New Synthetic Methods For Carborane Functionalization

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Functionalization of Carborane via Carboryne Intermediates

Author : Da Zhao
Publisher : Springer
ISBN 13 : 9811015694
Total Pages : 180 pages
Book Rating : 4.8/5 (11 download)

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Book Synopsis Functionalization of Carborane via Carboryne Intermediates by : Da Zhao

Download or read book Functionalization of Carborane via Carboryne Intermediates written by Da Zhao and published by Springer. This book was released on 2016-06-04 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis focuses on the development of new methods of functionalizing carboranes using o-carboryne intermediates. Functional carboranes are now finding a broad range of applications, including organic synthesis, drug design, polymers, catalysis, metal−organic frameworks, electronic devices and more. However, the limited number of efficient synthetic methods for obtaining functional carborane materials has restricted their applications. The methodologies established in this thesis represent simple, yet powerful strategies to assemble previously inaccessible, useful complex molecules, which will also have a significant impact on future synthetic, cluster and materials chemistry. Moreover, it discusses the first method for the in situ generation of electrophilic boron radical using photocatalysis.

New Synthetic Methods for Carborane Functionalization

Author : Daniel Eugene Kadlecek
Publisher :
ISBN 13 :
Total Pages : 516 pages
Book Rating : 4.:/5 (244 download)

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Book Synopsis New Synthetic Methods for Carborane Functionalization by : Daniel Eugene Kadlecek

Download or read book New Synthetic Methods for Carborane Functionalization written by Daniel Eugene Kadlecek and published by . This book was released on 2001 with total page 516 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Boron Science

Author : Narayan S. Hosmane
Publisher : CRC Press
ISBN 13 : 1439826633
Total Pages : 856 pages
Book Rating : 4.4/5 (398 download)

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Book Synopsis Boron Science by : Narayan S. Hosmane

Download or read book Boron Science written by Narayan S. Hosmane and published by CRC Press. This book was released on 2016-04-19 with total page 856 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boron has made a significant impact in our lives through its quiet use in fertilizers, fungicides, soaps, detergents, and heat-resistant glassware. Boron Science: New Technologies and Applications addresses the applications of boron in chemistry, industry, medicine, and pharmacology by explaining its role in problems such as catalysis and hydrobora

Advances in the Synthesis and Catalytic Applications of Boron Cluster

Author :
Publisher : Elsevier
ISBN 13 : 0323988326
Total Pages : 340 pages
Book Rating : 4.3/5 (239 download)

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Book Synopsis Advances in the Synthesis and Catalytic Applications of Boron Cluster by :

Download or read book Advances in the Synthesis and Catalytic Applications of Boron Cluster written by and published by Elsevier. This book was released on 2022-09-25 with total page 340 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Catalysis, Volume 71 highlights new advances in the field, with this new volume presenting interesting chapters on a variety of topics, including Advances in the catalytic and photocatalytic behavior of carborane derived metal complexes, Transition metal catalyzed synthesis of derivatives of polyhedral boron hydrides with B-N, B-P, B-O and B-S bonds, Recent advances in transition metal catalyzed selective cage BH functionalization of o-carboranes, Boron Compounds for Catalytic Applications, Regioselective Carborane B-H/C-H Functionalization, and Derivatization of monocarborane and dodecaborate anions by controlled B–H activation. - Provides the authority and expertise of leading contributors from an international board of authors - Presents the latest release in Advances in Catalysis serials - Updated release includes the latest information on advances in the synthesis and catalytic applications of boron cluster

Carboranes

Author : Russell N. Grimes
Publisher : Academic Press
ISBN 13 : 0128019050
Total Pages : 1060 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Carboranes by : Russell N. Grimes

Download or read book Carboranes written by Russell N. Grimes and published by Academic Press. This book was released on 2016-08-09 with total page 1060 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carboranes, Third Edition, by Russell Grimes, is the definitive resource on the subject. Completely updated with a wealth of research and review articles published in this active field since the previous volume was released in 2011, the book provides a readable and concise introduction to the basic principles underlying the synthesis, structures, and reactions of carboranes, heterocarboranes, and metallacarboranes. Following the valuable foundational information, the book explores the advances in practical applications for the many areas in which experts have discovered that carboranes afford new possibilities for solving problems and advancing the science. These disciplines include polymer science, catalysis, biomedicine, nanomaterials, and others. - Winner of a 2017 Textbook Excellence Award (Texty) from the Textbook and Academic Authors Association - Includes over 2,000 molecular structure drawings throughout the text - Features expanded coverage on applications of carboranes, particularly in biomedicine and nanomaterials, given the growth of research in these areas - Presents extended and updated tables, listing thousands of compounds with key literature references, provided online via the book's website - Explores the advances in practical applications for the many areas in which experts have discovered that carboranes afford new possibilities for solving problems and advancing the science

Carboranes

Author : Russell N. Grimes
Publisher : Academic Press
ISBN 13 : 012374170X
Total Pages : 1159 pages
Book Rating : 4.1/5 (237 download)

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Book Synopsis Carboranes by : Russell N. Grimes

Download or read book Carboranes written by Russell N. Grimes and published by Academic Press. This book was released on 2011-03-10 with total page 1159 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carboranes, Second Edition is designed as a comprehensive source of information in a field that has experienced enormous growth in both its fundamental and applied aspects in the four decades since the publication of Carboranes (1970). During this long period thousands of original research papers have appeared, along with many review articles and book chapters dealing with aspects of carborane chemistry. As carborane science has grown in complexity, and applications have advanced steadily in areas such as medicine, nanostructured and electroactive materials, catalysis, polymers, and others, the need for a monograph covering the entire area in a unified treatment has become increasingly apparent. This volume has two principal objectives, the first of which is to provide a readable and concise introduction to the basic principles underlying the synthesis, structures, reactivity, and applications of carboranes and metallacarboranes at a level suitable for readers in industry and academe who are not trained in boron chemistry but find themselves working with, or lecturing about carboranes. Secondly, the book furnishes a trove of detailed information for workers active in carborane science and associated technologies. To that end, it incorporates tables listing thousands of specific compounds keyed to literature references, together with more than 2,000 molecular structure drawings that illuminate the accompanying discussion. Thorough treatment of the synthesis, structures, and reactions of carboranes, heterocarboranes, and metallacarboranes in the first 13 chapters is followed by four chapters detailing advances in practical applications in polymer science, catalysis, medicine, and other areas. Includes over 2,000 molecular structure drawings throughout the text Features tables listing thousands of compounds with key literature references

At the Interface of Main Group and Organometallic Chemistry

Author : Ariane Perez-Gavilan
Publisher :
ISBN 13 :
Total Pages : 296 pages
Book Rating : 4.:/5 (799 download)

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Book Synopsis At the Interface of Main Group and Organometallic Chemistry by : Ariane Perez-Gavilan

Download or read book At the Interface of Main Group and Organometallic Chemistry written by Ariane Perez-Gavilan and published by . This book was released on 2012 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthetic Inorganic Chemistry

Author : Ewan J. M. Hamilton
Publisher : Elsevier
ISBN 13 : 0128189339
Total Pages : 525 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Synthetic Inorganic Chemistry by : Ewan J. M. Hamilton

Download or read book Synthetic Inorganic Chemistry written by Ewan J. M. Hamilton and published by Elsevier. This book was released on 2021-04-17 with total page 525 pages. Available in PDF, EPUB and Kindle. Book excerpt: Synthetic Inorganic Chemistry: New Perspectives presents summaries of the work of some of the most creative researchers in the field. The book highlights the most novel approaches and burgeoning applications of synthetic inorganic chemistry in development. Topics include non-precious metals in catalysis, smart inorganic polymers, new inorganic therapeutics, new photocatalysts for hydrogen production, and more. As the first volume in the Developments in Inorganic Chemistry series, this work is a valuable resource for students and researchers working in inorganic chemistry and material science. - Illustrates the scope and vitality of modern synthetic inorganic chemistry - Shows the centrality of inorganic chemistry, addressing a variety of global challenges - Serves to define the current, important and expanding roles of synthetic inorganic chemistry in interdisciplinary areas such as materials science, synthetic organic chemistry, homogeneous and heterogeneous catalysis

Boron-Based Compounds

Author : Evamarie Hey-Hawkins
Publisher : John Wiley & Sons
ISBN 13 : 1119275555
Total Pages : 490 pages
Book Rating : 4.1/5 (192 download)

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Book Synopsis Boron-Based Compounds by : Evamarie Hey-Hawkins

Download or read book Boron-Based Compounds written by Evamarie Hey-Hawkins and published by John Wiley & Sons. This book was released on 2018-07-23 with total page 490 pages. Available in PDF, EPUB and Kindle. Book excerpt: Noted experts review the current status of boron-containing drugs and materials for molecular medical diagnostics Boron-Based Compounds offers a summary of the present status and promotes the further development of new boron-containing drugs and advanced materials, mostly boron clusters, for molecular medical diagnostics. The knowledge accumulated during the past decades on the chemistry and biology of bioorganic and organometallic boron compounds laid the foundation for the emergence of a new area of study and application of boron compounds as lipophilic pharmacophores and modulators of biologically active molecules.This important text brings together in one comprehensive volume contributions from renowned experts in the field of medicinal chemistry of boron compounds. The authors cover a range of the most relevant topics including boron compounds as modulators of the bioactivity of biomolecules, boron clusters as pharmacophores or for drug delivery, boron compounds for boron neutron capture therapy (BNCT) and for diagnostics, as well as in silico molecular modeling of boron- and carborane-containing compounds in drug design. Authoritative and accessible, Boron-Based Compounds: Contains contributions from a panel of internationally renowned experts in the field Offers a concise summary of the current status of boron-containing drugs and materials used for molecular diagnostics Highlights the range and capacity of boron-based compounds in medical applications Includes information on boron neutron capture therapy and diagnostics Designed for academic and industrial scientists, this important resource offers the cutting-edge information needed to understand the current state of boron-containing drugs and materials for molecular medical diagnostics.

Metal-catalyzed Cross-coupling Reactions

Author : François Diederich
Publisher : John Wiley & Sons
ISBN 13 : 3527612203
Total Pages : 540 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Metal-catalyzed Cross-coupling Reactions by : François Diederich

Download or read book Metal-catalyzed Cross-coupling Reactions written by François Diederich and published by John Wiley & Sons. This book was released on 2008-07-11 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon-carbon bond forming reactions are arguably the most important processes in chemistry, as they represent key steps in the building of complex molecules from simple precursors. Among these reactions, metal-catalyzed cross-coupling reactions are extensively employed in a wide range of areas of preparative organic chemistry, ranging from the synthesis of complex natural products, to supramolecular chemistry, and materials science. In this work, a dozen internationally renowned experts and leaders in the field bring the reader up to date by documenting and critically analyzing current developments and uses of metal-catalyzed cross-coupling reactions. A particularly attractive and useful feature, that enhances the practical value of this monograph, is the inclusion of key synthetic protocols, in experimental format, chosen for broad utility and application. This practice-oriented book can offer the practitioner short cuts to ensure they remain up-to-date with the latest developments.

Vertex-Selective Functionalization of Icosahedral Boron Clusters

Author : Rafal Miroslaw Dziedzic
Publisher :
ISBN 13 :
Total Pages : 69 pages
Book Rating : 4.:/5 (113 download)

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Book Synopsis Vertex-Selective Functionalization of Icosahedral Boron Clusters by : Rafal Miroslaw Dziedzic

Download or read book Vertex-Selective Functionalization of Icosahedral Boron Clusters written by Rafal Miroslaw Dziedzic and published by . This book was released on 2019 with total page 69 pages. Available in PDF, EPUB and Kindle. Book excerpt: Icosahedral boron clusters (e. g. C2B10H12, [CB11H12]1-, [B12H12]2-) are aromatic molecules that can serve as 3-dimensional scaffolds in molecular materials. Vertex-selective functionalization of boron cluster B H bonds allows tuning of the electronic properties and spatial arrangement of boron cluster-bound moieties. Vertex-selective functionalization of icosahedral boron clusters is desirable for making complex molecules based on boron cluster scaffolds. Thus new functionalization methods for boron clusters are needed which can append a variety of functional groups with atomic precision. Vertex-specific functionalization of polyhedral boranes is possible by leveraging the anisotropic electron density and inductive effects of the icosahedral boron clusters to control the site of functionalization. By adapting existing palladium-catalyzed cross-coupling chemistry to polyhedral boranes we are able to form B O, B N, and B C bonds with amines, heterocycles, alkoxides, boronic acids, and small nucleophiles (e.g. F, OH, NH2, and CN). Our discovery of Pd-catalyzed isomerization ("cage-walking") of bromo-meta-carborane (9-Br-m-C2B10H11) into four Br-m-C2B10H11 regioisomers enables synthesis of several regioisomer products from a single starting material. Incorporation of the cage-walking process into Pd-catalyzed cross-coupling allows synthesis of all four boron-vertex (B(9), B(5), B(4), and B(2)) functionalized meta-carborane regioisomers from 9-Br-m-C2B10H11. Additionally, vertex-selective functionalization enables tuning of physical properties, such as melting point and electrochemical behavior, that expand the utility of polyhedral boranes to new application. We are interested in tuning the chemical stability and weak coordination properties of polyhedral borane anions for ionic liquid electrolytes and flow-battery applications.

Synthesis and Applications of Nanocarbons

Author : Jean-Charles Arnault
Publisher : John Wiley & Sons
ISBN 13 : 1119429382
Total Pages : 320 pages
Book Rating : 4.1/5 (194 download)

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Book Synopsis Synthesis and Applications of Nanocarbons by : Jean-Charles Arnault

Download or read book Synthesis and Applications of Nanocarbons written by Jean-Charles Arnault and published by John Wiley & Sons. This book was released on 2020-09-21 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: A crucial overview of the cutting-edge in nanocarbon research and applications In Synthesis and Applications of Nanocarbons, the distinguished authors have set out to discuss fundamental topics, synthetic approaches, materials challenges, and various applications of this rapidly developing technology. Nanocarbons have recently emerged as a promising material for chemical, energy, environmental, and medical applications because of their unique chemical properties and their rich surface chemistries. This book is the latest entry in the Wiley book series Nanocarbon Chemistry and Interfaces and seeks to comprehensively address many of the newly surfacing areas of controversy and development in the field. This book introduces foundational concepts in nanocarbon technology, hybrids, and applications, while also covering the most recent and cutting-edge developments in this area of study. Synthesis and Applications of Nanocarbons addresses new discoveries in the field, including: · Nanodiamonds · Onion-like carbons · Carbon nanotubes · Fullerenes · Carbon dots · Carbon fibers · Graphene · Aerographite This book provides a transversal view of the various nanocarbon materials and hybrids and helps to share knowledge between the communities of each material and hybrid type.

Advances in Organometallic Chemistry and Catalysis

Author : Armando J. L. Pombeiro
Publisher : John Wiley & Sons
ISBN 13 : 1118742893
Total Pages : 848 pages
Book Rating : 4.1/5 (187 download)

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Book Synopsis Advances in Organometallic Chemistry and Catalysis by : Armando J. L. Pombeiro

Download or read book Advances in Organometallic Chemistry and Catalysis written by Armando J. L. Pombeiro and published by John Wiley & Sons. This book was released on 2013-10-11 with total page 848 pages. Available in PDF, EPUB and Kindle. Book excerpt: A contemporary compilation of recent achievements in organometallic chemistry The prestigious International Conference on Organometallic Chemistry (ICOMC) was launched in 1963, providing a forum for researchers from around the world to share their findings and explore new paths to advance our knowledge and application of organometallic chemistry. The 25th ICOMC, held in Lisbon in 2012, gathered more than 1,200 participants from 54 countries. This volume celebrates the 25th Silver Edition and the 50th Gold Year of the ICOMC. Featuring contributions from invited 25th ICOMC speakers, Advances in Organometallic Chemistry and Catalysis highlights recent achievements and new and emerging areas of research in the field. Its seven sections cover: Activation and Functionalization of Carbon Single Bonds and Small Molecules Organometallic Synthesis and Catalysis Organometallic Polymerization Catalysis Organometallic Polymers and Materials Organometallic Chemistry and Sustainable Energy Bioorganometallic Chemistry Organometallic Electrochemistry Chapters discuss fundamental underlying concepts, offer illustrative examples and cases, and explore future avenues for continued research. Readers will discover basic principles and properties of organometallic compounds, reaction mechanisms, and detailed descriptions of current applications. Collectively, these chapters underscore the versatility, richness, and potential of modern organometallic chemistry, including its interrelationships with other scientific disciplines. All the contributions are extensively referenced, providing a gateway to the most important original research papers and reviews in organometallic chemistry. Presenting a contemporary understanding of organometallic chemistry and its many applications, Advances in Organometallic Chemistry and Catalysis is recommended for all researchers in the field, from students to advanced investigators.

Handbook Of Boron Science: With Applications In Organometallics, Catalysis, Materials And Medicine (In 4 Volumes)

Author : Narayan S Hosmane
Publisher : World Scientific
ISBN 13 : 1786344432
Total Pages : 1051 pages
Book Rating : 4.7/5 (863 download)

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Book Synopsis Handbook Of Boron Science: With Applications In Organometallics, Catalysis, Materials And Medicine (In 4 Volumes) by : Narayan S Hosmane

Download or read book Handbook Of Boron Science: With Applications In Organometallics, Catalysis, Materials And Medicine (In 4 Volumes) written by Narayan S Hosmane and published by World Scientific. This book was released on 2018-08-07 with total page 1051 pages. Available in PDF, EPUB and Kindle. Book excerpt: Boron science features in numerous fields including organic chemistry, organometallic chemistry and medicine. Boron is unique in all aspects of science and engineering and has made a significant impact in our daily lives through its use in fertilizers, germicides, fungicides, soaps, detergents, cancer drugs as well as many household glassware utensils, ceramics and cell phone windows. These volumes bring together an array of internationally renowned scientists to discuss the very latest developments in the application of boron in a broad range of disciplines. This multi-reference work describes the topic by appointing leading researchers to write on current developments in boron science, showcasing its importance to the four separate areas described in each volume: Organometallic Chemistry, Catalysis, Materials Chemistry and Medicine.Written to cover the full range of applications and innovations in boron science, this all-encompassing work offers us a one-stop reference compiled by world-leading researchers and practitioners of the subject, making it perfect for undergraduate and graduate students of chemistry, and researchers and practitioners interested in their professional development.

Dissertation Abstracts International

Author :
Publisher :
ISBN 13 :
Total Pages : 906 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Dissertation Abstracts International by :

Download or read book Dissertation Abstracts International written by and published by . This book was released on 2008 with total page 906 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Metal Catalyzed Cross-Coupling Reactions and More

Author : Armin de Meijere
Publisher : John Wiley & Sons
ISBN 13 : 3527655603
Total Pages : 1640 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Metal Catalyzed Cross-Coupling Reactions and More by : Armin de Meijere

Download or read book Metal Catalyzed Cross-Coupling Reactions and More written by Armin de Meijere and published by John Wiley & Sons. This book was released on 2013-12-04 with total page 1640 pages. Available in PDF, EPUB and Kindle. Book excerpt: This three volume book is the follow-up handbook to the bestselling volume "Metal-Catalyzed Cross-Coupling Reactions", the definitive reference in the field. In line with the enormous developments in this area, this is not a new edition, but rather a new book in three volumes with over 50% more content. This new content includes C-H activation, shifting the focus away from typical cross-coupling reactions, while those topics and chapters found in de Meijere/Diederich's book have been updated and expanded. With its highly experienced editor team and the list of authors reading like an international Who's-Who in the field, this work will be of great interest to every synthetic chemist working in academia and industry.

Essential Reagents for Organic Synthesis

Author : Philip L. Fuchs
Publisher : John Wiley & Sons
ISBN 13 : 1119278309
Total Pages : 636 pages
Book Rating : 4.1/5 (192 download)

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Book Synopsis Essential Reagents for Organic Synthesis by : Philip L. Fuchs

Download or read book Essential Reagents for Organic Synthesis written by Philip L. Fuchs and published by John Wiley & Sons. This book was released on 2016-09-06 with total page 636 pages. Available in PDF, EPUB and Kindle. Book excerpt: From Boron Trifluoride to Zinc, the 52 most widely used reagents in organic synthesis are described in this unique desktop reference for every organic chemist. The list of reagents contains classics such as N-Bromosuccinimide (NBS) and Trifluoromethanesulfonic Acid side by side with recently developed ones like Pinacolborane and Tetra-n-propylammonium Perruthenate (TPAP). For each reagent, a concise article provides a brief description of all important reactions for which the reagent is being used, including yields and reaction conditions, an overview of the physical properties of the reagent, its storage conditions, safe handling, laboratory synthesis and purification methods. Advantages and disadvantages of the reagent compared to alternative synthesis methods are also discussed. Reagents have been hand-picked from among the 5000 reagents contained in EROS, the Encyclopedia of Reagents for Organic Synthesis. Every organic chemist should be familiar with these key reagents that can make almost every reaction work.