N-heterocyclic Carbenes Coated Nanocrystals and Supracrystals

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Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (12 download)

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Book Synopsis N-heterocyclic Carbenes Coated Nanocrystals and Supracrystals by : Xiang Ling

Download or read book N-heterocyclic Carbenes Coated Nanocrystals and Supracrystals written by Xiang Ling and published by . This book was released on 2015 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Les nanomatériaux ont beaucoup captivé l'attention pour leur propriétés uniques, fortement associées à leurs dimensions nanoscopiques. En particulier, les nanoparticules (NP) à base de métaux nobles (Au, Ag) présentent des propriétés mécaniques, électroniques, optiques et magnétiques particulières intéressantes pour le développement d'applications dans de nombreux domaines à fort impact sociétal. En raison de leur stabilité élevée par rapport aux autres nano- particules métalliques, les nanoparticules d'or ont été abondamment explorées pour les nanotechnologies. Ces dernières décennies, les NHC ont émergé en tant que classe essentielle de ligands neutres en chimie organométallique. Les NHC sont caractérisés par leur flexibilité synthétique élevée, leur géométrie spécifique, et une liaison métal-Ccarbène très forte dans les complexes métalliques. Toutes ces propriétés ont été largement étudiées et exploitées pour les applications en catalyse homogène et pour le développement de complexes biologiquement actifs. Par comparaison, l'utilisation des NHC dans les matériaux reste largement peu explorée. Dans ce travail, le potentiel de ligands NHC dans le domaine des nanomatériaux, comme des agents de revêtement pour le produit nanocristaux de synthèse de l'or (et l'argent), la produit de stabilisation et de l'auto-assemblage dans supracrystals ont été explorés. Tout d'abord, des complexes d'argent et d'or-NHC qui sont bien définies avec différents ligands qui sont connus comme le NHC, sont étudiés pour leur pertinence afin de générer des astable nanocristaux (NCs) dans des conditions réductrices avec un bon contrôle de la taille des nanocristaux. Nous démontrons que le Au et le Ag NCs peuvent tous être formés par la réduction des complexes métal-NHC avec les amine-boranes. L'efficacité du procédé, la taille moyenne et la taille de la répartition des nanocristaux dépendent fortement de la structure du ligand NHC. Cependant, nous démontrons dans cette partie que les différentes voies sont impliqués à générer des nanocristaux par Au ou Ag précurseurs, comme une spécifique réaction observée entre Ag-NHC et thiols conduisant à la formation de thiolates argent alors que le Au-NHC correspondant reste inchangé...

Metal Nano 3D Superlattices

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Publisher : John Wiley & Sons
ISBN 13 : 3527344802
Total Pages : 452 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Metal Nano 3D Superlattices by : Marie-Paule Pileni

Download or read book Metal Nano 3D Superlattices written by Marie-Paule Pileni and published by John Wiley & Sons. This book was released on 2023-01-10 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Nano 3D Superlattices Unique view on producing metal nano 3D superlattices by differing their morphologies, crystalline structures, chemical, and physical properties After presenting an overview on the various factors involved in producing metal 3D superlattices called supracrystals by differing their morphologies, crystalline structures, chemical, physical, and intrinsic properties, Metal Nano 3D Superlattices: Synthesis, Properties, and Applications reveals the existence of new materials with unexpected properties. Readers will gain insight into the various approaches on the production and on the specific properties of nanocrystals self-assembled in 3D superlattices also called colloidal crystals, supra or super crystals. These properties open up new avenues of research and potentially aiding in major progress. Overall, the work reviews the progress of and gives perspective on assembled nanocrystals, with a concentrated focus on self-assemblies of metal nanocrystals. Sample topics covered by the highly qualified and internationally awarded author include: Syntheses of nanocrystals with low size distribution. The wide variety of self-assembled nanocrystals in 3D superlattices strongly depends on an impressive number of parameters. The intrinsic chemical and physical properties of 3D superlattices of nanocrystals opens the way to the discovery of unexpected properties. This concerns growth processes, coherent breathing of in 3D superlattices, electron transport through thick assemblies, etc. A strong analogy between atomic crystals and 3D superlattices of nanocrystals emerge: incompressible nanocrystals and coating agents act as mechanical springs holding together the nanocrystals and replace respectively, in atomic crystals, atoms and atomic bonds. The intrinsic chemical and physical properties of nanocrystals and their assemblies depend on their crystalline structures called nanocrystallinity. Collective properties due to dipolar interactions between nanocrystals are pointed out. Water soluble suprastructures act as efficient universal nanoheaters. In addition, reconstruction near the cytoplasmic membrane in tumor cells of nanocrystal self-assemblies takes place opening various biomedical applications. The physical (optical, magnetic, electronic, vibrational) properties of isolated nanocrystals remain present in addition to the intrinsic and collective properties. This allows to benefit from the unique properties of nanocrystals while avoiding their potential size-related risks in future applications. Metal Nano 3D Superlattices offers a deep dive into their synthesis, chemical and physical properties, and applications and is an essential resource for inorganic chemists, materials scientists, physical chemists, surface chemists, and medicinal chemists conducting research related to or involved in the practical application of the topics covered within.

N-heterocyclic Carbenes

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Publisher : Royal Society of Chemistry
ISBN 13 : 1849730423
Total Pages : 469 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis N-heterocyclic Carbenes by : Silvia Díez-González

Download or read book N-heterocyclic Carbenes written by Silvia Díez-González and published by Royal Society of Chemistry. This book was released on 2011 with total page 469 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the last fifteen years, N-heterocyclic carbenes (NHCs) have mostly been used as ancillary ligands for the preparation of transition metal-based catalysts. Compared to phosphorus-containing ligands, NHCs tend to bind more strongly to metal centres, avoiding the necessity for the use of excess ligand in catalytic reactions. The corresponding complexes are often less sensitive to air and moisture, and have proven remarkably resistant to oxidation. Recent developments in catalysis applications have been facilitated by the availability of carbenes stable enough to be bottled, particularly for their use as organocatalysts. This book shows how N-heterocyclic carbenes can be useful in various fields of chemistry and not merely laboratory curiosities or simple phosphine mimics. NHCs are best known for their contribution to ruthenium and palladium-catalysed reactions but the scope of this book is much broader. The synthesis of NHC ligands and their corresponding metal complexes are covered in depth. Moreover, the biological activity of NHC-containing complexes, as well as an overview of their theoretical aspects are included. Such metal species are further examined, not only in terms of their catalytic applications, but also of their stereoelectronic parameters and reactivity/stability. Finally, special attention is given to the hot topic of organocatalysis. The book will be of interest to postgraduates, academic researchers and those working in industry.

Molecular Technology, Volume 4

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Publisher : John Wiley & Sons
ISBN 13 : 3527345884
Total Pages : 428 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Molecular Technology, Volume 4 by : Hisashi Yamamoto

Download or read book Molecular Technology, Volume 4 written by Hisashi Yamamoto and published by John Wiley & Sons. This book was released on 2019-08-05 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt: Edited by foremost leaders in chemical research together with a number of distinguished international authors, this fourth volume summarizes the most important and promising recent developments in synthesis, polymer chemistry and supramolecular chemistry. Interdisciplinary and application-oriented, this ready reference focuses on innovative methods, covering new developments in catalysis, synthesis, polymers and more.

The Organometallic Chemistry of N-heterocyclic Carbenes

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Publisher : John Wiley & Sons
ISBN 13 : 1118698800
Total Pages : 352 pages
Book Rating : 4.1/5 (186 download)

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Book Synopsis The Organometallic Chemistry of N-heterocyclic Carbenes by : Han Vinh Huynh

Download or read book The Organometallic Chemistry of N-heterocyclic Carbenes written by Han Vinh Huynh and published by John Wiley & Sons. This book was released on 2017-01-23 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Organometallic Chemistry of N-heterocyclic Carbenes describes various aspects of N-heterocyclic Carbenes (NHCs) and their transition metal complexes at an entry level suitable for advanced undergraduate students and above. The book starts with a historical overview on the quest for carbenes and their complexes. Subsequently, unique properties, reactivities and nomenclature of the four classical NHCs derived from imidazoline, imidazole, benzimidazole and 1,2,4-triazole are elaborated. General and historically relevant synthetic aspects for NHCs, their precursors and complexes are then explained. The book continues with coverage on the preparation and characteristics of selected NHC complexes containing the most common metals in this area, i.e. Ni, Pd, Pt, Ag, Cu, Au, Ru, Rh and Ir. The book concludes with an overview and outlook on the development of various non-classical NHCs beyond the four classical types. Topics covered include: Stabilization, dimerization and decomposition of NHCs Stereoelectronic properties of NHCs and their evaluation Diversity of NHCs Isomers of NHC complexes and their identification NMR spectroscopic signatures of NHC complexes normal, abnormal and mesoionic NHCs The Organometallic Chemistry of N-heterocyclic Carbenes is an essential resource for all students and researchers interested in this increasingly important and popular field of research.

Ionic Liquids (ILs) in Organometallic Catalysis

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Publisher : Springer
ISBN 13 : 3662478579
Total Pages : 354 pages
Book Rating : 4.6/5 (624 download)

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Book Synopsis Ionic Liquids (ILs) in Organometallic Catalysis by : Jairton Dupont

Download or read book Ionic Liquids (ILs) in Organometallic Catalysis written by Jairton Dupont and published by Springer. This book was released on 2015-07-13 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal

N-Heterocyclic Carbenes in Organocatalysis

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Publisher : John Wiley & Sons
ISBN 13 : 3527343105
Total Pages : 436 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis N-Heterocyclic Carbenes in Organocatalysis by : Akkattu T. Biju

Download or read book N-Heterocyclic Carbenes in Organocatalysis written by Akkattu T. Biju and published by John Wiley & Sons. This book was released on 2019-05-06 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt: Summarizing the emerging field of N-heterocyclic carbenes used in organocatalysis, this is an excellent overview of the synthesis and applications of NHCs focusing on carbon-carbon and carbon-heteroatom bond formation. Alongside comprehensive coverage of the synthesis, characteristics and applications, this handbook and ready reference also includes chapters on NHCs for polymerization reactions and natural product synthesis.

N-Heterocyclic Carbenes in Synthesis

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Publisher : Wiley-VCH
ISBN 13 : 3527609407
Total Pages : 319 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis N-Heterocyclic Carbenes in Synthesis by : Steven P. Nolan

Download or read book N-Heterocyclic Carbenes in Synthesis written by Steven P. Nolan and published by Wiley-VCH. This book was released on 2006-12-13 with total page 319 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first handbook to focus solely on the application of N-heterocyclic carbenes in synthesis covers metathesis, organocatalysis, oxidation and asymmetric reactions, along with experimental procedures. Written by leading international experts this is a valuable and practical source for every organic chemist.

Atomically Precise Metal Nanoclusters

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Publisher : Elsevier
ISBN 13 : 0323908802
Total Pages : 666 pages
Book Rating : 4.3/5 (239 download)

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Book Synopsis Atomically Precise Metal Nanoclusters by : Thalappil Pradeep

Download or read book Atomically Precise Metal Nanoclusters written by Thalappil Pradeep and published by Elsevier. This book was released on 2022-10-08 with total page 666 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atomically Precise Metal Nanoclusters discusses the host of exciting properties that can be better harnessed with a solid understanding of their different structures and subsequent properties at the molecular level. The book delves into the foundational chemistry of numerous key atomically precise clusters and provides guidance on key approaches employed to examine them. Beginning with an introduction to the properties and fundamental nano-chemistry of atomically precise metal nanoclusters, the book then explores key approaches for their synthesis, examination and modification, including chromatography, mass spectrometry, single crystal diffraction, electron microscopy and computational approaches. A final section covers specific nanoclusters and cluster systems. User will find the important knowledge of an experienced team of contributors who provide a detailed guide to understanding, investigating and utilizing these useful structures that is ideal for anyone working in related fields. Presents a comprehensive guide that combines key knowledge, approaches and other types of metal nanocluster Supports an understanding of important interactions and approaches using clear figures Highlights future needs and prospects in the field

Building and Probing Small for Mechanics

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Publisher : Springer Nature
ISBN 13 : 303056777X
Total Pages : 235 pages
Book Rating : 4.0/5 (35 download)

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Book Synopsis Building and Probing Small for Mechanics by : Christian Joachim

Download or read book Building and Probing Small for Mechanics written by Christian Joachim and published by Springer Nature. This book was released on 2020-09-11 with total page 235 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents mechanics miniaturization trends explored step by step, starting with the example of the miniaturization of a mechanical calculator. The ultra-miniaturization of mechanical machinery is now approaching the atomic scale. In this book, molecule-gears, trains of molecule-gears, and molecule motors are studied -one molecule at a time- on a solid surface, using scanning probe manipulation protocols and in solution as demonstrated in the European project "MEMO". All scales of mechanical machinery are presented using the various lithography techniques currently available, from the submillimeter to the nanoscale. Researchers and nanomechanical engineers will find new inspirations for the construction of minute mechanical devices which can be used in diverse hostile environments, for example under radiation constraints, on the surface membrane of a living cell or immersed in liquid. The book is presented in a format accessible for university students, in particular for those at the Master and PhD levels.

Gold Nanostars

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Publisher : Springer
ISBN 13 : 3319207687
Total Pages : 93 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis Gold Nanostars by : Giuseppe Chirico

Download or read book Gold Nanostars written by Giuseppe Chirico and published by Springer. This book was released on 2015-08-03 with total page 93 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Brief focuses on the synthesis, functionalization techniques, optical properties and biomedical application of gold nanostars (GNS). Various facilities of gold nanostars synthesis as well as functionalization of GNS with PEG, organic dyes, bioactive compounds are discussed. The authors discuss physical origin of the Localized Surface Plasmon Resonances and the way the nano-environment affects them. The implication of the LSPR of gold nanostars surface enhanced Raman scattering is also discussed. The emphasis has been done on the application of GNS for current and emerge needs of medicine, biology and pharmacy. Moreover, properties of gold nanostars as contrast agents for in vivo imaging and interaction of GNS with cells are also discussed in this Brief.

Cooperative Catalysis

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Publisher : John Wiley & Sons
ISBN 13 : 3527336893
Total Pages : 452 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Cooperative Catalysis by : René Peters

Download or read book Cooperative Catalysis written by René Peters and published by John Wiley & Sons. This book was released on 2015-04-27 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by experts in the field, this is a much-needed overview of the rapidly emerging field of cooperative catalysis. The authors focus on the design and development of novel high-performance catalysts for applications in organic synthesis (particularly asymmetric synthesis), covering a broad range of topics, from the latest progress in Lewis acid / Br?nsted base catalysis to e.g. metal-assisted organo catalysis, cooperative metal/enzyme catalysis, and cooperative catalysis in polymerization reactions and on solid surfaces. The chapters are classified according to the type of cooperating activating groups, and describe in detail the different strategies of cooperative activation, highlighting their respective advantages and pitfalls. As a result, readers will learn about the different concepts of cooperative catalysis, their corresponding modes of operation and their applications, thus helping to find a solution to a specific synthetic catalysis problem.

Metal Nanocrystals

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Publisher : American Chemical Society
ISBN 13 : 0841299013
Total Pages : 164 pages
Book Rating : 4.8/5 (412 download)

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Book Synopsis Metal Nanocrystals by : Kallum M. Koczkur

Download or read book Metal Nanocrystals written by Kallum M. Koczkur and published by American Chemical Society. This book was released on 2020-07-31 with total page 164 pages. Available in PDF, EPUB and Kindle. Book excerpt: Our society depends heavily on metals. They are ubiquitous construction materials, critical interconnects in integrated circuits, common coinage materials, and more. Excitingly, new uses for metals are emerging with the advent of nanoscience, as metal crystals with nanoscale dimensions can display new and tunable properties. The optical and photothermal properties of metal nanocrystals have led to cancer diagnosis and treatment platforms now in clinical trials, while, at the same time, the ability to tune the surface features of metal nanocrystals is giving rise to designer catalysts that enable more sustainable use of precious resources. These are just two examples of how metal nanocrystals are addressing important social needs.

N-Heterocyclic Carbenes in Transition Metal Catalysis

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Publisher : Springer
ISBN 13 : 3540369309
Total Pages : 240 pages
Book Rating : 4.5/5 (43 download)

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Book Synopsis N-Heterocyclic Carbenes in Transition Metal Catalysis by : Frank Glorius

Download or read book N-Heterocyclic Carbenes in Transition Metal Catalysis written by Frank Glorius and published by Springer. This book was released on 2007-02-05 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book leading experts have surveyed major areas of application of NHC metal complexes in catalysis. The authors have placed a special focus on nickel- and palladium-catalyzed reactions, on applications in metathesis reactions, on oxidation reactions and on the use of chiral NHC-based catalysts. This compilation is rounded out by an introductory chapter and a chapter dealing with synthetic routes to NHC metal complexes.

Gold Catalysis: An Homogeneous Approach

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Publisher : World Scientific
ISBN 13 : 1783265558
Total Pages : 564 pages
Book Rating : 4.7/5 (832 download)

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Book Synopsis Gold Catalysis: An Homogeneous Approach by : Veronique Michelet

Download or read book Gold Catalysis: An Homogeneous Approach written by Veronique Michelet and published by World Scientific. This book was released on 2014-06-20 with total page 564 pages. Available in PDF, EPUB and Kindle. Book excerpt: Research on designing new catalytic systems has been one of the most important fields in modern organic chemistry. One reason for this is the predominant contribution of catalysis to the concepts of atom economy and green chemistry in the 21st century. Gold, considered catalytically inactive for a long time, is now a fascinating partner of modern chemistry, as scientists such as Bond, Teles, Haruta, Hutchings, Ito and Hayashi opened new perspectives for the whole synthetic chemist community. This book presents the major advances in homogeneous catalysis, emphasizing the methodologies that create carbon-carbon and carbon-heteroatom bonds, the applications that create diversity and synthesize natural products, and the recent advances and challenges in asymmetric catalysis and computational research.It provides readers with in-depth information about homogeneous gold-catalyzed reactions and presents several explanations for the scientific design of a catalyst. Readers will be able to understand the entire gold area and find solutions to problems in catalysis.Gold Catalysis — An Homogeneous Approach is part of the Catalytic Science Series and features prominent authors who are experts in their respective fields.

Nanocrystals Forming Mesoscopic Structures

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Publisher : Wiley-VCH
ISBN 13 : 9783527311705
Total Pages : 346 pages
Book Rating : 4.3/5 (117 download)

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Book Synopsis Nanocrystals Forming Mesoscopic Structures by : Marie-Paule Pileni

Download or read book Nanocrystals Forming Mesoscopic Structures written by Marie-Paule Pileni and published by Wiley-VCH. This book was released on 2005-12-02 with total page 346 pages. Available in PDF, EPUB and Kindle. Book excerpt: Focusing on both academic questions and applications of self-assembly of this extremely important class of compounds, this book discusses not only the self-organization of inorganic and magnetic nanocrystals, but also their collective optical and magnetic properties, as well as the in-situ fabrication of metal nanoparticles in solid matrices. Professor Marie-Paule Pileni, a distinguished leader in this field, is joined by a select group of expert authors to provide 14 chapters covering important aspects of self-assembled nanomaterials. The result is invaluable reading for inorganic and physical chemists, colloid chemists, polymer chemists, materials scientists, physicists, and chemical engineers working with and/or developing nanoparticle systems.

Nanoparticles in Catalysis

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Publisher : John Wiley & Sons
ISBN 13 : 3527346074
Total Pages : 384 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Nanoparticles in Catalysis by : Karine Philippot

Download or read book Nanoparticles in Catalysis written by Karine Philippot and published by John Wiley & Sons. This book was released on 2021-06-28 with total page 384 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanoparticles in Catalysis Discover an essential overview of recent advances and trends in nanoparticle catalysis Catalysis in the presence of metal nanoparticles is an important and rapidly developing research field at the frontier of homogeneous and heterogeneous catalysis. In Nanoparticles in Catalysis, accomplished chemists and authors Karine Philippot and Alain Roucoux deliver a comprehensive guide to the key aspects of nanoparticle catalysis, ranging from synthesis, activation methodology, characterization, and theoretical modeling, to application in important catalytic reactions, like hydrogen production and biomass conversion. The book offers readers a review of modern and efficient tools for the synthesis of nanoparticles in solution or onto supports. It emphasizes the application of metal nanoparticles in important catalytic reactions and includes chapters on activation methodology and supported nanoclusters. Written by an international team of leading voices in the field, Nanoparticles in Catalysis is an indispensable resource for researchers and professionals in academia and industry alike. Readers will also benefit from the inclusion of: A thorough introduction to New Trends in the Design of Metal Nanoparticles and Derived Nanomaterials for Catalysis An exploration of Dynamic Catalysis and the Interface Between Molecular and Heterogeneous Catalysts A practical discussion of Metal Nanoparticles in Water: A Relevant Toolbox for Green Catalysis Organometallic Metal Nanoparticles for Catalysis A concise treatment of the opportunities and challenges of CO2 Hydrogenation to Oxygenated Chemicals Over Supported Nanoparticle Catalysts Perfect for catalytic, organic, inorganic, and physical chemists, Nanoparticles in Catalysis will also earn a place in the libraries of chemists working with organometallics and materials scientists seeking a one-stop resource with expert knowledge on the synthesis and characterization of nanoparticle catalysis.