New Aspects Of Zirconium Containing Organic Compounds

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New Aspects of Zirconium Containing Organic Compounds

Author : Ilan Marek
Publisher : Springer Science & Business Media
ISBN 13 : 9783540222217
Total Pages : 200 pages
Book Rating : 4.2/5 (222 download)

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Book Synopsis New Aspects of Zirconium Containing Organic Compounds by : Ilan Marek

Download or read book New Aspects of Zirconium Containing Organic Compounds written by Ilan Marek and published by Springer Science & Business Media. This book was released on 2005-02-18 with total page 200 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal carbene complexes have made their way from organometallic curiosities to valuable reagents and catalysts. They offer novel synthetic opportunities in carbon-carbon bond formation based on either carbene-centered reactions or on metal-templated processes which makes them indispensable in modern synthetic methodology. The most prominent metal carbenes are now either commercially available or easy to synthesize and handle with modern laboratory techniques. This volume organized in eight chapters written by the leading scientists in the field illustrates the theoretical background, non-classical nucleophilic and cycloaddition patterns, chromium-templated benzannulation and photo-induced reactions, rhodium-catalyzed carbene transfer as well as the principles and applications of olefin metathesis which has coined the progress in synthetic methodology over the past decade. Designed for researchers in academia and industry as well as graduate students it presents the state-of-the-art potential of carbene complexes in modern organic synthesis.

Organometallic Chemistry of Titanium, Zirconium, and Hafnium

Author : P.C. Wailes
Publisher : Elsevier
ISBN 13 : 0323156479
Total Pages : 313 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Organometallic Chemistry of Titanium, Zirconium, and Hafnium by : P.C. Wailes

Download or read book Organometallic Chemistry of Titanium, Zirconium, and Hafnium written by P.C. Wailes and published by Elsevier. This book was released on 2012-12-02 with total page 313 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic Chemistry of Titanium, Zirconium, and Hafnium covers the chemistry of organic complexes of titanium, zirconium, and hafnium having metal-to-carbon linkage. This book is organized into eight chapters that consider the significant developments in delineating the chemistry of these metal derivatives. This book starts with a description of the stability and bonding in cyclopentadienyl derivatives of the metals, based on the thermodynamic and spectroscopic evidence. The remaining chapters discuss the preparation and reactions of titanium-, zirconium-, and hafnium-bonded organic compounds. These chapters also look into the synthetic difficulties encountered from the reactions and preparation of these compounds. The stabilization and adduct formation of these metal complexes are also explored. Organic chemists and organic chemistry researchers and students will find this book invaluable.

The Chemistry of Zirconacycles and 2,6-Diazasemibullvalenes

Author : Shaoguang Zhang
Publisher : Springer
ISBN 13 : 3662450216
Total Pages : 182 pages
Book Rating : 4.6/5 (624 download)

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Book Synopsis The Chemistry of Zirconacycles and 2,6-Diazasemibullvalenes by : Shaoguang Zhang

Download or read book The Chemistry of Zirconacycles and 2,6-Diazasemibullvalenes written by Shaoguang Zhang and published by Springer. This book was released on 2014-11-05 with total page 182 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this thesis, the author introduces two strategies used to construct various types of N-heterocycles, based on the chemistry of zirconacycles and 2,6-diazasemibullvalenes. In the first part, the author presents the development of multi-component cyclization of a zirconacyclobutene-silacyclobutene fused compound, nitriles and unsaturated compounds. These reactions provide synthetically useful methodology for various N-heterocycles such as 3-acyl pyrrole, pyrrolo[3,2-d]pyridazine and dihydropyrroloazepine, which are all difficult to synthesize by other means. The isolation and characterization of the key three-fused-ring Zr/Si-containing intermediates are also described in detail. These results show that the zirconacyclobutene-silacyclobutene fused compound behaves as a “chemical transformer” upon treatment with various substrates via the “coordination-induced skeleton rearrangement” mechanism. In the second part, the author demonstrates the synthesis and isolation of a series of 2,6-diazasemibullvalenes (NSBVs) from the reaction of 1,4-dilithio-1,3-dienes and nitriles, highlighting the significant progress made for the first time in this work: (1) determination of X-ray crystal structure of a substituted 2,6-diazasemibullvalene; (2) measurement of the activation barrier of its rapid intramolecular aza-Cope rearrangement in solution; (3) exploration of several reaction types of NSBV with diverse ring-expansion products and “bowl-shape” or “cage-shape” N-containing polycyclic skeletons; (4) demonstration of the localized structure as the predominant form and the homoaromatic delocalized structure as a minor component in the equilibrium using theoretical analysis. Based on well-founded results, this work sheds new light on this controversial topic.

Chemical Thermodynamics of Zirconium

Author :
Publisher : Elsevier
ISBN 13 : 0080457533
Total Pages : 544 pages
Book Rating : 4.0/5 (84 download)

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Book Synopsis Chemical Thermodynamics of Zirconium by :

Download or read book Chemical Thermodynamics of Zirconium written by and published by Elsevier. This book was released on 2005-12-06 with total page 544 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume is part of the series on "Chemical Thermodynamics", published under the aegis of the OECD Nuclear Energy Agency. It contains a critical review of the literature on thermodynamic data for inorganic compounds of zirconium. A review team, composed of five internationally recognized experts, has critically reviewed all the scientific literature containing chemical thermodynamic information for the above mentioned systems. The results of this critical review carried out following the Guidelines of the OECD NEA Thermochemical Database Project have been documented in the present volume, which contains tables of selected values for formation and reaction thermodynamical properties and an extensive bibliography. * Critical review of all literature on chemical thermodynamics for compounds and complexes of Zr. * Tables of recommended Selected Values for thermochemical properties * Documented review procedure * Exhaustive bibliography * Intended to meet requirements of radioactive waste management community * Valuable reference source for the physical, analytical and environmental chemist.

Transition Metal Complexes of Neutral eta1-Carbon Ligands

Author : Remi Chauvin
Publisher : Springer
ISBN 13 : 364204722X
Total Pages : 260 pages
Book Rating : 4.6/5 (42 download)

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Book Synopsis Transition Metal Complexes of Neutral eta1-Carbon Ligands by : Remi Chauvin

Download or read book Transition Metal Complexes of Neutral eta1-Carbon Ligands written by Remi Chauvin and published by Springer. This book was released on 2009-12-18 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contents: Yves Canac and Remi Chauvin: Neutral eta1-carbon ligands: beyond carbon monoxide; Esteban P. Urriolabeitia: Ylide Ligands; Wolfgang Petz and Gernot Frenking: Carbodiphosphoranes and related ligands; Mareike C. Jahnke and F. Ekkehardt Hahn: Chemistry of N-Heterocyclic Carbene Ligands; Tsuyoshi Kato, Eddy Maerten, Antoine Baceiredo: Non-NHCs stable singlet carbene ligands; Victorio Cadierno, Sergio E. García-Garrido: All-Carbon-Substituted Allenylidene and Related Cumulenylidene Ligands; Victorio Cadierno, Sergio E. García-Garrido: Heteroatom-Conjugated Allenylidene and Related Cumulenylidene Ligands.

Nature's Building Blocks

Author : John Emsley
Publisher : Oxford University Press, USA
ISBN 13 : 9780198503408
Total Pages : 556 pages
Book Rating : 4.5/5 (34 download)

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Book Synopsis Nature's Building Blocks by : John Emsley

Download or read book Nature's Building Blocks written by John Emsley and published by Oxford University Press, USA. This book was released on 2003 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: A readable, informative, fascinating entry on each one of the 100-odd chemical elements, arranged alphabetically from actinium to zirconium. Each entry comprises an explanation of where the element's name comes from, followed by Body element (the role it plays in living things), Element ofhistory (how and when it was discovered), Economic element (what it is used for), Environmental element (where it occurs, how much), Chemical element (facts, figures and narrative), and Element of surprise (an amazing, little-known fact about it). A wonderful 'dipping into' source for the familyreference shelf and for students.

The Chemistry of Titanium, Zirconium and Hafnium

Author : R. J. H. Clark
Publisher : Elsevier
ISBN 13 : 1483159213
Total Pages : 150 pages
Book Rating : 4.4/5 (831 download)

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Book Synopsis The Chemistry of Titanium, Zirconium and Hafnium by : R. J. H. Clark

Download or read book The Chemistry of Titanium, Zirconium and Hafnium written by R. J. H. Clark and published by Elsevier. This book was released on 2013-10-22 with total page 150 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Titanium, Zirconium and Hafnium deals with the chemistry of titanium, zirconium, and hafnium and covers topics ranging from the occurrence and metallurgy of all three elements to their nuclear, physical, and chemical properties as well as analytical chemistry. The compounds of titanium, zirconium, and hafnium are also discussed. This volume is comprised of two chapters and opens with a historical overview and discovery of titanium, along with its occurrence and distribution, metallurgical aspects, and nuclear and physicochemical properties. The compounds of titanium are also considered, including alloys and complexes; hydrides and oxides; halides and oxyhalides; titanates and antimonides; and carbides and borides. The second chapter is devoted to zirconium and hafnium, their occurrence and metallurgy; and physical, chemical, and biological properties. Compounds of zirconium and hafnium are described, from alloys and hydrides to zirconates and hafnates; nitrides, phosphides, and arsenides; carbides, silicides, and germanides; molybdates, tungstates, halates, and perchlorates; alkoxides, mercaptides, and dithiocarbamates; and amides, alkylamides, triazenes, phthalocyanines, and bipyridyls. This book will be a valuable source of information for inorganic chemists.

Zirconium and Its Compounds

Author : Francis Preston Venable
Publisher :
ISBN 13 :
Total Pages : 184 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Zirconium and Its Compounds by : Francis Preston Venable

Download or read book Zirconium and Its Compounds written by Francis Preston Venable and published by . This book was released on 1922 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Organometallic Chemistry of Titanium, Zirconium, and Hafnium

Author : P. C. Wailes
Publisher :
ISBN 13 : 9780127303505
Total Pages : 302 pages
Book Rating : 4.3/5 (35 download)

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Book Synopsis Organometallic Chemistry of Titanium, Zirconium, and Hafnium by : P. C. Wailes

Download or read book Organometallic Chemistry of Titanium, Zirconium, and Hafnium written by P. C. Wailes and published by . This book was released on 1974-01-01 with total page 302 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic Chemistry of Titanium, Zirconium, and Hafnium...

Zirconium

Author : Greg Roza
Publisher : The Rosen Publishing Group, Inc
ISBN 13 : 1435857291
Total Pages : 50 pages
Book Rating : 4.4/5 (358 download)

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Book Synopsis Zirconium by : Greg Roza

Download or read book Zirconium written by Greg Roza and published by The Rosen Publishing Group, Inc. This book was released on 2009-01-15 with total page 50 pages. Available in PDF, EPUB and Kindle. Book excerpt: Pure zirconium (Zr) is a lustrous, grayish-white metal. It is highly malleable and ductile, and generally resists corrosion. Middle school readers learn about the discovery of zirconium, its place on the periodic table, atoms and subatomic particles, how zirconium is extracted and refined, how it is used in nuclear reactors The book explains the various zirconium compounds and alloys and their applications in ceramics, medical products, superconductors, and electronics, among others.

Zirconium and Hafnium

Author :
Publisher :
ISBN 13 :
Total Pages : 14 pages
Book Rating : 4.:/5 (3 download)

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Book Synopsis Zirconium and Hafnium by :

Download or read book Zirconium and Hafnium written by and published by . This book was released on 1993 with total page 14 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Chemistry of Organo-Zirconium and Hafnium Compounds

Author : D. J. Cardin
Publisher : Ellis Horwood Limited
ISBN 13 : 9780131263840
Total Pages : 814 pages
Book Rating : 4.2/5 (638 download)

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Book Synopsis Chemistry of Organo-Zirconium and Hafnium Compounds by : D. J. Cardin

Download or read book Chemistry of Organo-Zirconium and Hafnium Compounds written by D. J. Cardin and published by Ellis Horwood Limited. This book was released on 1986-04-01 with total page 814 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Elements of Chemistry: Organic chemistry

Author : William Allen Miller
Publisher :
ISBN 13 :
Total Pages : 1068 pages
Book Rating : 4.:/5 (6 download)

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Book Synopsis Elements of Chemistry: Organic chemistry by : William Allen Miller

Download or read book Elements of Chemistry: Organic chemistry written by William Allen Miller and published by . This book was released on 1878 with total page 1068 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Chemical Behavior of Zirconium

Author : Warren B. Blumenthal
Publisher :
ISBN 13 :
Total Pages : 416 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis The Chemical Behavior of Zirconium by : Warren B. Blumenthal

Download or read book The Chemical Behavior of Zirconium written by Warren B. Blumenthal and published by . This book was released on 1958 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Bibliography of Zirconium

Author : Eleanor Abshire
Publisher :
ISBN 13 :
Total Pages : 224 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Bibliography of Zirconium by : Eleanor Abshire

Download or read book Bibliography of Zirconium written by Eleanor Abshire and published by . This book was released on 1958 with total page 224 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Metallurgy of Zirconium

Author : Benjamin Lustman
Publisher :
ISBN 13 :
Total Pages : 806 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis The Metallurgy of Zirconium by : Benjamin Lustman

Download or read book The Metallurgy of Zirconium written by Benjamin Lustman and published by . This book was released on 1955 with total page 806 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Elements and Compounds

Author : Chris Oxlade
Publisher : Heinemann-Raintree Library
ISBN 13 : 9781432900526
Total Pages : 56 pages
Book Rating : 4.9/5 (5 download)

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Book Synopsis Elements and Compounds by : Chris Oxlade

Download or read book Elements and Compounds written by Chris Oxlade and published by Heinemann-Raintree Library. This book was released on 2007 with total page 56 pages. Available in PDF, EPUB and Kindle. Book excerpt: What is the difference between a compound and a mixture? How do we know what atoms and molecules look like? Who first organized into the periodic table? This title explores how atoms and molecules combine to form elements and compounds , why they are given the names that they have, and how they are used in our everyday lives. You will also find several experiments that can be done at home.