New Techniques For The Study Of Electrodes And Their Reactions

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New Techniques for the Study of Electrodes and Their Reactions

Author : R.G. Compton
Publisher : Elsevier
ISBN 13 : 9780080868233
Total Pages : 503 pages
Book Rating : 4.8/5 (682 download)

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Book Synopsis New Techniques for the Study of Electrodes and Their Reactions by : R.G. Compton

Download or read book New Techniques for the Study of Electrodes and Their Reactions written by R.G. Compton and published by Elsevier. This book was released on 1989-04-01 with total page 503 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 29 gives an account of new techniques for the study of electrodes and their reactions. It extends and complements Volumes 26 and 27 of the series which provide an introductory treatment of modern electrochemical methodology and reactions. This volume covers the various branches of spectroelectrochemistry and also some recent purely electrochemical advances. In-situ spectroelectrochemical techniques are covered by chapters on infrared, Raman, EPR, ellipsometry, electroreflectance, and photocurrent spectroscopy. Ex-situ UHV experiments are treated in a separate chapter. New electrochemical directions are described in chapters on hydrodynamic methods, channel electrodes, and microelectrodes. A final chapter covers computing strategies for the on-line accumulation and processing of electrochemical data.

New Techniques for the Study of Electrodes and Their Reactions

Author : R. G. Compton
Publisher :
ISBN 13 : 9780444416315
Total Pages : 504 pages
Book Rating : 4.4/5 (163 download)

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Book Synopsis New Techniques for the Study of Electrodes and Their Reactions by : R. G. Compton

Download or read book New Techniques for the Study of Electrodes and Their Reactions written by R. G. Compton and published by . This book was released on 1989 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Handbook of Electrochemistry

Author : Cynthia G. Zoski
Publisher : Elsevier
ISBN 13 : 0444519580
Total Pages : 935 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis Handbook of Electrochemistry by : Cynthia G. Zoski

Download or read book Handbook of Electrochemistry written by Cynthia G. Zoski and published by Elsevier. This book was released on 2007-02-07 with total page 935 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry which are essential for everyone working in the field, presenting an overview of electrochemical conventions, terminology, fundamental equations, and electrochemical cells, experiments, literature, textbooks, and specialized books. Part 2 focuses on the different laboratory aspects of electrochemistry which is followed by a review of the various electrochemical techniques ranging from classical experiments to scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry. Applications of electrochemistry include electrode kinetic determinations, unique aspects of metal deposition, and electrochemistry in small places and at novel interfaces and these are detailed in Part 4. The remaining three chapters provide useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials. * serves as a source of electrochemical information * includes useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials * reviews electrochemical techniques (incl. scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry)

Electrochemical Methods for Neuroscience

Author : Adrian C. Michael
Publisher : CRC Press
ISBN 13 : 1420005863
Total Pages : 540 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Electrochemical Methods for Neuroscience by : Adrian C. Michael

Download or read book Electrochemical Methods for Neuroscience written by Adrian C. Michael and published by CRC Press. This book was released on 2006-12-13 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the first implant of a carbon microelectrode in a rat 35 years ago, there have been substantial advances in the sensitivity, selectivity and temporal resolution of electrochemical techniques. Today, these methods provide neurochemical information that is not accessible by other means. The growing recognition of the versatility of electrochemi

Kinetics of Multistep Reactions

Author : Friedrich G. Helfferich
Publisher : Elsevier
ISBN 13 : 0080473180
Total Pages : 508 pages
Book Rating : 4.0/5 (84 download)

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Book Synopsis Kinetics of Multistep Reactions by : Friedrich G. Helfferich

Download or read book Kinetics of Multistep Reactions written by Friedrich G. Helfferich and published by Elsevier. This book was released on 2004-09-15 with total page 508 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book addresses primarily the engineer in industrial process development, the research chemist in academia and industry, and the graduate student intending to become a reaction engineer. In industry, competitive pressures put a premium on scale-up by large factors to cut development time. To be safe, such development should be based on "fundamental" kinetics that reflect the elementary steps of which the reaction consists. The book forges fundamental kinetics into a practical tool by presenting new, effective methods for elucidation of mechanisms and reduction of complexity without unacceptable sacrifice in accuracy: fewer equations (lesser computational load), fewer coefficients (fewer experiment to determine them). For network elucidation, new rules relating network configurations to observable kinetic behaviour allow incorrect networks to be ruled out by whole classes instead of one by one. For modelling, general equations and algorithms are given from which equations for specific networks can be recovered by simple substitutions. The procedures are illustrated with examples of industrial reactions including, among others, paraffin oxidation, ethoxylation, hydroformylation, hydrocyanation, shape-selective catalysis, ethane pyrolysis, styrene polymerization, and ethene oligomerization. Many of the rate equations have not been published before. The expanded edition of the 2001 title, Kinetics of Homogeneous Multistep Reactions includes new chapters on heterogeneous catalysis and periodic and chaotic re-actions; new sections on adsorption, statistical methods, and lumping; and other new detail. Contains new chapters on heterogeneous catalysis, oscillations and chaos Includes new sections on statistical methods, lumping adsorption and software and databases Provides a better understanding of complex reaction mechanisms

Oxoacidity: Reactions of Oxo-compounds in Ionic Solvents

Author : Victor L. Cherginets
Publisher : Elsevier
ISBN 13 : 0080455247
Total Pages : 401 pages
Book Rating : 4.0/5 (84 download)

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Book Synopsis Oxoacidity: Reactions of Oxo-compounds in Ionic Solvents by : Victor L. Cherginets

Download or read book Oxoacidity: Reactions of Oxo-compounds in Ionic Solvents written by Victor L. Cherginets and published by Elsevier. This book was released on 2005-02-15 with total page 401 pages. Available in PDF, EPUB and Kindle. Book excerpt: The generally accepted definitions of acids and bases together with the generalized definition for the solvent system introduced by the author for the description of both molecular and ionic solvents are discussed. The oxobasicity index introduced as a measure of relative oxoacidic properties of ionic melts (pIL) and methods of its determination are presented. Moreover, the oxoacidity scales of ionic melts based on alkali metal halides at different temperatures are constructed. The sequential addition method (SAM), proposed by the author to investigate the effect of oxide particle size on oxide solubilities is presented. This book is meant for specialists developing theoretical and applied aspects of molten salt chemistry, acid-base theories and solubility phenomena. It will also be useful for those chemists who wish to extend their knowledge of physical and solution chemistry. First book devoted to oxoacids and oxobases Aimed at specialists developing theoretical and applied aspects of molten salt chemistry, acid-base theories and solubility phenomena The perfect handbook for beginners looking for preliminary knowledge about methods of investigation

Modeling of Chemical Reactions

Author : R.W. Carr
Publisher : Elsevier
ISBN 13 : 008054617X
Total Pages : 317 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Modeling of Chemical Reactions by : R.W. Carr

Download or read book Modeling of Chemical Reactions written by R.W. Carr and published by Elsevier. This book was released on 2007-09-04 with total page 317 pages. Available in PDF, EPUB and Kindle. Book excerpt: Modeling of Chemical Reactions covers detailed chemical kinetics models for chemical reactions. Including a comprehensive treatment of pressure dependent reactions, which are frequently not incorporated into detailed chemical kinetic models, and the use of modern computational quantum chemistry, which has recently become an extraordinarily useful component of the reaction kinetics toolkit. It is intended both for those who need to model complex chemical reaction processes but have little background in the area, and those who are already have experience and would benefit from having a wide range of useful material gathered in one volume. The range of subject matter is wider than that found in many previous treatments of this subject. The technical level of the material is also quite wide, so that non-experts can gain a grasp of fundamentals, and experts also can find the book useful. A solid introduction to kinetics Material on computational quantum chemistry, an important new area for kinetics Contains a chapter on construction of mechanisms, an approach only found in this book

Analytical Electrochemistry

Author : Joseph Wang
Publisher : John Wiley & Sons
ISBN 13 : 0471460796
Total Pages : 228 pages
Book Rating : 4.4/5 (714 download)

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Book Synopsis Analytical Electrochemistry by : Joseph Wang

Download or read book Analytical Electrochemistry written by Joseph Wang and published by John Wiley & Sons. This book was released on 2004-03-24 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt: The critically acclaimed guide to the principles, techniques, and instruments of electroanalytical chemistry-now expanded and revised Joseph Wang, internationally renowned authority on electroanalytical techniques, thoroughly revises his acclaimed book to reflect the rapid growth the field has experienced in recent years. He substantially expands the theoretical discussion while providing comprehensive coverage of the latest advances through late 1999, introducing such exciting new topics as self-assembled monolayers, DNA biosensors, lab-on-a-chip, detection for capillary electrophoresis, single molecule detection, and sol-gel surface modification. Along with numerous references from the current literature and new worked-out examples, Analytical Electrochemistry, Second Edition offers clear, reader-friendly explanations of the fundamental principles of electrochemical processes as well as important insight into the potential of electroanalysis for problem solving in a wide range of fields, from clinical diagnostics to environmental science. Key topics include: The basics of electrode reactions and the structure of the interfacial region Tools for elucidating electrode reactions and high-resolution surface characterization An overview of finite-current controlled potential techniques Electrochemical instrumentation and electrode materials Principles of potentiometric measurements and ion-selective electrodes Chemical sensors, including biosensors, gas sensors, solid-state devices, and sensor arrays

Comprehensive Chemical Kinetics

Author : Nicholas Green
Publisher : Elsevier
ISBN 13 : 0080543448
Total Pages : 263 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Comprehensive Chemical Kinetics by : Nicholas Green

Download or read book Comprehensive Chemical Kinetics written by Nicholas Green and published by Elsevier. This book was released on 2003-11-21 with total page 263 pages. Available in PDF, EPUB and Kindle. Book excerpt: Unimolecular reactions are in principle the simplest chemical reactions, because they only involve one molecule. The basic mechanism, in which the competition between the chemical reaction step and a collisional deactivation leads to a pressure-dependent coefficient, has been understood for a long time. However, this is a rapidly developing field, and many new and important discoveries have been made in the past decade.This First Part Part of Two CCK Volumes dealing with Unimolecular Rections, deals with the Reaction Step. The first chapter is an introduction to the whole project, aiming to cover the material necessary to understand the content of the detailed chapters, as well as the history of the development of the area. Chapter 2 is a review of the modern view of the statistical theories, as embodied in the various forms of RRKM theory. Chapter 3 deals with the fully quantum mechanical view of reactive states as resonances. . Presents considerable advances in the field made during the last decade.. Treats both the statistical as well as the fully quantum mechanical view.

The Chemistry of Electrode Processes

Author : Ilana Fried
Publisher : Elsevier
ISBN 13 : 0323159524
Total Pages : 236 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis The Chemistry of Electrode Processes by : Ilana Fried

Download or read book The Chemistry of Electrode Processes written by Ilana Fried and published by Elsevier. This book was released on 2012-12-02 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Electrode Processes discusses "electrodics" or the science dealing with the transfer of an electric charge between a solid and liquid phase. This book reviews the applications of electrodics, the history of electrochemistry, and the basic definitions and concepts of the galvanic cell. This text also deals with the rate expressions associated with the different types of electrode reaction mechanism including the passing of Faradaic current, the current-voltage curve, mass transport overpotential, and the influence of surface structure on electrode processes. This book describes the electrode-solution interphase at equilibrium, the properties of such interphase, and the ways it can influence electrode kinetics. Any electrode reaction involves several steps and can be influenced by diffusion, adsorption and other parameters. The techniques to study electrode reactions and the electrode-solution interphase consists of equilibrium measurements, steady state measurement, and transient measurement. This text also describes the significant and potential uses of electrodics in technology which need less expensive equipment compared to using spectrophotometric techniques. This book is suitable chemists, for advanced students in analytical chemistry, physics, thermodynamics, and related subjects.

Electrode Kinetics: Principles and Methodology

Author : C.H. Bamford
Publisher : Elsevier
ISBN 13 : 9780080868202
Total Pages : 449 pages
Book Rating : 4.8/5 (682 download)

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Book Synopsis Electrode Kinetics: Principles and Methodology by : C.H. Bamford

Download or read book Electrode Kinetics: Principles and Methodology written by C.H. Bamford and published by Elsevier. This book was released on 1986-08-01 with total page 449 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volumes 26 and 27 are both concerned with reactions occurring at electrodes arising through the passage of current. They provide a comprehensive review of the study of electrode kinetics. The basic ideas and experimental methodology are presented in Volume 26 whilst Volume 27 deals with reactions at particular types of electrodes. Chapter 1 serves as an introduction to both volumes and is a survey of the fundamental principles of electrode kinetics. Chapter 2 deals with mass transport - how material gets to and from an electrode. Chapter 3 provides a review of linear sweep and cyclic voltammetry which constitutes an extensively used experimental technique in the field. Chapter 4 discusses a.c. and pulse methods which are a rich source of electrochemical information. Finally, chapter 5 discusses the use of electrodes in which there is forced convection, the so-called ``hydrodynamic electrodes''.

Laboratory Techniques in Electroanalytical Chemistry, Revised and Expanded

Author : Peter Kissinger
Publisher : CRC Press
ISBN 13 : 1351990713
Total Pages : 825 pages
Book Rating : 4.3/5 (519 download)

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Book Synopsis Laboratory Techniques in Electroanalytical Chemistry, Revised and Expanded by : Peter Kissinger

Download or read book Laboratory Techniques in Electroanalytical Chemistry, Revised and Expanded written by Peter Kissinger and published by CRC Press. This book was released on 2018-10-03 with total page 825 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume provides a practical, intuitive approach to electroanalytical chemistry, presenting fundamental concepts and experimental techniques without the use of technical jargon or unnecessarily extensive mathematics. This edition offers new material on ways of preparing and using microelectrodes, the processes that govern the voltammetric behavior of microelectrodes, methods for characterizing chemically modified electrodes, electrochemical studies at reduced temperatures, and more. The authors cover such topics as analog instrumentation, overcoming solution resistance with stability and grace in potentiostatic circuits, conductivity and conductometry, electrochemical cells, carbon electrodes, film electrodes, microelectrodes, chemically modified electrodes, mercury electrodes, and solvents and supporting electrolytes.

Techniques for Characterization of Electrodes and Electrochemical Processes

Author : Ravi Varma
Publisher : Wiley-Interscience
ISBN 13 : 9780471824992
Total Pages : 800 pages
Book Rating : 4.8/5 (249 download)

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Book Synopsis Techniques for Characterization of Electrodes and Electrochemical Processes by : Ravi Varma

Download or read book Techniques for Characterization of Electrodes and Electrochemical Processes written by Ravi Varma and published by Wiley-Interscience. This book was released on 1991-06-07 with total page 800 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by leading authorities in their respective fields, it presents review articles on in situ or quasi-in situ techniques for the characterization of electrodes and electrochemical processes--appropriate for surface or bulk phase analysis. Divided into two sections covering in situ monitoring and characterization of structure and compositions of electrodes, electrolytes and products during electrolysis in Part A, and electrochemical techniques and theoretical-modeling tools in Part B.

Microreaction Technology

Author : M. Matlosz
Publisher : Springer Science & Business Media
ISBN 13 : 3642567630
Total Pages : 584 pages
Book Rating : 4.6/5 (425 download)

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Book Synopsis Microreaction Technology by : M. Matlosz

Download or read book Microreaction Technology written by M. Matlosz and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 584 pages. Available in PDF, EPUB and Kindle. Book excerpt: IMRET 5 featured more than 80 oral and poster communications, covering the entire interdisciplinary field from design, production, modeling and characterization of microreactor devices to application of microstructured systems for production, energy and transportation, including many analytical and biological applications. A particularly strong topic was the investigation of the potential of microstructuring of reactors and systems components for process intensification. Perspectives of combining local, in situ, data acquisition with appropriate microstructuring of actuators and components within chemical and biological devices were explored in order to enhance process performance and facilitate process control.

Transient Techniques in Electrochemistry

Author : Digby Macdonald
Publisher : Springer Science & Business Media
ISBN 13 : 1461341450
Total Pages : 336 pages
Book Rating : 4.4/5 (613 download)

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Book Synopsis Transient Techniques in Electrochemistry by : Digby Macdonald

Download or read book Transient Techniques in Electrochemistry written by Digby Macdonald and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: The study of electrochemical reactions by relaxation or transient techniques has expanded rapidly over the last two decades. The impetus for the develop ment of these techniques has been the desire to obtain quantitative data on the rates of "fast" electrochemical processes, including those coupled to homogeneous chemical reactions in solution. This has necessarily meant the development of techniques that are capable of delineating the effects of mass transport and charge transfer at very short times. The purpose of this book is to describe how the various transient techniques may be used to obtain the desired information. Emphasis is placed upon the detailed mathematical development of the subject, since this aspect is the most frequently ignored in other texts in this field. In any relaxation or transient technique for the study of rate processes, it is necessary to disturb the reaction from equilibrium or the steady state by applying a perturbing impulse to the system. The system is then allowed to relax to a new equilibrium or steady-state position, and. the transient (i. e. , the response as a function of time) is analyzed to extract the desired kinetic information. In electrochemical studies the heterogeneous rate constants are, in general, dependent upon the potential difference across the interface, so that the perturbing impulse frequently takes the form of a known variation in potential as a function of time.

Laboratory Techniques in Electroanalytical Chemistry, Second Edition, Revised and Expanded

Author : Peter Kissinger
Publisher : CRC Press
ISBN 13 : 9780824794453
Total Pages : 1014 pages
Book Rating : 4.7/5 (944 download)

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Book Synopsis Laboratory Techniques in Electroanalytical Chemistry, Second Edition, Revised and Expanded by : Peter Kissinger

Download or read book Laboratory Techniques in Electroanalytical Chemistry, Second Edition, Revised and Expanded written by Peter Kissinger and published by CRC Press. This book was released on 1996-01-23 with total page 1014 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume provides a practical, intuitive approach to electroanalytical chemistry, presenting fundamental concepts and experimental techniques without the use of technical jargon or unnecessarily extensive mathematics. This edition offers new material on ways of preparing and using microelectrodes, the processes that govern the voltammetric behavior of microelectrodes, methods for characterizing chemically modified electrodes, electrochemical studies at reduced temperatures, and more. The authors cover such topics as analog instrumentation, overcoming solution resistance with stability and grace in potentiostatic circuits, conductivity and conductometry, electrochemical cells, carbon electrodes, film electrodes, microelectrodes, chemically modified electrodes, mercury electrodes, and solvents and supporting electrolytes.

Rotating Electrode Methods and Oxygen Reduction Electrocatalysts

Author : Wei Xing
Publisher : Elsevier
ISBN 13 : 0444633286
Total Pages : 322 pages
Book Rating : 4.4/5 (446 download)

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Book Synopsis Rotating Electrode Methods and Oxygen Reduction Electrocatalysts by : Wei Xing

Download or read book Rotating Electrode Methods and Oxygen Reduction Electrocatalysts written by Wei Xing and published by Elsevier. This book was released on 2014-03-26 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides the latest information and methodologies of rotating disk electrode and rotating ring-disk electrode (RDE/RRDE) and oxygen reduction reaction (ORR). It is an ideal reference for undergraduate and graduate students, scientists, and engineers who work in the areas of energy, electrochemistry science and technology, fuel cells, and other electrochemical systems. Presents a comprehensive description, from fundamentals to applications, of catalyzed oxygen reduction reaction and its mechanisms Portrays a complete description of the RDE (Rotating Disc Electrode)/RRDE (Rotating Ring-Disc Electrode) techniques and their use in evaluating ORR (Oxygen Reduction Reaction) catalysts Provides working examples along with figures, tables, photos and a comprehensive list of references to help understanding of the principles involved