairs I by : Gerhard Erker

Download or read book Frustrated Lewis Pairs I written by Gerhard Erker and published by Springer. This book was released on 2014-07-08 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: Discovery of Frustrated Lewis Pairs: Intermolecular FLPs for Activation of Small Molecules, by Douglas W. Stephan Intramolecular Frustrated Lewis Pairs: Formation and Chemical Features, by Gerald Kehr, Sina Schwendemann, Gerhard Erker Frustrated Lewis Pair Mediated Hydrogenations, by Douglas W. Stephan, Gerhard Erker Amine-Borane Mediated Metal-Free Hydrogen Activation and Catalytic Hydrogenation, by Victor Sumerin, Konstantin Chernichenko, Felix Schulz, Markku Leskelä, Bernhard Rieger, Timo Repo Hydrogen Activation by Frustrated Lewis Pairs: Insights from Computational Studies, by Tibor András Rokob, Imre Pápai Quantum Chemistry of FLPs and Their Activation of Small Molecules: Methodological Aspects, by Birgitta Schirmer, Stefan Grimme Computational Design of Metal-Free Molecules for Activation of Small Molecules, Hydrogenation, and Hydroamination, by Zhi-Xiang Wang, Lili Zhao, Gang Lu, Haixia Li, Fang Huang Computational Studies of Lewis Acidity and Basicity in Frustrated Lewis Pairs, by Thomas M. Gilbert Solid-State NMR as a Spectroscopic Tool for Characterizing Phosphane - Borane Frustrated Lewis Pairs, by Thomas Wiegand, Hellmut Eckert, Stefan Grimme

Frustrated Lewis Pairs II

Author : Gerhard Erker
Publisher : Springer
ISBN 13 : 3642377599
Total Pages : 321 pages
Book Rating : 4.6/5 (423 download)

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Book Synopsis Frustrated Lewis Pairs II by : Gerhard Erker

Download or read book Frustrated Lewis Pairs II written by Gerhard Erker and published by Springer. This book was released on 2013-12-12 with total page 321 pages. Available in PDF, EPUB and Kindle. Book excerpt: Frustrated Lewis Pairs: From Dihydrogen Activation to Asymmetric Catalysis, by Dianjun Chen, Jürgen Klankermayer Coexistence of Lewis Acid and Base Functions: A Generalized View of the Frustrated Lewis Pair Concept with Novel Implications for Reactivity, by Heinz Berke, Yanfeng Jiang, Xianghua Yang, Chunfang Jiang, Subrata Chakraborty, Anne Landwehr New Organoboranes in "Frustrated Lewis Pair" Chemistry, by Zhenpin Lu, Hongyan Ye, Huadong Wang Paracyclophane Derivatives in Frustrated Lewis Pair Chemistry, by Lutz Greb, Jan Paradies Novel Al-Based FLP Systems, by Werner Uhl, Ernst-Ulrich Würthwein N-Heterocyclic Carbenes in FLP Chemistry, by Eugene L. Kolychev, Eileen Theuergarten, Matthias Tamm Carbon-Based Frustrated Lewis Pairs, by Shabana Khan, Manuel Alcarazo Selective C-H Activations Using Frustrated Lewis Pairs. Applications in Organic Synthesis, by Paul Knochel, Konstantin Karaghiosoff, Sophia Manolikakes FLP-Mediated Activations and Reductions of CO2 and CO, by Andrew E. Ashley, Dermot O’Hare Radical Frustrated Lewis Pairs, by Timothy H. Warren and Gerhard Erker Polymerization by Classical and Frustrated Lewis Pairs, by Eugene Y.-X. Chen Frustrated Lewis Pairs Beyond the Main Group: Transition Metal-Containing Systems, by D. Wass Reactions of Phosphine-Boranes and Related Frustrated Lewis Pairs with Transition Metal Complexes, by Abderrahmane Amgoune, Ghenwa Bouhadir, Didier Bourissou

Iron Porphyrins

Author : A. B. P. Lever
Publisher : Wiley-VCH
ISBN 13 : 9780471187158
Total Pages : 322 pages
Book Rating : 4.1/5 (871 download)

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Book Synopsis Iron Porphyrins by : A. B. P. Lever

Download or read book Iron Porphyrins written by A. B. P. Lever and published by Wiley-VCH. This book was released on 1989-03-31 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: Porphyrins play a vital role in many biological functions including oxygen transport, electron transfer and catalyzing the incorporation of oxygen into other molecules. This current survey discusses the use of modern physical techniques to probe porphyrin structure and function. The authors review the data available through a particular technique and show what can be learned therefrom about the (electronic) structure and function of biologically important porphyrins. The techniques include magnetic circular dichroism, X-ray absorption fine structure (EXAFS) and Mössbauer spectroscopies. All contributors are well known in their respective fields, enjoying world-wide reputation.

Multiple Bonds between Metal Atoms

Author : F. Albert Cotton
Publisher : Springer Science & Business Media
ISBN 13 : 9780387250847
Total Pages : 856 pages
Book Rating : 4.2/5 (58 download)

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Book Synopsis Multiple Bonds between Metal Atoms by : F. Albert Cotton

Download or read book Multiple Bonds between Metal Atoms written by F. Albert Cotton and published by Springer Science & Business Media. This book was released on 2005-06-28 with total page 856 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides historical perspective as well as current data Abundantly illustrated with figures redrawn from literature data Covers all pertinent theory and physical chemistry Catalytic and chemotherapeutic applications are included

C-H Bond Activation and Catalytic Functionalization I

Author : Pierre H. Dixneuf
Publisher : Springer
ISBN 13 : 3319246305
Total Pages : 269 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis C-H Bond Activation and Catalytic Functionalization I by : Pierre H. Dixneuf

Download or read book C-H Bond Activation and Catalytic Functionalization I written by Pierre H. Dixneuf and published by Springer. This book was released on 2015-12-18 with total page 269 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal.

Reactivity of Metal-metal Bonds

Author : Malcolm H. Chisholm
Publisher :
ISBN 13 :
Total Pages : 344 pages
Book Rating : 4.:/5 (44 download)

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Book Synopsis Reactivity of Metal-metal Bonds by : Malcolm H. Chisholm

Download or read book Reactivity of Metal-metal Bonds written by Malcolm H. Chisholm and published by . This book was released on 1981 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Palladacycles

Author : Anant Kapdi
Publisher : Elsevier
ISBN 13 : 9780128155059
Total Pages : 0 pages
Book Rating : 4.1/5 (55 download)

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Book Synopsis Palladacycles by : Anant Kapdi

Download or read book Palladacycles written by Anant Kapdi and published by Elsevier. This book was released on 2019-06-15 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Palladacycles: Catalysis and Beyond provides an overview of recent research in palladacycles in catalysis for cross-coupling and similar reactions. In the quest for developing highly efficient and robust palladium-based catalysts for C-C bond formation via cross-coupling reactions, palladacycles have played a significant role. In recent years, they have found a wide variety of applications, ranging from catalysts for cross-coupling and related reactions, to their more recent application as anticancer agents. This book explores early examples of the use of palladacyclic complexes in catalysis employing azobenzene and hydrazobenzene as coordinating ligands. Its applications in processes such as selective reduction of alkenes, alkynes, or nitroalkanes are also covered. Palladacycles: Catalysis and Beyond reveals the tremendous advances that have taken place in the potential applications of palladacycles as versatile catalysts in academia and industry. It is a valuable resource for synthetic chemists, organometallic chemists, and chemical biologists.