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Modern Aspects Of Electrochemistry No 7
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Book Synopsis Modern Aspects of Electrochemistry No. 7 by : B. E. Conway
Download or read book Modern Aspects of Electrochemistry No. 7 written by B. E. Conway and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: Despite reductions in the level of research activity in most fields which, for reasons of economic decline, have taken place in the U.S. during the last year or two, world progress in the fundamental aspects has continued actively. An important aspect of such recent work has been the use of nonaqueous solvents in studies on the constitution of the double-layer and electrochemical reactions. Interpretation of the behavior of electrode interfaces in such solvents demands more knowledge of the solvation properties of ions in nonaqueous media. Chapter 1 by Pad ova on "Ionic Solvation in Nonaqueous and Mixed Solvents" gives an up to date review of the present state of knowledge in this field, together with tabulations of data that are likely to be of quantitative value in further investigations of both homogeneous and heterogeneous electrochemistry in such media. Electrochemical studies of cathodic processes in nonaqueous solvents have, in recent years, revealed the role of solvated electrons. These are of interest in new approaches to reductive electro-organic synthesis. Similarly, the generation of hydrated electrons in photo cathodic processes is of great interest. In Chapter 2, by Conway, the conditions under which solvated electrons can arise in electrode processes are critically examined and the electro-organic reactions that hwe been investigated are reviewed. The supposed electro generation of hydrated electrons in the water solvent and as inter mediates in cathodic hydrogen evolution is shown to be unlikely.
Book Synopsis Modern Aspects of Electrochemistry by : J. O'M Bockris
Download or read book Modern Aspects of Electrochemistry written by J. O'M Bockris and published by . This book was released on 1971 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Modern Aspects of Electrochemistry by : B. E. Conway
Download or read book Modern Aspects of Electrochemistry written by B. E. Conway and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 497 pages. Available in PDF, EPUB and Kindle. Book excerpt: As the subject of electrochemistry moves into the final quarter of the century, a number of developed areas can be assessed in depth while some new areas provide quantitatively and qualitatively novel data and results. The first chapter, by Kebarle, deals with an example of the latter type of field in which new information of the energetics and equilibria of reactions between ions and solvent molecules is studied in the gas phase and provides interesting basic information for treatments of ions in solution, i.e., ionic solvation. Chapter 2, by Hamann, discusses the behavior of electrolyte solutions under high pressures, a matter of intrinsic interest in relation to ion-solvent interaction and the structural aspects of the properties of ionic solutions, especially in water. This topic is also of current interest with regard to the physical chemistry of the marine environment, especially at great depths. In the article by Bloom and Snook (Chapter 3), models for treatments of molten salt systems are examined quantitatively in relation to the structure of molten ionic liquids and to the statistical mechanical approaches that can be meaningfully made to interpret their properties and electrochemical behavior.
Book Synopsis Modern Aspects of Electrochemistry by : 3Island Press
Download or read book Modern Aspects of Electrochemistry written by 3Island Press and published by . This book was released on 1972-02-01 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Modern Aspects of Electrochemistry 45 by : Ralph E. White
Download or read book Modern Aspects of Electrochemistry 45 written by Ralph E. White and published by Springer Science & Business Media. This book was released on 2009-08-12 with total page 351 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume maintains the series’ high standards, containing chapters covering topics such as the cathodic reduction of nitrate, and including discussion of product selectivity, current efficiency, and the thermodynamics and kinetics for the reactions studied.
Book Synopsis Modern Aspects of Electrochemistry by : John O M. Bockris
Download or read book Modern Aspects of Electrochemistry written by John O M. Bockris and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume contains five chapters covering areas of contemporary interest in the fields of electrolyte solutions, the state of solvent molecules at electrode surfaces, charged colloid interfaces, surface chemistry of oxide electrodes and electro chemistry, and bioelectrochemistry of charge transfer complexes. The first chapter, by Barthel, Wachter, and Gores, covers the topic of conductance of nonaqueous pro tic and aprotic electro lyte solutions. This field is not only of intrinsic interest in itself, illustrating the important departures of ion-transport behavior in organic solvents from that, more well known, in water, but the information and extensive new data presented in this chapter will be of interest to those working with nonaqueous alkali-metal batteries where the conductivity and ion-association behavior of electrolytes in various solvents other than water is of great importance. The second chapter is devoted to a very fundamental and ubiquitous aspect of electrochemistry of electrodes: the state of solvent molecules, adsorbed and oriented, at their surfaces. The role of solvent adsorption and orientation in double-layer proper ties, it will be recalled, remained poorly understood until the early 1960s. This chapter, by Trasatti, gives a thorough account of the present state of knowledge of solvent orientation at electrode interfaces and of the unsuspected (until recent years) role it plays in properties of the double layer and in determining the potential profile at charged metal surfaces in solution.
Book Synopsis MODERN ASPECTS OF ELECTROCHEMISTRY (Volume 7). by : JO'M BOCKRIS (ED.)
Download or read book MODERN ASPECTS OF ELECTROCHEMISTRY (Volume 7). written by JO'M BOCKRIS (ED.) and published by . This book was released on 1972 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Modern Aspects of Electrochemistry by : John O'M. Bockris
Download or read book Modern Aspects of Electrochemistry written by John O'M. Bockris and published by . This book was released on 1973 with total page 347 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Modern Aspects of Electrochemistry No. 6 by : J. O'M. Bockris
Download or read book Modern Aspects of Electrochemistry No. 6 written by J. O'M. Bockris and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 393 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the last decade, the evolution of electrochemistry away from concern with the physical chemistry of solutions to its more fruitful goal in the study of the widespread consequences of the transfer of electric charges across interphases has come to fruition. The turning of technology away from an onward rush, regardless, to progress which takes into account repercussions of techno logical activity on the environment, and the consequent need for a reduction and then termination of the injection of CO into 2 the atmosphere (greenhouse effect), together with a reckoning with air and water pollution in general, ensures a long-term need for advances in a basic knowledge of electrochemical systems, an increased technological use of which seems to arise from the environmental necessities. But a mighty change in attitude needs to spread among electro chemists (indeed, among all surface chemists) concerning the terms and level in which their field is discussed. The treatment of charge transfer reactions has often been made too vaguely, in terms, it seemed, of atom transfer, with the electron-transfer step, the essence of electrochemistry, an implied accompaniment to the transfer of ions across electrical double layers. The treatment has been in terms of classical mechanics, only tenable while inadequate questions were asked concerning the behavior of the electron in the interfacial transfer. No process demands a more exclusively quantal discussion than does electron transfer.
Book Synopsis Modern Aspects of Electrochemistry, Number 38 by : B. E. Conway
Download or read book Modern Aspects of Electrochemistry, Number 38 written by B. E. Conway and published by Springer Science & Business Media. This book was released on 2006-02-02 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume comprises six chapters on aspects of fundamental and applied electrochemical science that will be of interest both to researchers in the basic areas of the subject and to those involved in aspects of electrochemical technologies. Chapter 1 is the first part of a 2-part, major contribution by Joachim Maier on Solid State Electrochemistry: Thermodynamics and Kinetics of Charge Carriers in Solids. Part 2 will follow in volume 39 to be published in year 2005. This contribution reviews modern concepts of the equilibria involving charge carriers in solids in terms of concentrations of defects in solids and at grain-boundaries, including doping effects. Complementarily, kinetics of charge transfer and ion transfer are treated in some detail in relation to conductance, kinetics of surface processes and electrode-kinetics involving solid-state processes. This chapter will be of major interest to electrochemists and physicists in the semiconductor field and that involving ionic solids. In the second chapter, Appleby presents a detailed discussion and review in modern terms of a central aspect of electrochemistry: Electron Transfer Reactions With and Without Ion Transfer. Electron transfer is the most fundamental aspect of most processes at electrode interfaces and is also involved intimately with the homogeneous chemistry of redox reactions in solutions.
Book Synopsis Modern Electrochemistry by : John O'M. Bockris
Download or read book Modern Electrochemistry written by John O'M. Bockris and published by Springer Science & Business Media. This book was released on 1973-10-31 with total page 876 pages. Available in PDF, EPUB and Kindle. Book excerpt: 7 The Electrified Interface.- 7.1 Electrification of an Interface.- 7.1.1 The Electrode-Electrolyte Interface: The Basis of Electrodics.- 7.1.2 New Forces at the Boundary of an Electrolyte.- 7.1.3 The Interphase Region Has New Properties and New Structures.- 7.1.4 An Electrode Is Like a Giant Central Ion.- 7.1.5 The Consequences of Compromise Arrangements: The Electrolyte Side of the Boundary Acquires a Charge.- 7.1.6 Both Sides of the Interface Become Electrified: The So-Called "Electrical Double Layer"--7.1.7 Double Layers Are Characteristic of All Phase Boundaries.- 7.1.8 A Look into an El.
Book Synopsis Modern Aspects of Electrochemistry by : John O M. Bockris
Download or read book Modern Aspects of Electrochemistry written by John O M. Bockris and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 373 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume contains five chapters covering four topics of current research interest: splitting of water, lithium batteries, intercalation, and fundamental aspects of electrode processes. Two chapters are devoted to splitting of water. The first chapter, by Gutmann and Murphy, presents a comprehensive review of the classical methods of splitting water by electrolysis and also presents some novel techniques for splitting water. Chapter 2, by Gratzel, surveys the current research being done on water splitting using visible light. Two chapters are included that deal with the timely topics of lithium batteries and intercalation. The first, Chapter 3 by Marincic, presents a practical guide to the recent development of lithium batteries, while the second, Chapter 4 by McKinnon and Haering, presents and discusses various theoretical approaches to inter calation. The last chapter in the book, Chapter 5 by Khan, presents a survey of many of the fundamental concepts and misconceptions of electrode kinetics as applied to semiconductors in particular.
Book Synopsis Modern Aspects of Electrochemistry by : Brian E. Conway
Download or read book Modern Aspects of Electrochemistry written by Brian E. Conway and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 505 pages. Available in PDF, EPUB and Kindle. Book excerpt: It gives us pleasure in writing the Preface to this volume, in which we tried to bring together a number of stimulating and interesting people discussing physical electrochemistry. The first chapter, by Ashok Vijh, gives a remarkable account of electrochemistry as looked at from a physicist's point of view. Among the revelations of the chapter is that in a recent survey of leading areas in Science, two out of fifteen areas chosen were electrochemical and these two were the only chemical subjects chosen. In Mikhail Vorotyntsev's chapter, one finds a very modern study of the double layer, but tenuously connected with the simpler studies made in the safe harbor of mercury. In the pioneering chapter by Pons et al., one is looking at a cutting edge of electrochemistry at this time-the use of IR spectros copy in modes which allow the first practical determinations of the spectra of adsorbed species at the interface-an area pioneered by Pons himself. In Chapter 4, we have reached photoelectrochemistry once more, but now Tributsch speaks about what has rapidly become the major area of that topic, photoelectrocatalysis. Close to this chapter, and indeed intellectually connected with it, is that by Schmickler and Schultze about electron transfer reac tions at oxide-covered metal electrodes in which theories which are still relatively dubious for metal-solution surfaces are applied to complex systems involving oxides.
Book Synopsis Modern Aspects of Electrochemistry by : J. O'M. Bockris
Download or read book Modern Aspects of Electrochemistry written by J. O'M. Bockris and published by Springer. This book was released on 2012-11-25 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the last decade, the evolution of electrochemistry away from concern with the physical chemistry of solutions to its more fruitful goal in the study of the widespread consequences of the transfer of electric charges across interphases has come to fruition. The turning of technology away from an onward rush, regardless, to progress which takes into account repercussions of techno logical activity on the environment, and the consequent need for a reduction and then termination of the injection of CO into 2 the atmosphere (greenhouse effect), together with a reckoning with air and water pollution in general, ensures a long-term need for advances in a basic knowledge of electrochemical systems, an increased technological use of which seems to arise from the environmental necessities. But a mighty change in attitude needs to spread among electro chemists (indeed, among all surface chemists) concerning the terms and level in which their field is discussed. The treatment of charge transfer reactions has often been made too vaguely, in terms, it seemed, of atom transfer, with the electron-transfer step, the essence of electrochemistry, an implied accompaniment to the transfer of ions across electrical double layers. The treatment has been in terms of classical mechanics, only tenable while inadequate questions were asked concerning the behavior of the electron in the interfacial transfer. No process demands a more exclusively quantal discussion than does electron transfer.
Book Synopsis Modern Aspects of Electrochemistry by : J. O'M Bockris
Download or read book Modern Aspects of Electrochemistry written by J. O'M Bockris and published by . This book was released on 2014-09-01 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Modern Aspects of Electrochemistry, Band 7 by : J.OeM. Bockris
Download or read book Modern Aspects of Electrochemistry, Band 7 written by J.OeM. Bockris and published by . This book was released on 1972 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Modern Aspects of Electrochemistry 39 by : C. G. Vayenas
Download or read book Modern Aspects of Electrochemistry 39 written by C. G. Vayenas and published by Springer Science & Business Media. This book was released on 2006-05-05 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Volume will cover a broad range of topics in Electrochemistry in an authoritative manner by internationally renowned specialists. The topics include an overview of theoretical advances in quantitative treatment of solute-solvent interactions and an analysis of the formation mechanisms of porous silicon. Recent advances on the use of electrochemistry in medicine will be surveyed in a chapter by Dr. A. Vijh.
