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Organometallic Compounds Of The Group Iv Elements The Bond To Carbon 2 V The Bond To Halogens And Halogenoids
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Book Synopsis Organometallic Compounds of the Group IV Elements: The bond to carbon. 2 v. The bond to halogens and halogenoids by : Alan G. MacDiarmid
Download or read book Organometallic Compounds of the Group IV Elements: The bond to carbon. 2 v. The bond to halogens and halogenoids written by Alan G. MacDiarmid and published by . This book was released on 1968 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Organometallic Compounds of the Group IV Elements: The bond to carbon. 2 v by : Alan G. MacDiarmid
Download or read book Organometallic Compounds of the Group IV Elements: The bond to carbon. 2 v written by Alan G. MacDiarmid and published by . This book was released on 1968 with total page 632 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Organometallic Compounds of the Group IV Elements: The bond to carbon. 2 v. The bond to halogens and halogenoids by : Alan G. MacDiarmid
Download or read book Organometallic Compounds of the Group IV Elements: The bond to carbon. 2 v. The bond to halogens and halogenoids written by Alan G. MacDiarmid and published by . This book was released on 1968 with total page 650 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Organometallic Compounds of the Grooup IV Elements: The bond to halogens and hologenoids. (2v) by : Alan G. MacDiarmid
Download or read book Organometallic Compounds of the Grooup IV Elements: The bond to halogens and hologenoids. (2v) written by Alan G. MacDiarmid and published by . This book was released on 1972 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Organometallic Compounds by : B. J. Aylett
Download or read book Organometallic Compounds written by B. J. Aylett and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt: A very large number of organo derivatives is formed by the Group IV ele ments silicon, germanium, tin, and lead. In comparing the general properties of these elements, Table 1. 1 shows that the first ionization energies decrease (though not in a regular way) with increase in size and atomic number, con sistent with the general increase in metallic character of the elements. Electro negativity values (which have been the subject of considerable controversy) show no clear trend. Although purely inorganic compounds of tin(n) and leaden) are well known, almost all organo Group IV derivatives show an oxidation state of IV. Bonds to carbon become weaker on passing from silicon to lead, as do the element-element bonds themselves. With any particular element M (M = Si, Ge, Sn, or Pb), there is a small decrease in bond energy in the order: M-Ph > M - Me > M - Et. Although accurate data for organo derivatives are lacking, strengths of bonds to other elements probably decrease in the order: M-F> M-O > M-CI > M-H ~ M-N ~ M-S ~ M-Br > M-I, while for a particular element X, the order is: Si-X > Ge-X > Sn-X > Pb-X. It is therefore understandable that reactions leading to Si-F, Si-O, or Si-CI bonds are especially favoured in a thermodynamic sense.
Book Synopsis Organometallic Compounds of the Group IV Elements: Synthesis and properties of the silicon-halogen and silicon-halogenoid bond by : Alan G. MacDiarmid
Download or read book Organometallic Compounds of the Group IV Elements: Synthesis and properties of the silicon-halogen and silicon-halogenoid bond written by Alan G. MacDiarmid and published by . This book was released on 1968 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Organometallic Compounds of the Group IV Elements: Synthesis and properties of the germanium-halogen and germanium-halogenoid bond by : Alan G. MacDiarmid
Download or read book Organometallic Compounds of the Group IV Elements: Synthesis and properties of the germanium-halogen and germanium-halogenoid bond written by Alan G. MacDiarmid and published by . This book was released on 1972 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Advances in Organometallic Chemistry by :
Download or read book Advances in Organometallic Chemistry written by and published by Academic Press. This book was released on 1975-08-22 with total page 573 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Organometallic Chemistry
Book Synopsis Organo-metallic Compounds of the Group IV Elements. Vol.2. The Bond to Halogens and Halogenoids by : A. G. MacDiarmid
Download or read book Organo-metallic Compounds of the Group IV Elements. Vol.2. The Bond to Halogens and Halogenoids written by A. G. MacDiarmid and published by . This book was released on 1972 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Organometallic Compounds of the Group IV Elements by : Alan G. MacDiarmid
Download or read book Organometallic Compounds of the Group IV Elements written by Alan G. MacDiarmid and published by . This book was released on 1968 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis GeR4 Compounds and Ge(CH3) 3R Compounds up to Cyclic Alkyl Groups by : Frank Glockling
Download or read book GeR4 Compounds and Ge(CH3) 3R Compounds up to Cyclic Alkyl Groups written by Frank Glockling and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 247 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume opens the Gmelin series on organogermanium compounds, that is, those compounds containing at least one germanium-to-carbon bond. This whole series is being coordinated by Professor J. Satge of the Universite Paul Sabatier in Toulouse. Germanium is of historical interest because its existence was predicted by Newlands in 1864 and by Mendeleeff in 1871 although it was not isolated until1887 by Winkler. Mendeleeff's predictions of the properties of germanium and its compounds by comparison with what was known of the chemistry of its neighbors, silicon and tin, proved remarkably accurate and included predictions of the existence of organic derivatives GeR and of their properties. 4 Although significant applications are as yet lacking for organogermanium compounds in contrast to organo-silicon, -tin, and -lead compounds there has been considerable interest in the parallel development of its chemistry. Up to 1983 about 1500 publications have appeared on organogermanium chemistry. The material of the present series will be grouped in a similar way as for the organotin series beginning with compounds containing only one germanium atom (mononuclear com pounds) and continuing with binuclear up to polynuclear compounds. Within each group the compounds are arranged by the kind of non-carbon substituents rather than by following the usual Gmelin principle of the last position using the Gmelin system of elements.
Book Synopsis Organometallic Compounds of the Group Four Elements by : Alan G. MacDiarmid
Download or read book Organometallic Compounds of the Group Four Elements written by Alan G. MacDiarmid and published by . This book was released on 1968 with total page 619 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Organometallic Compounds of the Group IV Elements by : Alan G. MacDiarmid
Download or read book Organometallic Compounds of the Group IV Elements written by Alan G. MacDiarmid and published by . This book was released on 1968 with total page 261 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Organo-metallic Compounds of the Group IV Compounds. Vol.2. The Bond to Halogens and Halogenoids by : A. G. MacDiarmid
Download or read book Organo-metallic Compounds of the Group IV Compounds. Vol.2. The Bond to Halogens and Halogenoids written by A. G. MacDiarmid and published by . This book was released on 1972 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Organometallic Compounds written by and published by . This book was released on 1979 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Some Aspects of the Organometallic Chemistry of the Group VI Transition Metals by : Ezra Eddy Isaacs
Download or read book Some Aspects of the Organometallic Chemistry of the Group VI Transition Metals written by Ezra Eddy Isaacs and published by . This book was released on 1974 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The reaction of cycloheptatrienyltricarbonyl molybdenum cation with various main group V donor ligands (L) yielded, in general, mono-substituted complexes, [C[subscript 7]H[subscript 7]Mo(CO)[subscript 2]L][superscript +]. [superscript 31]P nmr studies on some related di-tertiary phosphine complexes provided a convenient and unequivocal determination of the stereochemistry. The reduction of the cationic cycloheptatrienyl complexes with sodium borohydride provided a suitable synthetic route to the group V derivatives of cyclo- heptatrienetricarbonylmolybdenum. The infrared, [superscript l]H and [superscript 13]C nmr, and mass spectral properties of these complexes were studied. Some main group IV ligands bonded to cycloheptatrienyldicarbonylmolybdenum were also prepared and studied by spectral means. A number of main group IV - group VI metal penta- carbonyl anionic derivatives have been prepared by the reaction of the chloropentacarbonyl anions with the organolithium compounds of the group IV elements. These compounds have the general formula, [R[subscript 3]M' -M(CO)[subscript 5]][superscript -] (where R = Me, Ph or halogen; M' = Si, Ge, Sn or Pb; M = Cr, Mo or W). Approximate carbonyl force constants were calculated from the infrared carbonyl stretching vibrations and these provided some insight into the nature of the metal-metal bonds. Transition metal nitrosyl derivatives have also been prepared by the reaction of some anionic complexes with nitrosonium hexafluorophosphate. These compounds have the general formula LM(CO)[subscript 4]NO (where L is a main group IV ligand or a halogen group and M is Mo or W). The carbonyl and nitrosyl force constants were calculated and are discussed in terms of the relative bonding properties of CO and NO ligands. Finally, the oxidation reaction of some dinuclear metal carbonyls with AgNO[subscript 2] led to the formation of metal carbonyls containing nitro ligands. Linkage isomerism involving nitro and nitrito species was encountered in solution. The [(CH[subscript 3]CN)[subscript 3]Re(CO)[subscript 3]] + cation was formed 2 - from the oxidation reaction of [Re[subscript 4](CO)[subscript 16]][superscript 2-] in acetonitrile.
Book Synopsis Rodd's Chemistry of Carbon Compounds by : E. H. Rodd
Download or read book Rodd's Chemistry of Carbon Compounds written by E. H. Rodd and published by . This book was released on 1975 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt:
